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61. 发明授权

US06811884B2 Water repellant surface treatment and treated articles 有权
公开(公告)号：US06811884B2
公开(公告)日：2004-11-02
申请号：US10328804
申请日：2002-12-24
申请人： George B. Goodwin , Chia-Cheng Lin
发明人： George B. Goodwin , Chia-Cheng Lin
IPC分类号： B32B904
CPC分类号： C03C17/3405 , B05D1/28 , B05D5/08 , B05D2203/35 , C09D4/00 , Y10T428/31663 , C08G77/04
摘要： A method is provided for applying a water repellant coating over a substrate surface. The surface is contacted with at least one coating composition including at least one perfluoroalkylalkylsilane, at least one hydrolyzable primer, e.g., a silane and/or siloxane, and at least one non-halogenated, e.g., non-fluorinated, alkylsilane. The perfluoroalkylalkylsilane and non-fluorinated alkylsilane can be selected such that the effective chain length of the non-fluorinated alkylsilane is equal to or longer than the effective chain length of the perfluoroalkylalkylsilane.

62. 发明授权

US06471360B2 Switchable electrochromic devices with uniform switching and preferential area shading 有权
公开(公告)号：US06471360B2
公开(公告)日：2002-10-29
申请号：US09919151
申请日：2001-07-31
申请人： Thomas G. Rukavina , Chia-Cheng Lin
发明人： Thomas G. Rukavina , Chia-Cheng Lin
IPC分类号： G02B2700
CPC分类号： B64C1/1492 , B64C1/1484 , G02F1/155 , G02F1/163
摘要： An electrochromic window assembly includes: a first transparent substrate having a first conductive coating on a surface thereof; a second transparent substrate having a second conductive coating on a surface thereof, the first transparent substrate and the second transparent substrate being spaced from each other to define a chamber therebetween; an electrochromic medium contained in the chamber, the electrochromic medium having a luminous transmittance that varies upon application of an electrical potential through the electrochromic medium; a plurality of first spaced facilities contacting the first conductive coating and capable of delivering electrical current to the first conductive coating; and a plurality of second spaced facilities contacting the second conductive coating and capable of delivering electrical current to the second conductive coating to establish the electrical potential through the electrochromic medium. The plurality of first spaced facilities and the plurality of second spaced facilities can be bus bars arranged about the perimeter of the window assembly. In addition, the window assembly can include a controller capable of controlling delivery of electrical current to selected ones of the plurality of first spaced facilities and selected ones of the plurality of second spaced facilities, such that the luminous transmittance through a first portion of the electrochromic medium is different from the luminous transmittance through a second portion of the electrochromic medium.

63. 发明授权

US06469119B2 Siloxane organic hybrid polymers 失效
标题翻译：硅氧烷有机杂化聚合物
公开(公告)号：US06469119B2
公开(公告)日：2002-10-22
申请号：US09771860
申请日：2001-01-29
申请人： John D. Basil , Chia-Cheng Lin , Robert M. Hunia , Helmut Franz
发明人： John D. Basil , Chia-Cheng Lin , Robert M. Hunia , Helmut Franz
IPC分类号： C08G7708
CPC分类号： C09D183/04 , C08F8/42 , C08J7/047 , C08J2483/00 , C08F26/10 , C08L2666/04 , C08L2666/54 , C08L2666/34
摘要： Siloxane organic hybrid polymers and a method of making them by condensation polymerization reaction of organoalkoxysilane in the presence of organic film-forming polymers are disclosed. Alkali metal carboxylic acid catalyst is also disclosed, as well as the incorporation of cerium oxide for attenuation of ultraviolet radiation.
摘要翻译：公开了硅氧烷有机杂化聚合物及其在有机成膜聚合物存在下通过有机烷氧基硅烷的缩聚反应制备它们的方法。还公开了碱金属羧酸催化剂，以及掺入氧化铈以减少紫外线辐射。

64. 发明授权

US6106605A Silica-free UV-absorbing abrasion resistant coatings 失效
标题翻译：无紫外线吸收耐磨涂层
公开(公告)号：US6106605A
公开(公告)日：2000-08-22
申请号：US898754
申请日：1997-07-23
申请人： John Darwin Basil , Chia-Cheng Lin , Robert Michael Hunia
发明人： John Darwin Basil , Chia-Cheng Lin , Robert Michael Hunia
IPC分类号： C08J7/04 , C08L83/04 , C09D183/06 , C09D183/08 , C09D5/32
CPC分类号： C08J7/042 , C09D183/06 , C09D183/08 , C08J2369/00 , C08J2433/06 , C08J2483/04 , C08L83/04
摘要： A silica-free, abrasion resistant and ultraviolet radiation resistant coating is disclosed comprising an organic UV absorbing compound such as hydroxybenzophenone in an inorganic oxide matrix formed by the hydrolysis and condensation of an organo alkoxysilane and a silicon other metal alkoxide.
摘要翻译：公开了一种无二氧化硅，耐磨损和抗紫外线辐射的涂层，其包含通过有机烷氧基硅烷和硅其它金属醇盐的水解和缩合形成的无机氧化物基质中的有机UV吸收化合物，例如羟基二苯甲酮。

65. 发明授权

US6025025A Water-repellent surface treatment 失效
标题翻译：防水表面处理
公开(公告)号：US6025025A
公开(公告)日：2000-02-15
申请号：US95200
申请日：1998-06-10
申请人： Bruce A. Bartrug , George B. Goodwin , Chia-Cheng Lin
发明人： Bruce A. Bartrug , George B. Goodwin , Chia-Cheng Lin
IPC分类号： B32B17/00 , B05D3/10 , C03C15/00 , C03C17/00 , C03C17/30 , C03C17/32 , C03C19/00 , C04B41/82 , C09K3/18 , B05D3/02
CPC分类号： B05D3/104 , C03C15/00 , C03C17/009 , C03C17/30 , C03C17/32 , C03C17/328 , C03C19/00 , C09K3/18 , C03C2218/31 , Y10S977/892
摘要： The present invention relates to a method of improving the durability of water-repellent films deposited on the surface of a substrate and to a coated article having a water-repellent film of improved durability deposited on the substrate surface. The method includes the steps of simultaneously abrasively and chemically preparing the surface to expose an increased number of bonding sites on the substrate surface by applying a dispersion including an acid solution and an abrasive material to the surface. The dispersion is then removed and the water-repellent film is formed over the prepared surface. The bonding sites react with the water-repellent film to more effectively bond the film to the substrate and thereby improve the durability of the water-repellent film. The abrading material is preferably selected from the group consisting of alumina, ceria, iron oxide, garnet, zirconia, silica, silicon carbide, chromic oxide, pumice and diamond, and the acid solution is preferably selected from the group consisting of solutions of hydrochloric acid, sulfuric acid, tartaric acid, phosphoric acid, hydrobromic acid, nitric acid, acetic acid, trifluoroacetic acid, oxalic acid and citric acid.
摘要翻译：本发明涉及一种提高沉积在基材表面上的防水膜的耐久性的方法和一种具有沉积在基材表面上的具有改善的耐久性的防水膜的涂布制品。该方法包括以下步骤：通过将包含酸溶液和研磨材料的分散体施加于表面，同时磨蚀和化学地制备表面以暴露基底表面上增加数量的结合部位。然后除去分散体，并在制备的表面上形成防水膜。结合部位与防水膜反应，更有效地将膜粘合到基板上，从而提高防水膜的耐久性。研磨材料优选选自氧化铝，二氧化铈，氧化铁，石榴石，氧化锆，二氧化硅，碳化硅，氧化铬，浮石和金刚石，酸溶液优选选自盐酸溶液，硫酸，酒石酸，磷酸，氢溴酸，硝酸，乙酸，三氟乙酸，草酸和柠檬酸。

66. 发明授权

US5385964A Silica-free UV-absorbing abrasion resistant coatings 失效
公开(公告)号：US5385964A
公开(公告)日：1995-01-31
申请号：US591921
申请日：1990-10-02
申请人： John D. Basil , Chia-Cheng Lin , Robert M. Hunia
发明人： John D. Basil , Chia-Cheng Lin , Robert M. Hunia
IPC分类号： C08J7/04 , C08L83/04 , C09D139/06 , C09D183/06 , C09D183/08 , C08K5/54
CPC分类号： C08J7/047 , C09D139/06 , C09D183/06 , C09D183/08 , C08J2369/00 , C08J2483/00 , C08L83/04
摘要： A silica-free, abrasion resistant and ultraviolet radiation resistant coating is disclosed comprising an organic UV absorbing compound such as hydroxybenzophenone in an inorganic oxide matrix formed by the hydrolysis and condensation of an organo alkoxysilane and a silicon other metal alkoxide.

67. 发明授权

US5344712A Abrasion resistant siloxane coatings containing ceria 失效
标题翻译：耐磨硅氧烷涂层含有二氧化铈
公开(公告)号：US5344712A
公开(公告)日：1994-09-06
申请号：US546484
申请日：1990-06-29
申请人： John D. Basil , Chia-Cheng Lin
发明人： John D. Basil , Chia-Cheng Lin
IPC分类号： C08J7/04 , C09D183/04 , B32B27/36
CPC分类号： C09D183/04 , C08J7/047 , C08J2483/00
摘要： Siloxane organic hybrid polymers and a method of making them by condensation polymerization reaction of organoalkoxysilane in the presence of organic film-forming polymers are disclosed wherein cerium oxide is incorporated for the attenuation of ultraviolet radiation.
摘要翻译：公开了硅氧烷有机杂化聚合物及其在有机成膜聚合物存在下通过有机烷氧基硅烷的缩聚反应制备它们的方法，其中掺入氧化铈以减少紫外线辐射。

68. 发明授权

US5328645A Gel promoters for silica sols 失效
标题翻译：硅溶胶凝胶促进剂
公开(公告)号：US5328645A
公开(公告)日：1994-07-12
申请号：US293405
申请日：1989-01-04
申请人： Chia-Cheng Lin , John D. Basil
发明人： Chia-Cheng Lin , John D. Basil
IPC分类号： C01B33/16 , B01J13/00
CPC分类号： C01B33/163
摘要： An alkoxysilane sol-gel composition and method for its production are disclosed whereby an alkoxysilane of the general formulaSi(OR).sub.4wherein R is an organic radical such as methyl, ethyl, propyl or butyl is hydrolyzed with an acid catalyst and the resulting acidic sol is further hydrolyzed and condensed in the presence of an alkaline component which accelerates gelation to form an inorganic oxide network.
摘要翻译：公开了一种烷氧基硅烷溶胶 - 凝胶组合物及其制备方法，其中通式为Si（OR）4（其中R为有机基团如甲基，乙基，丙基或丁基）的烷氧基硅烷用酸催化剂水解，得到酸性溶胶在碱性组分的存在下进一步水解和缩合，其加速凝胶化以形成无机氧化物网络。

69. 发明授权

US4824712A Treatment of glass to reduce venting during thermal treatment and a glass article made thereby 失效
标题翻译：玻璃的处理以减少热处理过程中的排气和由此制成的玻璃制品
公开(公告)号：US4824712A
公开(公告)日：1989-04-25
申请号：US785431
申请日：1985-10-08
申请人： Charlene A. Falleroni , Chia-Cheng Lin
发明人： Charlene A. Falleroni , Chia-Cheng Lin
IPC分类号： C03B8/02 , C03B27/012 , C03C17/02 , C03B23/02 , C03B23/26
CPC分类号： C03B27/012 , C03C17/02 , Y02P40/57 , Y10T428/24322 , Y10T428/24347 , Y10T428/31 , Y10T428/315
摘要： A method and composition for coating scored regions or holes in glass articles prior to heat treatment in order to maintain residual compressive stresses and reduce venting are disclosed. The method and composition of the present invention utilize silica-containing sols which gel and density and ultimately form glassy films during the heat treatment of the coated glass articles.
摘要翻译：公开了一种用于在热处理之前涂覆玻璃制品中的刻痕区域或孔的方法和组合物，以便保持残余的压缩应力并减少排气。本发明的方法和组合物在涂覆的玻璃制品的热处理中使用凝胶密度最终形成玻璃膜的含硅胶体。

70. 发明授权

US4814017A Aqueous organoalkoxysilane/metal oxide sol-gel compositions 失效
标题翻译：水性有机烷氧基硅烷/金属氧化物溶胶 - 凝胶组合物
公开(公告)号：US4814017A
公开(公告)日：1989-03-21
申请号：US915346
申请日：1986-10-03
申请人： Bulent E. Yoldas , Chia-Cheng Lin
发明人： Bulent E. Yoldas , Chia-Cheng Lin
IPC分类号： C09D183/04 , C09D183/14 , C09K3/00 , C08G79/00
CPC分类号： C09D183/14 , C09D183/04
摘要： A method is disclosed for making an organoalkoxysilane/metal oxide sol-gel composition in an essentially aqueous medium by partially hydrolyzing an organoalkoxysilane with a limited amount of water which is essentially completely consumed in the hydrolysis reaction, adding a metal alkoxide of titanium or zirconium to the essentially anhydrous partially hydrolyzed organoalkoxysilane, completely reacting the metal alkoxide with the partially hydrolyzed organoalkoxysilane to form an oxide network and then completely hydrolyzing the composition in water.
摘要翻译：公开了一种通过用基本上完全消耗在水解反应中的有限量的水部分水解有机烷氧基硅烷，在基本水性介质中制备有机烷氧基硅烷/金属氧化物溶胶 - 凝胶组合物的方法，将钛或锆的金属醇盐加入到基本上无水的部分水解的有机烷氧基硅烷，使金属醇盐与部分水解的有机烷氧基硅烷完全反应形成氧化物网络，然后在水中完全水解组合物。

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