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61. 发明授权

US4224346A Chewing gum composition containing one or more 2-oxabicyclooctane derivatives 失效
标题翻译：含有一种或多种2-氧杂双环辛烷衍生物的口香糖组合物
公开(公告)号：US4224346A
公开(公告)日：1980-09-23
申请号：US48803
申请日：1979-06-15
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , A23L1/226
CPC分类号： A23G4/06 , A23L27/2052
摘要： Described is a process for augmenting or enhancing the taste of a chewing gum comprising the step of adding to a chewing gum blend at least one 2-oxabicyclo[2.2.2]octane selected from the group consisting of 3-isopropyl-1,5,8-trimethyl-2-oxabicyclo[2.2.2]octane and 3-ethyl-1,5,8-trimethyl-2-oxabicyclo[2.2.2]octane.
摘要翻译：描述了增加或增强口香糖味道的方法，其包括将口香糖共混物中至少一种2-氧杂二环[2.2.2]辛烷加入到步骤中，该辛烷选自3-异丙基-1,5， 8-三甲基-2-氧杂二环[2.2.2]辛烷和3-乙基-1,5,8-三甲基-2-氧杂双环[2.2.2]辛烷。

62. 发明授权

US4207214A 2-Oxabicyclooctane derivatives in perfume compositions 失效
公开(公告)号：US4207214A
公开(公告)日：1980-06-10
申请号：US046368
申请日：1979-06-07
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/40 , C07C29/40 , C07D493/08 , C11B9/00 , A61K7/46
CPC分类号： C07D493/08 , A24B15/403 , C07C29/40 , C11B9/0034 , C11B9/008 , C07C2101/16
摘要： Described are derivatives of 2-oxabicyclo[2.2.2]octanes and precursors therefor. The oxabicyclooctanes are useful in perfumery.

63. 发明授权

US4084009A Flavoring with a hydroxy cyclohexenone derivative 失效
标题翻译：用羟基环己烯酮衍生物调味
公开(公告)号：US4084009A
公开(公告)日：1978-04-11
申请号：US774059
申请日：1977-03-03
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred Hugo Vock , Edward J. Shuster
IPC分类号： A23G4/00 , A23G4/06 , A23L27/20 , A24B15/34 , C07C13/23 , C07C29/40 , C07C29/50 , C07C45/59 , C07D317/72 , C11B9/00 , A23L1/226
CPC分类号： A23G4/06 , A23L27/203 , A24B15/34 , C07C13/23 , C07C29/40 , C07C45/34 , C07C45/59 , C07D317/72 , C11B9/0034 , C07C2101/16
摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma, perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of hydroxy cyclohexenone derivatives having the generic formula: ##STR1## wherein one of X and Y is a keto moiety having the structure: ##STR2## and the other of X and Y is a carbinol moiety having the structure: ##STR3## and wherein R is C.sub.1 -C.sub.5 alkyl.
摘要翻译：描述了用于食品，口香糖，牙膏和药用产品风味和香气，烟草香料和香气，香料和香料制品香气增强，增强和赋予组合物以及作为食品，口香糖，牙膏，药用产品的方法和组合物，烟草，香料和香料赋予的具有以下通式的羟基环己烯酮衍生物的芳香赋予材料：其中X和Y之一是具有以下结构的酮部分：X和Y是具有结构：，其中R是C 1 -C 5烷基。

64. 发明授权

US4201639A Processes for preparing cyclohexadiene derivatives 失效
标题翻译：制备环己二烯衍生物的方法
公开(公告)号：US4201639A
公开(公告)日：1980-05-06
申请号：US8886
申请日：1979-02-02
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C11B9/00 , B01J1/10 , C07C45/00
CPC分类号： C07C13/23 , A24B15/34 , C11B9/0034 , C07C2101/16 , Y10S204/912
摘要： Described is a process for preparing cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen comprising the step of reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene or a 1-alkyl-3,4,4-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product.
摘要翻译：描述了制备具有以下通式的环己二烯衍生物的方法：其中R是C 1 -C 5烷基之一，当R 2为氢时R 1为甲基，包括使1-烷基-3,5,5-三甲基环己烷 1,3-二烯或1-烷基-3,4,4-三甲基环己-1,3-二烯与氧在光存在下，紫外线敏化剂和碱性催化剂; 并分馏蒸馏生成的产物。

65. 发明授权

US4186149A Processes for preparing cyclohexadiene derivatives 失效
标题翻译：制备环己二烯衍生物的方法
公开(公告)号：US4186149A
公开(公告)日：1980-01-29
申请号：US8779
申请日：1979-02-02
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C07D317/72 , C11B9/00 , C07C45/00
CPC分类号： C07D317/72 , A24B15/34 , C07C13/23 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C11B9/0034 , C07C2101/16
摘要： Described is a process for preparing cyclohexadiene derivatives having the generic formula: ##STR1## by means of reacting a compound having the structure: ##STR2## with mineral acid selected from the group consisting of dilute hydrochloric acid, dilute phosphoric acid and dilute sulfuric acid; wherein R is C.sub.1 -C.sub.5 alkyl. The products produced by this process are useful for their organoleptic properties in perfumes, foodstuffs and tobaccos.
摘要翻译：描述了通过使具有以下结构的化合物与选自稀盐酸，稀磷酸和稀硫酸的无机酸反应制备具有以下通式的环己二烯衍生物的方法：＆lt; IMAGE＆gt; 其中R是C 1 -C 5烷基。通过该方法生产的产品对于其在香料，食品和烟草中的感官特性是有用的。

66. 发明授权

US4154763A 4-Butyl-3,4,5-trimethylcyclohexa-25-dienone 失效
标题翻译： 4-丁基-3,4,5-三甲基环己基-25-二烯酮
公开(公告)号：US4154763A
公开(公告)日：1979-05-15
申请号：US860121
申请日：1977-12-13
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C07D317/72 , C11B9/00 , C11D3/50 , C11D9/44 , C07C49/48
CPC分类号： C07D317/72 , A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C11B9/0034 , C11D3/50 , C11D9/442 , C07C2101/16
摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, produced by one of the following processes:(i) Reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product; or(ii) Reacting a 4-alkyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one with dilute aqueous mineral acid and distilling the resulting reaction product.Addition of one or more of the cyclohexadiene derivatives having the formula: ##STR2## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavoring compositions, chewing gums, toothpastes and medicinal products, sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco-like and "Oriental" aroma characteristics with sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco, "Oriental" flavor characteristics;(b) In perfumes, colognes and perfumed articles, warm sweet, slightly minty, woody, natural green, herbaceous, Jasmine-like, fruity aromas; and(c) In tobaccos and tobacco flavors, "dry black tobacco-like" notes, spicey notes, celery-like notes, black pepper-like notes, sweet notes and Virginia tobacco-like notes prior to and on smoking, in both the main stream and the side stream.
摘要翻译：描述了用于食品，口香糖，牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强，增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品，口香糖，牙膏，药用产品，烟草，香料和香料制品香气赋予材料：其中R是C 1 -C 5烷基之一，当R 2为R 1时，R 1为甲基是氢，当R 2为甲基时，R 1为氢，由以下方法之一制备：

67. 发明授权

US4135520A Tobacco flavoring with cyclohexadiene derivatives 失效
标题翻译：烟草香料与环己二烯衍生物
公开(公告)号：US4135520A
公开(公告)日：1979-01-23
申请号：US860122
申请日：1977-12-13
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C07D317/72 , C11B9/00 , C11D3/50 , C11D9/44 , A24B3/12
CPC分类号： C07D317/72 , A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C11B9/0034 , C11D3/50 , C11D9/442 , C07C2101/16
摘要： Cyclohexadiene derivatives as tobacco flavoring compositions.
摘要翻译：环己二烯衍生物作为烟草香料组合物。

68. 发明授权

US3967629A Bicyclic fragrance materials and processes therefor 失效
标题翻译：双环芳香材料及其工艺
公开(公告)号：US3967629A
公开(公告)日：1976-07-06
申请号：US402157
申请日：1973-10-01
申请人： Robert L. Chappell , Edward J. Shuster , Joaquin F. Vinals , Manfred H. Vock
发明人： Robert L. Chappell , Edward J. Shuster , Joaquin F. Vinals , Manfred H. Vock
IPC分类号： A24B3/12 , A23L27/20 , A24B15/34 , A61K8/31 , A61K8/34 , A61K8/35 , A61K8/37 , A61Q13/00 , C07C13/44 , C07C27/00 , C07C33/05 , C07C35/31 , C07C45/00 , C07C49/20 , C07C49/21 , C07C49/443 , C07C49/527 , C07C49/583 , C07C67/00 , C07C69/753 , C07C69/757 , C07C253/00 , C07C255/46 , C07C255/47 , C09K3/00 , C11B9/00 , C12G3/06 , A24B13/00 , A24B15/04
CPC分类号： C07C45/28 , A23L27/203 , A24B15/345 , C07C45/62 , C07C45/69 , C11B9/0046 , C12G3/06
摘要： The use of saturated and unsaturated polyalkyl bicyclo-[2.2.2]-octanes and/or alcohols and aldehydes thereof to alter organoleptic properties, and particularly the aroma, of consumable materials, together with compositions containing such bicyclic materials; and novel bicyclo-[2.2.2]-octane derivatives and processes for preparing them.
摘要翻译：使用饱和和不饱和的多烷基双环[2.2.2] - 辛烷和/或其醇和醛与含有这种双环材料的组合物一起改变消耗材料的感官特性，特别是芳香，和新型双环 - [2.2.2] - 辛烷衍生物及其制备方法。

69. 发明授权

US4154696A Detergent containing cyclohexadiene derivatives 失效
标题翻译：含有环己二烯衍生物的洗涤剂
公开(公告)号：US4154696A
公开(公告)日：1979-05-15
申请号：US917772
申请日：1978-06-21
申请人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
发明人： Kenneth K. Light , Bette M. Spencer , Joaquin F. Vinals , Jacob Kiwala , Manfred H. Vock , Edward J. Shuster
IPC分类号： A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C07D317/72 , C11B9/00 , C11D3/50 , C11D9/44 , C11D3/60
CPC分类号： C07D317/72 , A24B15/34 , C07C13/23 , C07C29/09 , C07C29/40 , C07C29/68 , C07C45/34 , C07C45/59 , C07C45/66 , C07C49/603 , C07C49/713 , C11B9/0034 , C11D3/50 , C11D9/442 , C07C2101/16
摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma; tobacco flavor and aroma; perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more cyclohexadiene derivatives having the generic formula: ##STR1## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, produced by one of the following processes:(i) Reacting a 1-alkyl-3,5,5-trimethylcyclohexa-1,3-diene with oxygen in the presence of light, an ultraviolet sensitizer, and a basic catalyst; and fractionally distilling the resulting product; or(ii) Reacting a 4-alkyl-4-hydroxy-3,5,5-trimethyl-2-cyclohexen-1-one with dilute aqueous mineral acid and distilling the resulting reaction product.Addition of one or more of the cyclohexadiene derivatives having the formula: ##STR2## wherein R is one of C.sub.1 -C.sub.5 alkyl, R.sub.1 is methyl when R.sub.2 is hydrogen, and R.sub.1 is hydrogen when R.sub.2 is methyl, to consumable materials is indicated to produce:(a) In foodstuffs, foodstuff flavoring compositions, chewing gums, toothpastes and medicinal products, sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco-like and "Oriental" aroma characteristics with sweet, hay-like, heliotropine-like, black pepper-like, woody, tobacco, "Oriental" flavor characteristics;(b) In perfumes, colognes and perfumed articles, warm sweet, slightly minty, woody, natural green, herbaceous, Jasmine-like, fruity aromas; and(c) In tobaccos and tobacco flavors, "dry black tobacco-like" notes, spicey notes, celery-like notes, black pepper-like notes, sweet notes and Virginia tobacco-like notes prior to and on smoking, in both the main stream and the side stream.
摘要翻译：描述了用于食品，口香糖，牙膏和药用产品香味和香气的方法和组合物; 烟草香气和香气; 香水和香水制品香气增强，增强和赋予组合物; 作为一种或多种具有以下通式的环己二烯衍生物的食品，口香糖，牙膏，药用产品，烟草，香料和香料制品香气赋予材料：其中R是C 1 -C 5烷基之一，当R 2为R 1时，R 1为甲基是氢，当R 2为甲基时，R 1为氢，由以下方法之一制备：

70. 发明授权

US4139650A Flavoring with a tricyclic alcohol 失效
标题翻译：用三环酒精调味
公开(公告)号：US4139650A
公开(公告)日：1979-02-13
申请号：US683310
申请日：1976-05-05
申请人： Kenneth K. Light , Edward J. Shuster , Joaquin F. Vinals , Manfred H. Vock
发明人： Kenneth K. Light , Edward J. Shuster , Joaquin F. Vinals , Manfred H. Vock
IPC分类号： C07C49/587 , A24B15/34 , C07C27/00 , C07C29/00 , C07C29/136 , C07C35/37 , C07C45/00 , C07C45/62 , C07C67/00 , C11B9/00 , A23L1/226
CPC分类号： C07C45/63 , A24B15/345 , C07C45/62 , C07C45/69 , C11B9/0042
摘要： Compositions for altering the flavor and/or aroma of consumable products including foods, tobacco and perfumes utilizing as the essential ingredient at least one organic tricyclic alcohol having the formula: ##STR1## wherein each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 is selected from the group consisting of hydrogen and methyl; wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond; and wherein when the dashed line is a carbon-carbon single bond, one of R.sub.2 or R.sub.3 is hydrogen.
摘要翻译：用于改变消费品的味道和/或香气的组合物，包括食品，烟草和香料，其利用至少一种具有下式的有机三环醇作为必需组分：其中R1，R2，R3，R4，R5和R6 选自氢和甲基; 其中虚线是碳 - 碳单键或碳 - 碳双键; 并且其中当虚线为碳 - 碳单键时，R 2或R 3中的一个为氢。

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