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    • 66. 发明申请
    • Using Diffusion Barrier Layer for CuZnSn(S,Se) Thin Film Solar Cell
    • 使用CuZnSn(S,Se)薄膜太阳能电池的扩散阻挡层
    • US20120097234A1
    • 2012-04-26
    • US12911877
    • 2010-10-26
    • Nestor A. BojarczukSupratik GuhaByungha ShinKejia Wang
    • Nestor A. BojarczukSupratik GuhaByungha ShinKejia Wang
    • H01L31/0224
    • H01L31/0326H01L31/022483H01L31/1864Y02E10/50Y02P70/521
    • Techniques for fabricating thin film solar cells, such as CuZnSn(S,Se) (CZTSSe) solar cells are provided. In one aspect, a method of fabricating a solar cell is provided that includes the following steps. A substrate is provided. The substrate is coated with a molybdenum (Mo) layer. A stress-relief layer is deposited on the Mo layer. The stress-relief layer is coated with a diffusion barrier. Absorber layer constituent components are deposited on the diffusion barrier, wherein the constituent components comprise one or more of sulfur (S) and selenium (Se). The constituent components are annealed to form an absorber layer, wherein the stress-relief layer relieves thermal stress imposed on the absorber layer, and wherein the diffusion barrier blocks diffusion of the one or more of S and Se into the Mo layer. A buffer layer is formed on the absorber layer. A transparent conductive electrode is formed on the buffer layer.
    • 提供了诸如CuZnSn(S,Se)(CZTSSe)(CZTSSe)太阳能电池制造薄膜太阳能电池的技术。 一方面,提供一种制造太阳能电池的方法,其包括以下步骤。 提供基板。 衬底被涂覆有钼(Mo)层。 应力消除层沉积在Mo层上。 应力消除层涂覆有扩散阻挡层。 吸收剂层组成成分沉积在扩散阻挡层上,其中构成组分包含硫(S)和硒(Se)中的一种或多种。 所述构成部件进行退火以形成吸收层,其中所述应力消除层减轻施加在所述吸收体层上的热应力,并且其中所述扩散阻挡层将所述S和Se中的一种或多种的扩散阻挡在所述Mo层中。 在吸收层上形成缓冲层。 在缓冲层上形成透明导电电极。
    • 69. 发明授权
    • Holey electrode grids for photovoltaic cells with subwavelength and superwavelength feature sizes
    • 具有亚波长和超波长特征尺寸的光伏电池的多孔电极网格
    • US08039292B2
    • 2011-10-18
    • US12621226
    • 2009-11-18
    • Supratik GuhaOki Gunawan
    • Supratik GuhaOki Gunawan
    • H01L21/44
    • H01L31/022433Y02E10/50
    • A photovoltaic cell and a method of forming an electrode grid on a photovoltaic semiconductor substrate of a photovoltaic cell are disclosed. In one embodiment, the photovoltaic cell comprises a photovoltaic semiconductor substrate; a back electrode electrically connected to a back surface of the substrate; and a front electrode electrically connected to a front surface of the substrate. The substrate, back electrode, and front electrode form an electric circuit for generating an electric current when said substrate absorbs light. The front electrode is comprised of a metal grid defining a multitude of holes. These holes may be periodic, aperiodic, or partially periodic. The front electrode may be formed by depositing nanospheres on the substrate; forming a metallic layer on the substrate, around the nanospheres; and removing the nanospheres, leaving an electrode grid defining a multitude of holes on the substrate.
    • 公开了一种光伏电池和在光伏电池的光电半导体衬底上形成电极栅格的方法。 在一个实施例中,光伏电池包括光电半导体衬底; 电连接到所述基板的背面的背面电极; 以及电连接到所述基板的前表面的前电极。 当基板吸收光时,基板,背面电极和正面电极形成用于产生电流的电路。 前电极由限定多个孔的金属网格组成。 这些孔可以是周期性的,非周期性的或部分周期性的。 前电极可以通过在衬底上沉积纳米球而形成; 在纳米球周围在基底上形成金属层; 并去除纳米球,留下在基底上限定多个孔的电极网格。