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    • 62. 发明专利
    • Film for retort food package
    • 回收食品包装膜
    • JP2009084379A
    • 2009-04-23
    • JP2007254500
    • 2007-09-28
    • Mitsui Chemicals IncPrime Polymer:Kk三井化学株式会社株式会社プライムポリマー
    • KAWADA ATSUOORUKAWA ATSUSHITAKEI KUNIHIKOITAKURA KEITAKIMURA TOKUTARO
    • C08F297/08B32B27/32B65D30/02B65D65/40B65D81/34C08J5/18
    • PROBLEM TO BE SOLVED: To provide a film for a retort food package which is excellent in transparency, impact-resistance, heat sealing property and heat resistance at satisfactory balance. SOLUTION: The film for the retort food package comprises a propylene-based random block copolymer (A) comprising 90-80 wt.% of a portion (D insol ) which is insoluble in n-decane at room temperature has been polymerized by a metallocene catalyst system, has a melt flow rate of 1-10 g/10 min and a melting point of 150-155°C and satisfies the following (1)-(3), and 10-20 wt.% of a portion (D sol ) which is soluble in n-decane at room temperature and satisfies the following (4)-(6). (1) Molecular weight distribution of D insol is 1.0-3.5, (2) an ethylene content in D insol is 0.5-13 mol%, (3) total of 2,1-insertion bonding amount and 1,3-insertion bonding amount of propylene in D insol is 0.2 mol% or less, (4) molecular weigh distribution of D sol is 1.0-3.5, (5) intrinsic viscositiy [η] in decalin of 135°C of D sol is 1.5-4.0 dL/g, and (6) an ethylene content in D sol is 15-35 mol%. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:提供一种蒸馏食品包装薄膜,其在良好的平衡下具有优异的透明性,耐冲击性,热封性和耐热性。 解决方案:用于蒸馏食品包装的薄膜包括一种基于丙烯的无规嵌段共聚物(A),其包含90-80重量%的部分(D 不溶物),其不溶于n- 癸烷在室温下已被茂金属催化剂体系聚合,熔体流动速率为1-10g / 10min,熔点为150-155℃,满足下列(1) - (3)和10 -20重量%的在室温下可溶于正癸烷的部分(D 溶胶),满足下列(4) - (6)。 (1)D sol 的分子量分布为1.0-3.5,(2)D 粘土中的乙烯含量为0.5-13mol%,(3)总共2 在D 中丙烯的1-插入接合量和1,3-插入键合量为0.2mol%以下,(4)D 溶胶的分子量分布为 1.0-3.5,(5)D 溶胶的135℃萘烷中的特性粘度[η]为1.5-4.0dL / g,(6)D 溶胶中的乙烯含量< / SB>为15-35摩尔%。 版权所有(C)2009,JPO&INPIT
    • 67. 发明专利
    • Propylenic polymer and application to shrinkable film
    • 丙烯聚合物和应用于可收缩膜
    • JP2006052313A
    • 2006-02-23
    • JP2004234772
    • 2004-08-11
    • Mitsui Chemicals Inc三井化学株式会社
    • INUKAI AKIHIROYAMAMOTO KOICHIROITAKURA KEITATAKEI KUNIHIKOSHIBUYA HIROSHIMATSUMURA HIDEJI
    • C08F10/06C08L23/10C08L57/02
    • PROBLEM TO BE SOLVED: To provide a shrinkable film which has a large heat shrinking factor, a small natural shrinking factor, and an excellent shrinkage balance, and to provide a propylenic polymer for the shrinkable film. SOLUTION: This propylenic polymer satisfies all of requirements consisting of [1] a MFR (230°C, 2.16 kgf) of 0.05 to 8 (g/10 min), [2] a melting point of ≤140°C determined by DSC, and [3] a n-decane soluble content of ≤3 wt.%. The propylenic polymer is preferably a (co)polymer obtained by polymerizing or copolymerizing propylene or the propylene with a 2 to 20C α-olefin excluding the propylene in the presence of a specific metallocene catalyst. The propylenic polymer (or its composition blended with a petroleum resin) is suitably used for shrinkable films or shrinkable labels. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种热收缩率大,收缩率小,收缩平衡优异的收缩性薄膜,为收缩性膜提供丙烯类聚合物。 解决方案:该丙烯类聚合物满足[1] MFR(230℃,2.16kgf)为0.05〜8(g / 10min),[2]熔点为140℃的[1] 通过DSC和[3]≤3重量%的正癸烷可溶物含量。 丙烯类聚合物优选是通过在特定的茂金属催化剂的存在下将丙烯或丙烯与除丙烯之外的2〜20℃的α-烯烃聚合或共聚得到的(共)聚合物。 丙烯聚合物(或其与石油树脂共混的组合物)适合用于可收缩膜或可收缩标签。 版权所有(C)2006,JPO&NCIPI
    • 68. 发明专利
    • Polypropylene composition and sealant film obtained therefrom
    • 聚丙烯组合物和密封胶膜
    • JP2006052312A
    • 2006-02-23
    • JP2004234771
    • 2004-08-11
    • Mitsui Chemicals Inc三井化学株式会社
    • YAMAMOTO KOICHIROINUKAI AKIHIROITAKURA KEITATAKEI KUNIHIKOSHIBUYA HIROSHIMATSUMURA HIDEJI
    • C08L23/10B32B27/32C08J5/18
    • PROBLEM TO BE SOLVED: To provide a polypropylene composition for sealant films, and to provide a sealant film.
      SOLUTION: This polypropylene composition is characterized by having an MFR (230°C, 2.16 kgf) of 1 to 50 (g/10 min), an n-decane-soluble fraction of ≤3 wt.%, one or more melting peaks (namely, melting points) determined by DSC on each of a high temperature side of ≥130°C and a low temperature side of ≤125°C, and a semi-crystallization time of ≤6 min. And a 1 to 100 μm-thick sealant film is obtained from the polypropylene composition. In addition, a laminate is characterized by being a laminate comprising the layer (X) of the sealant film and at least one film layer (Y) selected from the group consisting of polyolefin films, polystyrene films, polyester films, polyamide films, the laminate films of polyolefins to gas-barrier resin films, aluminum foils, paper, and vapor-deposited films.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种用于密封膜的聚丙烯组合物,并提供密封剂膜。 解决方案:该聚丙烯组合物的特征在于具有1至50(g / 10min)的MFR(230℃,2.16kgf),≤3wt%的正癸烷可溶级分,一种或多种 在≥130℃的高温侧和≤125℃的低温侧各自的DSC上测定的熔融峰(即熔点),半结晶时间≤6分钟。 从聚丙烯组合物得到1〜100μm厚的密封膜。 此外,层压体的特征在于包括密封剂膜的层(X)和至少一个选自聚烯烃膜,聚苯乙烯膜,聚酯膜,聚酰胺膜中的膜层(Y)的层压体,层压体 聚烯烃对阻气性树脂膜,铝箔,纸和气相沉积膜的膜。 版权所有(C)2006,JPO&NCIPI
    • 69. 发明专利
    • Propylenic polymer
    • 丙烯聚合物
    • JP2006008983A
    • 2006-01-12
    • JP2005077486
    • 2005-03-17
    • Mitsui Chemicals Inc三井化学株式会社
    • ITAKURA KEITAKADOSAKA AYAKOMATSUMURA HIDEJIHASHIZUME SATOSHISASAKI YOSHIO
    • C08F297/08
    • PROBLEM TO BE SOLVED: To provide a propylenic polymer having good heat resistance and good impact resistance in spite of having a low melting point. SOLUTION: This polymer is composed of a portion (D sol ) soluble in n-decane at room temperature and a portion (D insol ) insoluble in n-decane at room temperature, is obtained from propylene (M p ) and one or more olefins (M x ) selected from ethylene and ≥4C α-olefins, and simultaneously satisfies the following requirements (1) to (3). (1) GPC mol. wt. distributions (M w /M n ) of D sol and D insol are ≤4.0, respectively. (2) The melting point (T m ) of D insol is in a range of 140 to 155°C. (3) A heat distortion temperature HDT (load 0.45 MPa) and the amount W sol (wt%) of the portion soluble in n-decane at room temperature satisfy a relational expression: 100-W sol ≤HDT≤120-W sol . COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:尽管具有低熔点,但提供具有良好耐热性和良好抗冲击性的丙烯聚合物。 解决方案:该聚合物由在室温下可溶于正癸烷的部分(D 溶胶)和不溶于正癸烷的部分(D 不溶物)组成。 在室温下由丙烯(M SB SB)和一种或多种选自乙烯和≥4Cα-烯烃的烯烃(M x SB)获得,同时满足以下条件 要求(1)至(3)。 (1)GPC mol。 重量。 D 溶胶和D SB SB的分布分别为≤4.0。 (2)D SB SB的熔点(T SB> m SB)在140〜155℃的范围内。 (3)室温下可溶于正癸烷的部分的热变形温度HDT(负荷0.45MPa)和溶剂量(wt%)满足关系式:100W 溶胶≤HDT≤120-W 溶胶。 版权所有(C)2006,JPO&NCIPI
    • 70. 发明专利
    • Polypropylene resin composition
    • JP2004075984A
    • 2004-03-11
    • JP2003161702
    • 2003-06-06
    • Mitsui Chemicals Inc三井化学株式会社
    • ITAKURA KEITAHASHIMOTO MIKIOYODA KAORU
    • C08L23/10C08L23/26C08L25/12C08L51/06
    • PROBLEM TO BE SOLVED: To provide a polypropylene (PP) resin composition of light weight, having high strength and excellent surface peel resistance, and capable of giving a molded product at a low cost, by mixing a grafted modified PP resin, which has a high graft amount and a high molecular weight and is produced at a low cost, and an epoxy-modified acrylonitrile-styrene-based copolymer into the composition.
      SOLUTION: This PP resin composition contains (A) a crystalline PP resin and (B) a copolymer resin of vinyl bond-containing nitrile-based compound and an aromatic vinyl compound in a specified ratio, wherein the crystalline PP resin (A) contains 0.1 wt% or more of (A2) the grafted modified PP resin given by grafting a specific graft monomer on (A1) a specific crystalline PP resin as well as (A0) the crystalline PP resin, and the copolymer resin (B) contains 0.1 wt% or more of (B2) the epoxy-modified acrylonitrile-styrene-based copolymer as well as (B3) the copolymer resin of the vinyl bond-containing nitrile-based compound and the aromatic vinyl compound. Further, the composition satisfies inequalities (i) and (ii): (i) 0.5≤[η]
      MPP ≤3.0; and (ii) (MG)×([η]
      MPP )≥0.0050, wherein [η]
      MPP is an intrinsic viscosity (dL/g) of the resin (A2), and (MG) is a graft amount [mol based on 100 g of the resin (A2)] of the graft monomer.
      COPYRIGHT: (C)2004,JPO