专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

81. 发明授权

EP1107942B1 VERBESSERTES VERFAHREN ZUR HERSTELLUNG VON HEXAMETHYLENDIAMIN 有权
标题翻译：改进工艺用于生产己二胺
公开(公告)号：EP1107942B1
公开(公告)日：2004-05-12
申请号：EP99944417.7
申请日：1999-08-17
申请人： BASF AKTIENGESELLSCHAFT
发明人： FISCHER, Rolf , BASSLER, Peter , LUYKEN, Hermann , OHLBACH, Frank , MELDER, Johann-Peter , MERGER, Martin , ANSMANN, Andreas , REHFINGER, Alwin , VOIT, Guido
IPC分类号： C07C209/48 , C07C211/12
CPC分类号： C07C209/48 , C07C211/12
摘要： The invention relates to a method for the catalytic hydrogenation of adipodinitrile to hexamethylene diamine at a high temperature and at high pressure in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent. The method is characterised in that a) adipodinitrile is hydrogenated at temperatures of 70 to 220 °C and at pressures of 100 to 400 bar in the presence of catalysts based on elementary iron as the catalytic component, and ammonia as a solvent to produce a mixture containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and high boilers, until the sum of the 6-aminocapronitrile and adipodinitrile concentration is 1 to 50 wt. % in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated out of the hydrogenation discharge; c) hexamethylene diamine is separated out of the remaining mixture; d) 6-aminocapronitrile and adipodinitrile are separated from the high boilers together or separately and e) 6-aminocapronitrile, adipodinitrile or their mixtures are returned to step a).

82. 发明授权

EP1098869B1 VERBESSERTES VERFAHREN ZUR GLEICHZEITIGEN HERSTELLUNG VON 6-AMINOCAPRONITRIL UND HEXAMETHYLENDIAMIN 无效
标题翻译：改进方法的6-氨基己腈和六亚甲基二胺同时生产
公开(公告)号：EP1098869B1
公开(公告)日：2003-10-01
申请号：EP99934555.6
申请日：1999-07-02
申请人： BASF AKTIENGESELLSCHAFT
发明人： LUYKEN, Hermann , OHLBACH, Frank , ANSMANN, Andreas , BASSLER, Peter , FISCHER, Rolf , MELDER, Johann-Peter , MERGER, Martin , REHFINGER, Alwin , VOIT, Guido , ACHHAMMER, Günther
IPC分类号： C07C209/86 , C07C209/48 , C07C253/30 , C07C253/34
CPC分类号： C07C253/30 , C07C209/48 , C07C211/12 , C07C255/24
摘要： The invention relates to a method for simultaneous production of 6-aminocapronitrile and hexamethylenediamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the VIII subgroup thereby obtaining a mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers; b) distillative separation of hexamethylenediamine from the mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and high boilers or c1) distillative separating 6-aminocapronitrile and subsequently d1) distillative separation of adipodinitrile or c2) simultaneous distillative separation of 6-aminocapronitrile and adipodinitrile into separate fractions. The invention is characterized in that temperatures in the bottoms of the column in steps d1) or c2) are under 185 °C. The adipodinitrile thus obtained contains less impurities than for instance 1-amino-2-cyanocyclopentenes.

83. 发明授权

EP0801647B1 VERFAHREN ZUR GLEICHZEITIGEN HERSTELLUNG VON CAPROLACTAM UND HEXAMETHYLENDIAMIN 失效
标题翻译：程序己内酰胺和己二胺的同时生产
公开(公告)号：EP0801647B1
公开(公告)日：2003-06-04
申请号：EP95942198.3
申请日：1995-12-22
申请人： BASF AKTIENGESELLSCHAFT
发明人： ACHHAMMER, Günther , BASSLER, Peter , FISCHER, Rolf , FUCHS, Eberhard , LUYKEN, Hermann , SCHNURR, Werner , WITZEL, Tom
IPC分类号： C07D223/10 , C07C211/12 , C07C209/48
CPC分类号： C07C209/48 , C07D201/08
摘要： The invention concerns the simultaneous preparation of caprolactam and hexamethylene diamine from adipodinitrile, by the following steps: (a) the adipodinitrile is partially hydrogenated, producing a mixture substantially containing 6-aminocapronitrile, hexamethylene diamine, ammonia, adipodinitrile and hexamethylene imine (= 'the mixture'); (b) the mixture obtained in step (a) is distilled, producing ammonia, as the forerunnings, and a residue I, in the presence of a compound A which is inert in the distillation conditions, the ammonia not being separated totally; (c) the residue I, substantially containing 'the mixture', inert compound A and ammonia, the ammonia content being less than that of the mixture used in step (b), is subjected to a second distillation, producing a mixture of the inert compound A and ammonia, as the forerunnings, and a residue II; (d) the base II, substantially containing 'the mixture' and inert compound A, is subjected to distillation in a third column, producing the inert compound A, as the forerunnings, and a residue III; (e) the base III, substantially containing 'the mixture' and optionally an inert compound B, is subjected to distillation in a fourth column, producing forerunnings KP1, which substantially contain hexamethylene imine, optionally inert compound B and hexamethylene diamine, and a residue IV; (f) the forerunnings KP1 are subjected in a fifth column to distillation, producing forerunnings KP2, which substantially contain hexamethylene imine and optionally inert compound B, and a residue V, which substantially contains hexamethylene diamine with a degree of purity of at least 95 %, the forerunnings KP2 being fed to the third column or optionally only partially fed to the third column, and the rest being discarded; and (g) the residue IV, substantially containing 6-aminocapronitrile and adipodinitrile, is subjected in a sixth column to distillation, producing 6-aminocapronitrile with a degree of purity of at least 95 %, as forerunnings, and adiponitrile in the residue. The resultant 6-aminocapronitrile is cyclized to form caprolactam.

84. 发明公开

EP1280846A1 VERFAHREN ZUR HERSTELLUNG EINES POLYMERS UNTER VERWENDUNG VON CA-PROLACTAM 审中-公开
标题翻译：工艺提供使用己内酰胺聚合物
公开(公告)号：EP1280846A1
公开(公告)日：2003-02-05
申请号：EP01943299.6
申请日：2001-04-30
申请人： BASF AKTIENGESELLSCHAFT
发明人： OHLBACH, Frank , WINTERLING, Helmut , ANSMANN, Andreas , FISCHER, Rolf-Harmuth , MELDER, Johann-Peter , MAIXNER, Stefan , BASSLER, Peter , LUYKEN, Hermann
IPC分类号： C08G69/14 , C08G69/16
CPC分类号： C08G69/14 , C08G69/04 , C08G69/16 , Y10T428/29 , Y10T428/2969 , Y10T428/2971
摘要： The invention relates to a method for producing a polymer. Said method is characterized as follows: a) a mixture (I) containing 6-aminocapronitrile and water is converted into a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst; then b) the ammonia is removed from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers; subsequently c) the water is completely or partially eliminated from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers; and finally d) mixture (IV) is subjected to a polymerization reaction. The invention also relates to a polymer obtained according to said method, to its use in the production of fibres, flat material and moulded bodies that are obtained using a polymer of this type.

85. 发明公开

EP1198491A1 VERFAHREN ZUR HERSTELLUNG VON POLYAMIDEN AUS DINITRILEN UND DIAMINEN 有权
标题翻译：用于生产聚酰胺从二腈和二胺
公开(公告)号：EP1198491A1
公开(公告)日：2002-04-24
申请号：EP00954469.3
申请日：2000-07-11
申请人： BASF AKTIENGESELLSCHAFT
发明人： OHLBACH, Frank , LUYKEN, Hermann
IPC分类号： C08G69/28 , C08G69/00
CPC分类号： C08G69/04 , C08G69/28 , C08G69/38
摘要： A method for producing polyamides from dinitriles and diamines by reacting at least one dinitrile and at least one diamine with water at a temperature of 90-400 °C, at a pressure of 0.1 - 50*106 Pa and with a mol ratio of water to the sum of dinitrile plus diamine of at least 1:1 in the presence of a heterogeneous catalyst selected from the group consisting of aluminium oxide, zinc oxide, silicon oxide, oxides of the second to seventh subgroup of the periodic table, lanthanoid and actinide oxides, phyllosilicates and zeoliths; The invention also relates to polyamides obtained according to said method.

86. 发明授权

EP1017669B1 VERFAHREN ZUR HERSTELLUNG VON ALIPHATISCHEN ALPHA, OMEGA-AMINONITRILEN 无效
标题翻译：用于生产脂肪族α，ω-氨基腈
公开(公告)号：EP1017669B1
公开(公告)日：2002-04-03
申请号：EP98947530.6
申请日：1998-09-08
申请人： BASF AKTIENGESELLSCHAFT
发明人： VOIT, Guido , ANSMANN, Andreas , FISCHER, Rolf, Hartmuth , BASSLER, Peter , LUYKEN, Hermann , MERGER, Martin , FLICK, Klemens
IPC分类号： C07C253/30 , C07C255/24 , B01J23/745
CPC分类号： B01J23/745 , C07C253/30 , C07C255/24

87. 发明授权

EP0963369B1 VERFAHREN ZUR ABTRENNUNG VON 6-AMINOCAPRONITRIL AUS MISCHUNGEN, DIE 6-AMINOCAPRONITRIL UND EIN IMIN ENTHALTEN 失效
标题翻译：方法对混合物6-氨基己腈和最小（MIN）CONTAIN SEPARATING 6-氨基己腈
公开(公告)号：EP0963369B1
公开(公告)日：2001-09-05
申请号：EP98904088.6
申请日：1998-01-17
申请人： BASF AKTIENGESELLSCHAFT
发明人： BASSLER, Peter , LUYKEN, Hermann , REHFINGER, Alwin , RUST, Harald
IPC分类号： C07C253/34 , C07C255/24
CPC分类号： C07C253/34 , C07C255/24
摘要： The invention relates to a method for separating 6-aminocapronitrile from mixtures (I) containing 6-aminocapronitrile and an imine (II) by distillation. Said method is characterized in that distillation occurs in the presence of carbon dioxide.

88. 发明公开

EP1071653A1 KATALYSATOR AUF DER BASIS VON EISEN ZUR HYDRIERUNG VON ALPHA, OMEGA-DINITRILEN 有权
标题翻译：催化剂基于铁加氢α，ω-二腈
公开(公告)号：EP1071653A1
公开(公告)日：2001-01-31
申请号：EP99908940.2
申请日：1999-02-23
申请人： BASF AKTIENGESELLSCHAFT
发明人： VOIT, Guido , FISCHER, Rolf , BASSLER, Peter , ANSMANN, Andreas , LUYKEN, Hermann , MERGER, Martin , OHLBACH, Frank , REHFINGER, Alwin
IPC分类号： C07C209/48 , B01J23/78 , B01J23/889
CPC分类号： C07C253/30 , B01J23/8892 , C07C209/48 , C07C211/12 , C07C255/24
摘要： The invention relates to a substance which is suitable for use as a catalyst, containing a) iron or a compound based on iron or mixtures thereof, b) 0.001 to 0.3 wt. % in relation to a) of a promoter based on 2, 3, 4 or 5 elements from the following group: aluminium, silicon, zirconium, titanium and vanadium, c) 0 to 0.3 wt. % in relation to a) of a compound based on an alkaline and/or alkaline earth metal and d) 0.001 to 1 wt. % in relation to a) of manganese. The inventive substances can be used as catalysts for the hydrogenation of alpha-, omega-dinitriles.

89. 发明公开

EP1058677A2 VERFAHREN ZUR HYDRIERUNG VON ALIPHATISCHEN ALPHA, OMEGA-DINITRILEN 有权
标题翻译： PROCESS加氢脂肪族α，ω-二腈
公开(公告)号：EP1058677A2
公开(公告)日：2000-12-13
申请号：EP99915533.6
申请日：1999-02-23
申请人： BASF AKTIENGESELLSCHAFT
发明人： VOIT, Guido , OHLBACH, Frank , LUYKEN, Hermann , MERGER, Martin , REHFINGER, Alwin , FISCHER, Rolf, Hartmuth , BASSLER, Peter , ANSMANN, Andreas
IPC分类号： C07C209/00
CPC分类号： C07C253/30 , B01J23/02 , B01J23/78 , C07C209/48 , C07C211/12 , C07C255/24
摘要： The invention relates to a method for hydrogenating aliphatic alpha-, omega-dinitriles in the presence of a heterogeneous fixed-bed catalyst. The method is characterised in that the reaction mixture contains 2 νmol to 30 mmol Na, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, in relation to 10 mol of the aliphatic alpha-, omega-dinitrile used.

90. 发明公开

EP0961767A1 VERFAHREN ZUR GEWINNUNG VON HEXAMETHYLENDIAMIN AUS HEXAMETHYLENDIAMIN ENTHALTENDEN MISCHUNGEN 失效
标题翻译：一种获得二胺关己二胺含混合工
公开(公告)号：EP0961767A1
公开(公告)日：1999-12-08
申请号：EP98908025.0
申请日：1998-01-30
申请人： BASF AKTIENGESELLSCHAFT
发明人： BASSLER, Peter , FISCHER, Rolf , LUYKEN, Hermann , REHFINGER, Alwin , VOIT, Guido
IPC分类号： C07C209 , C07C211
CPC分类号： C07C209/84 , Y10S203/20 , C07C211/12
摘要： The invention relates to a method for obtaining hexamethylene diamine (I) from a mixture (II) containing (I) hexamethylene diamine, (III) hexamethylenimine, (IV) a compound selected from the group consisting of 2-aminomethyl cyclopentylamine and 1,2-diaminocyclohexane, (V) an imine, and (VI) adipodinitrile and 6-aminocaproic acid nitrile. According to said method, (a) a mixture (II) is subjected to distillation, yielding (a1) a low-boiling fraction which essentially contains (III), (a2) a medium-boiling fraction (VII) containing (I), (IV) and (V), and (a3) a high-boiling fraction containing (V) and (VI); (b) a mixture (VII) is subjected to distillation, yielding (b1) an overhead which essentially contains (IV) and (b2) a mixture (VIII) containing (I) and (V) as bottom residue; and (c) a mixture (VIII) is subjected to distillation, yielding (c1) (I) as overhead and (c2) a bottom residue which contains the essential part of (V).

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式