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81. 发明授权

US06350717B1 Catalyst and process for the selective hydrogenation of unsaturated compounds in hydrocarbon streams 失效
标题翻译：用于烃流中不饱和化合物的选择性氢化的催化剂和方法
公开(公告)号：US06350717B1
公开(公告)日：2002-02-26
申请号：US09385458
申请日：1999-08-30
申请人： Andrea Frenzel , Cristina Freire Erdbrügger , Ekkehard Schwab , Michael Hesse , Gerd Linden , Herbert Wanjek , Hans-Martin Allmann
发明人： Andrea Frenzel , Cristina Freire Erdbrügger , Ekkehard Schwab , Michael Hesse , Gerd Linden , Herbert Wanjek , Hans-Martin Allmann
IPC分类号： B01J2358
CPC分类号： C07C7/163 , B01J23/44 , B01J23/50 , B01J37/0201 , C07C5/05 , C07C5/09 , C07C2523/44 , C07C2523/50 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： A catalyst comprising at least one metal of the 10th group of the Periodic Table of the Elements and at least one metal of the 11th group of the Periodic Table of the Elements on an aluminum oxide support, wherein the metal or metals of the 10th group is or are essentially concentrated in an outer layer close to the surface of the catalyst particle, the metal or metals of the 11th group is or are distributed essentially uniformly over the volume of the catalyst particle and the weight ratio of the metal or metals of the 11th group to the metal or metals of the 10th group is not more than 1.95.
摘要翻译：一种催化剂，其包含元素周期表第10族中的至少一种金属和氧化铝载体上元素周期表第11族的至少一种金属，其中第10族的金属或金属为或基本上集中在接近催化剂颗粒表面的外层中，第11组的金属或金属基本均匀地分布在催化剂颗粒的体积上，并且第11位的金属或金属的重量比第10组金属或金属组不超过1.95。

82. 发明授权

US06274700B1 Catalyst and method for producing polytetrahydrofuran 失效
标题翻译：催化剂和生产聚四氢呋喃的方法
公开(公告)号：US06274700B1
公开(公告)日：2001-08-14
申请号：US09555872
申请日：2000-06-08
申请人： Karsten Eller , Heinz Rütter , Michael Hesse , Rainer Becker
发明人： Karsten Eller , Heinz Rütter , Michael Hesse , Rainer Becker
IPC分类号： C08G5968
CPC分类号： C08G65/2657 , C08G65/20
摘要： In a process for preparing polytetrahydrofuran, polytetrahydrofuran copolymers or diesters or monoesters thereof by polymerization of tetrahydrofuran in the presence of at least one telogen and/or comonomer over acid-activated montmorillonite catalysts, the montmorillonite catalyst after acid activation has a ratio of montmorillonite structure to the sum of muscovite and kaolin structures, determined from the intensities of the reflections at 2&thgr;=5.5° for montmorillonite, 2&thgr;=9.0° for muscovite and 2&thgr;=12.5° for kaolin measured in the X-ray powder pattern, of at least 5:1.
摘要翻译：在通过在酸活化蒙脱石催化剂上存在至少一种环糊精和/或共聚单体的情况下通过四氢呋喃聚合制备聚四氢呋喃，聚四氢呋喃共聚物或二酯或其单酯的方法中，酸活化后的蒙脱石催化剂具有蒙脱石结构与根据X射线粉末图案测定的蒙脱石的2θ= 5.5°的反射强度，白云母的2θ= 9.0°，高岭土的2θ= 12.5°，确定白云母和高岭土结构的总和为5： 1。

83. 发明授权

US06252039B1 Method for decoloring tetrahydrofuran polymers or copolymers 失效
标题翻译：四氢呋喃聚合物或共聚物脱色方法
公开(公告)号：US06252039B1
公开(公告)日：2001-06-26
申请号：US09402895
申请日：1999-10-13
申请人： Rainer Becker , Karsten Eller , Michael Hesse
发明人： Rainer Becker , Karsten Eller , Michael Hesse
IPC分类号： C08F600
CPC分类号： C08G65/20 , C08G65/30
摘要： A process for decolorizing polymers or copolymers which are obtained by cationic polymerization of tetrahydrofuran or of tetrahydrofuran and alkylene oxide, in the presence or absence of a telogen, comprises a) first, if desired, removing the low-boiling components by vacuum distillation or extraction and b) heating the remaining polymer or copolymer in the presence of at least one auxiliary selected from the group consisting of solid oxides and/or sheet silicates to from 20 to 150° C.
摘要翻译：在存在或不存在季铵盐时，通过四氢呋喃或四氢呋喃和环氧烷的阳离子聚合获得的聚合物或共聚物的脱色方法包括：a）如果需要，首先通过真空蒸馏或萃取除去低沸点组分在选自固体氧化物和/或片状硅酸盐的至少一种辅助剂存在下将剩余的聚合物或共聚物加热至20-150℃。

84. 发明授权

US6093677A Catalyst for dehydrogenating 1,4-butanediol to .gamma.-butyrolactone 有权
标题翻译：将1,4-丁二醇脱氢为γ-丁内酯的催化剂
公开(公告)号：US6093677A
公开(公告)日：2000-07-25
申请号：US323919
申请日：1999-06-02
申请人： Hans Jochen Mercker , Frank-Friedrich Pape , Joachim Simon , Andreas Henne , Michael Hesse , Ulrich Kohler , Roman Dostalek , Cristina Freire Erdbrugger , Detlef Kratz
发明人： Hans Jochen Mercker , Frank-Friedrich Pape , Joachim Simon , Andreas Henne , Michael Hesse , Ulrich Kohler , Roman Dostalek , Cristina Freire Erdbrugger , Detlef Kratz
IPC分类号： C07D307/33 , B01J23/72 , B01J23/78 , C07B61/00 , C07D315/00 , B01J23/70
CPC分类号： C07D315/00 , B01J23/78 , B01J23/72 , B01J35/0053 , B01J35/0066
摘要： A process for dehydrogenating 1,4-butanediol to .gamma.-butyrolactone in the gas phase in the presence of a copper-containing catalyst, wherein the catalyst contains 4-40% by weight of copper and 0-5% by weight of Na.sub.2 O, based on the total weight of the catalyst, on a carrier consisting of 80-100% by weight of SiO.sub.2 and 0-20% by weight of CaO.
摘要翻译：在含铜催化剂存在下，在气相中将1,4-丁二醇脱氢为γ-丁内酯的方法，其中催化剂含有4-40重量％的铜和0-5重量％的Na 2 O，基于在由80-100重量％的SiO 2和0-20重量％的CaO组成的载体上的催化剂的总重量。

85. 发明授权

US6057442A Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US6057442A
公开(公告)日：2000-05-02
申请号：US159089
申请日：1998-09-23
申请人： Joachim Wulff-Doring , Michael Hesse , Johann-Peter Melder , Philipp Buskens , Guido Voit , Frank Funke
发明人： Joachim Wulff-Doring , Michael Hesse , Johann-Peter Melder , Philipp Buskens , Guido Voit , Frank Funke
IPC分类号： C07D295/02 , B01J23/755 , B01J23/889 , C07B61/00 , C07C209/16 , C07D295/023
CPC分类号： C07D295/023 , B01J23/755 , B01J23/8892 , C07C209/16 , B01J23/8898 , Y02P20/582
摘要： Amines are prepared from primary or secondary alcohols and nitrogen compounds selected from the group of ammonia, primary and secondary amines, at from 80 to 250.degree. C. under pressures from 0.1 to 40 MPa with hydrogen in the presence of a catalyst comprising zirconium, copper and nickel, wherein the catalytically active composition comprises20-85% by weight of oxygen-containing zirconium compounds, calculated as ZrO.sub.2,1-30% by weight of oxygen-containing copper compounds, calculated as CuO,14-70% by weight of oxygen-containing nickel compounds, calculated as NiO, where the molar ratio of nickel to copper is greater than 1,0-10% by weight of oxygen-containing aluminum and/or manganese compounds, calculated as Al.sub.2 O.sub.3 and/or MnO.sub.2,and no oxygen-containing cobalt or molybdenum compounds.
摘要翻译：在含有锆，铜和铜的催化剂存在下，在氢气压力为0.1至40MPa的压力下，从伯，仲醇和选自氨，伯胺和仲胺的氮化合物制备胺。和镍，其中催化活性组合物包含20-85重量％的以ZrO 2计算的含氧锆化合物，1-30重量％的以CuO计的含氧铜化合物，14-70重量％以NiO计算的含氧镍化合物，其中镍与铜的摩尔比大于1-10重量％，以Al 2 O 3和/或MnO 2计算的含氧铝和/或锰化合物为0-10重量％含氧钴或钼化合物。

86. 发明授权

US5941770A Computer gaming system 失效
标题翻译：电脑游戏系统
公开(公告)号：US5941770A
公开(公告)日：1999-08-24
申请号：US851255
申请日：1997-05-05
申请人： Darrell Miers , Robert Reitzen , Bill Rommerdahl , Michael Hesse , Hein Hundal
发明人： Darrell Miers , Robert Reitzen , Bill Rommerdahl , Michael Hesse , Hein Hundal
IPC分类号： A63F1/00 , A63F1/18 , G07F17/32 , A63F7/06
CPC分类号： G07F17/32 , G07F17/3276 , G07F17/3293
摘要： The present invention comprises an intelligent gaming system that includes a game engine, simulation engine, and, in certain embodiments, a static evaluator. Embodiments of the invention include an intelligent, poker playing slot machine that allows a user to play poker for money against one or more intelligent, simulated opponents. The simulation engine generates actions for the simulated player(s). The simulation engine allows a real person, or user, to play against intelligent, simulated opponents. In addition, in certain embodiments a static evaluator offers another level of play in which the user can play against a predetermined criteria for winning. In one embodiment of the invention, the user plays against simulated opponent(s). In another embodiment of the invention, the user plays against simulated opponent(s) and against the predetermined criteria.
摘要翻译：本发明包括智能游戏系统，其包括游戏引擎，模拟引擎，以及在某些实施例中，静态评估器。本发明的实施例包括一种智能的扑克玩老虎机，其允许用户针对一个或多个智能模拟对手玩钱扑克。模拟引擎为模拟玩家生成动作。模拟引擎允许真正的人或用户对智能模拟对手进行对抗。此外，在某些实施例中，静态评估器提供另一个玩家级别，用户可根据预定的获胜标准进行游戏。在本发明的一个实施例中，用户对模拟的对手进行打击。在本发明的另一个实施例中，用户针对模拟对手并且抵制预定标准。

87. 发明授权

US5780681A Preparation of amines from olefins over oxides of group IVB or VIB or mixtures thereof on carriers 失效
标题翻译： IVB或VIB族氧化物或其混合物在载体上从烯烃制备胺
公开(公告)号：US5780681A
公开(公告)日：1998-07-14
申请号：US869759
申请日：1997-06-05
申请人： Karsten Eller , Rudolf Kummer , Michael Hesse
发明人： Karsten Eller , Rudolf Kummer , Michael Hesse
IPC分类号： B01J21/08 , B01J23/24 , B01J23/30 , B01J35/10 , C07B61/00 , C07C209/02 , C07C209/60 , C07C211/03 , C07C211/16 , C07C211/21 , C07C211/33 , C07C211/43
CPC分类号： C07C209/60 , B01J23/24 , Y02P20/582
摘要： Amines of general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl, R.sup.1 and R.sup.2 together form a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene chain and R.sup.3 or R.sup.5 is C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl, or R.sup.3 and R.sup.5 together form a C.sub.2 -C.sub.12 -alkylene chain, are prepared by reacting an olefin of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the above-mentioned meanings, with ammonia or primary or secondary amines of the general formula III ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meanings, at from 200.degree. to 350.degree. C. and from 100 to 300 bar in the presence of a heterogeneous catalyst, by a process in which the heterogeneous catalyst used is an oxide of group IVB or VIB or a mixture thereof on a carrier.
摘要翻译：通式I（I）的胺其中R 1，R 2，R 3，R 4，R 5和R 6各自为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20 - 炔基，C 3 -C 20 - 环烷基 C 4 -C 20烷基环烷基，C 4 -C 20环烷基烷基，芳基，C 7 -C 20烷基芳基或C 7 -C 20芳烷基，R 1和R 2一起形成饱和或不饱和的C 3 -C 9 - 亚烷基链，并且R 3或R 5是C 21 -C 200 - 烷基或C 21 -C 2-链烯基，或者R 3和R 5一起形成C 2 -C 12亚烷基链，通过使通式II的烯烃（II）反应，其中R3，R4，R5和R6具有在具有上述含义的氨基或伯或仲胺中，其中R1和R2具有上述含义，在200-350℃和100-300巴的存在下，的非均相催化剂，其中使用的非均相催化剂是IVB或VIB的氧化物或其载体上的混合物的方法。

88. 发明授权

US4929733A Preparation of N-heterocycles 失效
标题翻译： N-杂环的制备
公开(公告)号：US4929733A
公开(公告)日：1990-05-29
申请号：US207861
申请日：1988-06-17
申请人： Michael Hesse , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Michael Hesse , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07D209/08 , C07D295/023
CPC分类号： C07D295/023 , C07D209/08 , Y02P20/582
摘要： N-heterocycles of the general formulae (I) and (II) ##STR1## where R.sup.1 and R.sup.4 to R.sup.9 are each hydrogen, alkyl, aryl, aralkyl, alkylaryl or cycloalkyl and R.sup.2 and R.sup.3 are each an alkyl, alkylaryl, substituted alkyl or cycloalkyl group, are prepared by a process in which an olefin of the formula (III) or (IV) ##STR2## where R.sup.2 to R.sup.9 have the above meanings, is reacted with NH.sub.3 or with a primary amine of the formula H.sub.2 NR.sup.1, where R.sup.1 has the above meanings, in the presence of a zeolite as a catalyst.
摘要翻译：通式（I）和（II）的N-杂环化合物其中R 1和R 4至R 9各自为氢，烷基，芳基，芳烷基，烷基芳基或环烷基，R 2和R 3各自为烷基，烷基芳基，取代的烷基或环烷基的方法通过其中R 2至R 9具有上述含义的式（III）或（IV）的烯烃与NH 3或伯胺进行反应的方法制备式H2NR1，其中R1具有上述含义，在作为催化剂的沸石存在下。

89. 发明授权

US4914241A Preparation of diamines 失效
标题翻译：二胺的制备
公开(公告)号：US4914241A
公开(公告)日：1990-04-03
申请号：US206755
申请日：1988-06-15
申请人： Michael Hesse , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Michael Hesse , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07C209/60
CPC分类号： C07C209/60 , Y02P20/582
摘要： Diamines of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, alkyl, aryl, alkoxy, aralkyl or cycloalkyl and X is a group of the formula(CR.sup.4 R.sup.5).sub.m (II)where R.sup.4 and R.sup.5 have the meanings given above for R.sup.1 and m is from 1 to 12, are prepared by a process in which a diamine of the formula ##STR2## where R.sup.1, R.sup.2 and X are the groups described above, is reacted with an olefin of the formula ##STR3## where R.sup.6 and R.sup.9 are each hydrogen or alkyl which is straight-chain in the .alpha.-position, in the presence of a zeolite as a catalyst.
摘要翻译：式（I）的二胺其中R 1，R 2和R 3各自为氢，烷基，芳基，烷氧基，芳烷基或环烷基，X为式（CR 4 R 5）m（II）的基团，其中R 4和R 5具有对于R1和m给出的含义为1至12的方法通过以下方法制备：其中R1，R2和X为上述基团的式（III）的二胺与式（VI）其中R 6和R 9各自为氢或在α位为直链的烷基，在作为催化剂的沸石存在下。

90. 发明授权

US09115206B2 Nucleic acid expression construct and its use as a cell proliferation marker 有权
标题翻译：核酸表达构建体及其作为细胞增殖标志物的用途
公开(公告)号：US09115206B2
公开(公告)日：2015-08-25
申请号：US13383580
申请日：2010-07-15
申请人： Bernd K. Fleischmann , Michael Hesse , Alexandra Raulf
发明人： Bernd K. Fleischmann , Michael Hesse , Alexandra Raulf
IPC分类号： C07K14/47 , C12N15/63
CPC分类号： C07K14/4738 , C12N15/63
摘要： A nucleic acid expression construct which encodes a fusion protein includes a reporter protein and a protein with a wild-type destruction signal. A sequence encoding the fusion protein is operably linked to a non-endogenous promoter. The fusion protein localizes during a cell cycle progression to subcellular structures selected from a cell cortex, a contractile ring, and a midbody.
摘要翻译：编码融合蛋白的核酸表达构建体包括报道蛋白和具有野生型破坏信号的蛋白质。编码融合蛋白的序列与非内源启动子可操作地连接。融合蛋白在细胞周期进展期间定位到选自细胞皮质，收缩环和中间体的亚细胞结构。

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