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71. 发明授权

US06500952B1 Processes for preparing aminophenylsulfonylureas, and intermediates therefor 有权
标题翻译：制备氨基苯磺酰脲的方法及其中间体
公开(公告)号：US06500952B1
公开(公告)日：2002-12-31
申请号：US09664201
申请日：2000-09-18
申请人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
发明人： Gerhard Schnabel , Jan Vermehren , Lothar Willms
IPC分类号： C07D23942
CPC分类号： C07D521/00 , A01N47/36 , H01R33/06 , Y02A40/143
摘要： The invention relates to the preparation of compounds (I) in which A=H or acyl and R1, R21, R3, R, n, X, Y and Z are as defined in claim 1 by halogenation and rearrangement of compounds (II) (optionally salt) to give compounds (III) a) ammonolysis of (III) to (IV), reduction of the nitro group and reaction with carbamate (salts) (VI) of the formula Ar—OCO—N(M)—Het, where Ar=phenyl, M=H or cation and Het=heterocycle from formula (I), to give compounds (I) (A=H), or b) ammonolysis of (III) to (IV), reaction with carbamate (salt) (VI) and reduction of resulting compounds (VII) at the NO2 group to give compounds (I) (A=H), or c) reaction of (III) with cyanates and amines (VIII) of the formula HNR3—Het and reduction of the resulting compound (VII) at the NO2 group to give compounds (I) (A=H) and optional acylation if A is to be other than H. Compounds of the formulae (I) (A=H), (III), (IV), (V), (VI) (M=cation) and (VII) are novel.
摘要翻译：本发明涉及化合物（Ⅰ）的制备，其中A = H或酰基，R 1，R 21，R 3，R 4，n，X，Y和Z如权利要求1中所定义，通过卤化和重排化合物任选的盐），得到化合物（III）a）（III）至（IV）的氨解，硝基的还原和与式Ar-OCO-N（M）-Het的氨基甲酸酯（盐）（VI）的反应，其中Ar =苯基，M = H或阳离子和Het =来自式（I）的杂环，得到（III）至（IV）化合物（I）（A = H），orb）氨解，与氨基甲酸酯（VI）和还原所得化合物（VII）在NO 2基团上得到化合物（I）（A = H），orc）（III）与式HNR3-Het的氰酸酯和胺（VIII）的反应，还原所得到的化合物（Ⅶ）在NO2基团上得到化合物（I）（A = H），任选的酰化如果A不为H.式（I）（A = H），（III）（IV），（V），（VI）（M =阳离子）和（VII）是新颖的。

72. 发明授权

US06486096B1 Herbicidal compositions with acylated aminophenylsulfonylureas 有权
标题翻译：具有酰化氨基苯磺酰脲的除草组合物
公开(公告)号：US06486096B1
公开(公告)日：2002-11-26
申请号：US09371355
申请日：1999-08-10
申请人： Erwin Hacker , Hermann Bieringer , Gerhard Schnabel
发明人： Erwin Hacker , Hermann Bieringer , Gerhard Schnabel
IPC分类号： A01N4364
CPC分类号： A01N47/36 , A01N57/20 , A01N57/14 , A01N47/06 , A01N43/90 , A01N43/82 , A01N43/76 , A01N43/70 , A01N43/50 , A01N43/40 , A01N43/10 , A01N41/10 , A01N39/02 , A01N37/40 , A01N37/26 , A01N37/22 , A01N35/10 , A01N33/18 , A01N43/80 , A01N2300/00
摘要： Herbicide combinations which contain components (A) and (B) have synergistic herbicidal effects on: (A) one or more herbicides of the formula (I) or their salts, in which R1, R2, R3, X, Y and Z are defined as in claim 1, and (B) one or more herbicides from the group of the compounds consisting of (B1) foliar- and soil-acting herbicides which are effective selectively in cereals and some dicotyledonous crops against monocotyledonous and dicotyledonous harmful plants, (B2) herbicides which are effective selectively in cereals and some dicotyledonous crops against predominantly dicotyledonous harmful plants and (B3) herbicides which are to be employed nonselectively or in specifically tolerant crops and are effective against monocotyledonous and dicotyledonous harmful plants.
摘要翻译：含有组分（A）和（B）的除草剂组合对以下物质具有协同的除草效果：（A）一种或多种式（I）的除草剂或其盐，其中R1，R2，R3，X，Y和Z被定义（B）一种或多种由（B1）叶面和土壤作用除草剂组成的化合物组中的一种或多种除草剂，其在谷物中有效选择性，并且一些双子叶作物对抗单子叶和双子叶植物有害植物（B2 ）除草剂，其在谷物和一些双子叶植物中有效选择性地主要是双子叶有害植物和（B3）除草剂，其被选择性地或特异性耐受性作物，并且对单子叶和双子叶植物有害植物有效。

73. 发明授权

US06410482B1 (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators 失效
标题翻译：（Het）芳基磺酰脲具有氨基功能，它们的表现及其作为除草剂和植物生长调节剂的用途
公开(公告)号：US06410482B1
公开(公告)日：2002-06-25
申请号：US08855251
申请日：1997-05-13
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： C07D40112
CPC分类号： C07D521/00 , A01N47/36 , C07C311/46
摘要： (Het)Arylsulfonylureas having an imino function, their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which A is a (hetero)aromatic or heterocyclic bridge linked to the group SO2 by a direct bond, or via O, S, NH, CH2 or via alkylated NH or alkylated methylene, B is a group having an imino-containing fragment N═C—N, N═C—S, N═C—O or N═C—C which is linked to A by one of the nitrogen atoms of the fragment, R═H or an aliphatic radical, W═O or S and X, Y and Z are as defined in claim 1 are suitable as herbicides and plant growth regulators. The preparation is carried out for example similarly to known processes via novel intermediates of the formula (XII) (cf. claims 6 and 10),
摘要翻译：（Het）具有亚氨基功能的芳基磺酰脲，它们的制备及其作为除草剂和植物生长调节剂的用途式（I）化合物及其盐，其中A是通过直接连接到基团SO 2上的（杂）芳族或杂环桥或通过O，S，NH，CH 2或通过烷基化NH或烷基化亚甲基，B是具有亚氨基的片段N = CN，N = CS，N = CO或N = CC的基团，其通过所述片段的氮原子之一R = H或脂族基，W = O或S和X，Y和Z如权利要求1中所定义，适合作为除草剂和植物生长调节剂。通过式（XII）的新型中间体（参见权利要求6和10）类似于已知方法进行制备，

74. 发明授权

US5861357A 5-acylamino-2-alkoxycarbonylphenylsulfonylureas as selective herbicides 失效
标题翻译：作为选择性除草剂的5-酰基氨基-2-烷氧基羰基苯基磺酰脲
公开(公告)号：US5861357A
公开(公告)日：1999-01-19
申请号：US757372
申请日：1996-11-27
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer , Christopher Rosinger
IPC分类号： A01N47/36 , C07D521/00 , A01N43/20 , A01N43/54 , A01N43/66
CPC分类号： C07D521/00 , A01N47/36
摘要： Compounds of the formula (I) ##STR1## in which R.sup.1 to R.sup.5, X, W, n and Z are defined as in claim 1 are particularly suitable for use as selective herbicides in crops of useful plants.
摘要翻译：其中R1至R5，X，W，n和Z如权利要求1中所定义的式（I）化合物（I）特别适合用作有用植物作物中的选择性除草剂。

75. 发明授权

US5658854A Acylated aminophenylsulfonylureas; preparation and use as herbicides and plant growth regulators 失效
标题翻译：酰化氨基苯基磺酰脲作为除草剂和植物生长调节剂的制备和使用
公开(公告)号：US5658854A
公开(公告)日：1997-08-19
申请号：US268274
申请日：1994-06-30
申请人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
发明人： Gerhard Schnabel , Lothar Willms , Klaus Bauer , Hermann Bieringer
IPC分类号： C07D239/42 , A01N47/36 , A01N47/46 , A01P13/02 , C07C309/89 , C07C311/39 , C07C311/65 , C07D239/47 , C07D239/48 , C07D251/44 , C07D251/46 , C07D251/48 , C07D251/52 , C07D521/00 , C07D239/69 , A01N43/54
CPC分类号： C07D521/00 , A01N47/36 , C07C309/89 , C07C311/39 , C07C311/65
摘要： Acylated aminophenylureas, preparation and use as herbicides and plant growth regulatorsThe compounds of the formula I or their salts ##STR1## in which G is a radical G1, G2 or G3 ##STR2## R.sup.1 is H or alkyl, R.sup.2 is COOH, CSOH or a derivative of the carboxyl or thiocarboxyl group, of 1 to 20 carbon atoms, or acyl of the type CO-R.degree. of 1-12 carbon atoms, or an imino, hydrazone or oxime derivative of the group CO-R.degree., and R.degree. , R.sup.3a, R.sup.4a, R.sup.3b, R.sup.4b, W, X, Y and Z are as defined in claim 1, are suitable as selective herbicides and plant growth regulators in crops.The preparation is carried out in analogy to known processes (see claim 5) by way of intermediates, some of which are new, from the group consisting of benzene-sulfonamides (II), benzenesulfonyl isocyanates (IV) and benzesulfonyl chlorides (VI) and heterocyclically substituted carbamates (III), amines (V) and/or (thio)-isocyanates (XIX).
摘要翻译：酰化氨基苯基脲，作为除草剂和植物生长调节剂的制备和用途式I化合物或其盐，其中G是基团G1，G2或G3（G1）（图像）（G2）（G3）R1为H或烷基，R2为COOH，CSOH或含1-20个碳原子的羧基或硫代羧基的衍生物，或碳原子数为1〜12的CO-R DEG型酰基，或CO-R DEG基团的亚氨基，腙或肟衍生物，R DEG，R3a，R4a，R3b，R4b，W，X，Y和Z如权利要求1所定义，适合作为选择性除草剂和植物生长农作物的监管者。类似于已知方法（参见权利要求5），通过中间体（其中一些是新的），由苯磺酰胺（II），苯磺酰基异氰酸酯（IV）和苯磺酰氯（VI）和苯磺酰基异氰酸酯杂环取代的氨基甲酸酯（III），胺（V）和/或（硫代） - 异氰酸酯（XIX）。

76. 发明授权

US10159246B2 Copolymers of N-vinylcarboxamide and diallyldialkylammonium salt as dispersant for agrochemical formulations 有权
公开(公告)号：US10159246B2
公开(公告)日：2018-12-25
申请号：US14122469
申请日：2012-05-24
申请人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
发明人： Gerhard Schnabel , Ruth Wirschem , Paul Klingelhoefer , Lucelena Patricio Cardoso
IPC分类号： A01N25/10 , A01N43/56 , C05G3/02 , A01N25/04 , A01N25/30 , A01N47/24
摘要： The present invention relates to a composition comprising an agrochemical active substance and a copolymer which comprises an N-vinylcarboxamide and a diallyldialkylammonium salt incorporated into the polymer. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.

77. 发明授权

US09814233B2 Composition comprising a pesticide, a surfactant and an alkoxylate of 2-propyheptylamine 有权
公开(公告)号：US09814233B2
公开(公告)日：2017-11-14
申请号：US14001611
申请日：2012-02-27
申请人： Gerhard Schnabel , Paul Klingelhoefer , Marc Nolte , Richard Roger Evans , Gerd Kraemer , Silke Zeyer , Matthias Pfenning
发明人： Gerhard Schnabel , Paul Klingelhoefer , Marc Nolte , Richard Roger Evans , Gerd Kraemer , Silke Zeyer , Matthias Pfenning
IPC分类号： A01N33/08 , A01N25/30 , C07C217/08
CPC分类号： A01N33/08 , A01N25/30 , C07C217/08 , A01N57/20
摘要： The present invention relates to a composition comprising a pesticide, a surfactant and an alkoxylate. Moreover, the invention relates to a concentrate comprising the surfactant and the alkoxylate; and to a process for preparing the composition by bringing into contact the concentrate and a pesticide; or by bringing into contact the pesticide, the surfactant and the alkoxylate; and to the use of the surfactant by addition to a mixture comprising the pesticide and the alkoxylate. The invention furthermore relates to a method of controlling phytopathogenic fungi and/or undesired vegetation and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the plants to be protected from the respective pest, on the soil and/or on undesirable plants and/or the crop plants and/or their environment. Furthermore, the invention relates to seed comprising the composition.

78. 发明授权

US09585382B2 Composition comprising a pesticide and an acetal solvent 有权
标题翻译：包含农药和缩醛溶剂的组合物
公开(公告)号：US09585382B2
公开(公告)日：2017-03-07
申请号：US13457789
申请日：2012-04-27
申请人： Paul Klingelhoefer , Gerhard Schnabel , Ralf Pelzer , Wolfgang Spiegler
发明人： Paul Klingelhoefer , Gerhard Schnabel , Ralf Pelzer , Wolfgang Spiegler
IPC分类号： A01N25/02 , A01N43/40 , A01N43/42 , A01N43/84 , A01N47/24 , A01N31/16
CPC分类号： A01N25/02 , A01N31/16 , A01N43/40 , A01N43/42 , A01N43/84 , A01N47/24 , A01N2300/00
摘要： The present invention relates to an agrochemical composition comprising a pesticide and a solvent of the formula (B) as described hereinbelow. The invention furthermore relates to a process for the preparation of the composition by bringing the pesticide and the solvent into contact; a use of the solvent of the formula (B) as a solvent for pesticides; methods for controlling phytopathogenic fungi and/or undesired vegetation and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or on the plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and on seed comprising the composition.
摘要翻译：本发明涉及包含如下所述的农药和式（B）的溶剂的农药组合物。本发明还涉及通过使农药和溶剂接触来制备组合物的方法; 使用式（B）的溶剂作为农药的溶剂; 用于控制植物病原真菌和/或不期望的植物和/或不期望的昆虫或螨攻击和/或调节植物生长的方法，其中允许组合物作用于相应的害虫，其环境或待保护的植物上相关害虫，土壤和/或不期望的植物和/或作物植物和/或其环境上的害虫; 和包含组合物的种子。

79. 发明授权

US09198412B2 Method for enhancing the performance of a pesticide with guanidines 有权
标题翻译：用于提高具有胍的农药性能的方法
公开(公告)号：US09198412B2
公开(公告)日：2015-12-01
申请号：US14115222
申请日：2012-04-25
申请人： Gerhard Schnabel , Marc Nolte , Mariano Ignacio Etcheverry , Gerhard Genari , Thomas Kroehl , Matthias Bratz , Terrance Cannan , Steven Bowe , Chad Brommer , John Frihauf , Charles W. Finch , Walter Thomas
发明人： Gerhard Schnabel , Marc Nolte , Mariano Ignacio Etcheverry , Gerhard Genari , Thomas Kroehl , Matthias Bratz , Terrance Cannan , Steven Bowe , Chad Brommer , John Frihauf , Charles W. Finch , Walter Thomas
IPC分类号： A01N25/00 , A01N25/22 , A01N25/30 , A01N37/40 , A01N47/44
CPC分类号： A01N25/00 , A01N25/30 , A01N47/44 , A01N37/10 , A01N37/40 , A01N37/44 , A01N39/02 , A01N39/04 , A01N43/40 , A01N43/42 , A01N43/78 , A01N2300/00
摘要： The present invention relates to a method for enhancing the performance of a pesticide comprising the step of contacting an adjuvant and the pesticide, wherein the pesticide is present in a concentration of less than 10 wt % in the resulting composition containing the adjuvant and the pesticide, and wherein the adjuvant contains a guanidine of formula (A) as defined below, and/or a salt thereof. The invention also relates to a composition comprising an auxin-herbicide and said adjuvant; to a use of said adjuvant for enhancing the performance of a pesticide; and to a method of controlling undesired vegetation, which comprises allowing a herbicidal effective amount of said composition to act on plants, their habitat or on seed of said plants.
摘要翻译：本发明涉及一种提高农药性能的方法，包括使佐剂和农药接触的步骤，其中农药在含有佐剂和农药的组合物中的浓度小于10重量％并且其中所述佐剂含有如下定义的式（A）的胍和/或其盐。本发明还涉及包含生长素 - 除草剂和所述佐剂的组合物; 使用所述佐剂来提高农药的性能; 以及控制不希望的植物的方法，其包括允许除草有效量的所述组合物作用于植物，其栖息地或所述植物的种子上。

80. 发明申请

US20130165321A1 FORMULATIONS AND THEIR USE 审中-公开
标题翻译：制剂及其使用
公开(公告)号：US20130165321A1
公开(公告)日：2013-06-27
申请号：US13720035
申请日：2012-12-19
申请人： Stephan HUEFFER , Alejandra Garcia Marcos , Paul Klingelhoefer , Gerhard Schnabel
发明人： Stephan HUEFFER , Alejandra Garcia Marcos , Paul Klingelhoefer , Gerhard Schnabel
IPC分类号： A01N25/22
CPC分类号： A01N25/22 , A01N57/20 , A01N25/08 , A01N37/44 , A01N2300/00
摘要： The use of formulations comprising (A) one or more aminocarboxylates, selected from among methylglycine diacetate (MGDA) and its alkali metal salts, glutamic acid diacetate (GLDA) and its alkali metal salts, iminodisuccinate, hydroxyethylimine diacetate and ethyleneiminodisuccinate and the corresponding alkali metal salts, (B) at least one organic compound selected from among organic phosphates, organic phosphonates and organic phosphites and salts of the abovementioned organic compounds, and (C) optionally water, for application to plants or the ground.
摘要翻译：使用包含（A）一种或多种选自甲基甘氨酸二乙酸酯（MGDA）及其碱金属盐，谷氨酸二乙酸酯（GLDA）及其碱金属盐，亚氨基二琥珀酸盐，羟乙基亚氨基二乙酸酯和亚乙基亚氨基丁二酸氢盐的氨基羧酸盐和相应的碱金属盐，（B）选自有机磷酸盐，有机膦酸盐和有机亚磷酸盐的至少一种有机化合物和上述有机化合物的盐，和（C）任选的水，用于植物或地面。

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