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    • 69. 发明申请
    • CARBON FILM
    • 碳膜
    • US20120199553A1
    • 2012-08-09
    • US13183622
    • 2011-07-15
    • Yoshinori KogaMasataka HasegawaSumio IijimaKazuo TsugawaMasatou Ishihara
    • Yoshinori KogaMasataka HasegawaSumio IijimaKazuo TsugawaMasatou Ishihara
    • B44C1/22C23C16/50B82Y40/00
    • C23C16/26B24D11/003C03C17/007C03C17/22C03C2217/282C03C2217/42G02B1/105G02B1/14Y10T428/30
    • ProblemTo provide a carbon film and a laminate having optical characteristics of retaining high transparency, having high refraction index and less double refractivity, being excellent in electric insulating property, being capable of being coated at good adhesion to various substrates, and being capable of being formed at a low temperature, and applications thereof.Means for Solving the ProblemThe invention relates to a carbon film which has an approximate spectrum curve obtainable by superimposing, on a peak fitting curve A at a Bragg's angle (2θ±0.3°) of 43.9°, a peak fitting curve B at 41.7° and a base line in an X-ray diffraction spectrum by a CuKa1 ray, and has a film thickness of from 2 mm to 100 μm. The intensity of the fitting curve B relative to the intensity of the fitting curve A is preferably from 5 to 90% in the approximated spectrum described above. In the carbon film, the Raman shift has a peak at a 1333±10 cm−1 in the Raman scattering spectrum, and the half-value width of the peak is from 10 to 40 cm−1. Further, the invention relates to a laminate characterized by disposing, on the substrate, a carbon aggregate film of 2 nm to 100 μm thickness comprising an aggregate of carbon particles having an approximate spectrum curve described above. Moreover, the invention relates to an optical device, optical glass, wrist watch, electronic circuit substrate, or grinding tool having the laminate described above.
    • 问题为了提供具有保持高透明度,高折射率和较低双折射率的光学特性的碳膜和层压板,具有优异的电绝缘性,能够以良好的粘合力涂覆在各种基板上,并且能够 在低温下形成,其应用。 解决问题的手段本发明涉及一种具有近似光谱曲线的碳膜,其可通过在布拉格角(2θ= 0.3°)为43.9°的峰值拟合曲线A上叠加峰值拟合曲线B,在41.7° °,通过CuKa1射线在X射线衍射光谱中为基线,膜厚为2mm〜100μm。 拟合曲线B相对于拟合曲线A的强度的强度在上述近似光谱中优选为5〜90%。 在碳膜中,在拉曼散射光谱中,拉曼位移在1333±10cm -1处具有峰值,峰值的半值宽度为10至40cm -1。 此外,本发明涉及一种层压体,其特征在于在基板上设置包括具有上述近似光谱曲线的碳粒子聚集体的2nm至100μm厚度的碳聚集体膜。 此外,本发明涉及具有上述层压体的光学装置,光学玻璃,手表,电子电路基板或研磨工具。