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71. 发明专利

JP2000080283A FLAME-RETARDANT RESIN COMPOSITION 失效
公开(公告)号：JP2000080283A
公开(公告)日：2000-03-21
申请号：JP24823898
申请日：1998-09-02
申请人： TEIJIN CHEMICALS LTD
发明人： YAMANAKA KATSUHIRO , TAKEYA YUTAKA
IPC分类号： C09K21/08 , C08K5/527 , C08L69/00 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To obtain a flame-retardant resin composition having high flame retardance and capable of achieving excellent appearance of the resin surface on burning by including a thermoplastic resin and a specific phosphor-containing flame retarding agent and a fluorine resin. SOLUTION: This composition is obtained by including (A) 100 pts.wt. of a thermoplastic resin (ex. a polycarbonate resin), (B) 0.5-50 pts.wt. of a phosphor- containing flame retarding agent consisting of (i) a fluid gel obtained by reacting a metal alkoxide of the formula: M(OR)n [(n) is 3-6; R is a 1-10C aliphatic hydrocarbon; M is a metal such as Al, Ti, Si or B] and (ii) a cyclic phosphoric acid ester of the formula (R1 and R2 are each H or a 5-14C aromatic group having a 1-9C organic substituent) and (C) 0.01-5 pts.wt. of a fluorine resin. As the component (i), a product obtained by reacting a metal alkoxide of the formula: M(OR)n in the presence of an acidic or basic catalyst in a solvent consisting of water and a 1-6C monovalent alcohol at 0-100 deg.C is preferable.

72. 发明专利

JP2000072705A PRODUCTION OF BROMINE COMPOUND 失效
公开(公告)号：JP2000072705A
公开(公告)日：2000-03-07
申请号：JP24681098
申请日：1998-09-01
申请人： TEIJIN CHEMICALS LTD
发明人： TAKEYA YUTAKA , MONRI MASANORI , SHIMIZU YASUHIRO , TANABE SEIICHI , HOSHIMI HARUHISA
IPC分类号： C07C41/22 , C07C43/225 , C07C45/63 , C07C49/577 , C07C49/84 , C07C315/04 , C07C317/20 , C07C317/22 , C07C319/20 , C07C323/18 , C09K21/08
摘要： PROBLEM TO BE SOLVED: To provide a method for industrially producing a bromine compound having an excellent quality as a flame retardant for a plastic. SOLUTION: This method for producing a bromine compound of the formula R3-O-Ar1-Y-Ar2-O-R4 (Ar1 and Ar2 are each an aromatic hydrocarbon group or a saturated alicyclic hydrocarbon group; Y is a group which binds Ar1 with Ar2; R3 and R4 are each a group in which an unsaturated group in R1 or R2 is saturated by bromine atoms) by reacting a compound of the formula R1-O-Ar1- Y-Ar2-O-R2 (R1 and R2 are each a hydrocarbon group which has at least one aliphatic unsaturated group) which has an aliphatic unsaturated bond, with bromine comprises carrying out the reaction in the presence of a solvent inert to the reaction, and removing a substantial amount of the heat of the reaction to the exterior of the reaction system by the heat of vaporization of the solvent or the bromine.

73. 发明专利

JPH11292816A PURIFICATION OF BROMINE COMPOUND 失效
公开(公告)号：JPH11292816A
公开(公告)日：1999-10-26
申请号：JP9734198
申请日：1998-04-09
申请人： TEIJIN CHEMICALS LTD
发明人： TAHIRA YASUHISA , SATO TAKAHIRO , TAKEYA YUTAKA
IPC分类号： C07C41/40 , C07C43/225 , C08K5/06 , C08K5/07 , C08K5/41 , C08L23/00 , C08L25/04 , C08L55/02
摘要： PROBLEM TO BE SOLVED: To obtain the subject high-purity compound excellent in heat stability by adding a bromine compound in melted state, a good solvent and a poor solvent to a solid-liquid mixture comprising the poor solvent and seed crystal and mixing these components. SOLUTION: (A) A bromine compound of the formula [(m), (n), (p) and (q) are each 1-6; Ar and Ar are each a 5-16C aromatic hydrocarbon; Y is methylene or the like; R and R are each a 2-6C saturated hydrocarbon] in melted state [e.g. 2,2-bis [3,5-dibromo-4-(2,3-dibromopropyloxy)]phenyl}propane], (B) a good solvent [a solvent capable of dissolving >=5 wt.% bromine compound at 20 deg.C] (e.g. methylene chloride) and (C) a poor solvent [a solvent incapable of dissolving >=2 wt.% bromine compound at 20 deg.C] (e.g. methanol) are added to (D) a solid-liquid mixture comprising the poor solvent and seed crystal and these components are mixed to provide slurry comprising the good solvent, the poor solvent and bromine compound crystal and containing the crystal in a ratio of 0.01-70 wt.%.

74. 发明专利

JPH11236497A FLAME-RETARDANT RESIN COMPOSITION 失效
公开(公告)号：JPH11236497A
公开(公告)日：1999-08-31
申请号：JP5677598
申请日：1998-03-09
申请人： TEIJIN CHEMICALS LTD
发明人： SATO TAKAHIRO , MUKAI AKIHIRO , TAKEYA YUTAKA
IPC分类号： C08L69/00 , C08K3/26 , C08K3/32 , C08K5/521
摘要： PROBLEM TO BE SOLVED: To obtain a flame-relardant resin composition having high flame retardance without using halogen, etc., excellent in heat resistance and impact resistance and useful for OA equipment, etc., by making the composition include a polycarbonate-based resin, a specific cyclic phosphate compound, etc., at a specific ratio. SOLUTION: This resin composition comprises (A) 97-40 pts.wt. polycarbonate- based resin, (B) 0-55 pts.wt. styrene-based resin, (C) 2-20 pts.wt. cyclic phosphate compound having a skeleton of the formula [R is a 3-20C (substituted) phenyl, naphthyl, etc.], e.g. diphenylpentaethyritol diphosphate, (D) =0.02. Furthermore, the component B is preferably an ABS resin and the component D is preferably calcium carbonate, calcium phosphate or barium carbonate.

75. 发明专利

JPH11222451A PRODUCTION OF BROMINE COMPOUND 失效
公开(公告)号：JPH11222451A
公开(公告)日：1999-08-17
申请号：JP32042698
申请日：1998-11-11
申请人： TEIJIN CHEMICALS LTD
发明人： TAKEYA YUTAKA , MONRI MASANORI , TANABE SEIICHI , SHIMIZU YASUHIRO
IPC分类号： C07C41/22 , C07C43/225 , C07C315/04 , C07C317/22 , C07C319/20 , C07C323/20
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a highly pure bromine compound by reacting a compound having an aliphatic unsaturated bond with bromine. SOLUTION: This method for producing a bromine compound of the formula, R -O-Ar -Y-Ar -O-R [Ar and Ar are each the same or different 5-16C aromatic or 5-12C saturated alicyclic hydrocarbon (substituted by one or more halogens); Y is a 1-6C saturated hydrocarbon, sulfone, sulfide, ketone, a 2-6C alkylene oxide or a single bond; R and R are each the group of R and R saturated with bromine respectively] comprises adding a compound of the formula, R -O- Ar -Y-Ar -O-R [Ar , Ar and Y are same as the before; R and R are each the same or different 2-11C hydrocarbon having one or more aliphatic unsaturated groups with the proviso that either one of R and R can have a part of the unsaturated group modified with the addition of a halogen] or a solution thereof to bromine or a bromine solution to carry out bromination reaction.

76. 发明专利

JPH11193257A PURIFICATION OF BROMINE COMPOUND 失效
公开(公告)号：JPH11193257A
公开(公告)日：1999-07-21
申请号：JP30522198
申请日：1998-10-27
申请人： TEIJIN CHEMICALS LTD
发明人： TAKEYA YUTAKA , HOSHIMI HARUHISA , MUKAI AKIHIRO
IPC分类号： C07C41/40 , C07C43/225 , C07C45/81 , C07C49/84 , C07C315/06 , C07C317/22
摘要： PROBLEM TO BE SOLVED: To obtain a high-purity bromine compound excellent in thermal stability, by adding and mixing a crude solution of a bromine compound with a solid liquid mixture substance composed of a good solvent, a poor solvent and a seed crystal. SOLUTION: When a bromine compound represented by the formula [Ar and Ar are each a 6-10C aromatic hydrocarbon; Y is a 1-3C alkylene, sulfone or the like; R and R are each a 2-5C hydrocarbon; (m) and (n) are each 1-4; (p) and (q) are each 2 or 4] is crystallized from a crude solution thereof, the crude solution containing the compound represented by the formula at 5-95 wt.% concentration is added to a crystallization vessel containing a solid liquid mixture substance composed of a good solvent (preferably methylene chloride), a poor solvent (preferably methanol) and a seed crystal and mixed therewith. The ratio of the compound represented by the formula in a slurry composed of the poor solvent, good solvent and the crystal (the seed crystal and the deposited crystal) of the compound represented by the formula is 10-50 wt.%. 2,2-Bis[(3,5-dibromo-4-(2,3-dibromopropyloxy)}phenyl]propane is preferred as the compound represented by the formula.

77. 发明专利

JPH11171813A PRODUCTION OF BROMINE COMPOUND 失效
公开(公告)号：JPH11171813A
公开(公告)日：1999-06-29
申请号：JP33578797
申请日：1997-12-05
申请人： TEIJIN CHEMICALS LTD
发明人： TAKEYA YUTAKA , MONRI MASANORI , TANABE SEIICHI , SHIMIZU YASUHIRO
IPC分类号： C07C41/22 , C07C43/225 , C07C315/04 , C07C317/22 , C07C319/20 , C07C323/20
摘要： PROBLEM TO BE SOLVED: To obtain the subject high-purity compound having excellent heat stability, by reacting an aliphatic unsaturated bond-containing compound with bromine in the presence of a specific hydroxyl group-containing compound. SOLUTION: This aliphatic unsaturated bond-containing compound of formula I (X is a halogen; (m) and (n) are each 1-6; Ar and Ar are each a 5-16C aromatic hydrocarbon or a 5-12C saturated alicyclic hydrocarbon; Y is sulfido, ketone or the like; R and R are each an aliphatic unsaturated group-containing 2-11C hydrocarbon) or its solution in a solvent is brominated with bromine or a bromine solution. In the bromination, the reaction is carried out by using a hydroxyl group-containing compound of the formula; R -(OH)u (R is a mono- to tetrafunctional aliphatic group; (u) is 1-4) so as to give 0.5-10 hydroxyl groups of the hydroxyl group-containing compound based on 100 unsaturated groups of the compound of formula I to obtain the objective compound of formula II (R and R are each obtained by adding a bromine atom to at least one aliphatic unsaturated group of R and R ). Methanol or the like is preferable as the compound of the formula.

78. 发明专利

JPH11166087A FLAME-RETARDANT RESIN COMPOSITION 失效
公开(公告)号：JPH11166087A
公开(公告)日：1999-06-22
申请号：JP33414497
申请日：1997-12-04
申请人： TEIJIN CHEMICALS LTD
发明人： TAHIRA YASUHISA , TAKEYA YUTAKA
IPC分类号： C08K3/00 , C08K5/06 , C08L23/00 , C08L25/00 , C08L101/00
摘要： PROBLEM TO BE SOLVED: To obtain a resin composition that has excellent heat stability, reduced discoloration during the melting process at an elevated temperature and can provide a molding of good color tone by controlling specific impurities in a bromine compound to be used as a flame retarder to be lower than a prescribed level. SOLUTION: This composition comprises (A) 100 pts.wt. of a thermoplastic resin (preferably a polystyrene-based resin or polyolefin-based resin), (B) 1-50 pts.wt. of a bromine compound and (C) 0-25 pts.wt. of an inorganic flame- retarding aid. The component (B) mainly comprises a bromine compound of formula I (X is a halogen; m and n are each an integer of 1-6; p and q are each an integer of 0-10, where p+q is >1; Ar and Ar are each a 5-16C aromatic hydrocarbon; Y is a 1-6C saturated hydrocarbon; R and R are each a 2-11C hydrocarbon) (preferably more than 80%), in which the content of a compound of formula II (s and t are each an integer of 0-5 where s+1>1) is

79. 发明专利

JPH11158105A GRANULAR BROMINE COMPOUND AND ITS PRODUCTION 失效
公开(公告)号：JPH11158105A
公开(公告)日：1999-06-15
申请号：JP33171197
申请日：1997-12-02
申请人： TEIJIN CHEMICALS LTD
发明人： TAHIRA YASUHISA , SATO TAKAHIRO , TAKEYA YUTAKA
IPC分类号： C07C41/40 , C07C43/225 , C07C315/06 , C07C317/22 , C09K21/08
摘要： PROBLEM TO BE SOLVED: To produce the subject granule having good handleability and excellent long-term storage stability by granulating powder of a specific bromine compound at or above a specific temperature using a hot-air drier. SOLUTION: Powder of a bromine compound expressed by the formula ((m), (n), (p) and (q) are each 1-6; Ar and Ar are each a 5-16C bivalent aromatic hydrocarbon group; Y is methylene, propylene, isopropylidene, isobutylidene, cyclohexylidene, sulfone, ketone or single bond; R and R are each a 2-6C saturated hydrocarbon group) e.g. 2,2-bis[3,5-dibromo-4-(2,3-dibromopropyloxy) phenyl]propane} and having an average particle diameter of preferably 0.001-0.2 mm is granulated with a hot-air drier (preferably an oscillation drier) at >=50 deg.C preferably under normal pressure for 10 min to 30 hr.

80. 发明专利

JPH11158104A PRODUCTION OF GRANULAR BROMINE COMPOUND 失效
公开(公告)号：JPH11158104A
公开(公告)日：1999-06-15
申请号：JP33171097
申请日：1997-12-02
申请人： TEIJIN CHEMICALS LTD
发明人： TAHIRA YASUHISA , SATO TAKAHIRO , TAKEYA YUTAKA
IPC分类号： C07C41/34 , C07C43/225 , C07C315/06 , C07C317/22
摘要： PROBLEM TO BE SOLVED: To produce the subject granule having good handleability and excellent long-term storage stability by mixing powder of a specific bromine compound with a poor solvent at a high temperature and granulating the mixture. SOLUTION: Powder of a bromine compound expressed by the formula ((m), (n), (p) and (q) are each 1-6; Ar and Ar are each a 5-16C bivalent aromatic hydrocarbon group; Y is methylene, propylene, isopropylidene, isobutylidene, cyclohexylidene, sulfone, ketone or single bond; R and R are each a 2-6C saturated hydrocarbon group) e.g. 2,2-bis[3,5-dibromo-4-(2,3-dibromopropyloxy) phenyl]propane} and having an average particle diameter of preferably 0.01-0.2 mm is mixed with a poor solvent (especially water, n-butanol, n-heptane, etc.), at a weight ratio of 0.5:99.5 to 50:50 at >=50 deg.C and the mixture is granulated for 30 min to 30 hr.

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