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61. 发明申请

US20130217935A1 PROCESS TO MAKE OLEFINS FROM METHANOL AND ISOBUTANOL 审中-公开
标题翻译：从甲醇和异丁醇制备油脂的方法
公开(公告)号：US20130217935A1
公开(公告)日：2013-08-22
申请号：US13813170
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22
CPC分类号： C07C1/22 , B01J29/40 , B01J2229/42 , C07C1/20 , C07C1/24 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G2300/1014 , C10G2300/1022 , C10G2300/201 , C10G2300/4081 , C10G2400/20 , C12P5/026 , C12P7/16 , Y02E50/10 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C11/06 , C07C11/08 , C07C11/04
摘要： The present invention relates to a process for making essentially ethylene and propylene comprising: a) providing an alcohol mixture (A) comprising about 20 w % to 100% isobutanol, b) introducing in a reactor (A) a stream comprising the mixture (A) mixed with methanol or dimethyl ether or mixture thereof, optionally water, optionally an inert component, c) contacting said stream with a catalyst (A1) in said reactor (A), the MTO reactor, at conditions effective to convert at least a part of the alcohol mixture (A) and at least a part of the methanol and/or dimethyl ether to olefins, d) recovering from said reactor (A) an effluent comprising: ethylene, propylene, butene, water, optionally unconverted alcohols, various hydrocarbons, and the optional inert component of step b), e) fractionating said effluent of step d) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种基本上制备乙烯和丙烯的方法，包括：a）提供包含约20重量％至100重量％异丁醇的醇混合物（A），b）在反应器（A）中引入包含混合物（A ）与甲醇或二甲醚或其混合物，任选的水，任选的惰性组分混合，c）使所述流与所述反应器（A）中的催化剂（A1），所述MTO反应器在有效地转化至少一部分的醇混合物（A）和至少一部分甲醇和/或二甲醚至烯烃，d）从所述反应器（A）回收包含乙烯，丙烯，丁烯，水，任选未转化的醇，各种烃和步骤b）的任选的惰性组分，e）将步骤d）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4个或更多个碳原子的烃组成的馏分，水和任选的惰性 com 步骤a）的方法，任选地在反应器（A）的入口处全部或部分地回收乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多个碳原子的烃组成的馏分。

62. 发明申请

US20130172638A1 PROCESS FOR THE HYDROCONVERSION OF A LOW QUALITY HYDROCARBONACEOUS FEEDSTOCK 有权
标题翻译：低品质石油天然气原料的降解方法
公开(公告)号：US20130172638A1
公开(公告)日：2013-07-04
申请号：US13808425
申请日：2011-07-05
申请人： Didier Borremans , Jean-Pierre Dath , Kai Hortmann
发明人： Didier Borremans , Jean-Pierre Dath , Kai Hortmann
IPC分类号： B01J27/051 , B01J27/043
CPC分类号： B01J27/051 , B01J23/745 , B01J27/043 , B01J31/2295 , B01J37/20 , B01J2231/60 , B01J2531/56 , B01J2531/64 , B01J2531/842 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/44 , C10G2300/703
摘要： The invention concerns a process for upgrading lower quality carbonaceous feedstock using a slurry catalyst composition. The use of particular organometallic compounds as precursors for the dispersed active catalyst allows for reduced coke formation.
摘要翻译：本发明涉及一种使用浆料催化剂组合物来提升低质量碳质原料的方法。使用特定的有机金属化合物作为分散的活性催化剂的前体允许减少焦炭形成。

63. 发明申请

US20110124934A1 Process for Making Crystalline Metallosilicates 审中-公开
标题翻译：制备结晶金属硅酸盐的方法
公开(公告)号：US20110124934A1
公开(公告)日：2011-05-26
申请号：US12994570
申请日：2009-02-24
申请人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesterenko , Jean-Pierre Dath , Sander Van Donk
发明人： Metin Bulut , Pierre Jacobs , Delphine Minoux , Nikolai Nesterenko , Jean-Pierre Dath , Sander Van Donk
IPC分类号： C07C2/00 , C01B39/38
CPC分类号： C01B37/005 , B01J29/40 , B01J29/42 , B01J29/48 , C01B39/02 , C01B39/38 , C01P2002/72
摘要： The present invention provides a method for preparing a metallosilicate of MFI type, wherein organic templates, seeding techniques, using low aliphatic alcohols miscible with water or homogeneous starting solutions are not required.The present invention relates to a process for making a crystalline metallosilicate with high Si/Metal ratio comprising:a) providing an aqueous medium comprising OH− anions and a metal source, b) providing an aqueous medium comprising an inorganic water insoluble source of silicon, c) optionally providing a non aqueous liquid medium comprising optionally an organic source of silica, d) mixing the medium a), b) and the optional c) at conditions effective to crystallize the desired metallosilicate, e) recovering the desired metallosilicate, wherein in the mixture a)+b)+c), before crystallization, the ratio Si org/Si inorganic is
摘要翻译：本发明提供了一种制备MFI型金属硅酸盐的方法，其中不需要使用与水混合的低脂肪醇或均相起始溶液的有机模板，接种技术。本发明涉及一种制备具有高Si /金属比的结晶金属硅酸盐的方法，其包括：a）提供包含OH-阴离子和金属源的水性介质，b）提供包含无机水不溶性硅源的水性介质， c）任选地提供包含任选的二氧化硅有机源的非水液体培养基，d）在有效使结晶期望的金属硅酸盐的条件下混合培养基a），b）和任选的c），e）回收所需的金属硅酸盐，其中混合物a）+ b）+ c），在结晶之前，Si org / Si无机物的比例<0.3，有利地<0.2，优选为0，OH- / SiO 2的摩尔比为至少0.3，有利地为0.3至0.62，优选为0.31〜0.61，更优选为0.32〜0.61，非常优选为0.33〜0.6，基本上不存在模板。在另一个实施方案中，在回收所需的金属硅酸盐之前，插入步骤e），f）和g）步骤：e）将反应混合物a）+ b）+ c）冷却至约室温，f）将反应混合物的pH降低至少0.1，优选0.3至4，更优选0.5至3，g）使所得到的步骤f）的混合物在有效继续所需金属硅酸盐结晶的条件下进行。

64. 发明申请

US20070114155A1 Hydrotreating and/or hydrocracking catalyst of hydrocarbons and preparation thereof 有权
标题翻译：烃的加氢处理和/或加氢裂化催化剂及其制备
公开(公告)号：US20070114155A1
公开(公告)日：2007-05-24
申请号：US10567564
申请日：2004-08-04
申请人： Thierry Cholley , Jean-Pierre Dath
发明人： Thierry Cholley , Jean-Pierre Dath
IPC分类号： C10G65/00
CPC分类号： B01J31/0254 , B01J23/85 , B01J23/88 , B01J23/882 , B01J37/0203 , B01J37/0236 , B01J37/20 , C10G45/08 , C10G47/12 , C10G2300/70
摘要： The invention relates to a hydroconversion catalyst, which comprises a refractory oxide support, at least one metal selected from group VIII and at least one metal selected from group VIB and which is characterized in that it has at least one organic compound containing at least one oxime group of formula (I)>C═NOR1, in which R1 is selected among hydrogen and alkyl, allyl, aryl, alkylene or cycloaliphatic groups, and combinations thereof, these groups being able to be substituted by at least one electron donor group.
摘要翻译：本发明涉及一种加氢转化催化剂，其包含难熔氧化物载体，至少一种选自VIII族的金属和至少一种选自VIB族的金属，其特征在于其具有至少一种含有至少一个肟的有机化合物式（I）的基团C-NOR 1其中R 1选自氢和烷基，烯丙基，芳基，亚烷基或脂环族基团及其组合，其中R 1，这些基团能够被至少一个电子给体基团取代。

65. 发明授权

US06448198B1 Acid catalyst with a sulfated zirconia base and its uses 失效
标题翻译：具有硫酸化氧化锆基体的酸催化剂及其用途
公开(公告)号：US06448198B1
公开(公告)日：2002-09-10
申请号：US09613585
申请日：2000-07-10
申请人： Georges Szabo , Pedro Nascimento , Alain Milan , Sebastien Decker , Joeri Denayer , Jean-Pierre Dath
发明人： Georges Szabo , Pedro Nascimento , Alain Milan , Sebastien Decker , Joeri Denayer , Jean-Pierre Dath
IPC分类号： B01J27053
CPC分类号： B01J21/066 , B01J27/053 , B01J37/0009
摘要： The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 135 m2/g, a pore volume greater than or equal to 0.16 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions. In a preferred embodiment of the method of the present invention, a hydrated zirconia gel is washed with a soluble polar organic solvent (other than water). In accordance with the method including this washing step, a solid acid catalyst containing pure mass sulfated zirconia in a crystallized form has a surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.2 cm3/g, and more preferably greater than or equal to 0.25 cm3/g, and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m) and preferably greater than or equal to 30 Angstroms (30×10−10 m).
摘要翻译：本发明涉及含有大量负载或大量硫酸化氧化锆和至少一种氢化过渡金属的酸催化剂。该催化剂的特征在于硫酸化氧化锆是结晶形式，并且其表现出大于或等于135m 2 / g的比表面积，大于或等于0.16cm 3 / g的孔体积和平均孔径大于或等于20埃（20x10-10米）。本发明还涉及制备该催化剂的方法以及该催化剂在需要使用酸型催化剂的烃转化化学反应中的用途，例如异构化，烷基化，低聚反应或甚至轻质烃脱水反应，以及还有较重的烃加氢裂化和加氢异构化反应。在本发明方法的优选实施方案中，用可溶性极性有机溶剂（水除外）洗涤水合氧化锆凝胶。根据包括该洗涤步骤的方法，含有结晶形式的纯质量硫酸化氧化锆的固体酸催化剂具有大于或等于150m 2 / g的表面积，大于或等于0.2cm 3 / g的孔体积，更优选大于或等于0.25cm 3 / g，平均孔径大于或等于20埃（20×10 -10 m），优选大于或等于30埃（30×10 -10 m）。

66. 发明授权

US06294500B1 Production of polyethylene having a bimodal molecular weight distribution 失效
标题翻译：生产具有双峰分子量分布的聚乙烯
公开(公告)号：US06294500B1
公开(公告)日：2001-09-25
申请号：US09432187
申请日：1999-11-02
申请人： Guy Debras , Jean-Pierre Dath
发明人： Guy Debras , Jean-Pierre Dath
IPC分类号： B01J2326
CPC分类号： C08F10/02 , C08F210/16 , Y02P20/52 , C08F4/24 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/05 , C08F2500/07
摘要： A process for producing high density polyethylene, the process comprising polymerising ethylene, or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, in the presence of a catalyst system comprising first and second chromium-based catalysts, the first chromium-based catalyst having been reduced and reoxidised and the second chromium-based catalysts having been activated, fluoridised before or during the activation step, and reduced, the first and second chromium-based catalysts having a pore volume difference of at least 0.8 cc/g. There is further provided a catalyst system for the production of high density polyethylene by polymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising from 3 to 10 carbon atoms, the catalyst system comprising first and second chromium-based catalysts, the first chromium-based catalyst having been reduced and reoxidised and the second chromium-based catalyst been activated, fluoridised before or after the activation step, and reduced, and the first and second chromium-based catalysts having a pore volume difference of at least 0.8 cc/g. There is further provided the use of the catalyst system for increasing the biomodality of the molecular weight distribution of a high density polyethylene.
摘要翻译：一种生产高密度聚乙烯的方法，该方法包括在包含第一和第二铬基催化剂的催化剂体系存在下聚合乙烯或共聚乙烯和含有3-10个碳原子的α-烯烃共聚单体，第一种铬的催化剂已经被还原和再氧化，并且第二铬基催化剂已经在活化步骤之前或期间被活化，氟化，并且还原了具有至少0.8cc / g的孔体积差的第一和第二种铬基催化剂。还提供了一种用于通过聚合乙烯或共聚乙烯和包含3至10个碳原子的α-烯烃共聚单体生产高密度聚乙烯的催化剂体系，所述催化剂体系包含第一和第二铬基催化剂，第一铬 - 已经还原和再氧化并且第二铬基催化剂在活化步骤之前或之后被活化，氟化，还原，并且第一和第二铬基催化剂的孔体积差异至少为0.8cc / g。还提供了催化剂体系用于增加高密度聚乙烯的分子量分布的生物学性质的用途。

67. 发明授权

US10464053B2 Method for making a catalyst comprising a phosphorous modified zeolite and use of said zeolite 有权
公开(公告)号：US10464053B2
公开(公告)日：2019-11-05
申请号：US14236750
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/06 , B01J29/85 , B01J29/40 , B01J37/02 , B01J29/70 , B01J29/65 , B01J37/10 , B01J37/28 , C07C1/20 , C07C1/24 , C07C2/66 , C07C2/86 , C07C4/06 , C10G29/20 , C10G29/22 , C10G3/00 , B01J37/00 , C07C1/22 , C07C2/08
摘要： A method to make a phosphorus modified zeolite can include providing a zeolite having at least one ten member ring, making an ion-exchange, steaming the zeolite, and introducing phosphorus on the zeolite. The zeolite can be mixed with one or more binders and shaping additives, and then shaped. A metal can be introduced, and the catalyst can be washed, calcined, and steamed in an equilibration step. The steaming can be at performed at a steam severity (X) of at least about 2. The steaming can be performed at a temperature above 625° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatics by alcohols with olefins and/or alcohols.

68. 发明授权

US09056806B2 Process to make olefins from isobutanol 有权
标题翻译：从异丁醇制备烯烃的方法
公开(公告)号：US09056806B2
公开(公告)日：2015-06-16
申请号：US13813115
申请日：2011-07-08
申请人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
发明人： Cindy Adam , Delphine Minoux , Nikolai Nesterenko , Sander Van Donk , Jean-Pierre Dath
IPC分类号： C07C1/22 , C07C1/20 , C07C4/06 , C07C11/06 , C07C2/12
CPC分类号： C07C1/24 , C07C1/20 , C07C1/22 , C07C2/12 , C07C4/06 , C07C11/06 , C07C29/00 , C07C2529/40 , C07C2529/85 , C08F210/02 , C08F210/06 , C12P7/16 , Y02P30/42
摘要： The present invention relates to a process for the conversion of an alcohols mixture (A) comprising about 20 w % to 100% isobutanol to make essentially propylene, comprising: a) introducing in a reactor (A) a stream comprising the mixture (A), mixed with a stream (D1) comprising olefins having 4 carbon atoms or more (C4+ olefins), optionally water, optionally an inert component, b) contacting said stream with a catalyst (A1) at a temperature above 500° C. in said reactor (A) at conditions effective to dehydrate at least a part of the isobutanol and other alcohols, if any, and make a cracking, c) recovering from said reactor (A) an effluent comprising: ethylene, propylene, water, optionally unconverted alcohols of the mixture (A), various hydrocarbons, and the optional inert component of step a), d) fractionating said effluent of step c) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), optionally recycling ethylene in whole or in part at the inlet of the reactor (A), optionally recycling the fraction consisting essentially of hydrocarbons having 4 carbon atoms or more at the inlet of the reactor (A).
摘要翻译：本发明涉及一种将包含约20％至100％异丁醇的醇混合物（A）转化成基本上丙烯的方法，其包括：a）在反应器（A）中引入包含混合物（A）的料流，与包含具有4个或更多碳原子的烯烃（C 4 +烯烃），任选的水，任选的惰性组分的流（D1）混合，b）在所述的温度高于500℃的温度下使所述料流与催化剂（A1）接触反应器（A）在有效使至少一部分异丁醇和其它醇脱水的条件下（如果有的话）并且产生裂化，c）从所述反应器（A）回收包含乙烯，丙烯，水，任选未转化的醇混合物（A），各种烃和步骤a）的任选的惰性组分，d）将步骤c）的所述流出物分馏以产生至少一种乙烯流，丙烯料流，基本上由具有4碳原子的烃组成的馏分原子或更多，水和步骤a）的任选的惰性组分，任选地在反应器（A）的入口处全部或部分地循环乙烯，任选地在反应器（A）的入口处循环基本上由具有4个或更多碳原子的烃组成的馏分，。

69. 发明授权

US08981173B2 Method for making a catalyst comprising a phosphorus modified zeolite to be used in a MTO process 有权
标题翻译：制备催化剂的方法，该催化剂包含用于MTO工艺中的磷改性沸石
公开(公告)号：US08981173B2
公开(公告)日：2015-03-17
申请号：US13522623
申请日：2011-01-25
申请人： Nikolai Nesterenko , Sander Van Donk , Delphine Minoux , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Sander Van Donk , Delphine Minoux , Jean-Pierre Dath
IPC分类号： C07C1/24 , B01J29/85 , B01J29/06 , B01J29/40 , B01J37/28 , C07C1/20 , B01J27/16 , B01J37/00
CPC分类号： C07C1/24 , B01J27/16 , B01J29/06 , B01J29/40 , B01J29/85 , B01J37/0009 , B01J37/0045 , B01J37/06 , B01J37/08 , B01J37/28 , B01J2229/18 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C2529/40 , C07C2529/85 , C07C11/02
摘要： The present invention is the use of a catalyst in a MTO process to convert an alcohol or an ether into light olefins wherein said catalyst comprises a phosphorus modified zeolite and is made by a method comprising the following steps in this order, a) the essential portion of the phosphorus is introduced into a zeolite comprising at least one ten members ring in the structure, b) the phosphorus modified zeolite of step a) is mixed with at least a component selected among one or more binders, salts of alkali-earth metals, salts of rare-earth metals, clays and shaping additives, b)* making a catalyst body from mixture b), c) an optional drying step or an optional drying step followed by a washing step, d) a calcination step, d*) an optional washing step followed by drying, e) optionally a small portion of phosphorus is introduced in the course of step b) or b)* or at end of step b) or b)*.
摘要翻译：本发明是在MTO方法中使用催化剂将醇或醚转化为轻质烯烃，其中所述催化剂包含磷改性沸石，并通过包括以下步骤的方法制备：a）主要部分的磷被引入到在结构中包含至少一个十元环的沸石中，b）步骤a）的磷改性沸石与至少一种选自一种或多种粘合剂，碱土金属盐，稀土金属盐，粘土和成型添加剂，b）*从混合物b）制备催化剂体，c）任选的干燥步骤或任选的干燥步骤，然后洗涤步骤，d）煅烧步骤d *）任选的洗涤步骤然后干燥，e）在步骤b）或b）*或步骤b）或b）*的末端引入任选的少量磷。

70. 发明申请

US20140296599A1 Catalyst Comprising a Phosphorous Modified Zeolite and Having Partly an Alpo Structure 有权
标题翻译：包含磷改性沸石和部分Alpo结构的催化剂
公开(公告)号：US20140296599A1
公开(公告)日：2014-10-02
申请号：US14236765
申请日：2012-07-25
申请人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
发明人： Nikolai Nesterenko , Delphine Minoux , Cindy Adam , Jean-Pierre Dath
IPC分类号： B01J29/85 , C07C2/86 , C07C2/66 , C07C1/24 , C07C4/06
CPC分类号： C07C2/66 , B01J29/40 , B01J29/405 , B01J29/7049 , B01J29/85 , B01J35/1038 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/10 , B01J37/28 , B01J2229/16 , B01J2229/183 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/40 , B01J2229/42 , C07C1/24 , C07C2/864 , C07C4/06 , C07C2529/40 , C07C2529/70 , C07C2529/80 , C07C2529/83 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： A catalyst can include a phosphorus modified zeolite having partly an ALPO structure. The ALPO structure can be determined by a signal between 35-45 ppm in 27Al MAS NMR spectrum. The zeolite can include at least one ten member ring in the structure thereof. The catalyst can also include a binder and one or more metal oxides. The catalyst can be used in processes in the presence of steam at high temperatures, such as temperatures that are above 300° C. and up to 800° C. The catalyst can be used in alcohol dehydration, olefin cracking, MTO processes, and alkylation of aromatic compounds with olefins and/or alcohols.
摘要翻译：催化剂可以包括部分具有ALPO结构的磷改性沸石。 ALPO结构可以通过27Al MAS NMR光谱中35-45ppm之间的信号来确定。沸石可以在其结构中包括至少一个十元环。催化剂还可以包括粘合剂和一种或多种金属氧化物。该催化剂可以在高温存在下的工艺中使用，例如高于300℃和高达800℃的温度。催化剂可用于醇脱水，烯烃裂解，MTO工艺和烷基化的芳族化合物与烯烃和/或醇。

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