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61. 发明授权

US09409116B2 Porous polymer network materials 有权
标题翻译：多孔聚合物网络材料
公开(公告)号：US09409116B2
公开(公告)日：2016-08-09
申请号：US14405653
申请日：2012-12-13
申请人： THE TEXAS A&M UNIVERSITY SYSTEM
发明人： Hong-Cai Zhou , Julian Sculley , Weigang Lu
IPC分类号： B01D53/02 , F17C11/00 , B01D53/04 , C08J9/00 , B01J20/26 , B01J20/28
CPC分类号： B01D53/04 , B01D53/02 , B01D2253/202 , B01D2256/10 , B01D2257/504 , B01D2257/7025 , B01D2259/4525 , B01J20/265 , B01J20/267 , B01J20/28066 , C08J9/00 , C08J2365/00 , C08J2383/00 , C08J2385/00 , F17C11/007 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156
摘要： Functionalized Porous Polymer Networks (PPNs) exhibiting favourable characteristics such as high surface area′ and gas uptake properties are disclosed, including methods of making such networks. A method of preparing a porous polymer network, comprising: (a) a step of homo-coupling a monomer in the presence of 2,2′-bipyridyl, 1,5-cycloocta-1,5-diene, a mixed solvent of DMF/THF and a compound or mixture selected from the group consisting of bis(1,5-cydoocta-1,5-diene)nickel(0), Ni(PPH3) 4, and Zn/NiCI2/NaBr/PPH3 at a temperature in the range of 20 to 40° C. These stable PPNs may be useful in the context of carbon capture, gas storage and separation, and as supports for catalysts.
摘要翻译：公开了表现出有利特征如高表面积和气体吸收性能的功能化多孔聚合物网络（PPN），包括制备这种网络的方法。一种制备多孔聚合物网络的方法，包括：（a）在2,2'-联吡啶，1,5-环辛-1,5-二烯，DMF的混合溶剂存在下使单体均相偶联的步骤 / THF和选自双（1,5-环己基-1,5-二烯）镍（0），Ni（PPH 3）4和Zn / NiCl 2 / NaBr / PPH 3的化合物或混合物，温度为范围为20至40℃。这些稳定的PPN可用于碳捕获，气体储存和分离以及作为催化剂的载体。

62. 发明授权

US09114352B2 Staged membrane process for high pressure hydrogen production 有权
标题翻译：用于高压氢生产的分阶段膜工艺
公开(公告)号：US09114352B2
公开(公告)日：2015-08-25
申请号：US13717876
申请日：2012-12-18
申请人： L'Air Liquide Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
发明人： Trapti Chaubey , Bhadra S. Grover , Pascal Tessier
IPC分类号： C01B3/02 , B01D53/22 , B01D71/02 , C01B3/50 , B01D53/04
CPC分类号： B01D53/228 , B01D53/04 , B01D53/226 , B01D53/229 , B01D71/022 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2257/80 , C01B3/505 , C01B2203/0205 , C01B2203/025 , C01B2203/0283 , C01B2203/043 , C01B2203/145 , C01B2203/147 , C01B2203/148 , C01B2203/86 , Y02C10/10 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y02P30/30
摘要： A hydrogen purification process is provided. This process includes separating hydrogen from a hydrogen containing stream in at least two sequential palladium membrane purification zones, wherein each purification zone has a permeate side, wherein the permeate side pressure of purification zones are not the same.
摘要翻译：提供氢气净化方法。该方法包括在至少两个顺序的钯膜净化区中从含氢气流分离氢，其中每个纯化区具有渗透侧，其中净化区的渗透侧压力不相同。

63. 发明申请

US20150144085A1 METAL COMPLEX, AND ABSORBENT MATERIAL, STORAGE MATERIAL AND SEPARATION MATERIAL COMPRISING METAL COMPLEX 有权
标题翻译：金属复合材料和吸收材料，储存材料和分离材料，包含金属复合材料
公开(公告)号：US20150144085A1
公开(公告)日：2015-05-28
申请号：US14410681
申请日：2013-06-28
申请人： KURARAY CO., LTD.
发明人： Yasutaka Inubushi , Chikako Ikeda , Takashi Hori , Masanori Miura , Takuya Inagaki
IPC分类号： B01D53/04 , B01D53/047 , C07F1/08 , F02B43/02 , B01J20/22 , B01J20/28
CPC分类号： B01D53/0462 , B01D53/02 , B01D53/047 , B01D2253/112 , B01D2253/204 , B01D2256/10 , B01D2256/16 , B01D2256/24 , B01D2256/245 , B01D2257/102 , B01D2257/104 , B01D2257/108 , B01D2257/11 , B01D2257/50 , B01D2257/504 , B01D2257/7022 , B01D2257/7025 , B01D2259/40011 , B01J20/223 , B01J20/226 , B01J20/28023 , B01J20/28033 , B01J20/28038 , C01B32/50 , C07C63/28 , C07F1/08 , F02B43/02 , F17C11/005 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y02P20/51 , Y02T10/32
摘要： The metal complex comprises a multivalent carboxylic acid compound, at least one metal ion selected from ions of metals belonging to Groups 2 to 13 of the periodic table, an organic ligand capable of multidentate binding to the metal ion, and a C1 or C2 monocarboxylic acid compound. The metal complex has excellent gas adsorption, storage, and separation performance as well as excellent durability. The metal complex is stably present under high temperature and high humidity, and can maintain high adsorption performance.
摘要翻译：金属络合物包括多价羧酸化合物，选自属于周期表第2至13族的金属的离子中的至少一种金属离子，能够与金属离子多元结合的有机配体，以及C1或C2单羧酸复合。金属络合物具有优良的气体吸附，储存和分离性能以及优异的耐久性。金属络合物在高温高湿下稳定存在，可以保持较高的吸附性能。

64. 发明申请

US20140227157A1 CHEMICAL LOOPING REMOVAL OF VENTILATION AIR METHANE 有权
标题翻译：化学循环去除通风空气甲烷
公开(公告)号：US20140227157A1
公开(公告)日：2014-08-14
申请号：US14348500
申请日：2012-09-28
申请人： NEWCASTLE INNOVATION LIMITED
发明人： Behdad Moghtaderi , Elham Doroodchi
IPC分类号： B01D53/86
CPC分类号： B01D53/8668 , B01D53/72 , B01D2251/20 , B01D2255/20738 , B01D2255/20761 , B01D2257/7025 , C01B3/10 , C01B32/50 , Y02C20/20 , Y02E60/36 , Y02P20/142 , Y02P20/156
摘要： Methane is removed from ventilation air by cycling metal or metal oxide particles in a chemical looping process in one or more reactors where the metal particles are alternately reduced and oxidised, and passing ventilation air through one or more of said reactors to convert the air plus methane into reduced air plus water plus carbon dioxide. In one variation, ventilation air methane (VAM) is removed from ventilation air in coal mines using a chemical looping process to move metal or metal oxide particles between reactors such as a hydrogen generator (5) and a regenerator (7) to alternatively reduce and oxidise the particles such that VAM introduced into a combustor (6) provided with hydrogen from the hydrogen generator (5) can be processed in the regenerator (7) to produce air plus water plus carbon dioxide. Other variations involve the use of three reactors in the chemical looping process, or the use of an array of parallel inclined plates forming lamellas between upper and lower reactors to keep lighter particles in the upper oxidiser reactor and heavier particles in the lower reducer reactor.
摘要翻译：通过在一个或多个反应器中的化学循环过程中循环金属或金属氧化物颗粒将金属从通风空气中除去，其中金属颗粒被交替地还原和氧化，并且使通风空气通过一个或多个所述反应器以将空气加甲烷减少空气加水加二氧化碳。在一个实施例中，通过化学循环过程在煤矿的通风空气中除去通风空气甲烷（VAM），以在诸如氢发生器（5）和再生器（7）的反应器之间移动金属或金属氧化物颗粒，以交替地减少和氧化颗粒，使得可以在再生器（7）中处理从氢生成器（5）引入到具有氢气的燃烧器（6）中的VAM以产生空气加水加二氧化碳。其他变化涉及在化学循环过程中使用三个反应器，或者使用在上反应器和下反应器之间形成薄片的平行倾斜板阵列，以将上部氧化剂反应器中的较轻颗粒保持在较低的还原反应器中较重的颗粒。

65. 发明申请

US20140010753A1 HYDROGEN PRODUCTION WITH CARBON CAPTURE 有权
标题翻译：氢气生产与碳捕获
公开(公告)号：US20140010753A1
公开(公告)日：2014-01-09
申请号：US14020073
申请日：2013-09-06
申请人： Narasimhan Sundaram , John W. Viets
发明人： Narasimhan Sundaram , John W. Viets
IPC分类号： C01B3/22
CPC分类号： C01B3/22 , B01D53/0473 , B01D53/1475 , B01D53/75 , B01D2252/20447 , B01D2252/20484 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/25 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2259/4141 , C01B3/32 , C01B3/48 , C01B3/52 , C01B3/56 , C01B31/20 , C01B32/50 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0811 , C01B2203/1041 , C01B2203/1211 , C01B2203/1235 , C01B2203/1264 , C01B2203/145 , C01B2203/86 , Y02C10/06 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y02P30/30
摘要： Systems and methods for hydrogen production with carbon capture are provided. A hydrogen containing stream can be divided so that a portion of the stream is processed for separation of CO2. A hydrogen enriched stream formed during separation of CO2 and another portion of the hydrogen containing stream can be processed in a cycling adsorber unit to form a hydrogen product stream. Optionally, the cycling adsorber unit can be operated to form a plurality of tail gas streams. The hydrogen containing stream can be a reformed hydrocarbon stream and/or an input stream previously exposed to a water gas shift catalyst. Optionally, a portion of the reformed hydrocarbon stream can be a reformed biocomponent stream.
摘要翻译：提供了利用碳捕集技术制氢的系统和方法。可以将含氢的流分开，使得一部分流被处理以分离CO 2。在分离CO 2和另一部分含氢气流期间形成的富氢流可以在循环吸附器单元中加工以形成氢产物流。任选地，循环吸附器单元可以被操作以形成多个尾气流。含氢气流可以是重整的烃流和/或先前暴露于水煤气变换催化剂的输入流。任选地，重整烃流的一部分可以是重整的生物组分流。

66. 发明授权

US08551217B2 Six bed pressure swing adsorption process operating in normal and turndown modes 有权
标题翻译：六床变压吸附过程在正常和调节模式下运行
公开(公告)号：US08551217B2
公开(公告)日：2013-10-08
申请号：US13185099
申请日：2011-07-18
申请人： Mohamed S. A. Baksh , Marian Simo
发明人： Mohamed S. A. Baksh , Marian Simo
IPC分类号： B01D53/047
CPC分类号： B01D53/047 , B01D53/0423 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/304 , B01D2256/16 , B01D2257/102 , B01D2257/11 , B01D2257/50 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2257/80 , B01D2259/40039 , B01D2259/40041 , B01D2259/40075 , B01D2259/4061 , B01D2259/4062 , B01D2259/41 , B01D2259/4145 , B01D2259/4146 , C01B3/56 , C01B2203/043 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156
摘要： The present invention relates to a six bed pressure swing adsorption (PSA) system utilizing new and advanced cycles to obtain enhanced hydrogen recovery from a hydrogen containing feed gas (i.e., synthesis gas). In one such cycle each of the six beds has four pressure equalization steps, and at least one of the beds is receiving and processing said feed gas to obtain a hydrogen product gas (i.e., a 6-1-4 cycle).
摘要翻译：本发明涉及利用新的和先进的循环从含氢原料气（即合成气）获得增强的氢回收的六床变压吸附（PSA）系统。在一个这样的循环中，六个床中的每个床具有四个压力平衡步骤，并且至少一个床正在接收和处理所述进料气体以获得氢气产物（即，6-1-4循环）。

67. 发明申请

US20130131344A1 ORGANO-METALLIC FRAMEWORKS DERIVED FROM CARBENOPHILIC METALS AND METHODS OF MAKING SAME 审中-公开
标题翻译：从碳化金属衍生的有机金属框架及其制造方法
公开(公告)号：US20130131344A1
公开(公告)日：2013-05-23
申请号：US13578579
申请日：2011-02-12
申请人： Omar M. Yaghi , Alexander U. Czaja , Kounosuke Oisaki
发明人： Omar M. Yaghi , Alexander U. Czaja , Kounosuke Oisaki
IPC分类号： C07F15/00
CPC分类号： C07F15/006 , B01D53/02 , B01D2253/204 , B01D2253/306 , B01D2257/104 , B01D2257/108 , B01D2257/11 , B01D2257/406 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2259/4525 , B01J20/226 , B01J31/04 , B01J31/1691 , B01J31/181 , B01J31/1815 , B01J31/183 , B01J31/2273 , B01J2531/0222 , B01J2531/26 , B01J2531/824 , C01B3/0015 , Y02C10/08 , Y02C20/20 , Y02E60/328 , Y02P20/152 , Y02P20/156
摘要： The disclosure provides organic frameworks comprising increased stability.
摘要翻译：本公开提供了包括增加的稳定性的有机骨架。

68. 发明申请

US20130019750A1 SIX BED PRESSURE SWING ADSORPTION PROCESS OPERATING IN NORMAL AND TURNDOWN MODES 有权
标题翻译：第六台压力摆动吸附过程在正常和涡流模式下运行
公开(公告)号：US20130019750A1
公开(公告)日：2013-01-24
申请号：US13185099
申请日：2011-07-18
申请人： Mohamed S. A. Baksh , Marian Simo
发明人： Mohamed S. A. Baksh , Marian Simo
IPC分类号： B01D53/047
CPC分类号： B01D53/047 , B01D53/0423 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/304 , B01D2256/16 , B01D2257/102 , B01D2257/11 , B01D2257/50 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2257/80 , B01D2259/40039 , B01D2259/40041 , B01D2259/40075 , B01D2259/4061 , B01D2259/4062 , B01D2259/41 , B01D2259/4145 , B01D2259/4146 , C01B3/56 , C01B2203/043 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156
摘要： The present invention relates to a six bed pressure swing adsorption (PSA) system utilizing new and advanced cycles to obtain enhanced hydrogen recovery from a hydrogen containing feed gas (i.e., synthesis gas). In one such cycle each of the six beds has four pressure equalization steps, and at least one of the beds is receiving and processing said feed gas to obtain a hydrogen product gas (i.e., a 6-1-4 cycle).
摘要翻译：本发明涉及利用新的和先进的循环从含氢原料气（即合成气）获得增强的氢回收的六床变压吸附（PSA）系统。在一个这样的循环中，六个床中的每个床具有四个压力平衡步骤，并且至少一个床正在接收和处理所述进料气体以获得氢气产物（即，6-1-4循环）。

69. 发明申请

US20120288439A1 HYDROGEN PRODUCTION WITH CARBON CAPTURE 有权
标题翻译：氢气生产与碳捕获
公开(公告)号：US20120288439A1
公开(公告)日：2012-11-15
申请号：US13468300
申请日：2012-05-10
申请人： Narasimhan Sundaram , John W. Viets
发明人： Narasimhan Sundaram , John W. Viets
IPC分类号： C01B3/56 , B01D53/047
CPC分类号： C01B3/22 , B01D53/0473 , B01D53/1475 , B01D53/75 , B01D2252/20447 , B01D2252/20484 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/25 , B01D2256/16 , B01D2257/502 , B01D2257/504 , B01D2257/7025 , B01D2259/4141 , C01B3/32 , C01B3/48 , C01B3/52 , C01B3/56 , C01B31/20 , C01B32/50 , C01B2203/0233 , C01B2203/0283 , C01B2203/0415 , C01B2203/043 , C01B2203/0811 , C01B2203/1041 , C01B2203/1211 , C01B2203/1235 , C01B2203/1264 , C01B2203/145 , C01B2203/86 , Y02C10/06 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y02P30/30
摘要： Systems and methods for hydrogen production with carbon capture are provided. A hydrogen containing stream can be divided so that a portion of the stream is processed for separation of CO2. A hydrogen enriched stream formed during separation of CO2 and another portion of the hydrogen containing stream can be processed in a cycling adsorber unit to form a hydrogen product stream. Optionally, the cycling adsorber unit can be operated to form a plurality of tail gas streams. The hydrogen containing stream can be a reformed hydrocarbon stream and/or an input stream previously exposed to a water gas shift catalyst. Optionally, a portion of the reformed hydrocarbon stream can be a reformed biocomponent stream.
摘要翻译：提供了利用碳捕集技术制氢的系统和方法。可以将含氢的流分开，使得一部分流被处理以分离CO 2。在分离CO 2和另一部分含氢气流期间形成的富氢流可以在循环吸附器单元中加工以形成氢产物流。任选地，循环吸附器单元可以被操作以形成多个尾气流。含氢气流可以是重整的烃流和/或先前暴露于水煤气变换催化剂的输入流。任选地，重整烃流的一部分可以是重整的生物组分流。

70. 发明申请

US20030167921A1 ACTIVATED CARBON AS SOLE ADSORBENT IN RAPID CYCLE HYDROGEN PSA 有权
标题翻译：活性炭作为快速循环氢PSA中的纯吸附剂
公开(公告)号：US20030167921A1
公开(公告)日：2003-09-11
申请号：US10094185
申请日：2002-03-08
发明人： Timothy Christopher Golden , Edward Landis Weist
IPC分类号： B01D053/02
CPC分类号： B01D53/0473 , B01D53/02 , B01D2253/102 , B01D2253/25 , B01D2253/34 , B01D2253/342 , B01D2256/16 , B01D2256/20 , B01D2257/102 , B01D2257/104 , B01D2257/11 , B01D2257/502 , B01D2257/504 , B01D2257/702 , B01D2257/7025 , B01D2258/0208 , C01B3/56 , C01B2203/043 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , Y02C10/08 , Y02C20/20 , Y02P20/152 , Y02P20/156 , Y10S95/901
摘要： A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and said apparatus are substantially free of zeolite adsorbents; feeding a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.
摘要翻译：一种用于从进料气中回收产物气体的变压吸附方法，包括：提供包含含有活性炭作为主要成分的吸附剂组合物的变压吸附装置，其中吸附剂组合物和所述装置基本上不含沸石吸附剂; 在不超过20秒的进料周期内将进料气体进料到变压吸附装置中; 并从变压吸附装置回收产品气体。该方法和装置特别适用于燃料电池和其它需要用于生产高纯度氢的紧凑，快速循环系统的应用。

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