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    • 81. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US4950578A
    • 1990-08-21
    • US381209
    • 1989-07-18
    • Morio YagiharaKazunobu Katoh
    • Morio YagiharaKazunobu Katoh
    • G03C1/06G03C1/485G03C8/00
    • G03C1/48561G03C1/061
    • A silver halide photographic material is disclosed, comprising a support having thereon at least one of silver halide photographic emulsion layers and other hydrophilic colloid layers, wherein at least one of said silver halide photographic emulsion layers and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein at least one of A.sub.1 and A.sub.2 represent a hydrogen atom and the other represents a hydrogen atom, a sulfonyl group or an acyl group; G.sub.1 represents a carbonyl group, a sulfonyl group, a sulfoxy group, a ##STR2## group, a ##STR3## group, or an iminomethylene group; L.sub.1 represents a bivalent group; X.sub.1 represents --O-- or an ##STR4## group wherein R.sub.4 is hydrogen, an alkyl group or an aryl group; Y.sub.1 represents ##STR5## R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group, a heterocyclic group, --OR.sub.5 or --NR.sub.5 R.sub.6 wherein R.sub.5 is an aliphatic group, an aromatic group or a heterocyclic group, and R.sub.6 is a hydrogen atom, an liphatic group, an aromatic group or a heterocyclic group; and R.sub.3 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aralkyl group, an aryloxy group, a hydrazino group or an amino group.
    • 公开了一种卤化银照相材料,其包括其上具有卤化银照相乳剂层和其它亲水胶体层中的至少一种的载体,其中所述卤化银照相乳剂层和其它亲水胶体层中的至少一种含有式 (I):其中A 1和A 2中的至少一个表示氢原子,另一个表示氢原子,磺酰基或酰基; G 1表示羰基,磺酰基,磺氧基,基团,基团或亚氨基亚甲基基团; L1表示二价基团; X1表示-O-或其中R4为氢,烷基或芳基的基团; Y1表示R1和R2各自表示脂族基,芳基,杂环基,-OR5或-NR5R6,其中R5是脂族基,芳族基或杂环基,R6是氢原子, 脂族基,芳基或杂环基; R 3表示氢原子,烷基,芳基,烷氧基,芳烷基,芳氧基,肼基或氨基。
    • 82. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4416978A
    • 1983-11-22
    • US387128
    • 1982-06-10
    • Masakazu MorigakiMorio YagiharaTakashi Ozawa
    • Masakazu MorigakiMorio YagiharaTakashi Ozawa
    • G03C7/26C07C41/00C07C43/20C07C43/225C07C67/00C07C69/035C07C301/00C07C309/63C07C309/65C07C309/73C07D231/52G03C7/327G03C7/392G03C1/40
    • G03C7/3928G03C7/3275
    • A silver halide color photographic light-sensitive material containing a magenta color image forming polymer coupler latex and at least one compound represented by the following general formula (I) ##STR1## wherein R represents an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a R.sub.4 CO-- group, a R.sub.5 SO.sub.2 -- group or a R.sub.6 NHCO-- group; R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkoxy group or an alkenoxy group; R.sub.3 represents a hydrogen atom, an alkyl group, an alkenyl group or an aryl group; and R.sub.4, R.sub.5 and R.sub.6 each represents an alkyl group, an alkenyl group, an aryl group or a heterocyclic group.The silver halide color photographic light-sensitive material has good film strength, a reduced layer thickness and provides a stable magenta image having an improved sharpness and fastness to light while preventing the formation of yellow stain in non-image areas. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
    • 含有品红色成像聚合物成色剂胶乳和至少一种由以下通式(I)表示的化合物的卤化银彩色照相感光材料其中R表示烷基,烯基,芳基, 杂环基,R4CO-基,R5SO2-基或R6NHCO-基; R 1和R 2可以相同或不同,各自表示氢原子,卤素原子,烷基,烯基,烷氧基或烯氧基; R3表示氢原子,烷基,烯基或芳基; R4,R5和R6各自表示烷基,烯基,芳基或杂环基。 卤化银彩色摄影感光材料具有良好的膜强度,降低的层厚度,并提供了稳定的品红色图像,其具有改善的清晰度和光稳定性,同时防止在非图像区域中形成黄色污点。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。
    • 83. 发明授权
    • Color photographic silver halide light-sensitive material
    • 彩色摄影卤化银感光材料
    • US4294918A
    • 1981-10-13
    • US168917
    • 1980-07-14
    • Morio YagiharaYukio Yokota
    • Morio YagiharaYukio Yokota
    • G03C7/34C09B53/00C09B55/00G03C7/305G03C1/40
    • G03C7/30523
    • A color photographic silver halide light-sensitive material is described containing a colorless photographic cyan color-forming coupler having, in a position for coupling with the oxidation product of an aromatic primary amine developing agent, as a coupling-off group, at least one alkoxy group substituted with a sulfinyl group represented by the formula (I)-O-R-SO-R.sub.1 (I)wherein R represents a saturated or unsaturated, divalent aliphatic group which may be straight or branched chain and may be substituted; and R.sub.1 represents a substituted or unsubstituted straight or branched chain alkyl group, an alkenyl group, an aralkyl group, an aralkenyl group, a cycloalkyl group, an aryl group or a heterocyclic group; and said heterocyclic group being connected with a sulfinyl group on the position of a carbon atom of the heterocyclic group.
    • 描述了一种彩色照相卤化银感光材料,其含有无色摄影青色成色剂,其在与芳族伯胺显影剂的氧化产物偶联的位置作为偶联离去基团,至少一个烷氧基 用式(I)-OR-SO-R 1(I)表示的亚磺酰基取代的基团,其中R表示饱和或不饱和的二价脂族基团,其可以是直链或支链并且可以被取代; R 1表示取代或未取代的直链或支链烷基,烯基,芳烷基,芳烯基,环烷基,芳基或杂环基; 并且所述杂环基与杂环基的碳原子的位置上的亚磺酰基连接。
    • 84. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4187110A
    • 1980-02-05
    • US858225
    • 1977-12-07
    • Morio YagiharaMitsugu TanakaTakeshi HiroseToshiaki Aono
    • Morio YagiharaMitsugu TanakaTakeshi HiroseToshiaki Aono
    • G03C7/26C07C67/00C07C301/00C07C309/72C07C313/00C07C317/14C07C317/24C07C317/28C07C317/44C07C323/22C07C323/52C07C323/56C07C323/66C07C323/67C07D249/12C07D249/18C07D257/04C07D417/12C07D417/14C07D487/04G03C1/04G03C7/305G03C7/32G03C1/06
    • C07D257/04C07C205/45G03C7/305G03C7/30535Y10S430/158
    • A silver halide photographic light-sensitive material containing a development inhibitor releasing compound, which is capable of forming a substantially colorless product, and which is represented by the following general formula (I): ##STR1## wherein X represents ##STR2## --SO.sub.2 R.sub.1, --SO.sub.2 OR.sub.1, --SO.sub.2 NH.sub.2, --SO.sub.2 NHR.sub.1, --SO.sub.2 N(R.sub.1).sub.2, --CN, --N.sup.+ (R.sub.1).sub.3 or ##STR3## R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group and further two R.sub.1 groups can combine and represent an atomic group necessary to form, together with the nitrogen atom to which they are attached, a nitrogen-containing heterocyclic group; R represents an aromatic group substituted with at least one of a nitro group, an acyl group, an alkoxycarbonyl group, a cyano group, a sulfamoyl group, a carbamoyl group, an aryloxycarbonyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkoxysulfonyl group and an aryloxysulfonyl group; and Y represents a group capable of being released from the compound represented by the general formula (I) upon reaction with the oxidation product of a developing agent to provide an arylmercapto compound, a heterocyclic mercapto compound, a triazole compound, a benzotriazole compound or a naphthotriazole compound which has a development inhibiting effect.
    • 含有显影抑制剂释放化合物的卤化银照相感光材料,其能够形成基本上无色的产物,并且由以下通式(I)表示:其中X表示 -SO2R1,-SO2OR1,-SO2NH2,-SO2NHR1,-SO2N(R1)2,-CN,-N +(R1)3或R1表示脂族基团,芳香族基团或杂环基团, 可以组合并表示与其连接的氮原子一起形成含氮杂环基所需的原子团; R表示被硝基,酰基,烷氧基羰基,氰基,氨磺酰基,氨基甲酰基,芳氧基羰基,烷基磺酰基,芳基磺酰基,烷氧基磺酰基中的至少一种取代的芳基 和芳氧基磺酰基; Y表示与显影剂的氧化物反应后能够从通式(I)表示的化合物中释放的基团,提供芳基巯基化合物,杂环巯基化合物,三唑化合物,苯并三唑化合物或 萘并三唑化合物,其具有显影抑制作用。
    • 85. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4157916A
    • 1979-06-12
    • US815407
    • 1977-07-13
    • Morio YagiharaMitsugu TanakaToshiaki AonoTakeshi Hirose
    • Morio YagiharaMitsugu TanakaToshiaki AonoTakeshi Hirose
    • G03C7/26C07D249/18C07D249/22C07D487/04G03C7/305G03C7/00G03C1/76G03C5/30
    • C07D487/04C07D249/18C07D249/22G03C7/305Y10S430/158
    • A silver halide photographic light-sensitive material containing a novel development inhibitor releasing coupler compound, capable of forming a substantially colorless product, represented by the following general formula (I): ##STR1## wherein R represents ##STR2## X represents ##STR3## --SO.sub.2 R.sub.2, --SO.sub.2 OR.sub.2, --SO.sub.2 N(R.sub.2).sub.2, --SO.sub.2 NHR.sub.2, --CN, --N.sup.+ (R.sub.2).sub.3 or ##STR4## R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group or a heterocyclic group and further two R.sub.2 groups can combine and represent an atomic group necessary to form, together with the nitrogen atom to which they are attached, a nitrogen-containing heterocyclic group; and Y represents a group capable of being released from the compound represented by the general formula (I) upon reaction with the oxidation product of a color developing agent to provide a compound which has a development inhibiting effect and having a triazole ring bonded to the carbon atom through the nitrogen atom at the 1-position thereof.
    • 含有下述通式(I)表示的能够形成基本无色的产物的新型显影抑制剂释放成色剂化合物的卤化银照相感光材料:其中R表示X表示< 图像> -SO 2 R 2,-SO 2 OR 2,-SO 2 N(R 2)2,-SO 2 NHR 2,-CN,-N +(R 2)3或R 1和R 2各自表示脂族基,芳基或杂环基, R2基团可以组合并且表示与它们所连接的氮原子一起形成含氮杂环基所需的原子团; Y表示与彩色显影剂的氧化物反应后能够从由通式(I)表示的化合物释放的基团,提供具有显影抑制作用的化合物,并且具有与碳键合的三唑环 原子通过其1位上的氮原子。
    • 86. 发明授权
    • Electron beam or X-ray negative-working resist composition
    • 电子束或X射线负极抗蚀剂组合物
    • US06824948B1
    • 2004-11-30
    • US09759362
    • 2001-01-16
    • Toshiaki AoaiYutaka AdegawaMorio Yagihara
    • Toshiaki AoaiYutaka AdegawaMorio Yagihara
    • G03F7004
    • G03F7/0045G03F7/038
    • A negative-working resist composition for electron beams or X-rays comprising (A) a compound generating an acid and/or radical species by the irradiation of electron beams or X-rays, (B) a resin which is insoluble in water and soluble in an alkali aqueous solution, (C) a crosslinking agent causing crosslinking with the resin of component (B) by the action of an acid, and (D) a compound having at least one unsaturated bond capable of being polymerized by an acid and/or a radical, and a negative-working resist composition for electron beams or X-rays comprising (A) a compound generating an acid and/or radical species by the irradiation of electron beams or X-rays, (B′) a resin having at least one unsaturated bond polymerizable by an acid and/or an alkali, which is insoluble in water but soluble in an alkali aqueous solution, and (C) a crosslinking agent causing crosslinking with the resin (B′) by the action of an acid are disclosed.
    • 一种用于电子束或X射线的负性抗蚀剂组合物,包括(A)通过电子束或X射线的照射产生酸和/或自由基的化合物,(B)不溶于水和可溶的树脂 在碱性水溶液中,(C)通过酸的作用与成分(B)的树脂交联的交联剂,(D)具有至少一个能够被酸和/ 或用于电子束或X射线的负性抗蚀剂组合物,其包含(A)通过照射电子束或X射线产生酸和/或自由基的化合物,(B')具有 至少一个不溶于水但可溶于碱性水溶液的酸和/或碱可聚合的不饱和键,和(C)通过酸的作用与树脂(B')交联的交联剂 被披露。
    • 89. 发明授权
    • Silver halide photographic material
    • 卤化银照相材料
    • US5374499A
    • 1994-12-20
    • US161451
    • 1993-12-06
    • Senzo SasaokaMorio Yagihara
    • Senzo SasaokaMorio Yagihara
    • G03C1/06G03C1/34G03C1/42
    • G03C1/061G03C1/34G03C1/42Y10S430/167
    • A silver halide photographic material comprising a support having thereon at least one of a surface latent image type silver halide emulsion layer and other hydrophilic colloid layers is disclosed, in which said at least one of the emulsion layer and other hydrophilic colloid layers contains a compound represented by formula (I): ##STR1## wherein X represents ##STR2## R.sub.1 represents a hydrogen atom or a group capable of being converted to a hydrogen atom on hydrolysis; R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom or a substituent group; R.sub.5 and R.sub.6, which may be the same or different, each represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkylsulfonyl group, a substituted or unsubstituted arylsulfonyl group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted arylcarbonyl group, or a substituted or unsubstituted carbamoyl group; Y represents a group which accelerates adsorption onto silver halide grains; L represents a divalent linking group; and m represents 0 or 1.The photographic material has suitability for rapid processing and markedly improved abrasion resistance without undergoing reduction in sensitivity.
    • 公开了一种卤化银照相材料,其包含其上具有表面潜像型卤化银乳剂层和其它亲水胶体层中的至少一种的载体,其中乳液层和其它亲水胶体层中的至少一种含有表示的化合物 通式(I)表示:其中X表示R 1表示氢原子或在水解时能够转化为氢原子的基团。 R 2,R 3和R 4可以相同或不同,表示氢原子或取代基; R 5和R 6可以相同或不同,表示氢原子,取代或未取代的烷基,取代或未取代的芳基,取代或未取代的烷基磺酰基,取代或未取代的芳基磺酰基,取代或未取代的 烷基羰基,取代或未取代的芳基羰基,或取代或未取代的氨基甲酰基; Y表示加速吸附到卤化银颗粒上的基团; L表示二价连接基团; m表示0或1.照相材料适用于快速加工,并且显着提高耐磨性,而不会降低灵敏度。
    • 90. 发明授权
    • Method for forming images by silver salt diffusion transfer
    • 通过银盐扩散转移形成图像的方法
    • US5290661A
    • 1994-03-01
    • US921134
    • 1992-07-29
    • Yoshio IdotaMakoto IshiharaMorio Yagihara
    • Yoshio IdotaMakoto IshiharaMorio Yagihara
    • G03C8/36G03C8/06G03C8/28G03C5/54
    • G03C8/06G03C8/28
    • A method for sorting images by silver salt diffusion transfer comprisingimagewise exposing a light-sensitive element comprising a light-sensitive silver halide emulsion layer,developing the light-sensitive element in the presence of a silver halide solvent using an alkaline processing composition to turn at least a part of unexposed silver halide of the light-sensitive silver halide emulsion layer into a transfer silver halide complex salt, andtransferring at least a part of the silver halide complex salt to an image receiving layer comprising a silver precipitating agent to form images on the image receiving layer,wherein at least one compound represented by formula (I) is added to at least one of the light-sensitive element, an image receiving element comprising the image receiving layer, and the processing composition in an amount of at least 1.times.10.sup.-6 and less than 1.times.10.sup.-2 mol based on one mol of silver applied per unit area (m.sup.2): ##STR1## wherein Q represents an atomic group for forming a quinone ring; R represents a monovalent group which may be substituted or unsubstituted; and n is an integer of 0 to 4, whereby the maximum density can be increased for a short time.
    • 一种通过银盐扩散转印来分选图像的方法,其包括使包含感光卤化银乳剂层的感光元件成像曝光,使用碱处理组合物在卤化银溶剂的存在下显影所述感光元件, 将感光卤化银乳剂层的未曝光的卤化银的至少一部分转移到转移卤化银络合物盐中,并将至少一部分卤化银配盐转移到包含银沉淀剂的图像接收层上以形成图像 图像接收层,其中至少一种由式(I)表示的化合物被添加到至少一种光敏元件,包含图像接收层的图像接收元件和至少1的量的加工组合物 * 10-6且小于1×10-2摩尔,相对于每单位面积施加的1摩尔银(m2):(*化学结构*)(I)其中Q表示 n原子团,用于形成醌环; R表示可以被取代或未取代的一价基团; n为0〜4的整数,能够在短时间内增加最大密度。