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    • 72. 发明授权
    • System and method for analyzing a semiconductor surface
    • 用于分析半导体表面的系统和方法
    • US06749715B2
    • 2004-06-15
    • US09864605
    • 2001-05-24
    • Terry L. GiltonTroy R. Sorensen
    • Terry L. GiltonTroy R. Sorensen
    • C23F100
    • G01N1/32G01N35/1095
    • A method and apparatus for analyzing a semiconductor surface obtains a sample from a localized section of a wafer. The sample is obtained by isolating a section of a wafer with a sampling apparatus, dispensing liquid onto the isolated section of the wafer, dissolving compounds of interest in the liquid, removing a portion of the liquid, and analyzing the liquid and dissolved compounds of interest. The liquid can be an etching solution, an organic solvent, or other suitable solvent. Samples and analyses can, thus, be obtained as a function of position on the wafer. Analyses as a function of depth can also be determined by sampling and analyzing an isolated portion of the wafer as a function of time.
    • 用于分析半导体表面的方法和装置从晶片的局部截面获得样品。 样品是通过用采样设备分离晶片的一部分而获得的,将液体分配到晶片的隔离部分上,将感兴趣的化合物溶解在液体中,除去液体的一部分,以及分析感兴趣的液体和溶解的化合物 。 液体可以是蚀刻溶液,有机溶剂或其它合适的溶剂。 因此,可以根据晶片上的位置获得样品和分析。 作为深度的函数的分析也可以通过对晶片的隔离部分进行采样和分析来确定,作为时间的函数。
    • 73. 发明授权
    • Methods of metal doping a chalcogenide material
    • 金属掺杂硫族化物材料的方法
    • US06727192B2
    • 2004-04-27
    • US09797635
    • 2001-03-01
    • John T. MooreTerry L. Gilton
    • John T. MooreTerry L. Gilton
    • H01L21324
    • H01L45/04H01L27/101H01L28/24H01L45/085H01L45/1233H01L45/141H01L45/142H01L45/143H01L45/144H01L45/1658H01L45/1675
    • A method of metal doping a chalcogenide material includes forming a metal over a substrate. A chalcogenide material is formed on the metal. Irradiating is conducted through the chalcogenide material to the metal effective to break a chalcogenide bond of the chalcogenide material at an interface of the metal and chalcogenide material and diffuse at least some of the metal outwardly into the chalcogenide material. A method of metal doping a chalcogenide material includes surrounding exposed outer surfaces of a projecting metal mass with chalcogenide material. Irradiating is conducted through the chalcogenide material to the projecting metal mass effective to break a chalcogenide bond of the chalcogenide material at an interface of the projecting metal mass outer surfaces and diffuse at least some of the projecting metal mass outwardly into the chalcogenide material. In certain aspects, the above implementations are incorporated in methods of forming non-volatile resistance variable devices. In one implementation, a non-volatile resistance variable device in a highest resistance state for a given ambient temperature and pressure includes a resistance variable chalcogenide material having metal ions diffused therein. Opposing first and second electrodes are received operatively proximate the resistance variable chalcogenide material. At least one of the electrodes has a conductive projection extending into the resistance variable chalcogenide material.
    • 金属掺杂硫族化物材料的方法包括在衬底上形成金属。 在金属上形成硫族化物材料。 通过硫属化物材料对金属进行辐射,有效地在金属和硫族化物材料的界面处破坏硫族化物材料的硫族化物键,并将至少一些金属向外扩散到硫族化物材料中。 金属掺杂硫族化物材料的方法包括用硫族化物材料包围突出的金属块的暴露的外表面。 通过硫族化物材料将辐射照射到突出金属质量块上,有效地在突出的金属质量外表面的界面处破坏硫族化物材料的硫族化物键,并将至少一些突出的金属块向外扩散到硫族化物材料中。 在某些方面,上述实施方式被并入形成非易失性电阻可变器件的方法中。 在一个实施方案中,对于给定的环境温度和压力,最高电阻状态的非易失性电阻可变器件包括在其中扩散有金属离子的电阻变化硫属化物材料。 反向的第一和第二电极在电阻可变硫属化物材料上可操作地接收。 至少一个电极具有延伸到电阻可变硫族化物材料中的导电突起。
    • 77. 发明授权
    • System and method for analyzing a semiconductor surface
    • 用于分析半导体表面的系统和方法
    • US06420275B1
    • 2002-07-16
    • US09386124
    • 1999-08-30
    • Terry L. GiltonTroy R. Sorensen
    • Terry L. GiltonTroy R. Sorensen
    • H01L21302
    • G01N1/32G01N35/1095
    • A method and apparatus for analyzing a semiconductor surface obtains a sample from a localized section of a wafer. The sample is obtained by isolating a section of a wafer with a sampling apparatus, dispensing liquid onto the isolated section of the wafer, dissolving compounds of interest in the liquid, removing a portion of the liquid, and analyzing the liquid and dissolved compounds of interest. The liquid can be an etching solution, an organic solvent, or other suitable solvent. Samples and analyses can, thus, be obtained as a function of position on the wafer. Analyses as a function of depth can also be determined by sampling and analyzing an isolated portion of the wafer as a function of time.
    • 用于分析半导体表面的方法和装置从晶片的局部截面获得样品。 样品是通过用采样设备分离晶片的一部分而获得的,将液体分配到晶片的隔离部分上,将感兴趣的化合物溶解在液体中,除去液体的一部分,以及分析感兴趣的液体和溶解的化合物 。 液体可以是蚀刻溶液,有机溶剂或其它合适的溶剂。 因此,可以根据晶片上的位置获得样品和分析。 作为深度的函数的分析也可以通过对晶片的隔离部分进行采样和分析来确定,作为时间的函数。
    • 79. 发明授权
    • Low temperature rinse of etching agents
    • 低温冲洗蚀刻剂
    • US06194326B1
    • 2001-02-27
    • US09544721
    • 2000-04-06
    • Terry L. Gilton
    • Terry L. Gilton
    • H01L213063
    • H01L21/02063
    • A wafer cleaning process is disclosed for quenching etch reactions while rinsing etch reactants and etch products from the wafer. Holes are etched through an insulating layer by reactive ion etch, for example. The holes might comprise contact openings over a semiconductor substrate, or vias through insulating layers between metal lines. An organic or polymer residue left in the holes is cleaned by a wet process. The cleaning process continues to attack sidewalls of the holes, undesirably widening them. The wafer is therefore rinsed with a rinse agent below 0° C., thermally quenching further etching of the sidewalls and affording greater control over the hole dimensions. At the same time, the rinse agent allows relatively rapid diffusion of etchants and etch products from narrow and deep openings. An exemplary rinse agent for such low temperature rinsing is dilute ethylene glycol (C2H6O2).
    • 公开了用于淬火蚀刻反应同时冲洗蚀刻反应物并从晶片蚀刻产物的晶片清洁工艺。 例如,通过反应离子蚀刻将孔蚀刻通过绝缘层。 这些孔可以包括半导体衬底上的接触开口,或通过金属线之间的绝缘层的通孔。 留在孔中的有机或聚合物残留物通过湿法清洗。 清洁过程继续攻击孔的侧壁,不期望地使它们变宽。 因此,晶片由冲洗剂在0℃以下漂洗,热淬火进一步蚀刻侧壁并提供对孔尺寸的更大控制。 同时,冲洗剂允许蚀刻剂和蚀刻产物从狭窄和深度开口的相对快速的扩散。 用于这种低温冲洗的示例性漂洗剂是稀乙二醇(C 2 H 6 O 2)。