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71. 发明授权

US4568760A Process for the preparation of lactic acid silyl esters 失效
标题翻译：制备乳酸甲硅烷基酯的方法
公开(公告)号：US4568760A
公开(公告)日：1986-02-04
申请号：US752204
申请日：1985-07-03
申请人： Bernd Gallenkamp , Hermann D. Krall
发明人： Bernd Gallenkamp , Hermann D. Krall
IPC分类号： C07F7/08 , C07F7/04 , C07F7/18
CPC分类号： C07F7/0818
摘要： Novel lactic acid silyl esters of the formula ##STR1## in which R represents alkyl or aryl, are obtained by a new process which comprises reacting a lactic acid of the formula ##STR2## with a chloromethylsilane of the formula ##STR3## in which R has the meaning indicated above, in the presence of a tertiary amine and, if appropriate, in the presence of an additional diluent, at temperatures between 50.degree. and 120.degree. C.
摘要翻译：通过新的方法获得式（I）的新颖的乳酸甲硅烷基酯，其中R代表烷基或芳基，其包括使式（II）的乳酸与下式的氯甲基硅烷反应：（III）其中R具有上述含义，在叔胺的存在下，如果合适的话，在另外的稀释剂存在下，在50-120℃的温度下进行。

72. 发明授权

US4424168A Preparation of .alpha.-cyano-3-phenoxy-benzyl 3-alkenyl-2,2-dimethyl-cyclopropanecarboxylates 失效
标题翻译： α-氰基-3-苯氧基 - 苄基3-烯基-2,2-二甲基 - 环丙烷羧酸酯的制备
公开(公告)号：US4424168A
公开(公告)日：1984-01-03
申请号：US417766
申请日：1982-09-13
申请人： Reimer Co/ lln , Bernd Gallenkamp , Hans-Joachim Diehr
发明人： Reimer Co/ lln , Bernd Gallenkamp , Hans-Joachim Diehr
IPC分类号： C07C255/39 , A01N53/08 , C07C67/00 , C07C253/00 , C07C121/75
CPC分类号： A01N53/00
摘要： A process for the preparation of a known pesticidal .alpha.-cyano-3-phenoxy-benzyl 3-alkenyl-2,2-dimethyl-cyclopropanecarboxylate of the general formula ##STR1## in which R.sup.1 and R.sup.2 independently of each other represent a hydrogen or halogen atom, R.sup.3 represents a hydrogen or halogen atom or an optionally substituted alkyl group, and R.sup.4 represents a halogen atom, an optionally substituted alkyl or alkenyl radical or an optionally substituted phenyl group, or, together with R.sup.3, represents an alkanediyl (alkylene) radical, comprises reacting a 3-alkenyl-2,2-dimethyl-cyclopropanecarboxylic acid-chloride of the general formula ##STR2## with a 3-phenoxy-benzaldehyde of the general formula ##STR3## --or an adduct thereof with an alkali metal bisulphite (hydrogen sulphite or pyrosulphite)--and an alkali metal cyanide, using an alkyl ester of a C.sub.1 to C.sub.6 carboxylic acid and water as diluents, if appropriate with the addition of an alkali metal bisulphite, at a temperature between -5 and +25.degree. C. The compounds of formula (I) may be so produced with a high proportion of the more pesticidally active isomers present.
摘要翻译：制备通式（I）的已知的杀虫α-氰基-3-苯氧基-3-链烯基-2,2-二甲基 - 环丙烷甲酸苄酯的方法，其中R 1和R 2彼此独立地表示氢或卤原子，R 3表示氢或卤素原子或任选取代的烷基，R 4表示卤素原子，任选取代的烷基或烯基或任选取代的苯基，或与R 3一起代表烷二基（亚烷基）基团，包括使通式（IMAGE）（II）的3-链烯基-2,2-二甲基 - 环丙烷甲酰氯与通式为（III）的3-苯氧基 - 苯甲醛反应，或者与碱金属亚硫酸氢盐（亚硫酸氢盐或焦亚硫酸盐）和碱金属氰化物的加合物，如果适用，加入碱金属亚硫酸氢盐，使用C1至C6羧酸的烷基酯和水作为稀释剂，在温度在-5和 + 25℃。式（I）化合物可以以高比例存在的杀虫活性异构体异构体来制备。

73. 发明授权

US4367344A Process for the preparation of 1-amino-cyclopropane-carboxylic acid compounds 失效
标题翻译：制备1-氨基 - 环丙烷 - 羧酸化合物的方法
公开(公告)号：US4367344A
公开(公告)日：1983-01-04
申请号：US180557
申请日：1980-08-22
申请人： Bernd Gallenkamp
发明人： Bernd Gallenkamp
IPC分类号： C07C227/00 , A01N53/00 , A01N53/10 , C07C67/00 , C07C227/18 , C07C229/48 , C07C231/00 , C07C231/12 , C07C233/52 , C07C233/81 , C07C101/18 , C07C101/14 , C07C125/06
CPC分类号： A01N53/00
摘要： A process for the preparation of 1-amino-cyclopropane-carboxylic acid or a derivative thereof of the general formula ##STR1## in which R.sup.1 represents hydrogen or alkyl andR.sup.2 represents hydrogen or a radical --CO--R.sup.3, whereinR.sup.3 represents hydrogen, alkyl, aryl or alkoxy, in which a 2-cycloamino-4-methylthio-butanoic acid ester ("acyl-methionine ester") of the general formula ##STR2## in which R.sup.3 has the meaning indicated above andR.sup.4 represents alkyl,is reacted successively with dimethyl sulphate and an alkali metal alcoholate, if appropriate in the presence of a diluent, at a temperature between 80.degree. C. and 150.degree. C., the product is then optionally saponified with aqueous alkali metal hydroxide or alkaline-earth metal hydroxide at a temperature between 70.degree. C. and 150.degree. C., the reaction mixture thereby obtained is acidified with concentrated hydrochloric acid at a temperature between 0.degree. C. and 30.degree. C., and the hydrochloride formed is then treated, in methanolic solution, with propylene oxide at a temperature between -5.degree. C. and +20.degree. C.
摘要翻译：制备通式为（I）的1-氨基 - 环丙烷 - 羧酸或其衍生物的方法，其中R 1表示氢或烷基，R 2表示氢或基团-CO-R 3，其中R 3表示氢，烷基，芳基或烷氧基，其中通式（IMA）（II）中的2-环氨基-4-甲硫基 - 丁酸酯（“酰基 - 甲硫氨酸酯”），其中R3具有上述含义，R4 代表烷基，如果合适，在稀释剂存在下，在80℃至150℃的温度下，依次与二甲基硫酸盐和碱金属醇盐反应，然后将产物任选地用碱金属氢氧化物水溶液皂化，或碱土金属氢氧化物，温度在70℃至150℃之间，由此得到的反应混合物用浓盐酸在0℃至30℃之间的温度下酸化，然后形成的盐酸盐在甲醇溶液中处理离子与环氧丙烷在-5℃至+ 20℃之间的温度下

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