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71. 发明授权

US4273662A 2-Oxabicyclooctane derivatives, processes for preparing same and organoleptic uses thereof 失效
标题翻译： 2-氧杂二环辛烷衍生物，其制备方法和感官用途
公开(公告)号：US4273662A
公开(公告)日：1981-06-16
申请号：US120103
申请日：1980-02-08
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： C11B9/00 , D06M13/18
CPC分类号： C11B9/008 , C11B9/0034
摘要： Described are derivatives of 2-oxabicyclo [2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff and medicinal product flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes.
摘要翻译：描述的是2-氧杂二环[2.2.2]辛烷及其前体，环己烯甲醇以及所述环己烯甲醇的低级烷基酯的衍生物。氧杂双环辛烷可用于香料和食品以及药用产品香料。环己烯甲醇可用作氧杂双环辛烷的前体。

72. 发明授权

US4269862A Use of 1,3,5,5-Tetramethyl-2-oxabicyclo[2.2.2]octane in augmenting or enhancing the aroma or taste of foodstuffs 失效
标题翻译：使用1,3,5,5-四甲基-2-氧杂双环[2.2.2]辛烷来增强或增强食品的香气或味道
公开(公告)号：US4269862A
公开(公告)日：1981-05-26
申请号：US77539
申请日：1979-09-21
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/40 , C07C29/40 , C07D493/08 , C11B9/00 , C11D3/50 , C11D9/44 , A23L1/226
CPC分类号： C07D493/08 , A24B15/403 , C07C29/40 , C11B9/0034 , C11B9/008 , C11D3/505 , C11D9/442 , C07C2101/16
摘要： Described is the use of 1,3,5,5-tetramethyl-2-oxabicyclo[2.2.2]octane for augmenting or enhancing the aroma or taste of foodstuffs.
摘要翻译：描述了1,3,5,5-四甲基-2-氧杂二环[2.2.2]辛烷用于增强或增强食品香气或味道的用途。

73. 发明授权

US4263208A 2-Oxabicyclooctane derivatives, processes for preparing same and organoleptic uses thereof 失效
标题翻译： 2-氧杂二环辛烷衍生物，其制备方法和感官用途
公开(公告)号：US4263208A
公开(公告)日：1981-04-21
申请号：US95092
申请日：1979-11-16
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： C07C29/40 , C07D493/08 , C11B9/00 , C07D311/00
CPC分类号： C07D493/08 , C07C29/40 , C11B9/0034 , C11B9/008 , C07C2101/16
摘要： Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff, medicinal product and tobacco flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes and are, themselves, useful for their organoleptic properties in perfumery and flavors as are the esters of said cyclohexenemethanols.
摘要翻译：描述的是2-氧杂二环[2.2.2]辛烷及其前体，环己烯甲醇以及所述环己烯甲醇的低级烷基酯的衍生物。氧杂双环辛烷可用于香料和食品，药用产品和烟草香精。环己烯甲醇可用作氧杂双环辛烷的前体，它们本身可用于香料和香料中的感官特性，以及所述环己烯甲醇的酯类。

74. 发明授权

US4248250A Use of cyclic chemical compounds for augmenting or enhancing the aroma or taste of smoking tobacco and smoking tobacco article 失效
标题翻译：使用环状化合物来增强或增强烟草和烟草制品的香气或味道
公开(公告)号：US4248250A
公开(公告)日：1981-02-03
申请号：US46362
申请日：1979-06-07
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/30 , A24B3/12
CPC分类号： A24B15/30
摘要： Described is a process for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of intimately admixing with smoking tobacco, an organoleptic property augmenting or enhancing quantity of a cyclic chemical compound having a structure selected from the group consisting of: ##STR1## wherein R.sub.1 is selected from the group consisting of hyrogen and methyl; R.sub.2 is C.sub.3 -C.sub.5 alkyl or alkenyl; and R.sub.5 is hydrogen or C.sub.1 -C.sub.4 acyl and wherein one of the dashed lines is a carbon-carbon single bond and the other of the dashed lines is a carbon-carbon double bond.Also described is a smoking tobacco article comprising (i) smoking tobacco; (ii) a wrapper holding in place said smoking tobacco and in intimate contact with a portion of said smoking tobacco and (iii) optionally a filter unit in partial contact with said wrapper and said smoking tobacco; said filter unit or said smoking tobacco having intimately admixed therewith at least one cyclic chemical compound having a structure selected from the group consisting of: ##STR2## wherein R.sub.1 is selected from the group consisting of hydrogen and methyl; R.sub.2 is C.sub.3 -C.sub.5 alkyl or alkenyl; and R.sub.5 is hydrogen or C.sub.1 -C.sub.4 acyl and wherein one of the dashed lines is a carbon-carbon single bond and the other of the dashed lines is a carbon-carbon double bond.
摘要翻译：描述了一种用于增强或增强烟草香气或味道的方法，其包括与吸烟烟草紧密混合的步骤，感官特性增强或增强量的具有选自以下的结构的环状化合物：其中R1选自氢和甲基; R2是C3-C5烷基或烯基; R5是氢或C1-C4酰基，其中虚线之一是碳 - 碳单键，另一个虚线是碳 - 碳双键。还描述了一种吸烟烟草制品，其包括（i）吸烟; （ii）将所述吸烟烟草保持在适当位置并与所述吸烟烟草的一部分紧密接触的包装物，和（iii）任选地与所述包装纸和所述吸烟烟草部分接触的过滤器单元; 所述过滤器单元或所述吸烟烟草与其中紧密混合的至少一种具有选自以下的结构的环状化合物：其中R 1选自氢和甲基; R2是C3-C5烷基或烯基; R5是氢或C1-C4酰基，其中虚线之一是碳 - 碳单键，另一个虚线是碳 - 碳双键。

75. 发明授权

US4229314A 2-Oxabicyclooctane derivatives, processes for preparing same and organoleptic uses thereof 失效
标题翻译： 2-氧杂二环辛烷衍生物，其制备方法和感官用途
公开(公告)号：US4229314A
公开(公告)日：1980-10-21
申请号：US052333
申请日：1979-06-27
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： C11D3/50 , C11D9/44
CPC分类号： C11D3/50 , C11D9/442
摘要： Described is a process for augmenting or enhancing the aroma of a solid or liquid detergent comprising the step of adding to a solid or liquid detergent base at least one cyclic chemical compound having a structure selected from the group consisting of: ##STR1##
摘要翻译：描述了一种用于增强或增强固体或液体洗涤剂香气的方法，其包括将至少一种具有选自以下的结构的至少一种环状化合物加入到固体或液体洗涤剂基质的步骤：

76. 发明授权

US4225470A Cyclohexane alkyl carbinol perfume compositions 失效
标题翻译：环己烷烷基甲醇香料组合物
公开(公告)号：US4225470A
公开(公告)日：1980-09-30
申请号：US85685
申请日：1979-10-17
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A23G3/00 , A23G3/36 , A23G4/00 , A23G4/06 , A23L27/20 , C07C29/40 , C07D493/08 , C11B9/00 , A61K7/46
CPC分类号： A23G3/36 , A23G4/06 , A23L27/203 , C07C29/40 , C07C403/08 , C07D493/08 , C11B9/0034 , C07C2101/16
摘要： Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff and medicinal product flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes.
摘要翻译：描述的是2-氧杂二环[2.2.2]辛烷及其前体，环己烯甲醇以及所述环己烯甲醇的低级烷基酯的衍生物。氧杂双环辛烷可用于香料和食品以及药用产品香料。环己烯甲醇可用作氧杂双环辛烷的前体。

77. 发明授权

US4221721A 2-Oxabicyclooctane derivatives, processes for preparing same and organoleptic uses thereof 失效
标题翻译： 2-氧杂二环辛烷衍生物，其制备方法和感官用途
公开(公告)号：US4221721A
公开(公告)日：1980-09-09
申请号：US52334
申请日：1979-06-27
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A23G3/00 , A23G3/36 , A23G4/00 , A23G4/06 , A23L27/20 , C07D493/08 , C11B9/00 , C07D309/04
CPC分类号： A23G3/36 , A23G4/06 , A23L27/203 , C07D493/08 , C11B9/0046
摘要： Described are cyclic chemical compounds useful for their organoleptic properties in flavors, fragrances, colognes, perfumed articles and smoking tobaccos defined according to the structure: ##STR1## wherein R.sub.1 is hydrogen or methyl and R.sub.2 is C.sub.4 or C.sub.5 alkyl or C.sub.3 alkenyl, specifically, the compounds having the structures: ##STR2##
摘要翻译：描述了根据以下结构定义的香料，香料，古龙香，加香制品和吸烟烟草中的感官特性的环状化合物：其中R1是氢或甲基，R2是C4或C5烷基或C3链烯基，具体地，具有以下结构的化合物：

78. 发明授权

US4448984A Mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效
公开(公告)号：US4448984A
公开(公告)日：1984-05-15
申请号：US458890
申请日：1983-01-18
申请人： Mark A. Sprecker , Marie R. Hanna , Richard J. Tokarzewski , Robert P. Belko , Hugh Watkins , Manfred H. Vock
发明人： Mark A. Sprecker , Marie R. Hanna , Richard J. Tokarzewski , Robert P. Belko , Hugh Watkins , Manfred H. Vock
IPC分类号： A24B15/34 , C07C47/347 , C07C47/445 , C07C43/162 , C07C35/28 , C07C67/035 , C07C67/04
CPC分类号： A24B15/345 , C07C47/347 , C07C47/445
摘要： Described are mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++] is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl. Also described are processes for preparing such mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives, and processes for using the above defined mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives for their organoleptic properties and compositions containing said mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives including perfumes, perfumed articles (such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softeners and cosmetic powders), foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos and smoking tobacco articles.

79. 发明授权

US4391284A Use in modifying smoking tobacco aroma and flavor or mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效
标题翻译：用于改变吸烟烟草香气和风味或单氧甲基取代的多羟基甲基萘衍生物
公开(公告)号：US4391284A
公开(公告)日：1983-07-05
申请号：US354387
申请日：1982-03-02
申请人： Mark A. Sprecker , Marie R. Hanna , Richard J. Tokarzewski , Robert P. Belko , Hugh Watkins , Manfred H. Vock
发明人： Mark A. Sprecker , Marie R. Hanna , Richard J. Tokarzewski , Robert P. Belko , Hugh Watkins , Manfred H. Vock
IPC分类号： A24B15/34 , C07C47/347 , C07C47/445 , A24B3/12 , A24B15/30
CPC分类号： A24B15/345 , C07C47/347 , C07C47/445
摘要： Described is the use in modifying, augmenting or enhancing the aroma or taste of smoking tobacco products of mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++]is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl.
摘要翻译：描述了用于改变，增强或增强具有以下通用结构的单氧代甲基取代的多羟基甲基萘衍生物的烟草产品的香气或味道：其中虚线表示碳 - 碳单键或碳 - 碳双键; 其中R1，R1'，R1“，R1”，R1“，R3，R5，R5'，R5”，R5“，R5”和R6表示氢或甲基，条件：（i）R1，R1'，R1“，R1”和R1“”中的至少四个为氢; 和（ii）R5，R5'，R5“，R5”和R5“中的至少四个表示氢; （ⅰ）具有以下结构的甲醛：（ⅱ）具有以下结构的亚烷基二氧基或二烷氧基甲基：（ⅲ）具有以下结构的羟基甲基：（ⅳ）具有以下结构的乙酰氧基甲基：其中R7和R8分别代表C1-C4低级烷基或R7和R8一起代表C2-C4亚烷基; 其中由以下各项表示的线：[++++]是（i）当R 7和R 8一起为C 2 -C 4亚烷基时的碳 - 碳单键或（ii）当R7和R8分别表示C1 -C4低级烷基。

80. 发明授权

US4301024A Use of cyclic chemical compounds for augmenting or enhancing the aroma of optical brightener composition 失效
标题翻译：使用环状化合物来增强或增强荧光增白剂组合物的香气
公开(公告)号：US4301024A
公开(公告)日：1981-11-17
申请号：US113290
申请日：1980-01-18
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/40 , C07C29/40 , C07D493/08 , C11B9/00 , C09K11/00
CPC分类号： C07D493/08 , A24B15/403 , C07C29/40 , C11B9/0034 , C11B9/008 , C07C2101/16
摘要： Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor, cyclohexenemethanols as well as lower alkyl esters of said cyclohexenemethanols. The oxabicyclooctanes are useful in perfumery and foodstuff, medicinal product and tobacco flavors. The cyclohexenemethanols are useful as precursors for the oxabicyclooctanes and are, themselves, useful for their organoleptic properties in perfumery and flavors as are the esters of said cyclohexenemethanols.
摘要翻译：描述的是2-氧杂二环[2.2.2]辛烷及其前体，环己烯甲醇以及所述环己烯甲醇的低级烷基酯的衍生物。氧杂双环辛烷可用于香料和食品，药用产品和烟草香精。环己烯甲醇可用作氧杂双环辛烷的前体，它们本身可用于香料和香料中的感官特性，以及所述环己烯甲醇的酯类。

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