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    • 71. 发明授权
    • Liquid crystal composition and liquid crystal display element
    • 液晶组成和液晶显示元件
    • US5779933A
    • 1998-07-14
    • US663226
    • 1996-06-17
    • Kanetsugu TerashimaFusayuki TakeshitaHitoshi YamamotoHiroaki Kawasyukuda
    • Kanetsugu TerashimaFusayuki TakeshitaHitoshi YamamotoHiroaki Kawasyukuda
    • C09K19/42C09K19/44C09K19/46C09K19/52G02F1/13
    • C09K19/46C09K19/42C09K19/44
    • A liquid crystal composition which comprises 1 to 15% of a first component (a compound selected from compounds of the formulae I-a and I-b), 8 to 40% of a second component (a compound of the formula II), 10 to 30% of a third component (a compound of the formula III), and 10 to 45% of a fourth component (a compound selected from compounds of the formulae IV-a, IV-b, IV-c and IV-d) ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.8 and R.sup.12 is a C.sub.1 -C.sub.10 alkyl group, R.sup.3 is a C.sub.1 -C.sub.10 alkyl group or a C.sub.2 -C.sub.10 alkenyl group, each of R.sup.4, R.sup.7 and R.sup.11 is a C.sub.1 -C.sub.10 alkyl group or alkoxy group, each of R.sup.5 and R.sup.9 is a C.sub.2 -C.sub.10 alkenyl group or alkenyloxy group, each of R.sup.6 and R.sup.10 is a C.sub.2 -C.sub.10 alkenyl group, and R.sup.13 is a C.sub.2 -C.sub.10 alkoxyalkyl group.
    • PCT No.PCT / JP96 / 00193 Sec。 371日期1996年6月17日第 102(e)1996年6月17日PCT PCT 1996年2月1日PCT公布。 WO96 / 34071 PCT出版物 日期:1996年10月31日一种液晶组合物,其包含1至15%的第一组分(选自式Ia和Ib的化合物的化合物),8至40%的第二组分(式II的化合物) 10至30%的第三组分(式III的化合物)和10至45%的第四组分(选自式IV-a,IV-b,IV-c和IV-d的化合物 (IV)图像(IV)图像(IV)图像(IV)图像(IV)图像(IV-a)<图像>(IV) (IV-d)其中R 1,R 2,R 8和R 12各自为C 1 -C 10烷基,R 3为C 1 -C 10烷基或C 2 -C 10链烯基,R 4,R 7和R 11各自为 C1-C10烷基或烷氧基,R5和R9各自为C2-C10烯基或烯氧基,R6和R10各自为C2-C10烯基,R13为C2-C10烷氧基烷基。
    • 72. 发明授权
    • Liquid crystal composition and electro-optic display device
    • 液晶组成和电光显示装置
    • US5776366A
    • 1998-07-07
    • US741720
    • 1996-10-31
    • Yoshitaka TomiTetsuya MatsushitaFusayuki TakeshitaKatsuyuki MurashiroEtsuo Nakagawa
    • Yoshitaka TomiTetsuya MatsushitaFusayuki TakeshitaKatsuyuki MurashiroEtsuo Nakagawa
    • G02F1/13C09K19/02C09K19/30C09K19/46C09K19/58C09K19/52
    • C09K19/586C09K19/0208C09K19/3001C09K19/3003C09K19/46C09K2019/0444
    • A chiral, nematic liquid crystal composition suitable to STN-LCD, having superior steepness, rapid response and being able to prevent occurrence of high order and low order domain of LCD, which composition contains as a first component, at least one compound expressed by the formula (1) ##STR1## as a second component, at least one compound expressed by the formula (2) ##STR2## and as a third component, at least one compound of benzonitrile group, ##STR3## and further having a chiral dopant as a fourth component. In the above formulas, R.sup.1 and R.sup.2 each represent a linear alkyl group of 1 to 10 carbon atoms, A and B each represent trans-1,4-cyclohexylene or 1,4-phenylene, and R.sup.3 represents a linear alkyl group of 1 to 10 carbon atoms, or a group wherein an optional --CH.sub.2 -- or two or more not adjacent --CH.sub.2 --s present in the above group are replaced by --O-- or --CH=CH--; X.sup.1 and X.sup.2 each independently represent H or F; C represents --COO--, --C.sub.2 H.sub.4 --, trans-1,4-cyclohexylene or 1,4-phenylene; and n represents 0 or 1, and as a fourth component, a chiral dopant in a quantity in which a ratio (d/p) of the thickness (d.mu.m) of a liquid crystal layer in a liquid crystal cell to be filled with the liquid crystal composition to the helical pitch thereof (p.mu.m) is 0.03 to 2.0.
    • 适用于STN-LCD的手性向列型液晶组合物,其具有优异的陡度,快速响应性并且能够防止LCD的高阶和低阶畴的发生,该组合物含有作为第一组分的至少一种化合物 式(1)作为第二组分的至少一种化合物作为第二组分,至少一种由式(2)表示的化合物(2)和作为第三组分的至少一种苄腈基化合物,&lt; IMAGE&gt; 3),并且还具有手性掺杂剂作为第四组分。 在上式中,R 1和R 2各自表示1〜10个碳原子的直链烷基,A和B各自表示反式-1,4-亚环己基或1,4-亚苯基,R3表示1〜 10个碳原子,或其中存在于上述基团中的任选的-CH 2 - 或两个或更多个不相邻的-CH 2 -S取代为-O-或-CH = CH-的基团; X1和X2各自独立地表示H或F; C表示-COO - , - C 2 H 4 - ,反式-1,4-亚环己基或1,4-亚苯基; n表示0或1,作为第四成分的手性掺杂剂,其中液晶单元中待填充的液晶层的厚度(dμm)的比值(dμm) 液晶组合物的螺旋间距(μm)为0.03〜2.0。