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81. 发明授权

US07230042B2 Flame retardant polymer compositions containing hydroxylamine esters 有权
标题翻译：含有羟胺酯的阻燃聚合物组合物
公开(公告)号：US07230042B2
公开(公告)日：2007-06-12
申请号：US10511853
申请日：2003-04-10
申请人： Michael Roth , Dirk Simon , Grant Leslie , Peter Nesvadba , Roswell Easton King , Nikolas Kaprinidis
发明人： Michael Roth , Dirk Simon , Grant Leslie , Peter Nesvadba , Roswell Easton King , Nikolas Kaprinidis
IPC分类号： C08K5/34 , C08K5/51 , C08K5/17 , C08K5/18
CPC分类号： C08K5/3435
摘要： The instant invention pertains to a thermoplastic organic polymer containing a conventional flame retardant and a hydroxylamine ester, in particular a tetraalkyl piperidine hydroxylamine ester. Further aspects of the invention are the use of hydroxylamine esters as flame retardants and a method for improving flame retardancy of a thermoplastic organic polymer.
摘要翻译：本发明涉及含有常规阻燃剂和羟胺酯，特别是四烷基哌啶羟胺酯的热塑性有机聚合物。本发明的其它方面是使用羟胺酯作为阻燃剂和改进热塑性有机聚合物的阻燃性的方法。

82. 发明申请

US20060194053A1 Comb copolymers with defined side chains and process for their manufacture 失效
公开(公告)号：US20060194053A1
公开(公告)日：2006-08-31
申请号：US10543427
申请日：2004-02-02
申请人： Jochen Fink , Michael Roth , Rudolf Pfaendner
发明人： Jochen Fink , Michael Roth , Rudolf Pfaendner
IPC分类号： C08G59/32 , C08L71/02
CPC分类号： C08F255/023 , C08F255/02 , C08F257/02 , C08F265/00 , C08F285/00 , C08F287/00 , C08F291/00 , C08F293/005 , Y10T428/2978
摘要： The present invention relates to the modification of copolymers, in particular of grafted copolymers into comb copolymers. The modification comprises the steps (i) of controlled radical polymerization of a polymer or copolymer bearing a epoxide group at one end resulting from the initiation step, and (ii) a heating step of the polymer prepared under (i) and a copolymer bearing a functional group either in the backbone or attached to a side chain, which is able to react with the epxide group. The result is a comb copolymer with well controlled chain length of the grafted side arms expressed for example by a low polydispersity.

83. 发明申请

US20060128903A1 Process for the controlled increase in the molecular weight of polyethylenes 有权
标题翻译：控制聚乙烯分子量增加的方法
公开(公告)号：US20060128903A1
公开(公告)日：2006-06-15
申请号：US11339214
申请日：2006-01-25
申请人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
发明人： Michael Roth , Rudolf Pfaendner , Peter Nesvadba , Marie-Odile Zink
IPC分类号： C08F8/32
CPC分类号： C07D491/10 , C07C239/22 , C07D209/44 , C07D211/94 , C07D233/32 , C07D233/38 , C07D241/08 , C07D295/24 , C07D401/14 , C07D487/10 , C07F9/59 , C08F2/38 , C08F4/00 , C08F8/30 , C08F8/50 , C08F110/02 , C08F110/06 , C08K5/3435 , C08L23/06 , C08L23/10 , C08L2023/44 , C08L2205/02 , C08L2666/06 , C08F8/00
摘要： The invention relates to novel cyclic hydroxylamine esters and to the use of known hydroxylamine esters selected from the group consisting of HALS (sterically hindered amine) compounds and the novel hydroxylamine esters achieving a controlled increase in the molecular weight of polyethylene.
摘要翻译：本发明涉及新的环状羟胺酯，以及选自HALS（空间位阻胺）化合物和新型羟胺酯的已知羟胺酯的用途，可实现聚乙烯分子量的可控增加。

84. 发明申请

US20050215720A1 Grafting of nitroxyl terminated oligomers or polymers onto thermoplastic polymers 失效
标题翻译：将硝酰基封端的低聚物或聚合物接枝到热塑性聚合物上
公开(公告)号：US20050215720A1
公开(公告)日：2005-09-29
申请号：US10518873
申请日：2003-06-12
申请人： Jochen Fink , Michael Roth , Rudolf Pfaendner
发明人： Jochen Fink , Michael Roth , Rudolf Pfaendner
IPC分类号： C08F4/00 , C08F8/00 , C08F8/30 , C08F10/00 , C08F293/00 , C08G81/02 , C08F2/00
CPC分类号： C08F293/005 , C08F4/00 , C08F8/30 , C08F10/00 , C08F2438/02 , C08G81/021 , C08F2/38
摘要： The instant invention relates to a process for the preparation of grafted polymers wherein in a first step A) a oligomer or polymer is prepared by controlled radical polymerization in the presence of a stable free nitroxyl radical or a nitroxylether to obtain a nitroxyl terminated oligomer or polymer and in a second step B) the nitroxyl terminated oligomer or polymer is mixed and reacted with a thermoplastic or elastomeric polymer or copolymer in its molten state at a temperature at which cleavage of the nitroxyl-polymer/oligomer bond occurs, whereby the nitroxyl terminated oligomer or polymer is grafted onto the thermoplastic or elastomeric polymer. A further subject of the present invention is a grafted polymer prepared by said process.
摘要翻译：本发明涉及一种制备接枝聚合物的方法，其中在第一步骤A）中，通过在稳定的游离硝酰基或硝酰基醚的存在下通过可控自由基聚合制备低聚物或聚合物，得到硝酰基封端的低聚物或聚合物并且在第二步骤B）中，将硝酰基封端的低聚物或聚合物与其熔融状态下的热塑性或弹性体聚合物或共聚物在发生硝酰基聚合物/低聚物键断裂的温度下反应，由此将硝酰基封端的低聚物或聚合物接枝到热塑性或弹性聚合物上。本发明的另一个主题是通过所述方法制备的接枝聚合物。

85. 发明授权

US06949594B2 Molecular weight modification of thermoplastic polymers 有权
标题翻译：热塑性聚合物的分子量改性
公开(公告)号：US06949594B2
公开(公告)日：2005-09-27
申请号：US10296346
申请日：2001-05-22
申请人： Michael Roth , Rudolf Pfaendner , Dirk Simon
发明人： Michael Roth , Rudolf Pfaendner , Dirk Simon
IPC分类号： C08L101/00 , C08K5/00 , C08K5/32 , C08K5/3435 , C08L23/00 , C08L25/00 , C08L5/3435 , C08L5/3412 , C08L5/3477 , C08L5/357
CPC分类号： C08K5/32 , C08K5/0025 , C08K5/3435 , C08L2023/44
摘要： The invention relates to a process for the molecular weight increase/crosslinking of non-halogen-containing thermoplastic polymers, in which process a composition comprising a) a non-halogen-containing thermoplastic polymer; b) a functional compound having at least two unsaturated carbon bonds; and c) an alkoxyamine having a structural unit (I), which forms free radicals at the melting temperature/processing temperature of the polymer, is mixed and heated above the melting point of the polymer in the case of crystalline polymers or the softening point in the case of amorphous polymers. The invention relates also to the composition itself, to the use thereof in increasing the molecular weight of polymers and to polymers having increased molecular weight or crosslinked polymers prepared in accordance with that process
摘要翻译：本发明涉及一种非卤素热塑性聚合物分子量增加/交联的方法，其中该方法包括a）一种非卤素热塑性聚合物; b）具有至少两个不饱和碳键的官能化合物; 和c）在聚合物的熔融温度/加工温度下，具有结构单元（I）的烷氧基胺在聚合物的熔融温度/加工温度下形成自由基，在结晶聚合物的情况下被混合并加热至高于聚合物的熔点或软化点无定形聚合物的情况。本发明还涉及组合物本身，其用于增加聚合物的分子量和具有增加的分子量的聚合物或根据该方法制备的交联聚合物

86. 发明授权

US06767949B1 Composition and method for color improvement of nitroxyl containing polymers 失效
标题翻译：用于含硝酰基聚合物的组合物和颜色改进方法
公开(公告)号：US06767949B1
公开(公告)日：2004-07-27
申请号：US10130866
申请日：2002-05-22
申请人： Rudolf Pfaendner , Michael Roth , Wiebke Wunderlich
发明人： Rudolf Pfaendner , Michael Roth , Wiebke Wunderlich
IPC分类号： C08L328
CPC分类号： C08K5/32 , C08K5/3435
摘要： The invention relates to a composition comprising, a) at least one oligomer, cooligomer, polymer or copolymer or blends thereof, containing a stable free nitroxyl radical (1); and b) a reducing agent; with the proviso that the composition is essentially free of a polymerizable monomer. A further subject is a process for improving the color of an oligomer, cooligomer, polymer or copolymer or blend thereof, containing a stable free nitroxyl radical (1); by adding a reducing agent to said polymer and heating said mixture to above the glass temperature in case of amorphous polymers or above the melting point in case of crystalline or semi-crystalline polymers
摘要翻译：本发明涉及一种组合物，其包含a）至少一种含有稳定的游离硝酰基（1）的低聚物，低聚物，聚合物或共聚物或其共混物; 和b）还原剂; 条件是组合物基本上不含可聚合单体。另一个课题是改进含有稳定的游离硝酰基（1）的低聚物，低聚物，聚合物或共聚物或其共混物的颜色的方法。通过在无定形聚合物的情况下向所述聚合物中加入还原剂并将所述混合物加热到玻璃化温度以上，或者在结晶或半结晶聚合物的情况下高于熔点

87. 发明授权

US06583245B1 Polymeric stabilizers having low polydispersity 有权
标题翻译：具有低多分散性的聚合物稳定剂
公开(公告)号：US06583245B1
公开(公告)日：2003-06-24
申请号：US09868762
申请日：2001-06-21
申请人： Alfred Steinmann , Michael Roth , Werner Stauffer , Peter Nesvadba , Andreas Mühlebach
发明人： Alfred Steinmann , Michael Roth , Werner Stauffer , Peter Nesvadba , Andreas Mühlebach
IPC分类号： C08F404
CPC分类号： C08K5/005 , C08F246/00
摘要： The present invention relates to a polymerizable composition, comprising a) at least one compound of formula (I) (RG)—A—(Stab) (I), wherein (Stab) is a light stabilizer radical selected from the group consisting of sterically hindered amines, hydroxyphenyl-s-triazines, hydroxyphenyl-benzotriazols and o-hydroxy-benzophenones; A is a spacer group or a direct bond; and (RG) is a group containing at least one ethylenically unsaturated functional group; and either b1) a compound of formula (II) Y—X (II), wherein X represents a group having at least one carbon atom and is such that the free radical derived from X is capable of initiating polymerization and Y represents a group being such that the free radical Y· derived from it forms a stable free radical; or b2) a stable free radical Y· and a free radical source from which a radical is formed capable of initiating polymerization, or b3) a compound of formula (III) and a catalytically effective amount of an oxidizable transition metal complex catalyst, wherein p represents a number greater than zero and defines the number of initiator fragments; q represents a number greater than zero; [In] represents a radically transferable atom or group capable of initiating polymerization and -[Hal] represents a leaving group; and optionally c) one or more ethylenically unsaturated monomers or oligomers different from those of formula (I). Further subjects of the invention are a polymerization process, the polymers, copolymers oligomers and cooligomers obtainable by this process and the use of the polymers, copolymers oligomers and cooligomers as heat or light stabilizers.
摘要翻译：本发明涉及可聚合组合物，其包含a）至少一种式（I）化合物，其中（Stab）是选自空间位阻胺，羟基苯基-s-三嗪，羟基苯基 - 苯并三唑并且邻羟基 - 二苯甲酮; A是间隔基团或直接键; 和（RG）是含有至少一个烯属不饱和官能团的基团; 和b1）式（II）的化合物，其中X表示具有至少一个碳原子的基团，并且使得衍生自X的自由基能够引发聚合，并且Y表示使得衍生自它形成一个稳定的自由基; 或b2）稳定的自由基Y.以及自由基源，其中形成能够引发聚合的自由基，或b3）式（III）的化合物和催化有效量的可氧化的过渡金属配合物催化剂，其中p表示数字大于零并且定义引发剂片段的数量; q表示大于零的数字; [In]表示能够引发聚合的可自由基转移的原子或基团， - [Hal]表示离去基团; 和任选地c）与式（I）的那些不同的一种或多种烯属不饱和单体或低聚物。本发明的其它主题是聚合方法，可通过该方法获得的聚合物，共聚物低聚物和冷却体，以及聚合物，共聚物低聚物和冷却剂作为热或光稳定剂的用途。

88. 发明授权

US6095698A Hybrid connector 失效
标题翻译：混合连接器
公开(公告)号：US6095698A
公开(公告)日：2000-08-01
申请号：US131808
申请日：1998-08-10
申请人： Martin Strab , Marcus Schulte , Richard Flieger , Michael Roth , Ernst Liebich , Werner Bittner
发明人： Martin Strab , Marcus Schulte , Richard Flieger , Michael Roth , Ernst Liebich , Werner Bittner
IPC分类号： H01R13/66 , G02B6/38 , G02B6/42 , H01R12/18 , H01R13/514 , H01R13/518 , H01R13/629 , H01R24/00 , G02B6/36
CPC分类号： G02B6/4292 , G02B6/3817 , H01R13/514 , H01R13/518 , H01R13/62905
摘要： A hybrid connector with electric plug-in connections and fiber-optic demountable connections for an electronic built-in unit. The hybrid connector has a female connector and an angular male connector strip having long side walls. The female connector has a cover cap with module chambers for holding electric receptacle modules and fiber-optic modules. Electrooptical transducers having connecting leads with ends defining solder terminals are assigned to the fiber-optic connectors of the fiber-optic modules. The electrooptical transducers are disposed in a base of the angular male connector strip. The electrooptical transducers are aligned in a row parallel to the long side walls on a side on which solder terminals of the male connector strip are located. In this manner, the length of the connecting leads including the solder terminals is as small as possible.
摘要翻译：具有电插头连接的混合连接器和用于电子内置单元的光纤可拆卸连接。混合连接器具有阴连接器和具有长侧壁的角形公连接器条。母连接器具有盖帽，其具有用于保持电插座模块和光纤模块的模块室。具有连接导线和具有端子定义焊接端子的电光传感器被分配给光纤模块的光纤连接器。电光学传感器设置在角度公连接器条的基部中。电光学传感器在阳连接器条的焊接端子所在的一侧与长边壁平行排列。以这种方式，包括焊接端子的连接引线的长度尽可能地小。

89. 发明授权

US5857205A Method for determining if data item characteristics in periodically updated and replaced files have unexpectedly changed 失效
标题翻译：用于确定周期性更新和替换的文件中的数据项特征是否意外改变的方法
公开(公告)号：US5857205A
公开(公告)日：1999-01-05
申请号：US695871
申请日：1996-08-12
申请人： Michael Roth
发明人： Michael Roth
IPC分类号： G06F11/00 , G06F11/34 , G06F17/30
CPC分类号： G06F11/0751 , G06F11/3452 , G06F11/3466 , G06F2201/88 , Y10S707/99952 , Y10S707/99953 , Y10S707/99954
摘要： A method for verifying computer generated data in periodically updated and replaced files to determine if data item characteristics in the files have changed in an unexpected manner. The method involves the steps of selecting a first version of each of the data item characteristics and selecting a second subsequent version of each of the data item characteristics. The first version of each of the data item characteristics and the second subsequent version of each of the data item characteristics are analyzed to produce first and second statistical profiles. The first and second statistical profiles of each of the data item characteristics are then compared to each other to determine if any of the data item characteristics have changed in an unexpected manner. Finally, the files being periodically updated and replaced are monitored to determine if the data item characteristics in the files have changed in an unexpected manner.
摘要翻译：一种用于在周期性更新和替换的文件中验证计算机生成的数据以确定文件中的数据项特征是否以意想不到的方式改变的方法。该方法包括以下步骤：选择每个数据项特征的第一版本，并选择每个数据项特征的第二后续版本。分析每个数据项特征的每个数据项特征和第二后续版本的第一版本以产生第一和第二统计概况。然后将每个数据项特征的第一和第二统计概况相互比较，以确定数据项特征中的任何一个是否以意想不到的方式改变。最后，监视定期更新和替换的文件，以确定文件中的数据项特征是否以意想不到的方式发生更改。

90. 发明授权

US5480328A Filter plug connector having a shield housing 失效
标题翻译：具有屏蔽壳体的过滤器插头连接器
公开(公告)号：US5480328A
公开(公告)日：1996-01-02
申请号：US365690
申请日：1994-12-29
申请人： Michael Roth , Karl Schneider , Ernst Liebich , Josef Dirmeyer , Egbert Wagner , Peter Moerkerke
发明人： Michael Roth , Karl Schneider , Ernst Liebich , Josef Dirmeyer , Egbert Wagner , Peter Moerkerke
IPC分类号： H01R13/648 , H01R13/658 , H01R13/719
CPC分类号： H01R13/719 , H01R13/65802 , H01R2201/26
摘要： In order to provide a simple connection between a shield housing and a strip body, the shield housing, which has resilient side parts with spring arms being bent inwards, is pushed over lead-in and sliding inclines on the strip body and automatically latches on an insertion side or front thereof. The spring arms of each side part, which are located alongside one another, alternately form contact elements providing contact between the shield housing and a mounting panel and sliding and latching elements for connecting the shield housing to the strip body. The invention is suitable for motor vehicle filter plug connectors.
摘要翻译：为了在屏蔽壳体和带状体之间提供简单的连接，具有弹性臂向内弯曲的弹性侧部的屏蔽壳被推入带状体上的引入和滑动倾斜并自动锁定在一个插入侧或前面。每个侧部的弹簧臂彼此并排设置，交替地形成接触元件，其提供屏蔽壳体和安装面板之间的接触以及用于将屏蔽壳体连接到带状体的滑动和闭锁元件。本发明适用于机动车辆过滤塞连接器。

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