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    • 67. 发明专利
    • Production of fluorescent substance
    • 生产荧光物质
    • JPS5971386A
    • 1984-04-23
    • JP17987082
    • 1982-10-15
    • Hitachi LtdKasei Optonix Co Ltd
    • KANEHISA OSAMUYAMAMOTO AKIRAMANABE TOSHIKATSUUEHARA YASUHIKO
    • C09K11/08C09K11/56
    • PURPOSE: To mass produce easily a fluorescent substance having a high luminace, by adding an activator, an organic compound capable of generating sulfurizing gas and sulfur to a raw material, and heating the resultant mixture in a closed vessel.
      CONSTITUTION: (B) Ce, Pr, Nd, Sm or Eu, etc. as an activator, (C) an organic compound capable of generating 0.1W3.0mol, based on one mole formed fluorescent substance, sulfurizing gas, e.g. (ethylene)thiourea or thioacetamide, (D) sulfur and further preferably (E) an alkali metallic compound, e.g. Li
      2 CO
      3 , are added to (A) a compound consisting of Mg, Ca or Sr as a raw material, and the resultant mixture is then heated at 1,200°C for 2hr in a closed vessel to give the aimed fluorescent substance.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过向原料中添加能够产生硫化气体和硫的有机化合物,并将所得混合物加热到密闭容器中,可以容易地大规模生产具有高亮度的荧光物质。 构成:(B)Ce,Pr,Nd,Sm或Eu等作为活化剂,(C)基于1摩尔形成的荧光物质,能够产生0.1-3.0摩尔的有机化合物,例如硫化气体。 (乙烯)硫脲或硫代乙酰胺,(D)硫,进一步优选(E)碱金属化合物,例如。 将Li 2 CO 3添加到(A)由作为原料的Mg,Ca或Sr组成的化合物中,然后将所得混合物在密封容器中在1,200℃加热2小时,得到目标荧光物质。