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    • 63. 发明授权
    • Oxidatively cross-linkable, water dilutable binders, a process for their
preparation and their use
    • 可氧化交联的水可稀释粘合剂,其制备方法及其用途
    • US4985506A
    • 1991-01-15
    • US371262
    • 1989-06-26
    • Harald BlumPeter HohleinMichael SonntagWolfgang Wellner
    • Harald BlumPeter HohleinMichael SonntagWolfgang Wellner
    • C08F8/14C08F8/44C08F20/02C08F22/06C08F222/00C08G81/02C09D133/00C09D133/04C09D135/00C09J133/00C09J133/04C09J135/00C09K3/10
    • C08F8/14C08F8/44C08F2810/20C08F2810/30
    • Oxidatively cross-linkable, water dilutable binders suitable for lacquers, coating compositions and sealing compounds are modified co-polymers of olefinically unsaturated compounds, having a molecular weight of 6000 to 160,000 and having for each 100 grams of solids content, a total of from60 to 250 milliequivalents of chemically incorporated carboxyl groups, of which from 10 to 100% are neutralized thereby rendering the product dilutable in water andfrom 15 to 50% by weight of chemically incorporated moieties corresponding to the formula--O--RwhereinR represents an olefinically monounsaturated or polyunsaturated aliphatic hydrocarbon having a molecular weight above 166 and containing from 12 to 22 carbon atoms, are prepared by:(a) preparing a co-polymer having a molecular weight from 5000 to 80,000, determined by gel permeation chromatography, and having intramolecular carboxylic acid anhydride units corresponding to the formula ##STR1## and an anhydride equivalent weight of from 240 to 1960 by a radically initiated co-polymerization of olefinically unsaturated dicarboxylic acid anhydrides with other olefinically unsaturated monomers,(b) reacting at least 50% of the acid anhydride units present in the co-polymer from (a) with an unsaturated monohydric alcohol corresponding to the formulaR--OH with anhydride ring opening ester formation, and(c) converting the free carboxyl groups in the reaction product of (b) to an extent of 10 to 100% into carboxylate groups by neutralization of the carboxys with a base.
    • 适用于漆,水溶性组合物和密封化合物的可氧化交联的水可稀释粘合剂是烯属不饱和化合物的改性共聚物,其分子量为6000至160,000,并且对于每100克固体含量,总共为60 至250毫当量的化学引入的羧基,其中10至100%被中和,使产物在水中可稀释,和15至50重量%的化学引入部分对应于式-OR,其中R表示烯属单不饱和或 分子量大于166且含有12至22个碳原子的多不饱和脂族烃通过以下方法制备:(a)通过凝胶渗透色谱法测定分子量为5000至80,000,并具有分子内羧酸的共聚物 对应于式“IMAGE”的酸酐单元和2当量的酸酐当量 通过烯属不饱和二羧酸酐与其它烯属不饱和单体的自由引发共聚,(b)使来自(a)的共聚物中存在的至少50%的酸酐单元与不饱和一元醇 对应于具有酸酐开环酯形成的式R-OH,和(c)通过用碱中和羧基将羧酸酯基团将(b)的反应产物中的游离羧基转化成羧酸酯基团 。