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71. 发明授权

US4941912A Herbicidal substituted sulphonylaminoazoles 失效
标题翻译：除草取代磺酰基氨基唑
公开(公告)号：US4941912A
公开(公告)日：1990-07-17
申请号：US317219
申请日：1989-02-28
申请人： Rolf Kirsten , Joachim Kluth , Christa Fest , Ernst Gesing , Klaus-Helmut Muller , Hans-Jochem Riebel , Peter Babczinski , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
发明人： Rolf Kirsten , Joachim Kluth , Christa Fest , Ernst Gesing , Klaus-Helmut Muller , Hans-Jochem Riebel , Peter Babczinski , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Harry Strang
IPC分类号： C07D401/14 , A01N43/56 , A01N43/653 , A01N43/66 , A01N43/80 , A01N51/00 , C07D249/14 , C07D401/04 , C07D403/04 , C07D403/14 , C07D409/14 , C07D417/14
CPC分类号： C07D401/04 , A01N43/56 , A01N43/653 , A01N43/66 , A01N43/80 , A01N51/00 , C07D403/04 , C07D403/14 , C07D409/14 , C07D417/14
摘要： Herbicidal substituted sulphonylaminoazoles of the formula ##STR1## in which R.sup.1 is optionally substituted alkyl, aralkyl, aryl or heteroaryl,R.sup.2 is hydrogen or --SO.sub.2 --R.sup.1,R.sup.3 is hydrogen, halogen, hydroxyl, mercapto, amino, or an optionally substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino radical,A is CH, nitrogen or,at least one of A, D and E is ##STR2## and the others may be that or CH or nitrogen, and X, Y and Z each is nitrogen or optionally substituted C, and salts thereof.
摘要翻译： R 1为任选取代的烷基，芳烷基，芳基或杂芳基，R 2为氢或-SO 2 -R 1，R 3为氢，卤素，羟基，巯基，氨基或任意取代的芳族取代的磺酰基氨基唑取代的烷基，烷氧基，烷硫基，烷基氨基或二烷基氨基，A是CH，氮，或者，A，D和E中的至少一个是，而其余可以是CH或氮，X，Y和Z各自是氮或任选取代的C，及其盐。

72. 发明授权

US4810283A Novel 1-aryl-4-nitro-pyrazole herbicides and plant growth regulators, compositions and use 失效
标题翻译：新型1-芳基-4-硝基 - 吡唑除草剂和植物生长调节剂，组合物和用途
公开(公告)号：US4810283A
公开(公告)日：1989-03-07
申请号：US925639
申请日：1986-10-30
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/38 , C07D231/40 , C07D401/04 , C07D231/16
CPC分类号： C07D231/38 , A01N43/56 , C07D401/04
摘要： Novel 1-aryl-4-nitro-pyrazoles which exhibit herbicidal and plant growth-regulating activity of the formula ##STR1## in which R.sup.1 represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl andR.sup.2 represents hydrogen, or represents in each case optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl, or represents a radical ##STR2## or R.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, represent a saturated heterocyclic radical, which can optionally contain further hetero atoms, andAr represents in each case optionally substituted phenyl or pyridyl,whereinX represents oxygen or sulphur andR.sup.3 represents hydrogen, alkyl, alkoxy, alkoxy-alkyl, alkylthio, alkylthioalkyl, alkylamino, di-alkylamino, halogenoalkyl, alkenyl or alkinyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents optionally substituted arylamino,but wherein R.sup.2 only represents hydrogen or a radical ##STR3## if R.sup.1 does not simultaneously represent unsubstituted alkyl or represent alkyl which is substituted by an alkoximino radical.
摘要翻译：表现出式（IMAGE）的除草和植物生长调节活性的新型1-芳基-4-硝基 - 吡唑，其中R 1在每种情况下表示任选取代的烷基，烯基，炔基或环烷基，R 2表示氢，或每个或任选取代的烷基，烯基，炔基或环烷基，或者表示基团，或者R 1和R 2与它们所键合的氮原子一起代表饱和杂环基团，其可以任选地含有其它杂原子，Ar 在每种情况下表示任选取代的苯基或吡啶基，其中X表示氧或硫，R 3表示氢，烷基，烷氧基，烷氧基 - 烷基，烷硫基，烷硫基烷基，烷基氨基，二烷基氨基，卤代烷基，烯基或炔基，或表示任选取代的环烷基或表示任选取代的芳基，或表示任选取代的芳氧基，或表示任选取代的芳硫基，或表示任选的亚芳基取代的芳基氨基，但其中R 2仅代表氢或基团，如果R 1不同时表示未取代的烷基或代表被烷基肟基取代的烷基。

73. 发明授权

US4806144A 5-Sulphonamido-1-aryl-pyrazoles 失效
标题翻译： 5-磺酰氨基-1-芳基 - 吡唑
公开(公告)号：US4806144A
公开(公告)日：1989-02-21
申请号：US817181
申请日：1986-01-08
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/38 , C07D231/42
CPC分类号： C07D231/42
摘要： A 5-sulphonamido-1-aryl-pyrazole of the formula (I) ##STR1## in which R.sup.1 represents hydrogen, nitro, nitroso or halogen,R.sup.2 represents hydrogen, alkyl or a radical R.sup.3 --SO.sub.2 --, or an inorganic or organic cation bonded in the form of a salt,R.sup.3 represents alkyl, alkenyl, cycloalkyl, halogeno-alkyl, hydroxyalkyl, alkoxyalkyl or unsubstituted or substituted aryl,R.sup.4 and R.sup.6 independently of one another represent cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radical --(O).sub.n --R.sup.9 andR.sup.5, R.sup.7 and R.sup.8 independently of one another and of R.sup.4 and R.sup.6 represent the same radicals as R.sup.4 and R.sup.6, and additionally represent hydrogen,whereinR.sup.9 represents alkyl, halogenoalkyl, amino, alkyl-amino or dialkylamino andn represents the number 0, 1 or 2.Such 5-sulphonamido-1-aryl-pyrazole being useful as a herbicide.
摘要翻译：式（I）的5-磺酰氨基-1-芳基 - 吡唑其中R 1表示氢，硝基，亚硝基或卤素，R 2表示氢，烷基或基团R 3 -SO 2 - 或无机或以盐形式键合的有机阳离子，R 3表示烷基，烯基，环烷基，卤代烷基，羟烷基，烷氧基烷基或未取代或取代的芳基，R 4和R 6彼此独立地表示氰基，硝基，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，卤代烷氧基或基团 - （O）n -R 9和R 5，R 7和R 8彼此独立地表示，并且R 4和R 6表示与R 4和R 6相同的基团，并且另外表示氢，其中R 9表示烷基，卤代烷基，氨基，烷基 - 氨基或二烷基氨基，n代表数字0,1或2.这种5-磺酰氨基-1-芳基 - 吡唑可用作除草剂。

74. 发明授权

US4772312A 5-amino-1-pyridyl-pyrazoles, composition containing them, and herbicidal method of using them 失效
标题翻译： 5-氨基-1-吡啶基 - 吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4772312A
公开(公告)日：1988-09-20
申请号：US866638
申请日：1986-05-22
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56
摘要： Herbicidally active novel 5-amino-1-pyridyl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen or represents alkyl with 1 to 12 carbon atoms,R.sup.2 represents hydrogen, nitro, nitroso or halogen, or represents a radical ##STR2## wherein R.sup.5 represents hydrogen, hydroxyl, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents alkoxy or alkylthio, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents alkylamino or dialkylamino, or represents optionally substituted arylamino,R.sup.3 represents hydrogen, or represents a radical ##STR3## or represents a radical --S(O).sub.n --R.sup.7, R.sup.4 represents hydrogen, or represents alkyl, or represents a radical ##STR4## or represents a radical --S(O).sub.n --R.sup.7, and, in the case where R.sup.3 represents an --SO.sub.2 --R.sup.7 radical, also represents an inorganic or organic cation bonded in salt form, andR.sup.6 represents hydrogen, alkyl, alkenyl, alkinyl, halogenoalkyl, alkoxyalkyl or alkylthioalkyl, or represents optionally substituted cycloalkyl, or represents optionally substituted aryl, or represents alkoxy or alkylthio, or represents optionally substituted aryloxy, or represents optionally substituted arylthio, or represents alkylamino or dialkylamino, or represents optionally substituted arylamino,X represents oxygen or sulphur,n represents the number 0, 1 or 2,R.sup.7 represents alkyl, halogenoalkyl or optionally substituted aryl andPy represents substituted C-linked pyridyl.Some of the intermediates wherein the 5-position of the pyrazole carries a halogen atom are also new.
摘要翻译：其中R1代表氢或代表具有1-12个碳原子的烷基，R2代表氢，硝基，亚硝基或卤素的除草活性的新颖的5-氨基-1-吡啶基吡唑，其中R1代表氢或代表基团或代表任意取代的环烷基，或表示任意取代的芳基，或表示烷氧基或烷硫基，或表示任选取代的芳氧基，或表示任选取代的芳硫基，或表示任选取代的芳硫基，或或表示任选取代的芳基氨基，R 3表示氢，或表示基团，或表示基团-S（O）n -R 7，R 4表示氢，或表示烷基，或表示基团。或表示基团-S（O）n -R 7，并且在R 3表示-SO 2 -R 7基团的情况下，也表示以盐形式键合的无机或有机阳离子，R 6表示代表氢，烷基，烯基，炔基，卤代烷基，烷氧基烷基或烷硫基烷基，或表示任意取代的环烷基，或表示任意取代的芳基，或表示烷氧基或烷硫基，或表示任意取代的芳氧基，或表示任意取代的芳硫基，或表示烷基氨基或二烷基氨基，或表示任选取代的芳基氨基，X表示氧或硫，n表示0,1或2，R7表示烷基，卤代烷基或任意取代的芳基，Py表示取代的C-连接的吡啶基。其中吡唑的5-位带有卤素原子的一些中间体也是新的。

75. 发明授权

US4772309A 5-acylamino-pyrazoles, composition containing them, and herbicidal and plant growth regulating method of using them 失效
标题翻译： 5-酰基氨基 - 吡唑，含有它们的组合物，以及使用它们的除草和植物生长调节方法
公开(公告)号：US4772309A
公开(公告)日：1988-09-20
申请号：US27756
申请日：1987-03-19
申请人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Jorg Stetter , Reinhold Gehring , Otto Schallner , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： C07D317/00 , A01N43/56 , A01N43/80 , A01N47/02 , C07D333/00 , C07D401/12 , C07D403/12 , C07D405/12 , C07D405/14 , C07D409/12 , C07D411/12 , C07D413/12 , C07D417/12 , C07D419/12
CPC分类号： C07D401/12 , A01N43/56 , A01N43/80 , A01N47/02 , C07D403/12 , C07D405/12 , C07D405/14 , C07D409/12 , C07D411/12 , C07D413/12 , C07D417/12
摘要： A 5-Acylamino-pyrazole derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl or optionally substituted cycloalkyl,R.sup.3 represents hydrogen or alkyl,R.sup.4 represents hydrogen or alkyl,X represents oxygen or sulphur,n represents the integer 0, 1 or 2,Ar represents in each case optionally substituted phenyl or pyridyl andHet represents an optionally substituted 5- or 6- membered heterocyclic radical linked via a carbon atom,which exhibit herbicidal and plant growth regulating activity.
摘要翻译：其中R 1表示氢，卤素或硝基，R 2表示氢，烷基，烯基，炔基或任意取代的环烷基，R 3表示氢或烷基，R 4表示氢或烷基，X 表示氧或硫，n表示整数0,1或2，Ar表示各自为任意取代的苯基或吡啶基，Het表示经由碳原子连接的任选取代的5-或6-元杂环基，其表现出除草和植物生长调节活性。

76. 发明授权

US4770693A 5-acylamino-1-phenylpyrazoles, composition containing them, and herbicidal method of using them 失效
标题翻译： 5-酰基氨基-1-苯基吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4770693A
公开(公告)日：1988-09-13
申请号：US947665
申请日：1986-12-30
申请人： Reinhold Gehring , Erich Klauke , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Erich Klauke , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , A01N20060101 , A01N47/02 , C07C67/00 , C07C253/00 , C07C255/66 , C07D20060101 , C07D231/38 , C07D231/40 , C07D231/44
CPC分类号： C07D231/38 , A01N43/56 , C07C243/00 , C07C255/00 , C07D231/40
摘要： Herbicidally active novel substituted 5-acylamino-1-phenylpyrazoles of the formula ##STR1## in which R.sup.1 represents cyano, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, alkenylaminocarbonyl or alkinylaminocarbonyl,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl, optionally substituted cycloalkyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl or optionally substituted aryl andR.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7, which are identical or different, represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylsulphonyl, alkoxycarbonyl or a radical --R.sup.8,whereinR.sup.8 represents halogenoalkyl, with the proviso that at least one of the radicals R.sup.3, R.sup.4, R.sup.5, R.sup.6 or R.sup.7 represents a radical --R.sup.8, but R.sup.1 does not represent cyano if R.sup.5 represents trifluoromethyl. Many of the intermediates are also novel.
摘要翻译： R1代表氰基，烷氧基羰基，链烯氧基羰基，烷氧基羰基，氨基羰基，烷基氨基羰基，链烯基氨基羰基或烷基氨基羰基的除草活性新型取代的5-酰基氨基-1-苯基吡唑，其中R1代表氰基，烷氧基羰基，烷基氨基羰基，链烯基氨基羰基或烷基氨基羰基，R2代表氢，烷基，烯基，炔基，任选取代的环烷基，烷氧基烷基，烷硫基烷基，卤代烷基或任意取代的芳基，R 3，R 4，R 5，R 6和R 7相同或不同，代表氢，卤素，氰基，硝基，烷基，烷氧基，烷基磺酰基，烷氧基羰基或基团-R8，其中 R8表示卤代烷基，条件是R 3，R 4，R 5，R 6或R 7中的至少一个表示基团-R 8，但如果R 5表示三氟甲基，R 1不表示氰基。许多中间体也是新颖的。

77. 发明授权

US4740232A Substituted 5-amino-1-phenylpyrazoles composition containing them and herbicidal method of using them 失效
标题翻译：含有它们的5-氨基-1-苯基吡唑组合物和使用它们的除草方法
公开(公告)号：US4740232A
公开(公告)日：1988-04-26
申请号：US754048
申请日：1985-07-11
申请人： Reinhold Gehring , Jorg Stetter , Otto Schallner , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Jorg Stetter , Otto Schallner , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/38 , C07D231/40 , C07D231/14
CPC分类号： C07D231/38
摘要： Herbicidally active 5-amino-1-phenylpyrazoles of the formula ##STR1## in which R is CN, or an ester or amido group,R.sup.1 is an organic radical,R.sup.2 is an organic radical, hydrogen or an acyl or thioacyl radical,R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 can be hydrogen or various organic radicals but at least one is a haloalkyl, haloalkoxy, haloalkylthio, haloalkylsulphinyl or haloalkylsulphonyl radical, but R is not CN at the same time as R.sup.5 is CF.sub.3. The compounds ##STR2## are intermediates therefor and are also herbicidal.
摘要翻译：其中R为CN或式（Ⅰ）或酰氨基的式“IMAGE”的除草活性的5-氨基-1-苯基吡唑为R1为有机基团，R2为有机基团，氢或酰基或硫代酰基，R3， R 4，R 5，R 6和R 7可以是氢或各种有机基团，但至少一个是卤代烷基，卤代烷氧基，卤代烷硫基，卤代烷基亚磺酰基或卤代烷基磺酰基，但R 5不是CN，同时是R5是CF3。化合物“IMAGE”是其中间体，也是除草剂。

78. 发明授权

US4711658A 5-perfluoroacylamino-4-nitro-1-arylpyrazole salts, plant growth regulating and herbicidal composition containing them, and plant growth regulating and herbicidal method of using them 失效
标题翻译： 5-全氟酰基氨基-4-硝基-1-芳基吡唑盐，含有它们的植物生长调节和除草组合物，以及使用它们的植物生长调节和除草方法
公开(公告)号：US4711658A
公开(公告)日：1987-12-08
申请号：US934047
申请日：1986-11-24
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/40 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/40
摘要： 5-perfluoroacylamino-4-nitro-1-arylpyrazole salts of the formula ##STR1## in which R represents a perfluoroalkyl radical,M.sup..sym. represents one equivalent of a metal cation, or represents an optionally substituted ammonium ion andAr represents in each case optionally substituted phenyl or pyridyl,exhibit herbicidal and plant growth-regulating activity.
摘要翻译：其中R表示全氟烷基，M（+）表示1当量的金属阳离子，或表示任选取代的铵离子，Ar表示各自的全氟酰基氨基-4-硝基-1-芳基吡唑盐任选取代的苯基或吡啶基的情况，表现出除草和植物生长调节活性。

79. 发明授权

US4685957A 1-aryl-5-iminoaminopyrazoles, compositions containing them, and herbicidal method of using them 失效
标题翻译： 1-芳基-5-亚氨基氨基吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4685957A
公开(公告)日：1987-08-11
申请号：US885064
申请日：1986-07-14
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Klaus Lurssen , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/40 , A01N43/56 , C07D231/16 , C07D231/38 , C07D401/04
CPC分类号： C07D231/38 , A01N43/56 , C07D231/16 , C07D401/04
摘要： Plant growth regulants and herbicides of the formula ##STR1## in which R.sup.1 represents hydrogen or alkyl,R.sup.2 represents cyano or nitro,R.sup.3 and R.sup.4 independently of one another each represent hydrogen, alkyl, alkoxyalkyl, alkylthioalkyl or halogenoalkyl or represent optionally substituted aryl, orR.sup.3 and R.sup.4 together represent a divalent alkylene radical,R.sup.5 represents hydrogen or alkyl andAr represents optionally substituted phenyl, or represented optionally substituted pyridyl.
摘要翻译：其中R 1表示氢或烷基，R 2表示氰基或硝基，R 3和R 4各自独立地表示氢，烷基，烷氧基烷基，烷硫基烷基或卤代烷基，或表示任意取代的芳基，或 R3和R4一起表示二价亚烷基，R 5表示氢或烷基，Ar表示任选取代的苯基，或表示任选取代的吡啶基。

80. 发明授权

US4614533A Herbicidal 5-amino-1-phenylpyrazoles 失效
标题翻译：除草剂5-氨基-1-苯基吡唑
公开(公告)号：US4614533A
公开(公告)日：1986-09-30
申请号：US690347
申请日：1985-01-10
申请人： Otto Schallner , Reinhold Gehring , Erich Klauke , Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel
发明人： Otto Schallner , Reinhold Gehring , Erich Klauke , Jorg Stetter , Heinz-Jurgen Wroblowsky , Robert R. Schmidt , Hans-Joachim Santel
IPC分类号： A01N43/56 , A01N47/02 , A01N47/18 , A01N47/22 , A01N47/36 , A01N53/00 , A01N57/22 , A01N57/24 , C07C67/00 , C07C253/00 , C07C255/66 , C07C317/32 , C07C317/48 , C07C323/48 , C07D231/38 , C07D231/40 , C07F9/40 , C07F9/6509 , A01N57/16
CPC分类号： C07D231/38 , A01N43/56 , A01N47/02 , A01N47/18 , A01N47/22 , A01N47/36 , A01N53/00 , A01N57/22 , C07D231/40 , C07F9/4015 , C07F9/650935
摘要： Herbicidally active 5-amino-1-phenyl-pyrazoles, most of which are new, of the formula ##STR1##
摘要翻译：抗除草活性的5-氨基-1-苯基 - 吡唑，其中大部分是新的，具有式（IMAGE）

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