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    • 82. 发明专利
    • Fuel cell
    • 燃料电池
    • JPS60212961A
    • 1985-10-25
    • JP6773884
    • 1984-04-06
    • Hitachi Ltd
    • HONCHI AKIOMORI TOSHIKATSUKAHARA TOSHIKIIMAHASHI JINICHITAMURA KOUKI
    • H01M4/90H01M4/86
    • H01M4/86
    • PURPOSE:To prevent coagulation of an active catalyst on an electrode by forming a catalyst layer of a fuel cell electrode with a nonconductive inorganic compound carrier, a mixture of active catalyst and conductive particles, and a binder. CONSTITUTION:At least one of catalyst layers of a set of fuel cell electrodes is formed with nonconductive inorganic compound carrier having a conductivity of 10 OMEGAcm (at room temperature), a mixture of active catalyst such as platinum and conductive particles such as carbon, and a binder such as polytetrafluoroethylene. A fuel cell using this catalyst layer prevents coagulation of catalyst particles and shows steady cell voltage over a lengthy period of time.
    • 目的:通过形成具有非导电无机化合物载体的燃料电池电极的催化剂层,活性催化剂和导电颗粒的混合物以及粘合剂来防止电极上的活性催化剂的凝结。 构成:一组燃料电池电极中的至少一个催化剂层由导电率为10 -2欧米汞(室温)的非导电无机化合物载体形成,活性催化剂如铂和导电颗粒的混合物如 作为碳,以及粘合剂如聚四氟乙烯。 使用该催化剂层的燃料电池防止催化剂颗粒的凝结,并且在长时间内显示稳定的电池电压。
    • 83. 发明专利
    • Liquid fuel battery
    • 液体燃料电池
    • JPS60211772A
    • 1985-10-24
    • JP6577884
    • 1984-04-04
    • Hitachi Ltd
    • KITAMI NORIKOKUMAGAI TERUOKAMO YUUICHITAKEUCHI SEIJIIWAMOTO KAZUOHORIBA TATSUOTAMURA KOUKI
    • H01M4/86H01M8/08
    • H01M8/08H01M4/86
    • PURPOSE:To prevent deterioration in battery performance due to contactness between anode and air by providing a moistened film to the anode. CONSTITUTION:A layer consisting of a conductive and porous material which can sufficiently hold electrolyte is provided on the catalyst layer of anode. As the conductive and porous material, unwoven cloth or woven close of carbon, metal wool or porous plate can be used but any kind of material can be used so long as it is conductive, porous and has resistance for chemicals so that it is not corroded by fuel or electrolyte. If such a conductive and porous layer is moistened by electrolyte, the anode is kept wet. In case the anorite is drained while the battery is not used, contact between air and anode can be avoided and thereby degradation of battery performance can be prevented.
    • 目的:通过向阳极提供润湿膜,防止阳极与空气之间的接触导致的电池性能下降。 构成:在阳极的催化剂层上设置由能够充分保持电解质的导电性和多孔性材料构成的层。 作为导电性和多孔材料,可以使用无纺布或编织的碳,金属毛或多孔板,但是只要具有导电性,多孔性,并具有耐化学性,使其不被腐蚀,可以使用任何种类的材料 通过燃料或电解质。 如果这种导电和多孔层被电解质润湿,则阳极保持湿润。 在不使用电池的情况下排出异氰酸盐,可以避免空气和阳极之间的接触,从而可以防止电池性能的劣化。
    • 84. 发明专利
    • Fuel cell generator
    • 燃油电池发电机
    • JPS59211970A
    • 1984-11-30
    • JP8639983
    • 1983-05-17
    • Hitachi Ltd
    • HORIBA TATSUOKITAMI NORIKOKUMAGAI TERUOIWAMOTO KAZUOKAWANA HIDEJIROUTAKEUCHI SEIJIKAMO YUUICHITAMURA KOUKI
    • H01M8/04
    • H01M8/04223
    • PURPOSE:To obtain a fuel cell generator with stable cell performance by suppressing the cathode potential and preventing the growth of platinum grains on the cathode when the operation of the fuel cell is interrupted or stopped. CONSTITUTION:During the cell operation, methanol is fed from a fuel reservoir 15 to a cell proper 1 through a fuel feed valve 16, air is guided by an air blower 17 to the cell proper 1 through an air inlet valve 18, and steam and unreacted air is discharged outside the cell through an air outlet valve 19. When the cell is stopped, the connection of the cell proper 1 and a load circuit 2 is opened by a load switch 20, and in conjunction with it, the air inlet valve 18 and air outlet valve 19 are closed. As a result, the feed of oxygen to an air pole is cut off when the cell operation is stopped, and the potential increase at the air pole can be suppressed. The potential essentially suppressing the reaction at a positive electrode is preferably made 0.9V vs NHE or less.
    • 目的:通过抑制阴极电位并防止燃料电池的运行中断或停止时,阴极上的铂颗粒生长,从而获得具有稳定电池性能的燃料电池发生器。 构成:在电池操作期间,甲醇通过燃料供给阀16从燃料储存器15供给到电池本体1,空气由鼓风机17通过进气阀18引导到电池本体1,蒸汽和 未反应的空气通过排气阀19排出电池外部。当电池停止时,电池本体1和负载电路2的连接由负载开关20打开,并且与其一起,进气阀 18和排气阀19关闭。 结果,当电池操作停止时,将氧气供给到空气极被切断,并且可以抑制气柱的电位增加。 基本上抑制正极的反应的电位优选为0.9V vs NHE以下。
    • 85. 发明专利
    • Fuel element of liquid fuel cell and liquid fuel cell itself
    • 液体燃料电池和液体燃料电池的燃料元件
    • JPS58186170A
    • 1983-10-31
    • JP6741682
    • 1982-04-23
    • Hitachi Ltd
    • HORIBA TATSUOIWAMOTO KAZUOKAWANA HIDEJIROUFUJITA KAZUNORITAMURA KOUKI
    • H01M8/06H01M8/00H01M8/04H01M8/08
    • H01M8/08H01M8/00H01M8/04186
    • PURPOSE: To aim at improvement in the operatability of liquid fuel as well as the promotion of miniaturization and lightness of a cell, by making the liquid fuel turn into a state of non-liquidity through a physical or chemical means.
      CONSTITUTION: In this invention, methanol, formic acid, formalin or hydrazine, etc., are used by way of example, as the liquid fuel to be used, so that these fuel elements may be turned to a state of non-liquidity, there is a method that uses an adsorbent. As the adsorbent, for example, dextrin, dextran, cilica gel, an active carbon, etc., can be used. In addition, there are some chemical methods such that formic acid is converted into sodium formate, hydrazine into hydrazinium sulfate, and methanol into sodium methylate respectively, and furthermore formaldehyde is converted into paraformaldehyde after being polymerized. Doing like this, if a fuel element 1 being turned to a state of non-liquidity is held in a cartridge body 2 and formed into a cartridge type, operation for attaching/detaching the fuel element to/from a fuel cell becomes very simple.
      COPYRIGHT: (C)1983,JPO&Japio
    • 目的:通过物理或化学手段使液体燃料变成非流动性状态,旨在提高液体燃料的可操作性以及促进电池的小型化和轻量化。 构成:在本发明中,甲醇,甲酸,福尔马林或肼等作为例子使用作为所使用的液体燃料,使得这些燃料元件可以转向非流动性状态,那里 是使用吸附剂的方法。 作为吸附剂,可以使用例如糊精,葡聚糖,西葫芦,活性炭等。 另外还有一些化学方法,使甲酸分别转化成甲酸钠,肼转化成硫酸肼,甲醇分别转化为甲醇钠,此外甲醛在聚合后转化为多聚甲醛。 这样做,如果将燃料元件1变成非流动性状态被保持在盒体2中并形成为盒式,则将燃料元件附接/从燃料电池拆卸的操作变得非常简单。
    • 86. 发明专利
    • FUEL CELL
    • JPS58165266A
    • 1983-09-30
    • JP4980482
    • 1982-03-26
    • HITACHI LTD
    • FUJITA KAZUNORITAMURA KOUKIKAWANA HIDEJIROUIWAMOTO KAZUOHORIBA TATSUO
    • H01M4/88H01M8/02H01M8/08H01M8/10
    • PURPOSE:To improve the cell performance considerably by bearing water repellent particles and precious metal for performing catalysis on one face of an ion exchange film to integrate the oxidizing agent electrode and the ion exchange film thereby reducing the contact resistance between the ion exchange film and the electrode considerably. CONSTITUTION:Water repellent particles and platinum catalyst are born on one face of an ion exchange film 1 to form an air electrode 4, while dual function catalyst of platinum and ruthenium is born on the other face of the ion exchange film 1 to form a methanol electrode 7, where said air electrode 4 has the water repellent performance to form the three-phase interface thus to improve the performance as the air electrode for a methanol fuel cell considerably. Since no air gap is formed between the ion exchange film 1 and both electrodes 4, 7 the contact resistance is reduced considerably and carbon dioxide produced from the methanol electrode 7 will never be stored resulting in the improvement of the cell performance. Furthermore the independent process for manufacturing the air electrode and the methanol electrode and assembling in the fuel cell is not required, the manufacturing time can be shortened to 1/5. It can be applied on other type cells and similar effect can be achieved.
    • 89. 发明专利
    • LIQUID FUEL CELL
    • JPS57132678A
    • 1982-08-17
    • JP1568581
    • 1981-02-06
    • HITACHI LTD
    • IWAMOTO KAZUOKAWANA HIDEJIROUHORIBA TATSUOTAMURA KOUKI
    • H01M8/02H01M4/86H01M8/08
    • PURPOSE:To provide a compact lightweight liquid fuel cell producing a higher output by a construction wherein a fuel supply port and a carbon dioxide discharge port of the liquid fuel cell are provided at the predetermined place on the electrolyte side of the negative pole containing a ramified substance impregnated with fuel. CONSTITUTION:A liquid fuel cell is formed with a combination of the positive pole 2 made by coating a porous carbon base with a platinum catalyzer and the like; an ion exchange film 1; and a porous carbon base as the negative pole 3 containing a ramified porous substance 10 impregnated with fuel. This liquid fuel cell is provided with an oxidizer supply port 6 and an oxidizer discharge port 7 on its positive pole side 2; and a fuel supply port 8 and a carbon dioxide discharge port 9 on its negative pole side 3. In this case, the fuel supply port 8 and the carbon dioxide discharge port 9 are allowed to contact the surface of the negative pole 3 excluding the surface on its electrolyte side. In addition, liquid fuel 16 in a fuel tank 15 is uniformly supplied to the whole surface of the above mentioned substance 10 to be impregnated with fuel via a main stem 11, a minor main stem 12, a branch 13 and a thin line 14. It is also preferred to use a sintered porous substance less than several tens mu.
    • 90. 发明专利
    • Electrode catalyst for fuel cell and its production
    • 燃料电池用电极催化剂及其生产
    • JPS5768142A
    • 1982-04-26
    • JP14237880
    • 1980-10-14
    • Hitachi Ltd
    • TAKEUCHI SEIJIISHII KENZOUKAHARA TOSHIKIIMAHASHI JINICHITAKEUCHI MASAHITOOKADA HIDEOOKABE SHIGERUMATSUDA SHINPEINAKASHIMA FUMITOHIDA HIROSHITAMURA KOUKI
    • H01M4/90B01J27/20H01M4/86H01M4/88H01M4/92
    • H01M4/8821H01M4/8842H01M4/92H01M4/921H01M2004/8689H01M2300/0005H01M2300/0008
    • PURPOSE: To improve the performance of electrodes and stabilize the same by using an electrode catalyst depositing noble metal element particles on carbon type powder in the intervention of graphite fluoride particles in a non-colonial state.
      CONSTITUTION: A mixed system consisting of a water-alcohol type solvent contg. noble metal ions or complex ions of noble metals, a hydrophilic polymer, carbon type powder and graphite fluoride is heated for about 2W6hr at about 70°C, by which the catalyst is prepd. Noble metal elements are Pt, Pd, Ru, Ir, or a mixture of ≥2 kinds of these, and are compounded at 0.1W50wt% based on the weight of the carbon type powder. The graphite fluoride is compounded at 10W80wt% based on the total amt. of the noble metal elements and the carbon type powder. The carbon type powder is graphite, carbon black, active carbon or a mixture of ≥2 kinds of these. Polyvinyl alcohol or the like is used for the hydrophilic polymer and it is compounded at 0.1W50 based on the weight of the noble metal elements.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:为了提高电极的性能,并通过在非殖民状态的石墨氟化物颗粒介入中使用在碳型粉末上沉积贵金属元素颗粒的电极催化剂使其稳定。 构成:由水 - 醇型溶剂组成的混合体系 贵金属的贵金属离子或复合离子,亲水性聚合物,碳类粉末和氟化石墨在约70℃下加热约2-6小时,由此制备催化剂。 贵金属元素是Pt,Pd,Ru,Ir或这些的> = 2种的混合物,并且以碳粉末的重量计为0.1-50重量%。 氟化石墨基于总量为10-80重量%复合。 的贵金属元素和碳类粉末。 碳类粉末是石墨,炭黑,活性炭或其中> = 2种的混合物。 聚乙烯醇等用于亲水性聚合物,并且基于贵金属元素的重量将其复合为0.1-50。