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    • 72. 发明授权
    • Herbicidal pyrazolin-5-one derivatives, compositions and use
    • 除草剂吡唑啉-5-酮衍生物,组合物和用途
    • US5174808A
    • 1992-12-29
    • US610597
    • 1990-11-08
    • Heinz-Jurgen WroblowskyPeter BabczinskiKlaus LurssenHans-Joachim SantelRobert R. Schmidt
    • Heinz-Jurgen WroblowskyPeter BabczinskiKlaus LurssenHans-Joachim SantelRobert R. Schmidt
    • A01N43/56C07D231/22C07D401/04C07D405/04C07D405/06C07D409/04C07D409/06
    • C07D401/04C07D231/22C07D405/04C07D409/04C07D409/06
    • Herbicidal pyrazolin-5-one derivatives of the formula ##STR1## in which R.sup.1 represents alkyl, cycloalkyl, halogenoalkyl, alkenyl, alkynyl, alkenyl or alkynyl substituted by optionally substituted phenyl, halogenoalkenyl, alkoxy, alkoxyalkyl, alkylthioalkyl, alkylsulphonylalkyl, alkylsulphinylalkyl, alkoxycarbonylalkyl, in each case optionally substituted aryl, aralkyl, aryloxyalkyl or arylthioalkyl, an optionally substituted heterocycle, heterocyclylalkyl or the --NH--CO--R.sup.3 or --CO--O--R.sup.4 groups, in which R.sup.3 and R.sup.4 in each case independently of one another represent alkyl or aryl,R.sup.2 represents hydrogen, alkyl, cycloalkyl, halogenoalkyl, alkenyl, alkinyl, halogenoalkenyl, alkoxyalkyl, alkylthioalkyl, alkylsulphonylalkyl, alkylsuslphinylalkyl or alkoxycarbonylalkyl andAr represents optionally substituted aryl or a heterocycle which is optionally substituted and optionally fused,excluding the compounds 1-(3-chlorophenyl)-3-methylthiomethyl-4-(N-hydroxyaminomethylidene)-pyrazoline-5-one, 1-(4-chlorophenyl)-3-methylthiomethyl-4-(N-hydroxyaminomethylidene)-pyrazolin-5-one, 1-(4-trifluoronethylphenyl-3-methylthiomethyl-4-(N-hydroxyaminomethylidene))-pyrazolin-5-one and 1-(4-n-nitrophenyl)-3-methylthiomethyl-4-(N-hydroxyaminomethylidene)-pyrazolin-5-one.
    • 式(Ⅰ)的除草吡唑啉-5-酮衍生物,其中R 1表示被任选取代的苯基,卤代烯基,烷氧基,烷氧基烷基,烷基硫代烷基,烷基磺酰基烷基,烷基亚磺酰基烷基,烷基磺酰基烷基, 烷氧基羰基烷基,在各种情况下均为任选取代的芳基,芳烷基,芳氧基烷基或芳硫基烷基,任选取代的杂环,杂环基烷基或-NH-CO-R 3或-CO-O-R 4基团,其中R 3和R 4各自独立地为 另一个代表烷基或芳基,R 2表示氢,烷基,环烷基,卤代烷基,烯基,炔基,卤代烯基,烷氧基烷基,烷基硫代烷基,烷基磺酰基烷基,烷基磺酰基烷基或烷氧基羰基烷基,Ar表示任选取代的芳基或任选被取代和任选稠合的杂环, 化合物1-(3-氯苯基)-3-甲硫基甲基-4-(N-羟基氨基亚甲基) - 吡唑并-5-酮, 1-(4-氯苯基)-3-甲基硫代甲基-4-(N-羟基氨基亚甲基) - 吡唑啉-5-酮,1-(4-三氟甲基苯基-3-甲硫基甲基-4-(N-羟基氨基甲基二烯) 5-(1-硝基苯基)-3-甲基硫代甲基-4-(N-羟基氨基亚甲基) - 对]吡唑-5-酮。
    • 76. 发明授权
    • Herbicidal substituted triazolinones
    • 除草取代的三唑啉酮
    • US5238902A
    • 1993-08-24
    • US852482
    • 1992-03-16
    • Kurt FindeisenHans-Joachim SantelKlaus LurssenRobert R. Schmidt
    • Kurt FindeisenHans-Joachim SantelKlaus LurssenRobert R. Schmidt
    • A01N47/38C07D249/14
    • C07D249/14A01N47/38
    • Herbicidal substituted triazolinones of the formula ##STR1## in which R.sup.1 and R.sup.2, independently of one another, each represents alkyl, alkenyl, alkynyl, halogenoalkyl, halogenoalkenyl, halogenoalkynyl, cyanoalkyl, alkoxyalkyl, alkoxy cycloalkyl or cycloalkylalkyl or aryl, aralkyl or heteroaryl, each of which is optionally substituted; or, together with the nitrogen atom to which they are bonded, represent an optionally substituted heterocycle,R.sup.3 and R.sup.4, independently of one another, each represents hydrogen, alkyl, alkenyl, alkynyl, halogenoalkyl, halogenoalkenyl, halogenoalkynyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, alkylaminoalkyl, dialkylaminoalkyl, alkoxycarbonylalkyl or alkoxycarbonylalkenyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl or cycloalkenylalkyl, each of which is optionally substituted; optionally substituted heterocyclylalkyl; aralkyl, aroyl or aryl, each of which is optionally substituted, alkoxy, alkenyloxy, alkynyloxy, aralkyloxy or aryloxy or, together with the nitrogen to which they are bonded, represent an optionally substituted heterocycle,R.sup.5 represents alkyl or cycloalkyl andX represents oxygen or sulphur.
    • 式(I)的除草取代的三唑啉酮其中R 1和R 2彼此独立地表示烷基,烯基,炔基,卤代烷基,卤代烯基,卤代炔基,氰基烷基,烷氧基烷基,烷氧基环烷基或环烷基烷基或芳基,芳烷基或 杂芳基,其各自任选被取代; 或者与它们所键合的氮原子一起表示任选取代的杂环,R 3和R 4彼此独立地表示氢,烷基,烯基,炔基,卤代烷基,卤代烯基,卤代炔基,氰基烷基,羟基烷基,烷氧基烷基, 烷基氨基烷基,二烷基氨基烷基,烷氧基羰基烷基或烷氧基羰基烯基,环烷基,环烷基烷基,环烯基或环烯基烷基,其各自任选被取代; 任选取代的杂环基烷基; 芳烷基,芳酰基或芳基,其各自为任选取代的烷氧基,烯氧基,炔氧基,芳烷氧基或芳氧基,或与它们所键合的氮一起代表任选取代的杂环,R 5表示烷基或环烷基,X表示氧或 硫。
    • 77. 发明授权
    • Pesticidal 3-aryl-pyrrolidine-2,4-diones
    • 杀虫剂3-芳基 - 吡咯烷-2,4-二酮
    • US5186737A
    • 1993-02-16
    • US678479
    • 1991-04-01
    • Reiner FischerBernd BaasnerHermann HagemanAndreas KrebsAlbrecht MarholdHans-Joachim SantelRobert R. SchmidtKlaus LurssenBenedikt BeckerKlaus SchallerHarry Strang
    • Reiner FischerBernd BaasnerHermann HagemanAndreas KrebsAlbrecht MarholdHans-Joachim SantelRobert R. SchmidtKlaus LurssenBenedikt BeckerKlaus SchallerHarry Strang
    • A01N43/36A01N47/06C07D207/38C07D405/12
    • C07D405/12A01N43/36A01N47/06C07D207/38
    • Insecticidal, acaricidal, herbicidal and antimycotic 3-aryl-pyrrolidine-2,4-diones of the formula ##STR1## in which X represents alkyl, halogen or alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,Z represents alkyl, halogen or alkoxy,n represents a number from 0-3,R represents hydrogen or represents the groups --CO--R.sup.1 or --CO--O--R.sup.2, in whichR.sup.1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl which can be interrupted by hetero atoms, each of which radicals is optionally substituted by halogen, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, andR.sup.2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or optionally substituted phenyl or cycloalkyl, each of which radicals is optionally substituted by halogen,A represents alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, or cycloalkyl which is optionally interrupted by a hetero atom, each of which radicals is optionally subsituted by halogen, or represents arylalkyl which is optionally substituted by halogen, alkyl, halogenoalkyl, alkoxy or nitro,B and C* independently of one another represent hydrogen, alkyl or alkoxyalkyl.
    • 式(I)的杀虫,杀螨,除草和抗真菌性3-芳基 - 吡咯烷-2,4-二酮其中X代表烷基,卤素或烷氧基,Y代表氢,烷基,卤素,烷氧基或卤代烷基,Z 表示烷基,卤素或烷氧基,n表示0-3的数,R表示氢或表示基团-CO-R1或-CO-O-R2,其中R1表示烷基,烯基,烷氧基烷基,烷硫基烷基,聚烷氧基烷基或环烷基 任何取代的苯基,取代的杂芳基,取代的苯氧基烷基或取代的噻唑烷基,或代表任意取代的苯基,任选取代的苯基烷基,取代的杂芳基, 取代的苯氧基烷基和取代的硫代氧基烷基,R 2表示烷基,链烯基,烷氧基烷基,聚烷氧基烷基或任选取代的苯基或环烷基,各w 任选被卤素取代的基团,A代表烷基,烯基,炔基,烷氧基烷基,聚烷氧基烷基,烷硫基烷基或环烷基,任选被杂原子中断,每个基团任选被卤素取代,或表示任选取代的芳基烷基 卤素,烷基,卤代烷基,烷氧基或硝基,B和C *彼此独立地表示氢,烷基或烷氧基烷基。
    • 79. 发明授权
    • Pesticidal tautomers of 3-aryl-pyrrolidine-2,4-diones and use thereas
    • 3-芳基 - 吡咯烷-2,4-二酮的杀虫互变异构体
    • US5045560A
    • 1991-09-03
    • US460208
    • 1990-01-02
    • Reiner FischerBernd BaasnerHermann HagemannAndreas KrebsAlbrecht MarholdHans-Joachim SantelRobert R. SchmidtKlaus LurssenBenedikt BeckerKlaus SchallerHarry Strang
    • Reiner FischerBernd BaasnerHermann HagemannAndreas KrebsAlbrecht MarholdHans-Joachim SantelRobert R. SchmidtKlaus LurssenBenedikt BeckerKlaus SchallerHarry Strang
    • A01N43/36A01N47/06C07D207/38C07D405/12
    • C07D405/12A01N43/36A01N47/06C07D207/38
    • Insecticidal, acaricidal, herbicidal and antimycotic 3-aryl-pyrrolidine-2,4-diones of the formula ##STR1## in which X represents alkyl, halogen or alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,Z represents alkyl, halogen or alkoxy,n represents a number from 0-3,R represents hydrogen or represents the groups --CO--R.sup.1 or --CO--O--R.sup.2, in whichR.sup.1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl which can be interrupted by hetero atoms, each of which radicals is optionally substituted by halogen, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, andR.sup.2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or optionally substituted phenyl or cycloalkyl, each of which radicals is optionally substituted by halogen,A represents alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, or cycloalkyl which is optionally interrupted by a hetero atom, each of which radicals is optionally substituted by halogen, or represents arylalkyl which is optionally substituted by halogen, alkyl, halogenoalkyl, alkoxy or nitro,B and C* independently of one another represent hydrogen, alkyl or alkoxyalkyl.
    • 式(I)的杀虫,杀螨,除草和抗真菌性3-芳基 - 吡咯烷-2,4-二酮其中X代表烷基,卤素或烷氧基,Y代表氢,烷基,卤素,烷氧基或卤代烷基,Z 表示烷基,卤素或烷氧基,n表示0-3的数,R表示氢或表示基团-CO-R1或-CO-O-R2,其中R1表示烷基,烯基,烷氧基烷基,烷硫基烷基,聚烷氧基烷基或环烷基 任何取代的苯基,取代的杂芳基,取代的苯氧基烷基或取代的噻唑烷基,或代表任意取代的苯基,任选取代的苯基烷基,取代的杂芳基, 取代的苯氧基烷基和取代的硫代氧基烷基,R 2表示烷基,链烯基,烷氧基烷基,聚烷氧基烷基或任选取代的苯基或环烷基,各w 任选被卤素取代的基团,A代表烷基,链烯基,炔基,烷氧基烷基,聚烷氧基烷基,烷硫基烷基或环烷基,任选被杂原子间隔,每个基团任选被卤素取代,或表示任选取代的芳基烷基 卤素,烷基,卤代烷基,烷氧基或硝基,B和C *彼此独立地表示氢,烷基或烷氧基烷基。