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71. 发明申请

US20050020436A1 Production of catalysts for olefin conversion 失效
标题翻译：生产用于烯烃转化的催化剂
公开(公告)号：US20050020436A1
公开(公告)日：2005-01-27
申请号：US10691811
申请日：2003-10-23
申请人： Jean-Pierre Dath , Luc Delorme , Jacques-Francois Grootjans , Xavier Vanhaeren , Walter Vermeiren
发明人： Jean-Pierre Dath , Luc Delorme , Jacques-Francois Grootjans , Xavier Vanhaeren , Walter Vermeiren
IPC分类号： B01J29/06 , B01J29/40 , B01J37/10 , C10G11/05
CPC分类号： C10G11/05 , B01J29/40 , B01J2229/16 , B01J2229/26 , B01J2229/42
摘要： A process for producing a catalyst for olefin cracking, the process comprising the steps of providing an MFI-type crystalline silicate catalyst, heating the catalyst in steam to remove aluminum from the crystalline silicate framework and extracting aluminum from the catalyst by contacting the catalyst with a complexing agent for aluminum to remove from pores of the framework aluminum deposited therein during the steaming step thereby to increase the silicon/aluminum atomic ratio of the catalyst; and calcining the catalyst at elevated temperature.
摘要翻译：一种制备用于烯烃裂解的催化剂的方法，该方法包括以下步骤：提供MFI型结晶硅酸盐催化剂，在蒸汽中加热催化剂以从结晶硅酸盐骨架中除去铝，并从催化剂中提取铝，使催化剂与在蒸汽步骤期间，铝的络合剂从沉积在其中的骨架铝的孔中除去，从而提高催化剂的硅/铝原子比; 并在高温下煅烧催化剂。

72. 发明授权

US06646176B1 Production of olefins 失效
标题翻译：生产烯烃
公开(公告)号：US06646176B1
公开(公告)日：2003-11-11
申请号：US09206208
申请日：1998-12-05
申请人： Jean-Pierre Dath , Luc Delorme , Jacques-François Grootjans , Xavier Vanhaeren , Walter Vermeiren
发明人： Jean-Pierre Dath , Luc Delorme , Jacques-François Grootjans , Xavier Vanhaeren , Walter Vermeiren
IPC分类号： C07C406
CPC分类号： C10G11/05 , C10G2400/20
摘要： A process for the catalytic cracking of an olefin-containing feedstock which is selective towards light olefins in the effluent, the process comprising contacting a hydrocarbon feedstock containing at least one olefin with a MFI-type crystalline silicate catalyst having a silicon/aluminum atomic ratio of at least about 180, which has been obtained by pretreating so as to increase the silicon/aluminum atomic ratio thereof by heating the catalyst in steam and de-aluminating the catalyst by treating the catalyst with a complexing agent for aluminum, at an inlet temperature of from 500 to 600° C. and at an olefin partial pressure of from 0.1 to 2 bars to produce an effluent with an olefin content of lower molecular weight than that of the feedstock.
摘要翻译：一种对流出物中的轻质烯烃具有选择性的含烯烃原料的催化裂化方法，该方法包括使含有至少一种烯烃的烃原料与硅/铝原子比为至少约180，其通过预处理而获得，以便通过在蒸汽中加热催化剂和使催化剂脱铝来提高其硅/铝原子比，通过用铝络合剂处理催化剂，在入口温度为 500至600℃，烯烃分压为0.1至2巴，以产生烯烃含量低于原料分子量的流出物。

73. 发明授权

US06410813B1 Production of olefins 失效
标题翻译：生产烯烃
公开(公告)号：US06410813B1
公开(公告)日：2002-06-25
申请号：US09596406
申请日：2000-06-19
申请人： Jean-Pierre Dath , Walter Vermeiren , Koen Herrebout
发明人： Jean-Pierre Dath , Walter Vermeiren , Koen Herrebout
IPC分类号： C07C402
CPC分类号： C10G51/06 , B01J29/40 , B01J2229/16 , B01J2229/36 , C07C4/06 , C09K2019/546 , C10G11/05 , C10G2400/20 , C07C11/02
摘要： A process for cracking an olefin-containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600° C., at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30h−1 to produce an effluent with an olefin content of lower molecular weight than that of the feedstock.
摘要翻译：一种用于裂解对流出物中的轻质烯烃具有选择性的含烯烃的烃原料的方法，该方法包括使含有一种或多种烯烃的烃原料通过含有选自具有硅的MFI型结晶硅酸盐的结晶硅酸盐的反应器 /铝原子比为180以上的硅/铝原子比为150〜800的MEL型结晶硅酸盐，其入口温度为500〜600℃，进行了蒸汽工序，在烯烃分压为0.1至2巴，并且原料以5至30小时-1的LHSV通过催化剂以产生具有比原料低的分子量的烯烃含量的流出物。

74. 发明授权

US6150294A Production of crystalline silicate catalyst having monoclinic structure 有权
标题翻译：具有单斜结构的结晶硅酸盐催化剂的生产
公开(公告)号：US6150294A
公开(公告)日：2000-11-21
申请号：US206209
申请日：1998-12-05
申请人： Jean-Pierre Dath , Luc Delorme , Jacques-Fran.cedilla.ois Grootjans , Xavier Vanhaeren , Walter Vermeiren
发明人： Jean-Pierre Dath , Luc Delorme , Jacques-Fran.cedilla.ois Grootjans , Xavier Vanhaeren , Walter Vermeiren
IPC分类号： B01J29/40 , B01J37/06 , C01B39/36 , C10G11/05
CPC分类号： B01J29/40 , B01J2229/16 , B01J2229/36 , B01J2229/37 , C10G2400/20
摘要： A process for producing a crystalline silicate catalyst having a monoclinic structure, the process comprising providing a crystalline silicate of the MFI-type having a silicon/aluminum atomic ratio lower than 80; treating the crystalline silicate with steam and thereafter leaching aluminum from the crystalline silicate by contact with an aqueous solution of a leachant to provide a silicon/aluminum atomic ratio in the catalyst of at least 80 whereby the catalyst has a monoclinic structure.
摘要翻译：一种制备具有单斜结构的结晶硅酸盐催化剂的方法，该方法包括提供硅/铝原子比低于80的MFI型晶体硅酸盐; 用蒸汽处理结晶硅酸盐，然后通过与浸出剂的水溶液接触从结晶硅酸盐中浸出铝，以使催化剂中的硅/铝原子比至少为80，由此催化剂具有单斜晶体结构。

75. 发明授权

US11351529B2 Catalyst for use in hydrotreatment, comprising metals from groups VIII and VIB, and preparation with citric acid and C1-C4 dialkyl succinate 有权
公开(公告)号：US11351529B2
公开(公告)日：2022-06-07
申请号：US14005936
申请日：2012-02-10
申请人： Bertrand Guichard , Laurent Simon , Valentina De Grandi , Delphine Minoux , Jean-Pierre Dath
发明人： Bertrand Guichard , Laurent Simon , Valentina De Grandi , Delphine Minoux , Jean-Pierre Dath
IPC分类号： B01J31/34 , B01J31/02 , B01J38/52 , C10G45/04 , B01J37/20 , C10G47/12 , B01J23/882 , B01J23/94 , B01J35/00 , B01J31/04 , B01J38/62 , C10G45/08 , C10G45/50 , B01J23/883 , B01J37/02 , B01J23/85 , C10G45/06 , C10G45/68 , C10G45/10 , C10G45/12 , C10G45/54 , C10G47/14 , C10G47/18 , B01J21/04 , B01J37/00 , B01J21/12
摘要： A catalyst which comprises an amorphous support based on alumina, a C1-C4 dialkyl succinate, citric acid and optionally acetic acid, phosphorus and a hydrodehydrogenating function comprising at least one element from group VIII and at least one element from group VIB; the most intense bands comprised in the Raman spectrum of the catalyst are characteristic of Keggin heteropolyanions (974 and/or 990 cm−1), C1-C4 dialkyl succinate and citric acid (in particular 785 and 956 cm−1). Also a process for preparing said catalyst in which a catalytic precursor in the dried, calcined or regenerated state containing the elements of the hydrodehydrogenating function, and optionally phosphorus, is impregnated with an impregnation solution comprising at least one C1-C4 dialkyl succinate, citric acid and optionally at least one compound of phosphorus and optionally acetic acid, and is then dried. Further, the use of said catalyst in any hydrotreatment process.

76. 发明授权

US10300467B2 Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite 有权
公开(公告)号：US10300467B2
公开(公告)日：2019-05-28
申请号：US14236736
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/85 , C07C4/06 , C07C2/86 , C07C2/08 , C07C1/22 , B01J37/10 , B01J37/28 , B01J29/40 , C07C1/20 , C07C1/24 , C07C2/66 , C10G29/20 , C10G29/22 , C10G3/00 , B01J37/00 , B01J29/65 , B01J29/70
摘要： A method to make a phosphorus modified zeolite can include providing a zeolite including at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with one or more binders and shaping additives, and then shaping the mixture. The method can include making a ion-exchange. The shaped mixture can be steamed. Phosphorous can be introduced on the catalyst to introduce at least 0.1 wt % of phosphorus, such as be dry impregnation or chemical vapor deposition. A metal, such as calcium, can be introduced. The catalyst can be washed, calcinated, and then steamed. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.

77. 发明授权

US09067199B2 Method for making a catalyst comprising a phosphorus modified zeolite to be used in an alcohols dehydration process 有权
标题翻译：用于制备包含用于醇脱水过程中的磷改性沸石的催化剂的方法
公开(公告)号：US09067199B2
公开(公告)日：2015-06-30
申请号：US13522633
申请日：2011-01-25
申请人： Nikolai Nesterenko , Sander Van Donk , Delphine Minoux , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Sander Van Donk , Delphine Minoux , Jean-Pierre Dath
IPC分类号： C07C1/24 , B01J29/85 , B01J29/06 , B01J29/40 , B01J37/28 , C07C1/20 , B01J27/16 , B01J37/00
CPC分类号： C07C1/24 , B01J27/16 , B01J29/06 , B01J29/40 , B01J29/85 , B01J37/0009 , B01J37/0045 , B01J37/06 , B01J37/08 , B01J37/28 , B01J2229/18 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C2529/40 , C07C2529/85 , C07C11/02
摘要： The present invention is the use of a catalyst to convert an alcohol into light olefins in a dehydration process wherein said catalyst comprises a phosphorus modified zeolite and is made by a method comprising the following steps in this order, a) the essential portion of the phosphorus is introduced into a zeolite comprising at least one ten members ring in the structure, b) the phosphorus modified zeolite of step a) is mixed with at least a component selected among one or more binders, salts of alkali-earth metals, salts of rare-earth metals, clays and shaping additives, b)* making a catalyst body from mixture b), c) an optional drying step or an optional drying step followed by a washing step, d) a calcination step, d*) an optional washing step followed by drying, e) optionally a small portion of phosphorus is introduced in the course of step b) or b)* or at end of step b) or b)*.
摘要翻译：本发明是在脱水方法中使用催化剂将醇转化为轻质烯烃，其中所述催化剂包含磷改性沸石，并通过包括以下步骤的方法制备：a）磷的主要部分被引入到在结构中包含至少一个十元环的沸石中，b）步骤a）的磷改性沸石与至少一种选自一种或多种粘合剂，碱土金属盐，稀有盐 - 矿物金属，粘土和成型添加剂，b）*从混合物b）制备催化剂体，c）任选的干燥步骤或任选的干燥步骤，然后洗涤步骤，d）煅烧步骤，d *）任选洗涤步骤，然后干燥，e）任选地在步骤b）或b）*或步骤b）或b）*的末端引入少量的磷。

78. 发明申请

US20140243570A1 Use of a Catalyst Comprising a Phosphorous Modified Zeolite in an Alcohol Dehydration Process 有权
标题翻译：在醇脱水过程中使用包含磷改性沸石的催化剂
公开(公告)号：US20140243570A1
公开(公告)日：2014-08-28
申请号：US14236726
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath , Joseph Lopez , Patrick Euzen
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , B01J29/40 , B01J29/85 , B01J37/10 , B01J37/28 , C07C2527/14 , C07C2529/06 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： A catalyst can be used to convert an alcohol in a dehydration process into an olefin having the same number of carbon atoms as the alcohol. The catalyst can include a phosphorus modified zeolite made by providing a zeolite with at least one ten member ring in the structure, steaming the zeolite, mixing the zeolite with binders and shaping additives, and shaping the zeolite. An ion-exchange step can be performed, and the shaped catalyst can be steamed. Phosphorus can be introduced on the catalyst at an amount of at least 0.1 wt %, such as by dry impregnation or chemical vapor deposition. A metal can be introduced. The catalyst can be washed and/or calcinated, and steamed in an equilibration step. The steaming severity (X) can be at least about 2. The catalyst can be steamed at a temperature above 625° C., such as a temperature ranging from 700 to 800° C.
摘要翻译：催化剂可用于将脱水过程中的醇转化为具有与醇相同数目的碳原子的烯烃。催化剂可以包括通过在结构中提供具有至少一个十元环的沸石而制成的磷改性沸石，蒸煮沸石，将沸石与粘合剂和成型添加剂混合，以及成型沸石。可以进行离子交换步骤，并且可以蒸成型催化剂。磷可以以至少0.1重量％的量引入催化剂上，例如通过干浸渍或化学气相沉积。可以引入金属。可以将催化剂洗涤和/或煅烧，并在平衡步骤中蒸煮。蒸汽浓度（X）可以至少约为2.催化剂可以在高于625℃的温度下蒸煮，例如700-800℃的温度。

79. 发明申请

US20140051901A9 Catalytic Cracking 审中-公开
标题翻译：催化裂化
公开(公告)号：US20140051901A9
公开(公告)日：2014-02-20
申请号：US12097537
申请日：2006-12-14
申请人： Jean-Pierre Dath , Walter Vermeiren , Andre Noiret
发明人： Jean-Pierre Dath , Walter Vermeiren , Andre Noiret
IPC分类号： B01J29/14 , C07C4/06 , B01J29/08 , B01J29/072 , B01J29/06
CPC分类号： B01J29/40 , B01J29/084 , B01J29/80 , B01J37/0045 , B01J2229/16 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G11/05
摘要： A process for producing a catalyst additive for an FCC catalytic cracking process, the process comprising the steps of providing an MFI or MEL aluminosilicate having a silicon/aluminium atomic ratio of from 10 to 250; de-aluminating the MFI or MEL aluminosilicate by extracting from 20 to 40 wt % of the alumina therefrom; combining the de-aluminated MFI or MEL aluminosilicate with a binder; and calcining the combination of the de-aluminated MFI or MEL aluminosilicate and the binder at elevated temperature to produce the catalyst additive.
摘要翻译：一种用于制备用于FCC催化裂化过程的催化剂添加剂的方法，所述方法包括以下步骤：提供硅/铝原子比为10至250的MFI或MEL硅铝酸盐; 通过从其中提取20至40重量％的氧化铝，使MFI或MEL硅铝酸盐脱铝; 将脱铝的MFI或MEL硅铝酸盐与粘合剂组合; 并在升高的温度下煅烧脱铝的MFI或MEL硅铝酸盐和粘合剂的组合以产生催化剂添加剂。

80. 发明申请

US20130217943A1 DEHYDRATION OF ALCOHOLS ON ACIDIC CATALYSTS 有权
标题翻译：酒精在酸性催化剂上的脱水
公开(公告)号：US20130217943A1
公开(公告)日：2013-08-22
申请号：US13701774
申请日：2011-06-20
申请人： Delphine Minoux , Cindy Adam , Nikolai Nesterenko , Jean-Pierre Dath , Walter Vermeiren , Sander Van Donk
发明人： Delphine Minoux , Cindy Adam , Nikolai Nesterenko , Jean-Pierre Dath , Walter Vermeiren , Sander Van Donk
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2529/40 , C07C2529/65 , C07C2529/82 , C07C2529/83 , C07C2529/85 , Y02P20/52 , C07C11/04
摘要： The present invention is a process for the dehydration of an alcohol having at least 2 carbon atoms to make the corresponding olefin, comprising: a) introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, b) contacting said stream with an acidic catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, c) recovering from said reactor a stream (B) comprising: the inert component and at least an olefin, water and optionally unconverted alcohol, d) optionally fractionating the stream (B) to recover the unconverted alcohol and recycling said unconverted alcohol to the reactor of step a), e) optionally fractionating the stream (B) to recover the inert component, water and the olefin and optionally recycling said inert component and optionally a part of the water to the reactor of step a), wherein, f) an effective amount of a component capable to neutralize a part of the catalyst active site is introduced in stream (A) or directly in the dehydration reactor and g) optionally the temperature of the dehydration reactor is adjusted to increase the alcohol conversion or the olefin yield or both. In another embodiment at step f) an effective amount of a component capable to increase the selectivity for the desired corresponding olefin is introduced in stream (A) or directly in the dehydration reactor.The component introduced at step f) can be chosen from the group consisting of ammonia, organic ammonium salts, hydrazine, nitriles, amines (including pyridines, pyrrols, pyrrolydones and pyrrolidines), amides, imines, di-imines, imides, cyanates, isocyanates, nitrites and nitroso compounds, aldehydes, ketones, carboxylic esters, and their corresponding thio-compounds (thiols, sulphides, disulfides).
摘要翻译：本发明是使具有至少2个碳原子的醇脱水以制备相应的烯烃的方法，其包括：a）在反应器中引入至少包含醇，任选的水，任选的惰性组分的流（A） b）使所述物流与所述反应器中的酸性催化剂接触，在有效使所述醇的至少一部分脱水以制备烯烃的条件下，c）从所述反应器回收流（B），其包含：所述惰性组分和至少一种烯烃，水和任选的未转化的醇，d）任选地将料流（B）分馏以回收未转化的醇，并将所述未转化的醇再循环到步骤a）的反应器中，e）任选地将料流（B）分馏以回收惰性组分，水和烯烃，并任选地将所述惰性组分和任选的一部分水再循环到步骤a）的反应器中，其中f）有效量的能够中和一部分Ca 天然气活性位点以流（A）或直接在脱水反应器中引入，并且g）任选地调节脱水反应器的温度以增加醇转化率或烯烃产率或两者。在步骤f）的另一个实施方案中，有效量的能够增加所需相应烯烃的选择性的组分被引入到流（A）中，或直接在脱水反应器中引入。在步骤f）引入的组分可以选自氨，有机铵盐，肼，腈，胺（包括吡啶，吡咯，吡咯烷酮和吡咯烷），酰胺，亚胺，二亚胺，酰亚胺，氰酸酯，异氰酸酯，亚硝酸盐和亚硝基化合物，醛，酮，羧酸酯及其相应的硫代化合物（硫醇，硫化物，二硫化物）。

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