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61. 发明授权

US5543398A Para-C.sub.5 alkyl-substituted ethoxycyclohexanes, organoleptic uses thereof and processes for preparing same 失效
标题翻译：对-C5烷基取代的乙氧基环己烷，其感官用途及其制备方法
公开(公告)号：US5543398A
公开(公告)日：1996-08-06
申请号：US522122
申请日：1995-08-31
申请人： Michael G. Monteleone , Richard A. Weiss , Marc D. Evans , Marie R. Hanna
发明人： Michael G. Monteleone , Richard A. Weiss , Marc D. Evans , Marie R. Hanna
IPC分类号： C07C43/184 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0061 , C07C43/184 , C11B9/0034 , C07C2101/14
摘要： Described are compounds defined according to the structure: ##STR1## wherein Z represents para cyclohexylene or para phenylene and wherein R.sub.1, R.sub.2 and R.sub.3 are the same or different methyl or hydrogen; and wherein R.sub.4 represents hydrogen, methyl or ethyl with the proviso that the sum of the carbon atoms in R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 2. Also described are para-C.sub.5 alkyl-substituted ethoxycyclohexanes defined according to the structure: ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 represent the same or different methyl or hydrogen; and wherein R.sub.4 represents hydrogen, methyl or ethyl with the proviso that the sum of the carbon atoms in R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 2 and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles and hair preparations; as well as processes for preparing said para-C.sub.5 alkyl-substituted ethoxycyclohexanes.
摘要翻译：描述的是根据以下结构定义的化合物：其中Z代表对亚环己基或对亚苯基，其中R 1，R 2和R 3是相同或不同的甲基或氢; 并且其中R 4表示氢，甲基或乙基，条件是R 1，R 2，R 3和R 4中的碳原子之和为2.还描述了根据以下结构定义的对C5烷基取代的乙氧基环己烷：其中 R1，R2和R3表示相同或不同的甲基或氢; 并且其中R 4表示氢，甲基或乙基，条件是R 1，R 2，R 3和R 4中的碳原子之和为2，并且其用于增强或增强香料组合物，古龙水和香料制品的香气，包括但不限于固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品和头发制剂; 以及制备所述对C5烷基取代的乙氧基环己烷的方法。

62. 发明授权

US5378685A Process for preparing mixture of trimethyl and dimethylmethylene propyl polyhydropyrans, products produced thereby perfumery uses of such product 失效
标题翻译：制备三甲基和二甲基亚甲基丙基多羟基吡喃的混合物的方法，由此产生的产品由此产生香料的用途
公开(公告)号：US5378685A
公开(公告)日：1995-01-03
申请号：US214185
申请日：1994-03-17
申请人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna
发明人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna
IPC分类号： C07D309/04 , C07D309/12 , C11B9/00 , A61K7/46
CPC分类号： C07D309/12 , C07D309/04 , C11B9/008
摘要： Described is a process for preparing trimethyl and dimethylmethylene propyl polyhydropyran derivatives including compounds defined according to the structure: ##STR1## which defines a mixture wherein in the mixture, in each of the compounds one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines represents a carbon-carbon single bond as well as the compound having the structure: ##STR2## products produced thereby; perfumery uses of such products; process intermediates of such process including compounds defined according to the structures: ##STR3## wherein X represents chloro or bromo.
摘要翻译：描述了一种制备三甲基和二甲基亚甲基丙基多氢吡喃衍生物的方法，其包括根据以下结构定义的化合物：其定义为混合物，其中在每种化合物中，虚线中的一个为碳 - 碳双键，虚线中的每一个代表碳 - 碳单键，以及具有以下结构的化合物：由此产生的产物; 这种产品的香水用途; 该方法的加工中间体包括根据以下结构定义的化合物：其中X表示氯或溴。

63. 发明授权

US4956481A Adamantane derivatives, compositions of matter containing same, processes for preparing said adamantane derivatives and said compositions, and organoleptic and deodorancy uses of said adamantane derivatives and said compositions 失效
标题翻译：金刚烷衍生物，含有其的物质组合物，制备所述金刚烷衍生物和所述组合物的方法，以及所述金刚烷衍生物和所述组合物的感官和除臭用途
公开(公告)号：US4956481A
公开(公告)日：1990-09-11
申请号：US261275
申请日：1988-10-21
申请人： William Gillaspey , Myrna L. Hagedorn , Marie R. Hanna , Kathleen E. Boardwick , Charles E. J. Beck , Futoshi Fujioka , Anthony G. Branco , Anubhav Narula , Richard M. Boden
发明人： William Gillaspey , Myrna L. Hagedorn , Marie R. Hanna , Kathleen E. Boardwick , Charles E. J. Beck , Futoshi Fujioka , Anthony G. Branco , Anubhav Narula , Richard M. Boden
IPC分类号： A24B15/34 , C07C35/37 , C07C43/18 , C07C43/188 , C07C43/196 , C07C45/49 , C07C45/50 , C07C45/75 , C07C47/267 , C07C49/453 , C07C49/653 , C07C69/00 , C07D311/00 , C11B9/00
CPC分类号： C07D311/00 , A24B15/345 , C07C35/37 , C07C43/18 , C07C43/188 , C07C43/196 , C07C45/49 , C07C45/50 , C07C45/75 , C07C47/267 , C07C49/453 , C07C49/653 , C07C67/08 , C07C69/00 , C07C69/07 , C11B9/0042 , C07C2103/00 , C07C2103/74
摘要： Described are hydroxy adamantane compounds and derivatives thereof and a process for preparing same.
摘要翻译：描述的是羟基金刚烷化合物及其衍生物及其制备方法。

64. 发明授权

US4933488A Triisobutylene alcohols and esters, uses thereof in perfumery and halogenated intermediates useful for preparing same 失效
标题翻译：三异丁烯醇和酯，其用于可用于制备它的香料和卤代中间体中
公开(公告)号：US4933488A
公开(公告)日：1990-06-12
申请号：US456744
申请日：1989-12-26
申请人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna
发明人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna
IPC分类号： C07C33/025 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07C33/025 , C07C67/11 , C11B9/0015
摘要： Described are triisobutylene alcohols and esters and halogenated intermediates for preparing same defined according to the generic structure: ##STR1## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 " and R.sub.2 " are the same or different and each represents hydrogen, chloro, bromo, hydroxyl or a C.sub.1 -C.sub.3 acyloxy with the provisos that when the dashed line in the 4--4' position is a carbon-carbon double bond then R.sub.1 " is hydrogen and R.sub.2 " is not hydrogen; and R.sub.1 " and R.sub.2 " are not both hydrogen.Also described are the uses of the triisobutylene alcohols and esters in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to perfumed polymers solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations.
摘要翻译：描述了根据一般结构定义的三异丁烯醇和酯和卤代中间体，其中虚线中的一个代表碳 - 碳单键，虚线中的另一个代表碳 - 碳双键; 其中R 1“和R 2”相同或不同，各自表示氢，氯，溴，羟基或C 1 -C 3酰氧基，条件是当4-4'位的虚线是碳 - 碳双键，则R1“是氢，R2”不是氢; 并且R1“和R2”不都是氢。还描述了三异丁烯醇和酯在增强或增强香料组合物，古龙水和加香制品的香气中的用途，包括但不限于：固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，化妆粉和头发制剂。

65. 发明授权

US4933321A Triisobutylene alcohols and esters, uses thereof in perfumery and halogenated intermediates useful for preparing same 失效
标题翻译：三异丁烯醇和酯，其用于可用于制备它的香料和卤代中间体中
公开(公告)号：US4933321A
公开(公告)日：1990-06-12
申请号：US457174
申请日：1989-12-26
申请人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna
发明人： Mark A. Sprecker , Robert P. Belko , Marie R. Hanna
IPC分类号： C07C33/025 , C11B9/00 , C11D3/50
CPC分类号： C07C33/025 , C07C67/11 , C11B9/0015 , C11D3/50
摘要： Described are triisobutylene alcohols and esters and halogenated intermediates for preparing same defined according to the generic structure: ##STR1## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 " and R.sub.2 " are the same or different and each represents hydrogen, chloro, bromo, hydroxyl or a C.sub.1 -C.sub.3 acyloxy with the provisos that when the dashed line in the 4-4' position is a carbon-carbon double bond then R.sub.1 " is hydrogen and R.sub.2 " is not hydrogen; and R.sub.1 " and R.sub.2 " are not both hydrogen.Also described are the uses of the triisobutylene alcohols and esters in augmenting or enhancing the aroma of perfume composition, colognes and perfumed articles including but not limited to perfumed polymers solid or liquid anionic, cationic, nonionic or switterionic detergents, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations.
摘要翻译：描述了根据一般结构定义的三异丁烯醇和酯和卤代中间体，其中虚线中的一个代表碳 - 碳单键，虚线中的另一个代表碳 - 碳双键; 其中R 1“和R 2”相同或不同，各自表示氢，氯，溴，羟基或C 1 -C 3酰氧基，条件是当4-4'位的虚线是碳 - 碳双键，则R1“是氢，R2”不是氢; 并且R1“和R2”不都是氢。还描述了三异丁烯醇和酯在增强或增强香料组合物，古龙水和加香制品的香气中的用途，包括但不限于：固体或液体阴离子，阳离子，非离子或转换洗涤剂，织物柔软剂组合物，织物柔软剂制品，化妆粉和头发制剂。

66. 发明授权

US4847292A Repelling animals with compositions comprising citronellyl nitrile, citronellol, alpha-terpinyl methyl ether and lemon oil 失效
标题翻译：用包含香茅腈，香茅醇，α-萜烯基甲基醚和柠檬油的组合物排斥动物
公开(公告)号：US4847292A
公开(公告)日：1989-07-11
申请号：US67252
申请日：1987-06-29
申请人： Ira Katz , Donald A. Withycombe, deceased , Marie R. Hanna
发明人： Ira Katz , Donald A. Withycombe, deceased , Marie R. Hanna
IPC分类号： A01N27/00 , A01N31/04 , A01N31/06 , A01N37/02 , A01N43/90 , A01N45/02 , A01N49/00
CPC分类号： A01N49/00 , A01N27/00 , A01N31/04 , A01N31/06 , A01N37/02 , A01N43/90 , A01N45/02 , A01N65/36 , Y10S514/918 , Y10S514/92
摘要： Described are animal control compositions and methods; which compositions comprise citronellyl nitrile, citronellol alpha-terpinyl methyl ether and lemon oil and, optionally, caryophyllene, isopulegol, isopulegyl acetate, one or more norbornyl alkyl ethers, one or more 3,4,5,6,6-pentamethyl hexanol-2 derivatives and quinine or one or more of its salts. The compositions can be used "as is" or in the form of a "controlled release" composition whereby the citronellyl nitrile, citronellol, alpha-terpinyl methyl ether and lemon oil and, optionally, the caryophyllene, isopulegol, isopulegyl acetate, one or more norbornyl alkyl ethers, one or more 3,4,5,6,6-pentamethyl hexanol-2 derivatives and quinine or one or more of its salts are intimately admixed (alone or with adjuvants including but not limited to other volatile, odorous ingredients) with a polymeric substance such as polyethylene in the form of pellets or functional articles, e.g., garbage bags.
摘要翻译：描述的是动物控制组合物和方法; 哪些组合物包括香茅腈，香茅醇α-萜烯基甲基醚和柠檬油，以及任选的石竹烯，异ule ol醇，醋酸异丁基酯，一种或多种降冰片基烷基醚，一种或多种3,4,5,6,6-五甲基己醇-2 衍生物和奎宁或其一种或多种盐。组合物可以“按原样”使用或以“控制释放”组合物的形式使用，其中香茅酰腈，香茅醇，α-萜烯基甲基醚和柠檬油以及任选的石竹烯，异ule ol醇，醋酸异己基酯，一种或多种降冰片基烷基醚，一种或多种3,4,5,6,6-五甲基己醇-2衍生物和奎宁或其一种或多种盐紧密混合（单独或与佐剂，包括但不限于其它挥发性，恶臭成分）与聚合物如聚乙烯形成颗粒或功能制品，例如垃圾袋。

67. 发明授权

US4772411A Ethyl norbornyl alkyl ethers, organoleptic uses thereof and process for preparing same 失效
标题翻译：乙基降冰片基烷基醚，其感官用途及其制备方法
公开(公告)号：US4772411A
公开(公告)日：1988-09-20
申请号：US149676
申请日：1988-01-28
申请人： Mark A. Sprecker , Margo Androulakis , Marie R. Hanna
发明人： Mark A. Sprecker , Margo Androulakis , Marie R. Hanna
IPC分类号： C07C43/18 , C11B9/00 , C11D3/50 , C11D7/18
CPC分类号： C11D3/3956 , C07C43/18 , C11B9/0042 , C11B9/0046 , C11D3/50
摘要： Described are ethyl norbornyl alkyl ethers of our invention defined according to the generic structure: ##STR1## wherein R represents C.sub.1 -C.sub.4 lower alkyl and organoleptic uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including but not limited to bleach compositions, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softener compositions, fabric softener articles, cosmetic powders and hair preparations. Also described is a process for preparing such ethyl norbornyl alkyl ethers of our invention by means of reaction of compounds defined according to the structure: ##STR2## and/or compounds defined according to the structure: ##STR3## in admixture with compounds having the structure: ##STR4## with hydrogen in the presence of a hydrogenation catalyst.
摘要翻译：描述了根据以下通用结构定义的本发明的乙基降冰片基烷基醚：其中R表示C1-C4低级烷基及其感官应用，用于增强或增强香水组合物，古龙水和香料制品的香气，包括但不限于漂白组合物，固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，加香聚合物，织物柔软剂组合物，织物柔软剂制品，化妆粉和头发制剂。还描述了通过根据以下结构定义的化合物的反应来制备本发明的这种乙基降冰片基烷基醚的方法：＆lt; IMAGE＆gt;和/或根据以下结构定义的化合物：＆lt; IMAGE＆gt;与具有结构的化合物：在氢化催化剂存在下用氢气。

68. 发明授权

US4582634A Use in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles of 1-phenylpenten-4-one-1 and methyl homologues thereof 失效
标题翻译：用于增强或增强1-苯基戊-4-酮-1及其甲基同系物的香料组合物，古龙水和香料制品的香气
公开(公告)号：US4582634A
公开(公告)日：1986-04-15
申请号：US656662
申请日：1984-10-01
申请人： Mark A. Sprecker , Marie R. Hanna
发明人： Mark A. Sprecker , Marie R. Hanna
IPC分类号： C07C45/68 , C07C45/71 , C07C49/794 , C11B9/00 , A61K7/46 , C11D9/30
CPC分类号： C11B9/0061 , C07C45/68 , C07C45/71 , C07C49/794
摘要： Described for use in augmenting or enhancing the aroma of perfume compositions, perfumed articles and colognes is the genus of compounds having the structure: ##STR1## wherein one of R.sub.1 or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen or wherein both R.sub.1 and R.sub.2 are hydrogen, hereinafter referred to as 1-phenylpenten-4-one-1 and methyl homologues thereof.
摘要翻译：描述用于增强或增强香料组合物，香料制品和古龙水的香气是具有以下结构的化合物的属：其中R 1或R 2中的一个为甲基，R 1或R 2中的另一个为氢或其中两个R 1 R2为氢，以下称为1-苯基戊-4-酮-1及其甲基同系物。

69. 发明授权

US4576742A Perfume uses of reactive product containing mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效
公开(公告)号：US4576742A
公开(公告)日：1986-03-18
申请号：US570100
申请日：1984-01-12
申请人： Mark A. Sprecker , Marie R. Hanna , Richard J. Tokarzewski , Robert P. Belko , Hugh Watkins , Manfred H. Vock
发明人： Mark A. Sprecker , Marie R. Hanna , Richard J. Tokarzewski , Robert P. Belko , Hugh Watkins , Manfred H. Vock
IPC分类号： A24B15/34 , C07C47/347 , C07C47/445 , A61K7/46 , C11B9/00
CPC分类号： A24B15/345 , C07C47/347 , C07C47/445
摘要： Described are mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties;(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++]is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl. Also described are processes for preparing such mono-oxomethyl substituted polyhydrodimethanonaphthalene derivative, and processes for using the above defined mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives, for their organoleptic properties and compositions containing said mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives including perfumes, perfumed articles (such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softeners and cosmetic powders), foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos and smoking tobacco articles.

70. 发明授权

US4541950A Use of macrocyclic lactone in augmenting or enhancing aroma or taste of consumable materials 失效
公开(公告)号：US4541950A
公开(公告)日：1985-09-17
申请号：US617584
申请日：1984-06-05
申请人： Augustinus G. Van Loveren , Marie R. Hanna , Domenick Luccarelli, Jr. , David R. Bowen , Manfred H. Vock , Wilhelmus J. Wiegers
发明人： Augustinus G. Van Loveren , Marie R. Hanna , Domenick Luccarelli, Jr. , David R. Bowen , Manfred H. Vock , Wilhelmus J. Wiegers
IPC分类号： C07D315/00 , C11B9/00 , A61K7/46
CPC分类号： C07D315/00 , C11B9/0073 , C11B9/0084
摘要： Described for use in augmenting or enhancing the aroma or taste of consumable materials including perfume compositions, colognes and perfumed articles, foodstuffs, chewing gums, toothpastes and medicinal products are the cis and/or trans isomers of the macrocyclic lactone defined according to the structure: ##STR1## produced according to the process of first reacting the ester defined according to the structure: ##STR2## with the alkenol having the structure: ##STR3## in order to produce the di-unsaturated ester having the structure: ##STR4## and then causing the said diester to undergo an internal metathesis to form the compound having the structure: ##STR5##

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