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    • 71. 发明申请
    • NONVOLATILE MEMORY DEVICE HAVING AN ELECTRODE INTERFACE COUPLING REGION
    • 具有电极接口连接区域的非易失性存储器件
    • US20120313063A1
    • 2012-12-13
    • US13156722
    • 2011-06-09
    • Yun WangTony ChiangImran Hashim
    • Yun WangTony ChiangImran Hashim
    • H01L47/00
    • H01L45/1608H01L27/2409H01L27/2436H01L27/2463H01L45/065H01L45/08H01L45/10H01L45/12H01L45/1226H01L45/1233H01L45/1253H01L45/145H01L45/146H01L45/1616H01L45/1625
    • Embodiments of the invention generally relate to a resistive switching nonvolatile memory device having an interface layer structure disposed between at least one of the electrodes and a variable resistance layer formed in the nonvolatile memory device, and a method of forming the same. Typically, resistive switching memory elements may be formed as part of a high-capacity nonvolatile memory integrated circuit, which can be used in various electronic devices, such as digital cameras, mobile telephones, handheld computers, and music players. In one configuration of the resistive switching nonvolatile memory device, the interface layer structure comprises a passivation region, an interface coupling region, and/or a variable resistance layer interface region that are configured to adjust the nonvolatile memory device's performance, such as lowering the formed device's switching currents and reducing the device's forming voltage, and reducing the performance variation from one formed device to another.
    • 本发明的实施例一般涉及具有设置在至少一个电极和形成在非易失性存储器件中的可变电阻层之间的界面层结构的电阻式开关非易失性存储器件及其形成方法。 通常,电阻式开关存储器元件可以形成为可用于各种电子设备(例如数码相机,移动电话,手持式计算机和音乐播放器)的大容量非易失性存储器集成电路的一部分。 在电阻式开关非易失性存储器件的一种结构中,界面层结构包括钝化区域,界面耦合区域和/或可变电阻层接口区域,其被配置为调整非易失性存储器件的性能,例如降低形成 器件的开关电流并降低器件的成型电压,并降低从一个成形器件到另一个器件的性能变化。
    • 73. 发明申请
    • METHODS FOR FORMING RESISTIVE-SWITCHING METAL OXIDES FOR NONVOLATILE MEMORY ELEMENTS
    • 形成非易失性存储元件的电阻式切换金属氧化物的方法
    • US20120149164A1
    • 2012-06-14
    • US13111230
    • 2011-05-19
    • Pragati KumarSandra G. MalhotraSean BarstowTony Chiang
    • Pragati KumarSandra G. MalhotraSean BarstowTony Chiang
    • H01L21/02
    • H01L45/1625H01L27/2409H01L27/2463H01L45/04H01L45/1233H01L45/146H01L45/1641
    • Nonvolatile memory elements are provided that have resistive switching metal oxides. The nonvolatile memory elements may be formed from resistive-switching metal oxide layers. Metal oxide layers may be formed using sputter deposition at relatively low sputtering powers, relatively low duty cycles, and relatively high sputtering gas pressures. Dopants may be incorporated into a base oxide layer at an atomic concentration that is less than the solubility limit of the dopant in the base oxide. At least one oxidation state of the metal in the base oxide is preferably different than at least one oxidation sate of the dopant. The ionic radius of the dopant and the ionic radius of the metal may be selected to be close to each other. Annealing and oxidation operations may be performed on the resistive switching metal oxides. Bistable metal oxides with relatively large resistivities and large high-state-to-low state resistivity ratios may be produced.
    • 提供具有电阻开关金属氧化物的非易失性存储元件。 非易失性存储元件可以由电阻式开关金属氧化物层形成。 金属氧化物层可以使用相对低的溅射功率,相对低的占空比和较高的溅射气体压力的溅射沉积形成。 掺杂剂可以以小于基底氧化物中的掺杂剂的溶解度极限的原子浓度结合到基底氧化物层中。 基底氧化物中金属的至少一种氧化态优选不同于掺杂剂的至少一种氧化态。 可以选择掺杂剂的离子半径和金属的离子半径彼此接近。 可以对电阻式开关金属氧化物进行退火和氧化操作。 可以制造具有相对较大的电阻率和大的高 - 低 - 电阻率比的双稳态金属氧化物。
    • 78. 发明授权
    • Methods for forming resistive-switching metal oxides for nonvolatile memory elements
    • 用于形成用于非易失性存储元件的电阻式开关金属氧化物的方法
    • US07977153B2
    • 2011-07-12
    • US12967530
    • 2010-12-14
    • Pragati KumarSandra G. MalhotraSean BarstowTony Chiang
    • Pragati KumarSandra G. MalhotraSean BarstowTony Chiang
    • H01L21/00H01L21/16H01L21/20H01L21/36
    • H01L45/1625H01L27/2409H01L27/2463H01L45/04H01L45/1233H01L45/146H01L45/1641
    • Nonvolatile memory elements are provided that have resistive switching metal oxides. The nonvolatile memory elements may be formed from resistive-switching metal oxide layers. Metal oxide layers may be formed using sputter deposition at relatively low sputtering powers, relatively low duty cycles, and relatively high sputtering gas pressures. Dopants may be incorporated into a base oxide layer at an atomic concentration that is less than the solubility limit of the dopant in the base oxide. At least one oxidation state of the metal in the base oxide is preferably different than at least one oxidation state of the dopant. The ionic radius of the dopant and the ionic radius of the metal may be selected to be close to each other. Annealing and oxidation operations may be performed on the resistive switching metal oxides. Bistable metal oxides with relatively large resistivities and large high-state-to-low state resistivity ratios may be produced.
    • 提供具有电阻开关金属氧化物的非易失性存储元件。 非易失性存储元件可以由电阻式开关金属氧化物层形成。 金属氧化物层可以使用相对低的溅射功率,相对低的占空比和较高的溅射气体压力的溅射沉积形成。 掺杂剂可以以小于基底氧化物中的掺杂剂的溶解度极限的原子浓度结合到基底氧化物层中。 基底氧化物中的金属的至少一种氧化态优选不同于掺杂剂的至少一种氧化态。 可以选择掺杂剂的离子半径和金属的离子半径彼此接近。 可以对电阻式开关金属氧化物进行退火和氧化操作。 可以制造具有相对较大的电阻率和大的高 - 低 - 电阻率比的双稳态金属氧化物。
    • 79. 发明授权
    • Methods for forming resistive-switching metal oxides for nonvolatile memory elements
    • 用于形成用于非易失性存储元件的电阻式开关金属氧化物的方法
    • US07863087B1
    • 2011-01-04
    • US12114655
    • 2008-05-02
    • Pragati KumarSandra G. MalhotraSean BarstowTony Chiang
    • Pragati KumarSandra G. MalhotraSean BarstowTony Chiang
    • H01L21/00H01L21/16H01L21/20H01L21/36
    • H01L45/1625H01L27/2409H01L27/2463H01L45/04H01L45/1233H01L45/146H01L45/1641
    • Nonvolatile memory elements are provided that have resistive switching metal oxides. The nonvolatile memory elements may be formed from resistive-switching metal oxide layers. Metal oxide layers may be formed using sputter deposition at relatively low sputtering powers, relatively low duty cycles, and relatively high sputtering gas pressures. Dopants may be incorporated into a base oxide layer at an atomic concentration that is less than the solubility limit of the dopant in the base oxide. At least one oxidation state of the metal in the base oxide is preferably different than at least one oxidation sate of the dopant. The ionic radius of the dopant and the ionic radius of the metal may be selected to be close to each other. Annealing and oxidation operations may be performed on the resistive switching metal oxides. Bistable metal oxides with relatively large resistivities and large high-state-to-low state resistivity ratios may be produced.
    • 提供具有电阻开关金属氧化物的非易失性存储元件。 非易失性存储元件可以由电阻式开关金属氧化物层形成。 金属氧化物层可以使用相对低的溅射功率,相对低的占空比和较高的溅射气体压力的溅射沉积形成。 掺杂剂可以以小于基底氧化物中的掺杂剂的溶解度极限的原子浓度结合到基底氧化物层中。 基底氧化物中金属的至少一种氧化态优选不同于掺杂剂的至少一种氧化态。 可以选择掺杂剂的离子半径和金属的离子半径彼此接近。 可以对电阻式开关金属氧化物进行退火和氧化操作。 可以制造具有相对较大的电阻率和大的高 - 低 - 电阻率比的双稳态金属氧化物。