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    • 72. 发明专利
    • Photo-crosslinkable polymers and crosslinked polymers obtained from them, useful in the microelectronics, automobile and aircraft industries, are new
    • DE10131536A1
    • 2003-01-16
    • DE10131536
    • 2001-06-29
    • INFINEON TECHNOLOGIES AG
    • HALIK MARCUSWALTER ANDREASLOWACK KLAUSSEZI RECAI
    • C08G73/02C08G73/10C08J5/18C09J179/08H01L21/312C08G83/00C09D5/24C08J3/24
    • Photo-crosslinkable polymers and crosslinked polymers obtained from them are new. The photo-crosslinkable polymers have the formula (I): RA(QXQ)d(Y NHZ (OH)2NHY QXQ)e(Y NHZ (OH)2NH)fRB (I) A(QXQ)a(Y )b(NHZ (OH)2NHY )c (Ia) (Y )g(QXQ)hA (Ib) RA = formula (Ia); RB = formula (Ib); A = H, hetero atom whose free valencies are saturated by H atoms, or a bonding residue which can include up to 30 C atoms and one or more hetero atoms; X = contains 1-500 repeating units; Y to Y = up to 50C double bonding residue, where Y to Y have at least two carbonyl groups, via which Y to Y are bonded to Q or to a Z-group bonded NH group, where at least the Y group is formed from a structural unit of formula (II); R = H or a bonding residue which can include one or more hetero atoms; Z to Z = up to 80C bonding residue, two pairs of which have vicinal bonds to adjacent O and N, from a six-member aromatic or five- or six-member heteroaromatic ring, which is part of the Z group (sic), and the bonding pairs can be from the same or different rings; a = 0 or 1, and when a = 0 and b = 1, A = ORx or NRx2,where Rx can be H or a 20C bonding residue, and when a = 1 and b = 1; b = 0 or 1 and when b = 0 a = 0; c = 1-100; d = 0 or 1; e = 0-20; f = 0-100; g = 0 or 1,and when g = 0 h = 0; and h = 0 or 1, and when h =0 and g =1, A =ORx or NRx2, and when h =1 g = 1. An Independent claim is included for a crosslinked polymer obtainable by subjection of the photo-polymerizable polymer (PPP) to: (a) heat treatment whereby the hydroxyamide group of the PPP is cyclized to an oxazole by splitting off water; and (b) crosslinking of the Y to Y groups, with structural units of formula (II) by radiation with light of wavelength 230 to 600 nm. Steps (a) and (b) can be in any order or simultaneous.