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    • 81. 发明授权
    • Colored low-expansion transparent glass ceramic
    • 彩色低膨胀透明玻璃陶瓷
    • US5010041A
    • 1991-04-23
    • US390771
    • 1989-08-08
    • Akihiro KoyamaKeiji KitamuraNobuyuki Yamamoto
    • Akihiro KoyamaKeiji KitamuraNobuyuki Yamamoto
    • C03C4/02C03C10/00C03C10/14
    • C03C10/0045C03C10/0027
    • A colored low-expansion transparent glass ceramic comprising 100 parts by weight of a base glass (a) having the following composition, the following coloring components (b) and the following auxiliary coloring component (c) mixed thereto in the following ratio, and in that the principal crystalline phase is .beta.-quartz solid solution.(a) Base glass______________________________________ (weight %) ______________________________________ LiO.sub.2 3.5 to 5.5 Na.sub.2 O 0 to 4.0 K.sub.2 O 0 to 4.0 Na.sub.2 O + K.sub.2 O 0.5 to 4.0 MgO 0.1 to 3.0 Al.sub.2 O.sub.3 20.5 to 23.0 SiO.sub.2 60.0 to 68.5 TiO.sub.2 1.0 to 7.0 ZrO.sub.2 0 to 3.5 TiO.sub.2 + ZrO.sub.2 3.5 to 7.0 P.sub.2 O.sub.5 0 to 4.0 ______________________________________ (b) Coloring components______________________________________ (part by weight) ______________________________________ CoO 0 to 0.02 Cr.sub.2 O.sub.3 0 to 0.05 MoO.sub.3 0 to 0.04 NiO 0 to 0.075 ______________________________________ (c) Auxiliary coloring componentAt least one selected from the group consisting of______________________________________ (part of weight) ______________________________________ Cl 0 to 0.6 Br 0 to 0.4, and I 0 to 0.03 ______________________________________ The total amount of auxiliary component is 0.002 to 0.7 part by weight.In order to produce such glass ceramic, a raw material so prepared as to produce a glass ceramic having a composition comprising 100 parts by weight of the base glass (a) having the above-described composition, the coloring components (b) and the auxiliary coloring components (c) mixed thereto in the above-described ratio is melted and cooled and the thus-obtained glass ceramic is heat treated so as to form .beta.-quartz solid solution crystals as the principal crystalline phase.
    • 包含100重量份具有以下组成的基础玻璃(a)的着色低膨胀透明玻璃陶瓷,以下列比例混合以下着色组分(b)和以下辅助着色组分(c),并在 主晶相为β-石英固溶体。 (a)基础玻璃 - (重量%)-LiO2 3.5〜5.5 -Na2O 0〜4.0-K2O 0〜4.0 -Na2O + K2O 0.5〜4.0 -MgO 0.1〜3.0 -Al2O3 20.5〜23.0 -SiO2 60.0〜68.5 -TiO2 1.0 至7.0-ZrO 2至3.5 -TiO 2 + ZrO 2 3.5至7.0 -P 2 O 5 0至4.0 - (b)着色组分 - (重量份)-CoO 0至0.02 -Cr 2 O 3 0至0.05-MoO 3 0至0.04 -NiO 0至 0.075 - (c)辅助着色成分选自 - (重量份数)-Cl 0〜0.6 -Br 0〜0.4,-I 0〜0.03的至少一种 - 辅助成分的总量为0.002〜 0.7重量份。 为了制造这种玻璃陶瓷,制备如下制备的玻璃陶瓷的原料,该玻璃陶瓷的组成包含100重量份具有上述组成的基础玻璃(a),着色组分(b)和助剂 将以上述比例混合的着色组分(c)熔化并冷却,将由此得到的玻璃陶瓷进行热处理,形成作为主晶相的β-石英固溶体晶体。