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71. 发明授权

US07297557B2 Method for chemically bonding Langmuir-Blodgett films to substrates 失效
标题翻译：将Langmuir-Blodgett膜化学键合到底物上的方法
公开(公告)号：US07297557B2
公开(公告)日：2007-11-20
申请号：US10880482
申请日：2004-06-30
申请人： Sean X. Zhang , Zhang-lin Zhou , Yong Chen
发明人： Sean X. Zhang , Zhang-lin Zhou , Yong Chen
IPC分类号： H01L21/00 , H01L21/31 , C12Q1/70
CPC分类号： H01L51/0075 , B05D1/202 , B82Y10/00 , G11C2213/77 , H01L27/285 , H01L51/0013 , H01L51/0024 , H01L51/0595 , Y10S977/708
摘要： A method of attaching a molecular layer to a substrate includes attaching a temporary protecting group(s) to a molecule having a molecular switching moiety with first and second connecting groups attached to opposed ends thereof. The temporary protecting group(s) is attached to the first and/or second connecting group so as to cause the opposed ends of the switching moiety to exhibit a difference in hydrophilicity such that one of the ends remains at at least one of a water/solvent interface and a water/air interface, and the other end remains in air during a Langmuir-Blodgett (LB) process. An LB film is formed on the interface. The temporary protecting group(s) is removed. The substrate is passed through the LB film to form the molecular layer chemically bonded on the substrate. The difference in hydrophilicity between the opposed ends causes formation of a substantially well-oriented, uniform LB film at the interface.
摘要翻译：将分子层连接到基底上的方法包括将临时保护基与具有分子切换部分的分子连接，第一和第二连接基团连接到其相对端。临时保护基团连接到第一和/或第二连接基团，以使开关部分的相对端部呈现亲水性差异，使得其中一个端部残留在水/ 溶剂界面和水/空气界面，另一端在Langmuir-Blodgett（LB）过程中保留在空气中。在界面上形成LB膜。临时保护组被删除。使衬底通过LB膜以形成化学键合在衬底上的分子层。在相对端之间的亲水性差异导致在界面处形成基本上良好取向的均匀的LB膜。

72. 发明申请

US20060051761A1 Organic ultrathin film, cumulate thereof and process for producing the same 审中-公开
标题翻译：有机超薄膜，其累积物及其制造方法
公开(公告)号：US20060051761A1
公开(公告)日：2006-03-09
申请号：US10527218
申请日：2003-09-09
申请人： Kuniharu Ijiro , Jin Matsumoto , Masatsugu Shimomura
发明人： Kuniharu Ijiro , Jin Matsumoto , Masatsugu Shimomura
IPC分类号： C12Q1/68 , C12M1/34 , C07H21/04
CPC分类号： G03C1/731 , B05D1/202 , B82Y30/00 , B82Y40/00 , G11B7/244
摘要： A novel organic ultrathin membrane characterized in that an amphiphilic compound having a pigment group and a nucleic acid base is aligned due to base-pairing with an oligonucleotide which is capable of forming a base pair with the nucleic acid base to thereby constitute a monolayer is provided. In this organic ultrathin membrane, free space is provided around a pigment molecule so as to enable photoisomerization of the pigment molecule in a high-density solid state. Thus, it is useful as an optical memory, etc. Further, a process for producing the organic ultrathin membrane is provided.
摘要翻译：一种新型有机超薄膜，其特征在于，具有颜料基团和核酸碱基的两亲性化合物由于与能与核酸碱基形成碱基对从而构成单层的寡核苷酸进行碱基配对而配对。在该有机超薄膜中，在颜料分子的周围设置自由空间，以使颜料分子以高密度固态进行光异构化。因此，作为光学存储器等是有用的。此外，提供了制造有机超薄膜的方法。

73. 发明申请

US20060003265A1 Molecular layer and method of forming the same 失效
标题翻译：分子层及其形成方法
公开(公告)号：US20060003265A1
公开(公告)日：2006-01-05
申请号：US10881150
申请日：2004-06-30
申请人： Sean Zhang , Yong Chen
发明人： Sean Zhang , Yong Chen
IPC分类号： G03C5/00
CPC分类号： H01L51/0595 , B05D1/202 , B82Y10/00 , G11C13/0014 , G11C13/0016 , H01L27/285 , H01L51/0075 , Y10T428/26 , Y10T428/31504 , Y10T428/31938
摘要： A molecular layer includes a Langmuir-Blodgett (LB) film of a molecule connected to a plurality of active device molecules, the molecule having a moiety with first and second connecting groups at opposed ends of the moiety. Each of the plurality of active device molecules includes a switching moiety, a self-assembling connecting group at one end of the switching moiety, and a linking group at an opposed end of the moiety. One or more defect site(s) exist between the plurality of active device molecules. A respective number of the first connecting groups of the LB film are connected to the plurality of active device molecules via at least some of the linking groups such that the LB film covers the plurality of active device molecules and the one or more defect site(s).
摘要翻译：分子层包括连接到多个活性器件分子的分子的Langmuir-Blodgett（LB）膜，该分子具有在该部分的相对端具有第一和第二连接基团的部分。多个有源器件分子中的每一个包括切换部分，在开关部分的一端的自组装连接基团和该部分的相对端的连接基团。在多个有源器件分子之间存在一个或多个缺陷位点。 LB膜的相应数量的第一连接基团经由至少一些连接基团连接到多个有源器件分子，使得LB膜覆盖多个有源器件分子和一个或多个缺陷部位）。

74. 发明授权

US06899947B2 Nanoparticle arrays and sensors using same 失效
标题翻译：纳米颗粒阵列和传感器使用相同
公开(公告)号：US06899947B2
公开(公告)日：2005-05-31
申请号：US10218185
申请日：2002-08-12
申请人： Alexander Wei , Beomseok Kim
发明人： Alexander Wei , Beomseok Kim
IPC分类号： B05D1/20 , G01N33/00 , G01N33/543 , G01N33/553 , G01N33/58 , B05D7/00 , B32B5/16
CPC分类号： B82Y15/00 , B05D1/202 , G01N33/0047 , G01N33/54393 , G01N33/553 , G01N33/588 , Y10T428/25 , Y10T428/256 , Y10T428/2982 , Y10T428/2989 , Y10T428/2991
摘要： A method for enhancing the dispersibility of calixarene-stabilized nanoparticles, which can be assembled into ordered, planar arrays of monoparticulate thickness, ring-like assemblies of discrete particle count, and other configurations.
摘要翻译：一种用于提高杯芳烃稳定的纳米颗粒的分散性的方法，其可以组装成单颗粒厚度的有序的平面阵列，离散粒子数的环状组件和其它构型。

75. 发明授权

US06319738B1 Two-dimensionally arrayed quantum device fabrication method 失效
标题翻译：二维阵列量子器件制造方法
公开(公告)号：US06319738B1
公开(公告)日：2001-11-20
申请号：US09577138
申请日：2000-05-24
申请人： Ichiro Yamashita
发明人： Ichiro Yamashita
IPC分类号： H01L2100
CPC分类号： H01L49/006 , B05D1/202 , B82Y10/00 , B82Y30/00 , B82Y40/00 , G11C2216/08 , H01L21/2254 , H01L21/3081 , H01L21/3086 , H01L21/76838 , H01L21/8222 , H01L27/156 , H01L29/66136 , H01L29/7613 , H01L33/06 , H01L33/18 , H01L2924/0002 , Y10S438/939 , Y10S438/945 , Y10S438/947 , Y10S438/962 , H01L2924/00
摘要： A quantum device is constituted from a two-dimensional array of quantum dots formed from metal atom aggregates contained in a metalloprotein complex. The metalloprotein is arranged on the surface of a substrate having an insulation layer with a pitch of the size of the metalloprotein complex. The diameter of the metal atom aggregates used in the quantum device is 7 nm or smaller, and the pitch of the metalloprotein complex is preferably from 11 to 14 nm.
摘要翻译：量子器件由金属蛋白复合物中包含的金属原子聚集体形成的量子点的二维阵列构成。金属蛋白被布置在具有金属蛋白复合物尺寸的间距的绝缘层的基底的表面上。在量子器件中使用的金属原子聚集体的直径为7nm以下，金属蛋白复合体的间距优选为11〜14nm。

76. 发明授权

US06287928B1 Two-dimensionally arrayed quantum device 失效
标题翻译：二维阵列量子器件
公开(公告)号：US06287928B1
公开(公告)日：2001-09-11
申请号：US09617799
申请日：2000-07-17
申请人： Ichiro Yamashita
发明人： Ichiro Yamashita
IPC分类号： H01L2100
CPC分类号： H01L49/006 , B05D1/202 , B82Y10/00 , B82Y30/00 , B82Y40/00 , G11C2216/08 , H01L21/2254 , H01L21/3081 , H01L21/3086 , H01L21/76838 , H01L21/8222 , H01L27/156 , H01L29/66136 , H01L29/7613 , H01L33/06 , H01L33/18 , H01L2924/0002 , Y10S438/939 , Y10S438/945 , Y10S438/947 , Y10S438/962 , H01L2924/00
摘要： A quantum device is constituted from a two-dimensional array of quantum dots formed from metal atom aggregates contained in metalloprotein complex. The metalloprotein is arranged on the surface of a substrate having an insulation layer with a pitch of the size of the metalloprotein complex. The diameter of the metal atom aggregates used in the quantum device is 7 nm or smaller, and the pitch of the metalloprotein complex is preferably from 11 to 14 nm.
摘要翻译：量子器件由金属蛋白复合物中包含的金属原子聚集体形成的量子点的二维阵列构成。金属蛋白被布置在具有金属蛋白复合物尺寸的间距的绝缘层的基底的表面上。在量子器件中使用的金属原子聚集体的直径为7nm以下，金属蛋白复合体的间距优选为11〜14nm。

77. 发明授权

US6114031A Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers 失效
标题翻译：成对沉积的半离聚物共聚聚合物的极化膜
公开(公告)号：US6114031A
公开(公告)日：2000-09-05
申请号：US246197
申请日：1999-01-11
申请人： Marion J. Roberts , John D. Stenger-Smith , Kenneth J. Wynne , Peter Zarras , Andrew P. Chafin , Richard A. Hollins , Geoffrey A. Lindsay
发明人： Marion J. Roberts , John D. Stenger-Smith , Kenneth J. Wynne , Peter Zarras , Andrew P. Chafin , Richard A. Hollins , Geoffrey A. Lindsay
IPC分类号： B05D1/20 , G02F1/361
CPC分类号： B82Y30/00 , B05D1/202 , B82Y20/00 , B82Y40/00 , G02F1/3616 , G02F1/3618 , Y10T428/261
摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.
摘要翻译：本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

78. 发明授权

US5684165A Substituted thieno�3,2b!thiophenes and their use 失效
标题翻译：取代噻吩并[3,2b]噻吩及其用途
公开(公告)号：US5684165A
公开(公告)日：1997-11-04
申请号：US423006
申请日：1995-04-14
申请人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Ude Scheunemann , Peter Boldt , Martin Blenkle
发明人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Ude Scheunemann , Peter Boldt , Martin Blenkle
IPC分类号： B05D1/20 , C07D495/04 , G02F1/35 , G02F1/355 , G02F1/361 , G02F1/365 , G02F1/37 , G02B6/02
CPC分类号： C07D495/04 , B05D1/202 , B82Y20/00 , B82Y30/00 , B82Y40/00 , G02F1/3614 , G02F1/3618
摘要： Compounds of the formula I ##STR1## in which R is a C.sub.1 - to C.sub.22 -alkyl radical, A.sup.1 and A.sup.2 are hydrogen or methyl or, A.sup.1 is hydrogen and A.sup.2 is the nitro group, and B is the cyano group, the nitro group or an electron-attracting organic group having a double bond which is in conjugation with the thieno�3,2-b!thiophene ring system, have a high dipole moment and a high polarizability and are suitable for purposes of nonlinear optics. If R in the formula I is a C.sub.12 - to C.sub.22 -alkyl radical, monomolecular layers can be applied to a substrate by the Langmuir-Blodgett method. The resulting layer elements are suitable, inter alia, as waveguides.
摘要翻译：其中R是C 1〜C 22 - 烷基的式I的化合物，A 1和A 2为氢或甲基，或者A 1为氢，A 2为硝基，B为氰基，硝基基团或具有与噻吩并[3,2-b]噻吩环体系共轭的双键的吸电子有机基团具有高偶极矩和高极化性，并且适用于非线性光学的目的。如果式I中的R是C 12 -C 22烷基，则可以通过Langmuir-Blodgett法将单分子层施加到基底上。所得到的层元件尤其适用于波导。

79. 发明授权

US5510200A Films for non-linear optics 失效
标题翻译：非线性光学膜
公开(公告)号：US5510200A
公开(公告)日：1996-04-23
申请号：US70341
申请日：1993-08-30
申请人： Geoffrey J. Ashwell
发明人： Geoffrey J. Ashwell
IPC分类号： B05D1/20 , C09K9/02 , G02F1/35 , G02F1/355 , G02F1/361 , B32B9/04
CPC分类号： B82Y20/00 , B05D1/202 , B82Y30/00 , B82Y40/00 , G02F1/3618 , Y10S428/91 , Y10S428/913 , Y10T428/31504 , Y10T428/31529
摘要： Multi-layer Langmuir-Blodgett films comprising alternate layers of an optically non-linear amphiphilic compound and a spacer compound wherein the spacer comprises at least two hydrophobic substituents, have high second order non-linear optical coefficients, are stable over a prolonged period and quadratic SHG enhancement based on the number of layers. They are useful in a variety of opto-electronic devices.
摘要翻译： PCT No.PCT / GB91 / 02096 Sec。 371日期：1993年8月30日 102（e）日期1993年8月30日PCT 1991年11月27日PCT PCT。出版物WO92 / 09374 日期：1992年6月11日。多层Langmuir-Blodgett膜包含光学非线性两亲性化合物和间隔化合物的交替层，其中间隔物包含至少两个疏水性取代基，具有高二阶非线性光学系数基于层数稳定长期稳定和二次SHG增强。它们在各种光电器件中非常有用。

80. 发明授权

US5270965A Method of driving device having metal-insulator-metal(mim)structure 失效
标题翻译：具有金属 - 绝缘体 - 金属（mim）结构的驱动装置的方法
公开(公告)号：US5270965A
公开(公告)日：1993-12-14
申请号：US58802
申请日：1993-05-10
申请人： Yoshihiro Yanagisawa , Hisaaki Kawade , Kunihiro Sakai , Hiroshi Matsuda , Haruki Kawada , Kiyoshi Takimoto , Yuko Morikawa , Ken Eguchi
发明人： Yoshihiro Yanagisawa , Hisaaki Kawade , Kunihiro Sakai , Hiroshi Matsuda , Haruki Kawada , Kiyoshi Takimoto , Yuko Morikawa , Ken Eguchi
IPC分类号： B05D1/20 , G11C11/56 , G11C13/02 , H01L45/00 , H01L29/28
CPC分类号： G11C13/0019 , B05D1/202 , B82Y10/00 , B82Y30/00 , B82Y40/00 , G11C11/5664 , G11C13/0014 , G11C13/0016
摘要： A method of driving a device having a pair of electrodes and organic insulating layer sandwiched therebetween. The device exhibits at least three states of different electroconductivities in response to an applied voltage. A transition from the first state to the second state is achieved by applying a voltage within a first predetermined range to the device in the first state, and a transition from the second state to the third state is achieved by applying a voltage within a second predetermined range to the device in the second state.
摘要翻译：驱动具有夹在其间的一对电极和有机绝缘层的器件的方法。该装置响应于施加的电压呈现出不同导电性的至少三种状态。通过在第一状态下将电压施加到第一预定范围内的装置来实现从第一状态到第二状态的转变，并且通过在第二状态到第二状态之间施加电压来实现从第二状态到第三状态的转变范围到第二个状态的设备。

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