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71. 发明授权

US5618871A Phenyl phosphites for use as stabilizers for organic materials 失效
标题翻译：苯基亚磷酸酯用作有机材料的稳定剂
公开(公告)号：US5618871A
公开(公告)日：1997-04-08
申请号：US383277
申请日：1995-02-03
申请人： Peter Nesvadba
发明人： Peter Nesvadba
IPC分类号： C07C39/23 , C07F9/6574 , C08K5/13 , C08K5/52 , C08K5/524 , C08K5/527 , C08L23/00 , C09K15/32
CPC分类号： C07C39/23 , C07F9/65742 , C07F9/65746 , C08K5/13 , C08K5/527 , C07C2101/16
摘要： Novel compounds of the formula I and formula II ##STR1## in which R and R.sub.1, independently of one another, are hydrogen or C.sub.1 -C.sub.4 alkyl or together with the carbon atom to which they are attached form a 3,4-dehydrocyclohexylidene ring,R.sub.2 is hydrogen, C.sub.1 -C.sub.8 alkyl or C.sub.5 -C.sub.6 cycloalkyl,R.sub.3 is C.sub.1 -C.sub.8 alkyl or C.sub.5-C.sub.6 cycloalkyl,R.sub.4, R.sub.5 and R.sub.6, independently of one another, are hydrogen or C.sub.1-C.sub.4 alkyl, R.sub.4, R.sub.5 and R.sub.6 together containing 1 to 4 carbon atoms, andR.sub.7 and R.sub.8 are hydrogen or together an additional direct bond, are described for use as stabilizers for organic materials against thermal, oxidative or light-induced degradation.
摘要翻译：式（I）和式II的新型化合物其中R和R 1彼此独立地是氢或C 1 -C 4烷基或与它们连接的碳原子一起形成 3,4-二氢亚环己基环，R 2是氢，C 1 -C 8烷基或C 5 -C 6环烷基，R 3是C 1 -C 8烷基或C 5 -C 6环烷基，R 4，R 5和R 6彼此独立地是氢或C 1 -C 4烷基，一起含有1至4个碳原子的R 5和R 6以及R 7和R 8是氢或一起另外的直接键，用作有机材料用于热，氧化或光诱导的降解的稳定剂。

72. 发明授权

US5437689A Composition and process for the preparation of articles having moulding stability 失效
标题翻译：用于制备具有成型稳定性的制品的组合物和方法
公开(公告)号：US5437689A
公开(公告)日：1995-08-01
申请号：US207561
申请日：1994-03-07
申请人： Manfred Rembold , Claude Eckhardt , Peter Nesvadba
发明人： Manfred Rembold , Claude Eckhardt , Peter Nesvadba
IPC分类号： C07D307/83 , D06L3/00 , D06L3/12 , D06P1/651 , D06P5/00 , D06P5/04 , C09B67/00 , D06P1/64
CPC分类号： D06P1/65131 , D06L3/1207 , D06L3/1214 , D06L3/1221 , D06L3/1228 , D06L3/125 , D06L3/1271 , D06P1/65112 , Y10S8/92 , Y10S8/924 , Y10S8/925 , Y10S8/931
摘要： A process is disclosed for treating polyamide fiber containing materials which process comprises applying a benzofuran-2-one compound to the material in order to enhance its moulding stability. In addition, compositions containing a fluorescent whitening agent and a benzofuran-2-one, and optionally one or more dyes, are disclosed.
摘要翻译：公开了一种用于处理含聚酰胺纤维的材料的方法，该方法包括将苯并呋喃-2-酮化合物施用于该材料以增强其成型稳定性。此外，公开了含有荧光增白剂和苯并呋喃-2-酮以及任选的一种或多种染料的组合物。

73. 发明授权

US5428177A 3-(Dihydrobenzofuran-5-yl)benzofuran-2-ones as stabilizers 失效
标题翻译： 3-（二氢苯并呋喃-5-基）苯并呋喃-2-酮作为稳定剂
公开(公告)号：US5428177A
公开(公告)日：1995-06-27
申请号：US124138
申请日：1993-09-20
申请人： Peter Nesvadba
发明人： Peter Nesvadba
IPC分类号： C07D307/83 , C07D407/04 , C08K5/15 , C08K5/1535 , C07D307/28
CPC分类号： C07D307/83 , C08K5/1535
摘要： Novel compounds of formula (1) ##STR1## wherein R.sub.1 is hydrogen, alkyl or alkaryl, R.sub.2 to R.sub.5 are independently hydrogen, chloro, alkyl phenylalkyl, aryl, cycloalkyl, alkoxy, alkylthio, hydroxy, amino or substituted amino, R.sub.6 is hydrogen, R.sub.7 and R.sub.8 are hydrogen or alkyl, R.sub.9 and R.sub.9 ' are hydrogen, alkyl or phenyl, and R.sub.10 is hydrogen or alkyl, are disclosed as stabilisers for protecting organic materials against thermal, oxidative or light-induced degradation.
摘要翻译：式（1）的新型化合物其中R1是氢，烷基或烷芳基，R2至R5独立地是氢，氯，烷基苯基烷基，芳基，环烷基，烷氧基，烷硫基，羟基，氨基或取代的氨基，R6 是氢，R7和R8是氢或烷基，R9和R9'是氢，烷基或苯基，R10是氢或烷基，被公开作为用于保护有机材料以防止热，氧化或光诱导的降解的稳定剂。

74. 发明授权

US5328623A Compositions containing n-heterocyclic phosphonates which contain 6 ring members 失效
标题翻译：含有6个环成员的n-杂环膦酸酯的组合物
公开(公告)号：US5328623A
公开(公告)日：1994-07-12
申请号：US928245
申请日：1992-08-10
申请人： Peter Nesvadba
发明人： Peter Nesvadba
IPC分类号： C07F9/40 , C07F9/58 , C08K5/53 , C08K5/5317 , C08K5/5373 , C08L101/00 , C09K15/30 , C10M137/12
CPC分类号： C08K5/5373
摘要： There are disclosed compositions comprising: A) an organic material which is susceptible to thermal, oxidative and/or light-induced degradation, and B) at least one compound of formula I and/or II, ##STR1## wherein R.sub.0 is hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.12 alkenyl, phenyl-C.sub.1 -C.sub.4 alkyl, --CO--R.sub.5 or --CO--OR.sub.5, R.sub.1 is hydrogen, methyl, ethyl or R.sub.1 together with R.sub.2 are ##STR2## R.sub.2 is hydrogen, methyl, ethyl or R.sub.2 together with R.sub.1 are ##STR3## R.sub.3 is hydrogen, methyl, ethyl or R.sub.3 together with R.sub.4 are ##STR4## R.sub.4 is hydrogen, methyl, ethyl or R.sub.4 together with R.sub.3 are ##STR5## R.sub.5 is C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl-C.sub.1 -C.sub.4 alkyl or phenyl, R.sub.6 and R.sub.7 are each independently of the other hydrogen, C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.12 cycloalkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl, R.sub.8 is C.sub.1 -C.sub.4 alkyl, and n is 0, 1 or 2, with the proviso that, in formula II, R.sub.3 is not hydrogen. The compounds of formula I and/or II are particularly effective antioxidants as well as processing stabilisers for synthetic polymers.
摘要翻译：公开的组合物包括：A）易受热，氧化和/或光诱导降解的有机材料，和B）至少一种式I和/或II的化合物，其中R 0是氢，C 1 -C 12烷基，C 5 -C 12环烷基，C 2 -C 12烯基，苯基-C 1 -C 4烷基，-CO-R 5或-CO-OR 5，R 1是氢，甲基，乙基或R 1与R 2一起是R 2是氢，甲基，乙基或R 2与R 1一起为R 3为氢，甲基，乙基或R 3与R 4一起为R 4为氢，甲基，乙基或R 4与R 3一起为R 1为C 1 -C 18烷基，C 5 -C 12环烷基苯基-C 1 -C 4烷基或苯基，R 6和R 7各自独立地为氢，C 1 -C 12烷基，C 5 -C 12环烷基，苯基或苯基-C 1 -C 4烷基，R 8为C 1 -C 4烷基，n为0,1或2 条件是在式II中，R 3不是氢。式I和/或II的化合物是特别有效的抗氧化剂以及合成聚合物的加工稳定剂。

75. 发明授权

US5322525A Process for treating polyamide containing articles to enhance their moulding stability 失效
标题翻译：用于处理含有聚酰胺的制品以提高其成型稳定性的方法
公开(公告)号：US5322525A
公开(公告)日：1994-06-21
申请号：US969617
申请日：1992-10-30
申请人： Manfred Rembold , Claude Eckhardt , Peter Nesvadba
发明人： Manfred Rembold , Claude Eckhardt , Peter Nesvadba
IPC分类号： C07D307/83 , D06L3/00 , D06L3/12 , D06P1/651 , D06P5/00 , D06P5/04 , D06M13/228 , C09B67/00
CPC分类号： D06P1/65131 , D06L3/1207 , D06L3/1214 , D06L3/1221 , D06L3/1228 , D06L3/125 , D06L3/1271 , D06P1/65112 , Y10S8/92 , Y10S8/924 , Y10S8/925 , Y10S8/931
摘要： A process is disclosed for treating polyamide fiber containing materials which process comprises applying a benzofuran-2-one compound to the material in order to enhance its moulding stability. In addition, compositions containing a fluorescent whitening agent and a benzofuran-2-one, and optionally one or more dyes, are disclosed.
摘要翻译：公开了一种用于处理含聚酰胺纤维的材料的方法，该方法包括将苯并呋喃-2-酮化合物施用于该材料以增强其成型稳定性。此外，公开了含有荧光增白剂和苯并呋喃-2-酮以及任选的一种或多种染料的组合物。

76. 发明授权

US08669398B2 Polymerisation initiator 失效
标题翻译：聚合引发剂
公开(公告)号：US08669398B2
公开(公告)日：2014-03-11
申请号：US13143355
申请日：2009-12-28
申请人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller
IPC分类号： C07C275/70
CPC分类号： C07D211/94 , C07C291/02 , C07C2601/14
摘要： The invention relates to novel O-dialkylamino-isoureas and polymerizable compositions comprising these O-dialkylamino-isoureas of compounds of the general formula (I). The invention further relates to the use of O-dialkylamino-isoureas as polymerization initiators, especially to prepare coatings or for controlled degradation of polyolefins.
摘要翻译：本发明涉及新的O-二烷基氨基 - 异脲和包含通式（I）化合物的这些O-二烷基氨基 - 异脲的可聚合组合物。本发明还涉及O-二烷基氨基 - 异脲作为聚合引发剂的用途，特别是制备涂层或用于聚烯烃的可控降解。

77. 发明申请

US20120108696A1 O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF 失效
公开(公告)号：US20120108696A1
公开(公告)日：2012-05-03
申请号：US13319244
申请日：2010-05-05
申请人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller , Bruno Spony
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Antoine Carroy , Marc Faller , Bruno Spony
IPC分类号： C07C251/58 , B05D3/00 , C08F6/00 , C08F20/18 , C08F10/06
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R100 and R101 are independently H, C1-18 alkyl, C3-C12cycloalkyl, C6-C14aryl, C1-C14heteroaryl, C7-C15aralkyl, C2-C14heteroaralkyl, Cyano, or R100 and R101 form together with the carbon to which they are attached a mono or polycyclic C3-C18 carbocyclic or C1-C18 heterocyclic ring; R102 and R103 are independently C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C6-C14aryl once or more than once substituted by C1-C18alkyl; C7-C15aralkyl, (CH3)3Si—; or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C7-C15aralkyl or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C1-C18alkylamino, bis(C1-C18alkyl)amino or tris(C1-C18alkyl)ammonium; R104 if n is 1 is H, C1-C18alkyl, C3-C12cycloalkyl, C7-C14aralkyl, C6-C14aryl or acyl selected from the group consisting of the following acyls —C(═O)—H, —C(═O)—C1-C18alkyl, —C(═O)—C2-d18alkenyl, —C(═O)—C6-C14aryl, —C(═O)—C2-C18alkenyl-C6-C14aryl, —C(═O)—O—C1C18alkyl, —C(═O)—O—C6-C14aryl, —C(═O)—NH—C1-C18alkyl, —C(═O)—NH—C6-C14aryl and —C(═O)—N(C1C18alkyl)2; or R102 and R104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R104 if n is more than 1 is di-, tri-, tetra-C1-C18alkylidene, diacyls, triacyls or tetraacyls and salts thereof.

78. 发明授权

US08168725B2 Degradation of polypropylene with hydroxylamine ester compositions 有权
标题翻译：用羟胺酯组合物降解聚丙烯
公开(公告)号：US08168725B2
公开(公告)日：2012-05-01
申请号：US13098557
申请日：2011-05-02
申请人： Michael Roth , Peter Nesvadba , David E. Horst
发明人： Michael Roth , Peter Nesvadba , David E. Horst
IPC分类号： C08F8/34 , C08L23/00 , C09K3/00 , C08K5/34 , C08K5/3435 , C08K5/42 , C08K5/36 , C08G73/10
CPC分类号： C08J11/28 , C08J2323/10 , C08J2323/12 , Y02W30/706
摘要： The invention relates to novel composition comprising hydroxylamine esters and thio compounds, which are suitable for lowering the molecular weight of polypropylene, propylene copolymers or polypropylene blends and result in an excellent degradation performance at temperatures below 220° C.
摘要翻译：本发明涉及包含羟胺酯和硫代化合物的新型组合物，其适用于降低聚丙烯，丙烯共聚物或聚丙烯共混物的分子量，并在低于220℃的温度下产生优异的降解性能。

79. 发明申请

US20120041093A1 POLYMERIZABLE COMPOSITIONS 有权
标题翻译：可聚合组合物
公开(公告)号：US20120041093A1
公开(公告)日：2012-02-16
申请号：US13258951
申请日：2010-03-26
申请人： Peter Nesvadba , Lucienne Bugnon Folger , Jean-Luc Birbaum , Marc Faller , Antoine Carroy
发明人： Peter Nesvadba , Lucienne Bugnon Folger , Jean-Luc Birbaum , Marc Faller , Antoine Carroy
IPC分类号： C07D211/98 , C08F2/00 , C08F2/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical —(CR8R9)—, Z1 is —O—, —NR10—, —CH2—, —(CR11R12)— or —C(═O)— and R1 to R12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.
摘要翻译：本发明涉及其中Q为直接键或二价基 - （CR 8 R 9） - ，Z 1为-O-，-NR 10 - ， - CH 2 - ， - （CR 11 R 12） - 或 - C（= O） - 和R 1至R 12是任选取代的烃残基，作为可用于由自由基引发的反应的基团的前体，例如不饱和单体的聚合和聚烯烃的降解。式（I）的大多数三氮烯也是新型的，并且还要求制备式（I）的三氮烯和包含它们的可聚合组合物。

80. 发明授权

US07956109B2 Degradation of polypropylene with hydroxylamine ester compositions 有权
标题翻译：用羟胺酯组合物降解聚丙烯
公开(公告)号：US07956109B2
公开(公告)日：2011-06-07
申请号：US11661450
申请日：2005-08-31
申请人： Michael Roth , Peter Nesvadba , David E. Horst
发明人： Michael Roth , Peter Nesvadba , David E. Horst
IPC分类号： C08K5/34 , C08K5/3435 , C08K5/36 , C08K5/372
CPC分类号： C08J11/28 , C08J2323/10 , C08J2323/12 , Y02W30/706
摘要： The invention relates to novel composition comprising hydroxylamine esters and thio compounds, which are suitable for lowering the molecular weight of polypropylene, propylene copolymers or polypropylene blends and result in an excellent degradation performance at temperatures below 220° C.
摘要翻译：本发明涉及包含羟胺酯和硫代化合物的新型组合物，其适用于降低聚丙烯，丙烯共聚物或聚丙烯共混物的分子量，并在低于220℃的温度下产生优异的降解性能。

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