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61. 发明授权

US06649695B1 Elastic sealing material on the basis of block copolymers made of isobutene and vinyl aromatic monomers 失效
标题翻译：基于由异丁烯和乙烯基芳族单体制成的嵌段共聚物的弹性密封材料
公开(公告)号：US06649695B1
公开(公告)日：2003-11-18
申请号：US10048833
申请日：2002-02-06
申请人： Hans Peter Rath , Arno Lange , Helmut Mach , Konrad Knoll
发明人： Hans Peter Rath , Arno Lange , Helmut Mach , Konrad Knoll
IPC分类号： C08F25510
CPC分类号： C08L53/00 , E06B3/66342
摘要： Linear or star block copolymers which have at least one polymer block A which is essentially composed of isobutene units and at least two polymer blocks B which are essentially composed of units which are derived from vinylaromatic monomers are used as resilient sealing material. In particular, such sealing materials are used for sealing the edge joints in insulation glass panes, and insulation glass panes have a flexible edge joint seal which contains one of the block copolymers.
摘要翻译：具有至少一个聚合物嵌段A的线性或星形嵌段共聚物用作弹性密封材料，其中聚合物嵌段A基本上由异丁烯单元组成，至少两个聚合物嵌段B基本上由衍生自乙烯基芳族单体的单元构成。特别地，这种密封材料用于密封绝缘玻璃板中的边缘接头，并且绝缘玻璃板具有包含嵌段共聚物之一的柔性边缘接头密封件。

62. 发明授权

US5998544A Preparation of graft copolymers 失效
标题翻译：接枝共聚物的制备
公开(公告)号：US5998544A
公开(公告)日：1999-12-07
申请号：US948233
申请日：1997-10-09
申请人： Axel Gottschalk , Ralf Engelhardt , Martin Weber , Konrad Knoll
发明人： Axel Gottschalk , Ralf Engelhardt , Martin Weber , Konrad Knoll
IPC分类号： C08G81/02 , C08L81/02 , C08L25/12 , C08L53/02
CPC分类号： C08G81/021
摘要： Graft copolymers are prepared by anionic polymerization which comprises reacting polymers (A) having at least one anionic chain end with polymers (B) which contain at least one nitrile group, in the presence of a solvent.
摘要翻译：通过阴离子聚合制备接枝共聚物，其包括使具有至少一个阴离子链端的聚合物（A）与含有至少一个腈基的聚合物（B）在溶剂存在下反应。

63. 发明授权

US5760134A Thermoplastic molding materials 失效
标题翻译：热塑性成型材料
公开(公告)号：US5760134A
公开(公告)日：1998-06-02
申请号：US721539
申请日：1996-09-26
申请人： Norbert Guntherberg , Konrad Knoll , Martin Weber
发明人： Norbert Guntherberg , Konrad Knoll , Martin Weber
IPC分类号： C08L51/00 , C08L53/02 , C08L51/04
CPC分类号： C08L51/003 , C08L53/02 , Y10S525/902
摘要： Thermoplastic molding materials of A) from 30 to 98% by weight of a graft polymer of a.sub.c) from 30 to 90% by weight of an elastomeric graft core and a.sub.s) from 10 to 70% by weight of a graft shell, B) from 1 to 50% by weight of a thermoplastic polymer, C) from 1 to 70% by weight of an elastomeric block copolymer, and D) from 0 to 30% by weight of a polymer having a star-like structure.
摘要翻译： A）30至98重量％的交联聚合物（ac）为30至90重量％的弹性体接枝芯，以及10至70重量％的接枝壳，B）从 1至50重量％的热塑性聚合物，C）1至70重量％的弹性体嵌段共聚物，和D）0至30重量％的具有星形结构的聚合物。

64. 发明授权

US5753777A Telechelics containing ethanolamine or oligoether-ol-amine end groups and process for the preparation thereof 失效
标题翻译：含有乙醇胺或低聚醚 - 醇 - 胺端基的电视电影及其制备方法
公开(公告)号：US5753777A
公开(公告)日：1998-05-19
申请号：US553664
申请日：1995-11-17
申请人： Klaus Bronstert , Konrad Knoll
发明人： Klaus Bronstert , Konrad Knoll
IPC分类号： C08F8/30 , C08C19/44 , C08F4/48 , C08F36/00 , C08F36/02 , C08F36/04 , C08G18/69 , C08F136/06 , C08F8/32 , C08F136/08
CPC分类号： C08G18/696 , C08C19/44 , C08F36/04
摘要： A polydiene which is obtainable by anionic polymerization of a diene using a bifunctional Li initiator followed by polymer-like reaction and which contains at least one ethanolamine or oligoetherolamine terminal group of the general structure I ##STR1## in which R.sup.1 denotes alkyl or aryl, Ar denotes aryl, R.sup.2 denotes alkyl or hydrogen, and R.sup.3 denotes aryl, alkyl, or hydrogen and X can assume a value from 1 to 10, and the hydrogenation products thereof.
摘要翻译： PCT No.PCT / EP94 / 01802 Sec。 371日期：1995年11月17日 102（e）1995年11月17日日期PCT PCT 1994年6月3日PCT公布。第WO94 / 29354号公报日期：1994年12月22日A聚二烯，其可以通过使用双官能的Li引发剂进行二聚体的阴离子聚合，然后进行聚合物样反应并含有至少一种通式II的乙醇胺或低聚乙酰胺末端基，Ar表示芳基，R2表示烷基或氢，R3表示芳基，烷基或氢，X可以为1至10的值，并且其氢化产物。

65. 发明授权

US5321093A Living polymers, the preparation thereof and the use thereof for preparing telechelic polymers 失效
标题翻译：活性聚合物，其制备方法及其制备远电子聚合物的用途
公开(公告)号：US5321093A
公开(公告)日：1994-06-14
申请号：US764870
申请日：1991-09-24
申请人： Klaus Bronstert , Konrad Knoll , Erich Haedicke
发明人： Klaus Bronstert , Konrad Knoll , Erich Haedicke
IPC分类号： C08C19/44 , C08F4/48 , C08F36/04 , C08F297/04 , C08F297/94
CPC分类号： C08F297/042 , C08C19/44 , C08F36/04
摘要： A process for preparing bifunctional living polymers which are able to forth bifunctional telechelic polymers or block copolymers with at least 3 blocks of conjugated dienes and/or vinylaromatics with molecular weights of from 1,500 to 500,000, by bifunctional initiators whose anionic centers are aliphatic carbon atoms which are substituted by lithium and an aliphatic hydrocarbon radical as well as by either 2 aryl radicals or by one aryl radical and one hydrogen radical, where one of the aryl radicals can also be part of the two anionic centers, in a first stage being reacted in the presence of not more than 2.5 moles of an aliphatic ether or a tertiary amine per mole of lithium and not less than 2 mol/l of a conjugated diene at from -40.degree. to +35.degree. C. with not less than two moles of diene, resulting in the formation of low molecular weight diene oligomers which in turn act as bifunctional initiators, and using the latter in a second reaction stage in a conventional manner at above 40.degree. C., with or without the addition of other monomers, to obtain polymers of the required molecular weight.
摘要翻译：制备双官能活性聚合物的方法，其能够通过双官能引发剂（其阴离子中心是脂族碳原子）与分子量为1,500至500,000的至少3个共轭二烯和/或乙烯基芳香族嵌段的双官能遥爪聚合物或嵌段共聚物被锂和脂族烃基以及2个芳基或一个芳基和一个氢基取代，其中一个芳基也可以是两个阴离子中心的一部分，在第一阶段中被反应在-40℃至+ 35℃下每摩尔锂和不小于2mol / l共轭二烯的摩尔数不超过2.5摩尔的脂族醚或叔胺的存在，不少于2摩尔的二烯，导致形成低分子量二烯低聚物，其又作为双官能引发剂，并在上述常规方式的第二反应阶段中使用后者 40℃，加入或不加入其它单体，得到所需分子量的聚合物。

66. 发明授权

US5122573A Preparation of polymers having tertiary chloride end groups 失效
标题翻译：具有氯化物末端组的聚合物的制备
公开(公告)号：US5122573A
公开(公告)日：1992-06-16
申请号：US696914
申请日：1991-05-08
申请人： Konrad Knoll , Klaus Bronstert , Dietmar Bender
发明人： Konrad Knoll , Klaus Bronstert , Dietmar Bender
IPC分类号： C08F8/20
CPC分类号： C08F8/20
摘要： A process for the preparation of polymers of isobutene having tertiary chloride groups by reaction of appropriate polymers which have been prepared by cationic polymerization of isobutene with hydrogen chloride.
摘要翻译：通过异丁烯的阳离子聚合制备的合适的聚合物与氯化氢的反应制备具有三氯化钛基团的异丁烯的聚合物的方法。

67. 发明授权

US09090768B2 Styrol/butadiene block copolymer mixtures for shrink films 有权
标题翻译：用于收缩膜的苯乙烯/丁二烯嵌段共聚物混合物
公开(公告)号：US09090768B2
公开(公告)日：2015-07-28
申请号：US11813742
申请日：2005-12-31
申请人： Konrad Knoll , Helmut Steininger , Michael Schuster , Daniel Wagner , Peter Merkel
发明人： Konrad Knoll , Helmut Steininger , Michael Schuster , Daniel Wagner , Peter Merkel
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08L2666/24
摘要： A mixture which comprises from 5 to 50% by weight of a block copolymer A, which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.; from 95 to 50% by weight of a block copolymer B, which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.; from 0 to 45% by weight of polystyrene or of a block copolymer C other than A and B; and from 0 to 6% by weight of a plasticizer; and its use for production of shrink films.
摘要翻译：包含5至50重量％的嵌段共聚物A的混合物，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内; 95至50重量％的嵌段共聚物B，其包含至少一种由乙烯基芳族单体组成的硬质块S，并且包含一种或多种共聚物嵌段（B / S）B，每个共聚物嵌段（B / S）B由20至60重量％的乙烯基芳族单体和80〜40重量％的二烯，玻璃化转变温度TgB在-70℃至0℃的范围内。 0至45重量％的聚苯乙烯或除A和B之外的嵌段共聚物C; 和0〜6重量％的增塑剂; 并用于生产收缩膜。

68. 发明授权

US08835560B2 Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms in the star 有权
标题翻译：具有星形分子结构的弹性嵌段共聚物，其中星形分子结构在星形中具有至少两个不同的臂
公开(公告)号：US08835560B2
公开(公告)日：2014-09-16
申请号：US13283275
申请日：2011-10-27
申请人： Konrad Knoll , Daniel Wagner , Andrea Colombo , Geert Verlinden
发明人： Konrad Knoll , Daniel Wagner , Andrea Colombo , Geert Verlinden
IPC分类号： C08F297/04 , C08F8/00 , B32B7/12
CPC分类号： B32B7/12 , C08F8/04 , C08F297/044 , Y10T428/139
摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.
摘要翻译：具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成型品，柔性管或型材挤出物。

69. 发明授权

US08466215B2 Thermoplastic linoleum 失效
标题翻译：热塑性油毡
公开(公告)号：US08466215B2
公开(公告)日：2013-06-18
申请号：US12747369
申请日：2008-12-11
申请人： Konrad Knoll , Michel Pepers , Peter Wolf , Piyada Charoensirisomboon
发明人： Konrad Knoll , Michel Pepers , Peter Wolf , Piyada Charoensirisomboon
IPC分类号： C08K9/00 , C09B67/00
CPC分类号： D06N1/00
摘要： The present invention relates to a thermoplastic molding composition comprising (A) as component A, particles composed of at least one oxidatively crosslinked vegetable oil as core, encapsulated by at least one thermoplastic, (B) as component B, at least one further thermoplastic compatible with the at least one thermoplastic present in the shell of component A, (C) as component C, at least one resin compatible with the at least one thermoplastic present in the shell of component A, (D) as component D, at least one filler, and (E) as component E, if appropriate, further additives, and also to a process for the production of the thermoplastic molding composition.
摘要翻译：本发明涉及一种热塑性模塑组合物，其包含（A）作为组分A，由至少一种氧化交联的植物油作为芯组成的颗粒，由至少一种热塑性塑料包封，（B）作为组分B，至少一种另外的热塑性相容性存在于组分A的外壳中的至少一种热塑性材料（C）作为组分C，至少一种与组分A壳体中存在的至少一种热塑性塑料相容的树脂，（D）作为组分D，至少一种填充剂和（E）作为组分E，如果合适的话，还可以使用其它添加剂，以及制备热塑性模塑组合物的方法。

70. 发明申请

US20120225995A1 USE OF VINYLAROMATIC-DIENE COPOLYMERS IN LACTAM COMPOSITIONS 有权
标题翻译：在LACTAM组合物中使用乙烯基二烯共聚物
公开(公告)号：US20120225995A1
公开(公告)日：2012-09-06
申请号：US13408298
申请日：2012-02-29
申请人： Philippe Desbois , Konrad Knoll , Anna Karina Möller
发明人： Philippe Desbois , Konrad Knoll , Anna Karina Möller
IPC分类号： C08L53/02
CPC分类号： C08L77/02 , C08G69/18 , C08L53/02
摘要： A lactam composition which comprises the following components: from 3 to 25% by weight of a random vinylaromatic-diene copolymer (A), where the random vinylaromatic-diene copolymer is composed of at least one block (S) which forms a hard phase and which is composed of vinylaromatic monomers, and of at least one random block (S/B) which forms a soft phase and which has vinylaromatic monomers and diene monomers, from 75 to 97% by weight of at least one lactam component (B), and also optionally reinforcing materials and/or additives has improved viscosity in the melt and can be used for producing polyamide moldings.
摘要翻译：一种内酰胺组合物，其包含以下组分：3至25重量％的无规乙烯基芳族二烯共聚物（A），其中无规乙烯基芳族二烯共聚物由至少一个形成硬相的嵌段（S）和由乙烯基芳族单体和形成软相的至少一种无规嵌段（S / B）组成，并且具有乙烯基芳族单体和二烯单体，75至97重量％的至少一种内酰胺组分（B），并且还可选地，增强材料和/或添加剂在熔体中具有改善的粘度，并且可用于生产聚酰胺模制品。

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