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71. 发明授权

US08968478B2 Pretreatment method for saccharification of plant fiber material and saccharification method 有权
标题翻译：植物纤维材料糖化预处理方法及糖化方法
公开(公告)号：US08968478B2
公开(公告)日：2015-03-03
申请号：US13254252
申请日：2010-03-08
申请人： Shinichi Takeshima , Takeshi Kikuchi
发明人： Shinichi Takeshima , Takeshi Kikuchi
IPC分类号： C13K1/02 , C13K1/04
CPC分类号： C13K1/02 , C13K1/04
摘要： A pretreatment method for saccharification of plant fiber materials includes: immersing the plant fiber material in a solution that contains an organic solvent, in which a cluster acid is dissolved, prior to saccharifying cellulose contained in the plant fiber material; and distilling off the organic solvent from the immersed plant fiber material to obtain a pretreated mixture that contains the cluster acid and the pretreated plant fiber material.
摘要翻译：用于植物纤维材料糖化的预处理方法包括：在将含有植物纤维材料的纤维素糖化之前，将植物纤维材料浸渍在含有簇酸溶解的有机溶剂的溶液中; 并从浸渍的植物纤维材料中蒸除有机溶剂，得到含有簇酸和预处理的植物纤维材料的预处理混合物。

72. 发明授权

US08932555B2 Catalyst for decomposition of sulfur trioxide and hydrogen production process 有权
标题翻译：三氧化硫分解催化剂和氢气生产工艺
公开(公告)号：US08932555B2
公开(公告)日：2015-01-13
申请号：US14118386
申请日：2012-05-18
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： C01B3/00 , C01B17/50 , C01B3/06 , B01J23/00 , B01J23/30 , B01J35/10 , B01J37/02 , B01J37/08 , C01B3/04 , C01B13/02 , B01J23/888 , B01J37/00 , B01J37/03 , B01J21/08
CPC分类号： C01B3/068 , B01J21/08 , B01J23/002 , B01J23/30 , B01J23/888 , B01J35/1057 , B01J35/1061 , B01J35/109 , B01J37/0018 , B01J37/0201 , B01J37/0205 , B01J37/024 , B01J37/033 , B01J37/088 , B01J2523/00 , C01B3/042 , C01B13/0203 , C01B13/0207 , C01B17/502 , Y02E60/324 , Y02E60/364 , B01J2523/17 , B01J2523/55 , B01J2523/69 , B01J2523/67 , B01J2523/47 , B01J2523/48 , B01J2523/3706 , B01J2523/3712 , B01J2523/3725
摘要： A sulfur trioxide decomposition catalyst, in particular, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process is disclosed. A sulfur trioxide decomposition catalyst that includes a composite oxide of tungsten, vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process that includes decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process is provided.
摘要翻译：公开了一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程制备氢气所需温度的三氧化硫分解催化剂。提供了包含钨，钒和至少一种选自过渡金属和稀土元素的金属的复合氧化物的三氧化硫分解催化剂。另外，提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法，进行通过S-I循环工序将三氧化硫分解成二氧化硫和氧的反应的氢气制造方法。

73. 发明申请

US20140086823A1 CATALYST FOR DECOMPOSITION OF SULFUR TRIOXIDE AND HYDROGEN PRODUCTION PROCESS 有权
标题翻译：用于分解三氧化硫和氢生产过程的催化剂
公开(公告)号：US20140086823A1
公开(公告)日：2014-03-27
申请号：US14118386
申请日：2012-05-18
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： C01B3/06 , C01B17/50
CPC分类号： C01B3/068 , B01J21/08 , B01J23/002 , B01J23/30 , B01J23/888 , B01J35/1057 , B01J35/1061 , B01J35/109 , B01J37/0018 , B01J37/0201 , B01J37/0205 , B01J37/024 , B01J37/033 , B01J37/088 , B01J2523/00 , C01B3/042 , C01B13/0203 , C01B13/0207 , C01B17/502 , Y02E60/324 , Y02E60/364 , B01J2523/17 , B01J2523/55 , B01J2523/69 , B01J2523/67 , B01J2523/47 , B01J2523/48 , B01J2523/3706 , B01J2523/3712 , B01J2523/3725
摘要： A sulfur trioxide decomposition catalyst, in particular, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process is disclosed. A sulfur trioxide decomposition catalyst that includes a composite oxide of tungsten, vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process that includes decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process is provided.
摘要翻译：公开了一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程制备氢气所需温度的三氧化硫分解催化剂。提供了包含钨，钒和至少一种选自过渡金属和稀土元素的金属的复合氧化物的三氧化硫分解催化剂。另外，提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法，进行通过S-I循环工序将三氧化硫分解成二氧化硫和氧的反应的氢气制造方法。

74. 发明授权

US08460471B2 Method for glycosylating and separating plant fiber material 有权
标题翻译：糖基化和分离植物纤维材料的方法
公开(公告)号：US08460471B2
公开(公告)日：2013-06-11
申请号：US12995756
申请日：2009-06-02
申请人： Shinichi Takeshima , Takeshi Kikuchi
发明人： Shinichi Takeshima , Takeshi Kikuchi
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： The invention relates to a method for hydrolyzing a plant fiber material to produce and separate a saccharide including glucose. The method includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material, and produce glucose. The cluster acid catalyst is subjected to a clustering enhancing treatment by which clustering of the cluster acid catalyst in a crystalline state is enhanced.
摘要翻译：本发明涉及一种用于水解植物纤维材料以产生和分离包括葡萄糖的糖的方法。该方法包括使用假熔融状态的簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。聚簇酸催化剂进行聚簇增强处理，通过该聚集增强处理，晶体状态的聚集酸催化剂的聚集得到增强。

75. 发明授权

US08034743B2 Method for production of an exhaust gas purification catalyst support and exhaust gas purification catalyst support 有权
标题翻译：生产废气净化催化剂载体和排气净化催化剂载体的方法
公开(公告)号：US08034743B2
公开(公告)日：2011-10-11
申请号：US12665119
申请日：2008-06-25
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： B01J21/04 , B01J21/06
CPC分类号： B01J21/063 , B01D53/945 , B01D2255/20707 , B01D2255/2092 , B01J23/40 , B01J23/42 , B01J23/464 , B01J23/58 , B01J37/0211 , B01J37/0242 , Y02T10/22
摘要： To provide a method of production of an exhaust gas purification catalyst support preventing a drop in the heat resistance of alumina or other catalyst support due to the presence of titania and provided with a sulfur poisoning suppression action by titania and an exhaust gas purification catalyst support produced by the same. A method of production of an exhaust gas purification catalyst support comprising, in a basic solution, making alumina particles adsorb ammonium ions and then bringing titania sol into contact with the alumina particle so as to make the alumina particles adsorb the titania particles. An exhaust gas purification catalyst support where at least base points on the alumina particle surfaces adsorb titania particles and the pH does not rise when immersed in an ammonium nitrate solution.
摘要翻译：提供一种生产排气净化催化剂载体的方法，其防止由于二氧化钛的存在而导致的氧化铝或其它催化剂载体的耐热性降低并且由二氧化钛提供硫中毒抑制作用和产生的废气净化催化剂载体同样的一种废气净化催化剂载体的制造方法，其特征在于，在碱性溶液中，使得氧化铝颗粒吸附铵离子，然后使二氧化钛溶胶与氧化铝颗粒接触，以使氧化铝颗粒吸附二氧化钛颗粒。一种废气净化催化剂载体，其中氧化铝颗粒表面上的至少基点吸附二氧化钛颗粒，并且当浸入硝酸铵溶液中时，pH不升高。

76. 发明申请

US20110180062A1 METHOD OF SACCHARIFICATION AND SEPARATION FOR PLANT FIBER MATERIALS 有权
标题翻译：植物纤维材料的分离和分离方法
公开(公告)号：US20110180062A1
公开(公告)日：2011-07-28
申请号：US12674427
申请日：2008-08-29
申请人： Shinichi Takeshima , Takeshi Kikuchi
发明人： Shinichi Takeshima , Takeshi Kikuchi
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： The present invention is to provide a high-purity aqueous saccharide solution by increasing the collection rate of cluster acid which is a hydrolysis catalyst for cellulose in saccharification and separation for cellulose using a cluster acid catalyst.A method of saccharification and separation for plant fiber materials of the present invention comprises: a hydrolysis step of hydrolyzing cellulose contained in the plant fiber materials using a cluster acid catalyst in a pseudo-molten state to produce saccharide, most of which is glucose; a first separation step of separating a mixture containing an aqueous saccharide solution in which at least a portion of the saccharide produced in the hydrolysis step is dissolved, a cluster acid organic solvent solution in which the cluster acid catalyst is dissolved, and residues into a solid content containing the residues and a liquid content containing the aqueous saccharide solution and the cluster acid organic solvent solution; and a second separation step of dehydrating the liquid content, which contains the aqueous saccharide solution and the cluster acid organic solvent solution and is separated in the first separation step, by a dehydration means capable of absorbing water through chemical absorption to deposit the saccharide in the aqueous saccharide solution, and separating a solid content containing the saccharide from a liquid content containing the cluster acid catalyst and the organic solvent.
摘要翻译：本发明是通过提高使用簇酸催化剂在纤维素糖化和分离纤维素中的纤维素水解催化剂的聚集酸的收集率来提供高纯度水性糖溶液。本发明的植物纤维材料的糖化分离方法包括：以假熔融状态使用簇酸催化剂水解纤维素所含的纤维素的水解步骤，生成糖，其中大部分为葡萄糖; 第一分离步骤，分离其中溶解了水解步骤中产生的糖的至少一部分的糖水溶液的混合物，其中溶解有簇酸催化剂的簇酸有机溶剂溶液和残留物固体含有残留物的含量和含有糖水溶液和簇酸有机溶剂溶液的液体含量; 以及第二分离步骤，其将含有糖水溶液和簇酸有机溶剂溶液的液体含量在第一分离步骤中脱水，由能够通过化学吸收吸收水分的脱水装置将糖沉积在水溶液，并将含有糖的固体含量与含有聚氨酯酸催化剂和有机溶剂的液体成分分离。

77. 发明授权

US07968490B2 Method for producing porous substances 有权
标题翻译：多孔物质的制造方法
公开(公告)号：US07968490B2
公开(公告)日：2011-06-28
申请号：US11631174
申请日：2005-07-11
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： B01J23/00 , B01J23/10 , C01G25/02
CPC分类号： C04B35/488 , B01J35/0013 , B01J35/1061 , B01J37/03 , C01G25/00 , C01P2006/16 , C01P2006/17 , C04B35/48 , C04B38/0038 , C04B2111/0081 , C04B2111/00853 , C04B38/0064
摘要： A porous substance producing method for producing a porous substance; by holding particles for precursors of the porous substance in micelles or inverse micelles kept in a dispersed state in a solvent with a surfactant; by agglomerating the particles of the micelles or inverse micelles to each other; and by baking the agglomerated particles. The method comprises the step of agglomerating the particles of the micelles or inverse micelles to each other by performing a treatment to resolve the dispersed state of the micelles or inverse micelles containing the particles for the precursors, with the surfactant.
摘要翻译：一种多孔物质的制造方法，通过在表面活性剂的溶剂中将分散状态的胶束中的多孔物质的前体或反胶束保持在溶剂中; 通过将胶束或反胶束的颗粒彼此聚结; 并通过烧结附聚颗粒。该方法包括通过进行处理以使表面活性剂分解含有前体颗粒的胶束或反胶束的分散状态来使胶束或反胶束的颗粒彼此附聚的步骤。

78. 发明授权

US07790649B2 Production process of exhaust gas purifying catalyst 有权
标题翻译：废气净化催化剂生产工艺
公开(公告)号：US07790649B2
公开(公告)日：2010-09-07
申请号：US12302536
申请日：2007-05-31
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： B01J31/12
CPC分类号： B01J37/0201 , B01D2255/2042 , B01D2255/2092 , B01J23/02 , B01J23/58 , B01J35/0033 , B01J37/0207 , B01J37/031
摘要： The present invention relates to a production process of an exhaust gas purifying catalyst, comprising impregnating a support with a solution containing a metal salt and then drying it to load a particle of the metal salt on the support, (a) wherein a base having a less tendency to adsorb and coordinate to the metal salt particle than ammonia is incorporated into the solution to make the solution basic, and thereby the metal salt particle is caused to have a negative zeta potential; or (b) wherein an acid and a base that adsorbs and coordinates to the metal salt particle are incorporated into the solution to make the solution acidic, and thereby the metal salt particle is caused to have a positive zeta potential.
摘要翻译：废气净化催化剂的制造方法技术领域本发明涉及废气净化用催化剂的制造方法，其特征在于，在含有金属盐的溶液中浸渍载体，然后将其干燥以将金属盐的粒子负载在载体上，（a）在溶液中加入较少吸附和配位金属盐颗粒的倾向，使溶液呈碱性，从而使金属盐颗粒具有负ζ电位; 或（b）其中将吸附和配合金属盐颗粒的酸和碱引入溶液中以使溶液呈酸性，从而使金属盐颗粒具有正的ζ电位。

79. 发明申请

US20100069232A1 AUTOMOBILE EXHAUST GAS PURIFICATION CATALYST AND METHOD OF PRODUCTION OF SAME 有权
标题翻译：汽车排气净化催化剂及其生产方法
公开(公告)号：US20100069232A1
公开(公告)日：2010-03-18
申请号：US12513171
申请日：2007-11-01
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： B01J23/46 , B01J21/06
CPC分类号： B01D53/945 , B01D2255/1025 , B01D2255/20715 , B01J21/066 , B01J23/464 , B01J35/006 , B01J35/1014 , B01J37/0207 , B01J37/0211 , B01J37/08 , Y02A50/2324 , Y02T10/22
摘要： An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2 in which Rh is supported as a catalyst metal preventing sintering of the support, raising the supporting efficiency, and raising the low temperature activity and a method of production of the same are provided. An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2, sintered under firing conditions where the as fired ZrO2 will substantially not be charged in a catalyst metal supporting treatment solution, in which Rh is supported as a catalyst metal in a particle state. The method of production includes a step of charging the support mainly comprised of ZrO2 fired under the above firing conditions by applying at least one treatment of an acid treatment and a base treatment and a step of dipping the charged state support in the catalyst supporting treatment solution including a colloid of Rh as the catalyst metal to make the Rh colloid be adsorbed on the support.
摘要翻译：本发明提供一种汽车排气净化催化剂，其特征在于，主要由作为催化剂金属负载的作为催化剂金属的ZrO 2的载体，能够防止烧结烧结，提高支持效率，提高低温活性的载体及其制造方法。一种汽车废气净化催化剂，由主要由ZrO 2组成的载体组成，在烧成条件下烧结ZrO 2基本上不会在催化剂金属负载处理溶液中充电，其中Rh作为催化剂金属以粒子状态负载。该制造方法包括以下步骤：在上述烧成条件下，通过进行至少一种酸处理和碱处理的处理，以及将带电状态的载体浸渍在催化剂负载处理液中的步骤，包括Rh的胶体作为催化剂金属，使Rh胶体吸附在载体上。

80. 发明授权

US07678733B2 Method for producing heat-resisting compound oxides 有权
标题翻译：耐热复合氧化物的制造方法
公开(公告)号：US07678733B2
公开(公告)日：2010-03-16
申请号：US11918484
申请日：2006-04-07
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： B01J23/10
CPC分类号： B01J23/63 , B01D53/945 , B01J21/063 , B01J21/066 , B01J23/10 , B01J35/0013 , B01J37/0018 , B01J37/0211 , B01J37/03 , C01G25/00 , C01G25/006 , C01P2006/12 , Y02T10/22
摘要： A method for producing a heat-resisting compound oxide in which first oxide particles are made to carry second fine particles having near charging characteristics. Said first oxide particles or their precursors are caused, before said first oxide particles or their precursors are caused to adsorb said first oxide particles or their precursors, to adsorb a predetermined acid or base so that they may be charged inversely of said second fine particles or their precursors to be adsorbed thereby. Said first oxide particles are caused to adsorb said second fine particles through said acid or base and are sintered to carry the same.
摘要翻译：一种制造耐热复合氧化物的方法，其中使第一氧化物颗粒携带具有接近充电特性的第二微粒。在使所述第一氧化物颗粒或其前体吸附所述第一氧化物颗粒或其前体之前，引入所述第一氧化物颗粒或其前体以吸附预定的酸或碱，使得它们可以与所述第二细颗粒相反地或与它们的前体被吸附。使所述第一氧化物颗粒通过所述酸或碱吸附所述第二细颗粒并进行烧结以承载它们。

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