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81. 发明授权

US4596594A Silicon-containing phenoxypropionic acid derivatives and herbicidal use 失效
标题翻译：含硅苯氧基丙酸衍生物和除草用途
公开(公告)号：US4596594A
公开(公告)日：1986-06-24
申请号：US774115
申请日：1985-09-09
申请人： Heinz Forster , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
发明人： Heinz Forster , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N55/00 , A01N55/10 , C07D277/68 , C07F7/08 , C07F7/10
CPC分类号： C07D277/68 , A01N55/00 , C07F7/0812 , C07F7/0818
摘要： Herbicidally active novel phenoxypropionic acid derivatives of the formula ##STR1## in which X represents oxygen or sulphur,Y represents oxygen, sulphur or the grouping of the formula NR,R represents hydrogen or alkyl with 1 to 6 carbon atoms,Z represents nitrogen or the CH group,R.sup.1 represents hydrogen or halogen andR.sup.2 represents alkyl with 1 to 6 carbon atoms.
摘要翻译：式“IMAGE”的除草活性新型苯氧基丙酸衍生物，其中X表示氧或硫，Y表示氧，硫或式NR的基团，R表示氢或具有1至6个碳原子的烷基，Z表示氮或 CH基，R 1表示氢或卤素，R 2表示具有1至6个碳原子的烷基。

82. 发明授权

US4518416A Certain trimethyl silyl-lower-alkyl esters of pyridyloxy-phenoxy-lower alkanoic acids, compositions containing same and herbicidal method of use 失效
标题翻译：吡啶氧基 - 苯氧基 - 低级链烷酸的某些三甲基甲硅烷基 - 低级烷基酯，含有该组合物的组合物和除草方法
公开(公告)号：US4518416A
公开(公告)日：1985-05-21
申请号：US495883
申请日：1983-05-18
申请人： Heinz Forster , Erich Klauke , Uwe Priesnitz , Hans-Jochem Riebel , Ludwig Eue , Robert R. Schmidt
发明人： Heinz Forster , Erich Klauke , Uwe Priesnitz , Hans-Jochem Riebel , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/40 , A01N43/50 , A01N43/56 , A01N43/653 , A01N55/00 , A01N57/16 , C07D213/64 , C07D213/643 , C07D405/12 , C07F7/08 , C07F9/58
CPC分类号： C07D213/643 , A01N43/40 , A01N43/50 , A01N43/56 , A01N43/653 , A01N55/00 , A01N57/16 , C07D405/12 , C07F7/0812 , C07F9/582
摘要： Novel substituted pyridyl-phenyl ethers of the formula ##STR1## in which X represents trifluoromethyl or chlorine,Y represents hydrogen or chlorine,R.sup.1 represents hydrogen or methyl andR.sup.2 represents formyl or the radicals of the formulae ##STR2## in which R.sup.3 represents alkyl with 1 to 4 carbon atoms, or the two radicals R.sup.3 together represent an alkylene chain with 2 or 3 carbon atoms,R.sup.4, R.sup.5, R.sup.6 and R.sup.7 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms,m represents 1 or 2,n represents 0 or 1 andZ represents trimethylsilyl, optionally substituted azolyl which is bonded via nitrogen or the radicals of the formulae ##STR3## in which R.sup.8 represents alkyl with 1 to 4 carbon atoms, or the two radicals R.sup.8 together represent an alkylene chain with 2 or 3 carbon atoms,R.sup.9 represents alkyl with 1 to 4 carbon atoms,X.sup.1 represents oxygen or sulphur andR.sup.10 and R.sup.11 independently of one another represent hydrogen or alkyl with 1 to 4 carbon atoms,and their use as herbicides.
摘要翻译：新颖的式（I）的取代的吡啶基 - 苯基醚，其中X表示三氟甲基或氯，Y表示氢或氯，R1表示氢或甲基，R2表示甲酰基或式“IMAGE”的基团，其中R3 表示具有1至4个碳原子的烷基，或两个基团R 3一起表示具有2或3个碳原子的亚烷基链，R 4，R 5，R 6和R 7彼此独立地表示氢或具有1至4个碳原子的烷基，m表示 1或2，n表示0或1，Z表示三甲基甲硅烷基，任选取代的通过氮键合的唑基或其中R 8表示具有1至4个碳原子的烷基的式“IMAGE”的基团，或两个基团R8一起表示具有2或3个碳原子的亚烷基链，R 9表示具有1至4个碳原子的烷基，X 1表示氧或硫，R 10和R 11彼此独立地表示氢或具有1至4个碳原子的烷基，并且它们用作除草剂。

83. 发明授权

US4187100A 4,5-Dichloro-imidazole-1-carboxylic acid aryl esters and their use as herbicides 失效
标题翻译： 4,5-二氯 - 咪唑-1-羧酸芳基酯及其作为除草剂的用途
公开(公告)号：US4187100A
公开(公告)日：1980-02-05
申请号：US948185
申请日：1978-10-02
申请人： Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
发明人： Klaus Sasse , Gunther Beck , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N47/22 , C07D233/68 , C07D233/90 , C07D487/14 , A01N9/22
CPC分类号： C07D487/14 , A01N47/22 , C07D233/68 , C07D233/90
摘要： A 4,5-dichloro-imidazole-1-carboxylic acid aryl ester of the formula ##STR1## in which X represents trifluoromethyl, cyano or a group ##STR2## in which R.sup.1 represents a saturated or unsaturated aliphatic radical, which can be carrying one or more substituents selected from halogen, alkoxy with 1 to 6 carbon atoms and alkylmercapto with 1 to 6 carbon atoms, R.sup.2 represents hydrogen, alkyl with 1 to 8 carbon atoms, alkenyl with up to 8 carbon atoms or the formyl group, R.sup.3 represents alkyl with 1 to 8 carbon atoms or alkenyl or alkynyl each with up to 8 carbon atoms, it being possible for each of these alkyl, alkenyl and alkynyl radicals to carry one or more substituents selected from alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms, phenyl (which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, trifluoromethyl and alkoxy with 1 to 4 carbon atoms), furyl or thienyl, or represents cycloalkyl with 5 to 7 carbon atoms in the ring which is optionally substituted by alkyl with 1 to 6 carbon atoms, or represents phenyl which may optionally carry one or more substituents selected from halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylmercapto with 1 to 4 carbon atoms and trifluoromethyl, or R.sup.2 and R.sup.3 conjointly with the adjoining nitrogen atom form an optionally substituted 5-membered to 7-membered heterocyclic radical in which 1 to 3 ring members may be selected from oxygen, sulfur and nitrogen, Y represents halogen, alkyl with 1 to 6 carbon atoms, trifluoromethyl, alkoxy with 1 to 6 carbon atoms, nitro, cyano or a ##STR3## group, in which R.sup.4 represents alkyl with 1 to 6 carbon atoms and n represents 0, 1, 2, 3, 4 or 5 which possesses plant protection properties especially herbicidal and plant growth regulant properties.
摘要翻译：其中X表示三氟甲基，氰基或其中R 1表示饱和或不饱和脂肪族基团的基团的4,5-二氯 - 咪唑-1-羧酸芳基酯，其中X表示三氟甲基，氰基或基团，携带一个或多个选自卤素，具有1至6个碳原子的烷氧基和1至6个碳原子的烷基巯基的取代基，R 2表示氢，具有1至8个碳原子的烷基，具有至多8个碳原子的烯基或甲酰基， R3表示具有1至8个碳原子的烷基或各自具有至多8个碳原子的烯基或炔基，这些烷基，烯基和炔基中的每一个可以携带一个或多个选自具有1至4个碳原子的烷氧基的取代基，具有1至4个碳原子的烷基巯基，苯基（其可任选地携带一个或多个选自卤素，具有1至4个碳原子的烷基，三氟甲基和具有1至4个碳原子的烷氧基）的取代基，呋喃基或噻吩基，或代表具有5个至7个碳原子在任选被具有1至6个碳原子的烷基取代的环中，或表示可任选地携带一个或多个选自卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基，具有1个碳原子的烷基巯基，至4个碳原子和三氟甲基，或R2和R3与相邻的氮原子结合形成任选取代的5元至7元杂环基，其中1至3个环成员可以选自氧，硫和氮，Y代表卤素，具有1至6个碳原子的烷基，三氟甲基，具有1至6个碳原子的烷氧基，硝基，氰基或者IMAGE基团，其中R 4表示具有1至6个碳原子的烷基，n表示0,1,2,3 ，4或5，其具有植物保护性，特别是除草和植物生长调节性质。

84. 发明授权

US4179277A 4,5-Dichloroimidazole-2-carboxylic acid derivatives 失效
标题翻译： 4,5-二氯咪唑-2-羧酸衍生物
公开(公告)号：US4179277A
公开(公告)日：1979-12-18
申请号：US770260
申请日：1977-02-18
申请人： Gunther Beck , Klaus Sasse , Helmut Heitzer , Ludwig Eue , Robert R. Schmidt , Hans Scheinpflug , Ingeborg Hammann , Wilhelm Brandes
发明人： Gunther Beck , Klaus Sasse , Helmut Heitzer , Ludwig Eue , Robert R. Schmidt , Hans Scheinpflug , Ingeborg Hammann , Wilhelm Brandes
IPC分类号： A01N43/50 , A01N43/90 , C07D233/68 , C07D233/90 , C07D401/14 , C07D403/04 , C07D405/12 , C07D413/04 , C07D471/14 , C07D487/04 , C07D487/14 , A01N9/22 , C07D233/66
CPC分类号： C07D471/14 , C07D233/68 , C07D233/90 , C07D487/04 , C07D487/14
摘要： 4,5-Dichloroimidazole-2-carboxylic acid derivatives of the formula ##STR1## in which the group ##STR2## represents a carbon atom which has three bonds to hetero-atoms, and their salts with bases,possess insecticidal, acaricidal, fungicidal, nematicidal and herbicidal properties.
摘要翻译：式（I）的4,5-二氯咪唑-2-羧酸衍生物，其中基团“IMAGE”表示与杂原子具有三个键的碳原子及其与碱的盐具有杀虫，杀螨，杀真菌，杀线虫和除草性质。

85. 发明授权

US4154597A 3-(1,3,4-Thiadiazol-2-yl)-5-acyloxy(carbamoyloxy)-hydantoin compounds and herbicidal compositions 失效
标题翻译： 3-（1,3,4-噻二唑-2-基）-5-酰氧基（氨基甲酰氧基） - 乙内酰脲化合物和除草组合物
公开(公告)号：US4154597A
公开(公告)日：1979-05-15
申请号：US804026
申请日：1977-06-06
申请人： Carl Metzger , Ludwig Eue , Robert R. Schmidt
发明人： Carl Metzger , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/824 , C07D417/04 , A01N9/12
CPC分类号： C07D417/04
摘要： 3-(1,3,4-THIADIAZOL-2-YL)-5-ACYLOXY(CARBAMOYLOXY)HYDANTOIN COMPOUNDS OF THE FORMULA: ##STR1## in which R is alkyl, haloalkyl, alkylmercapto or alkylsulfonyl,R.sup.1 is alkyl, andR.sup.2 is alkylcarbonyl, alkoxycarbonyl, alkylcarbamoyl or optionally substituted arylcarbonyl;Are remarkably active as herbicides and are particularly useful as selective herbicides in cotton cultivations or in cereal crops, including corn.
摘要翻译：式（I）其中R是烷基，卤代烷基，烷基巯基或烷基磺酰基，R 1是烷基，（C 1 -C 6）烷氧基羰基，并且R 2是烷基羰基，烷氧基羰基，烷基氨基甲酰基或任选取代的芳基羰基; 作为除草剂是可重复使用的，特别适用于选择性除草剂在棉花生产或谷物作物中，包括玉米。

86. 发明授权

US4073636A Azolylamidine compounds and herbicidal compositions 失效
标题翻译：唑基脒化合物和除草组合物
公开(公告)号：US4073636A
公开(公告)日：1978-02-14
申请号：US607986
申请日：1975-08-26
申请人： Erik Regel , Ludwig Eue , Robert R. Schmidt
发明人： Erik Regel , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D207/34 , C07D231/12 , C07D231/56 , C07D233/68 , C07D233/92 , C07D249/04 , C07D249/08 , C07D249/10 , A01N9/22
CPC分类号： C07D249/08 , C07D207/34 , C07D231/12 , C07D231/56 , C07D233/68 , C07D233/92 , C07D249/04
摘要： New azolylamidines of the formula ##STR1## WHEREIN N IS AN INTEGER FROM 0 TO 5,R.sup.1 is halogen, alkyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, halophenoxy or haloalkyl;R.sup.2 and R.sup.3, independently of one another, are each hydrogen, alkyl, alkoxyalkyl, cycloalkyl, alkoxy or alkoxycarbonylalkyl, of, preferably not more than 7 carbon atoms; or taken together, represent a lower alkylene bridge which can be interrupted by one or more hetero-atoms; andAz represents an azolyl radical selected from imidazol-1-yl, pyrrol-1-yl, pyrazol-1-yl,1,2,4-triazol-1-yl, 1,2,4-triazol-4-yl or 1,2,3-triazol-1-yl,And their salts are outstandingly effective herbicides showing particularly selective action.
摘要翻译：式（I）的新的吡唑基脒，其中N为0至5的整数，R 1为卤素，烷基，烷氧基，烷硫基，卤代烷氧基，卤代烷硫基，卤代苯氧基或卤代烷基; R 2和R 3彼此独立地为氢，烷基，烷氧基烷基，环烷基，烷氧基或烷氧基羰基烷基，优选不超过7个碳原子; 或一起代表可被一个或多个杂原子中断的低级亚烷基桥; 并且Az表示选自咪唑-1-基，吡咯-1-基，吡唑-1-基，1,2,4-三唑-1-基，1,2,4-三唑-4-基或 1,2,3-三唑-1-基，它们的盐是非常有效的除草剂，显示出特别的选择性作用。

87. 发明授权

US4058525A 4-Amino-5-thione-1,2,4-triazines 失效
标题翻译： 4-氨基-5-硫酮-1,2,4-三嗪
公开(公告)号：US4058525A
公开(公告)日：1977-11-15
申请号：US670911
申请日：1976-03-26
申请人： Wolfgang Hofer , Fritz Maurer , Hans-Jochem Riebel , Lothar Rohe , Ludwig Eue , Robert R. Schmidt
发明人： Wolfgang Hofer , Fritz Maurer , Hans-Jochem Riebel , Lothar Rohe , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D253/06 , A01N43/707 , C07D253/075 , C07D295/13
CPC分类号： C07D253/075 , A01N43/707 , C07D295/13
摘要： The invention provides new 4-amino-5-thione-1,2,4-triazine (4,5-H) of the formula ##STR1## in which R is alkyl of up to 8 carbon atoms, cycloalkyl of from 5 to 7 carbon atoms, cycloalkenyl of from 5 to 7 carbon atoms, phenyl, which can optionally be mono-substituted or polysubstituted by halogen, or alkoxyalkyl of from 1 to 4 carbon atoms per alkyl and alkoxy moiety, andR' is hydrogen or alkyl of up to 4 carbon atoms;Which are outstandingly effective as herbicides, particularly as selective herbicides.
摘要翻译：本发明提供了新颖的式（IMAGE）的4-氨基-5-硫酮-1,2,4-三嗪（4,5-H），其中R是至多8个碳原子的烷基，5至7个的环烷基碳原子，5至7个碳原子的环烯基，苯基，其可以任选被卤素单取代或多取代，或每个烷基和烷氧基部分具有1至4个碳原子的烷氧基烷基，R'是氢或烷基至4个碳原子; 作为除草剂特别有效，特别是选择性除草剂。

88. 发明授权

US3993469A Azolylamidine compounds and herbicidal compositions 失效
标题翻译：唑基脒化合物和除草组合物
公开(公告)号：US3993469A
公开(公告)日：1976-11-23
申请号：US459156
申请日：1974-04-08
申请人： Erik Regel , Ludwig Eue , Robert R. Schmidt
发明人： Erik Regel , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N37/52 , A01N43/52 , A01N43/647 , A01N57/00 , A01P13/00 , C07C275/70 , C07D207/327 , C07D207/34 , C07D231/12 , C07D231/56 , C07D233/56 , C07D233/61 , C07D233/68 , C07D233/92 , C07D233/95 , C07D235/06 , C07D235/08 , C07D249/04 , C07D249/08 , C07D249/10 , C07D521/00 , C07D233/90
CPC分类号： C07D249/08 , C07C275/70 , C07D207/34 , C07D231/12 , C07D231/56 , C07D233/56 , C07D233/68 , C07D233/92 , C07D235/06 , C07D249/04
摘要： New azolylamidines of the formula ##SPC1##Whereinn is an integer from 0 to 5,R.sup.1 is halogen, alkyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, halophenoxy or haloalkyl;R.sup.2 and R.sup.3, independently of one another, are each hydrogen, alkyl, alkoxyalkyl, cycloalkyl, alkoxy or alkoxycarbonylalkyl, of, preferably not more than 7 carbon atoms; or taken together, represent a lower alkylene bridge which can be interrupted by one or more hetero-atoms; andAz represents an azolyl radical selected from imidazol-1-yl, pyrrol-1-yl, pyrazol-1-yl, 1,2,4-triazol-1-yl, 1,2,4-triazol-4-yl or 1,2,3-triazol-1-yl,And their salts are outstandingly effective herbicides showing particularly selective action.
摘要翻译：新的具有下式的氮杂脒基，其中N为0至5的整数，R 1为卤素，烷基，烷氧基，烷硫基，卤代烷氧基，卤代烷硫基，卤代苯氧基或卤代烷基; R2和R3彼此独立地为氢，烷基，烷氧基烷基，环烷基，烷氧基或烷氧基羰基烷基，优选不超过7个碳原子; 或一起代表可被一个或多个杂原子中断的低级亚烷基桥; 并且Az表示选自咪唑-1-基，吡咯-1-基，吡唑-1-基，1,2,4-三唑-1-基，1,2,4-三唑-4-基或 1,2,3-三唑-1-基，它们的盐是非常有效的除草剂，显示出特别的选择性作用。

89. 发明授权

US4767444A Herbicidal and microbiocidal 2-trifluoromethyl-benzimidazoles 失效
标题翻译：除草和杀微生物的2-三氟甲基 - 苯并咪唑
公开(公告)号：US4767444A
公开(公告)日：1988-08-30
申请号：US58062
申请日：1987-06-04
申请人： Gerhard Heywang , Bernd Baasner , Albrecht Marhold , Ernst Kysela , Michael Schwamborn , Gerd Hanssler , Wilfried Paulus , Hans-Joachim Santel , Robert R. Schmidt , Hans-Georg Schmitt
发明人： Gerhard Heywang , Bernd Baasner , Albrecht Marhold , Ernst Kysela , Michael Schwamborn , Gerd Hanssler , Wilfried Paulus , Hans-Joachim Santel , Robert R. Schmidt , Hans-Georg Schmitt
IPC分类号： A01N43/52 , A01N43/90 , A01N47/02 , C07D235/10 , C07D491/04 , C07D491/056
CPC分类号： C07D491/04 , C07D235/10
摘要： The present invention relates to new 2-trifluoromethyl-benzimidazoles of the general formula (I) ##STR1## in which R.sup.1 represents halogenoalkyl,R.sup.2 represents optionally substituted alkyl orR.sup.1 and R.sup.2 together represent optionally substituted alkylene,R.sup.3 represents hydrogen or alkyl,X and Y independently of one another represent oxygen and sulphur,m represents 0 or 1 andn represents 0 or 1,a process for their preparation and their use as herbicides and microbicides.
摘要翻译：本发明涉及通式（I）的新的2-三氟甲基 - 苯并咪唑，其中R 1表示卤代烷基，R 2表示任选取代的烷基或R 1和R 2一起代表任意取代的亚烷基，R 3表示氢或烷基， X和Y彼此独立地表示氧和硫，m表示0或1，n表示0或1，它们的制备方法及其作为除草剂和杀微生物剂的用途。

90. 发明授权

US4638004A Substituted phenylsulphonylureas 失效
标题翻译：取代苯基磺酰脲
公开(公告)号：US4638004A
公开(公告)日：1987-01-20
申请号：US734503
申请日：1985-05-15
申请人： Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel , Gerd Hanssler , Klaus Lurssen
发明人： Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel , Gerd Hanssler , Klaus Lurssen
IPC分类号： A01N57/00 , A01N47/36 , A01N55/00 , A01N55/10 , C07D239/42 , C07D239/47 , C07D249/14 , C07D413/12 , C07D521/00 , C07F7/08 , C07D239/46 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , A01N55/00 , C07F7/0812
摘要： Plant growth-regulating and fungicidally active novel substituted phenylsulphonylureas of the formula ##STR1## in which R is hydrogen, halogen, alkyl, alkoxy, halogenoalkyl or nitro,Y is oxygen or sulphur,Het is ##STR2## T is --X--CH.sub.2 --Si(CH.sub.3).sub.3, or ##STR3## or, if Het is ##STR4## can also be ##STR5## --O--CH.sub.2 --CN or --O--CH.sub.2 --CO--CH.sub.3, E is nitrogen or CH,R.sup.1 and R.sup.2 each independently is alkyl, alkoxy, or alkoxyalkyl,X is oxygen, sulphur, the sulphinyl group or the sulphonyl group,X' is hydrogen or alkyl andR.sup.3 is hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl or optionally substituted aralkyl.
摘要翻译：其中R为氢，卤素，烷基，烷氧基，卤代烷基或硝基，Y为氧或硫的式为“IMAGE”的植物生长调节和杀真菌活性新型取代苯基磺酰脲，Het为-X-CH2- Si（CH 3）3或或者如果Het是也可以是-O-CH 2 -CN或-O-CH 2 -CO-CH 3，E是氮或CH，R 1和R 2各自独立地是烷基，烷氧基或烷氧基烷基，X是氧，硫，亚磺酰基或磺酰基，X'是氢或烷基，R 3是氢，烷基，烯基，炔基，卤代烷基，卤代烯基，烷氧基烷基，芳烷基。

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