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    • 62. 发明申请
    • Preparation of supported catalysts for polymerization
    • 负载聚合催化剂的制备
    • US20070179051A1
    • 2007-08-02
    • US10588391
    • 2005-02-02
    • Shahram MihanJoachim Wulff-DoringAlexander KopplWolfgang Rohde
    • Shahram MihanJoachim Wulff-DoringAlexander KopplWolfgang Rohde
    • C08F2/00B01J23/00
    • C08F210/16C08F4/65912C08F4/65925C08F10/00C08F4/025C08F4/24C08F4/65916C08F210/14C08F2500/12C08F2500/17C08F2500/18C08F2500/24C08F4/22C08F4/78
    • The invention relates to a process for preparing a supported catalyst, in particular for the polymerization and/or copolymerization of olefins, which comprises: a) preparing a hydrogel; b) milling the hydrogel to give a finely particulate hydrogel; c) producing a slurry based on the finely particulate hydrogel; d) drying the slurry comprising the finely particulate hydrogel to give the support for catalysts; e) producing the supported catalyst by applying at least one transition metal and/or at least one transition metal compound to the support for catalysts and, if appropriate, activating the applied metal and/or compound, wherein a finely particulate hydrogel in which at least 5% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦3 μm; and/or at least 40% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦12 μm, and/or at least 75% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦35 μm, is produced in step b) and a support which can be prepared as set forth in steps a) to d) is used to produce catalysts in step e).
    • 本发明涉及一种制备负载型催化剂的方法,特别是用于烯烃的聚合和/或共聚合,其包括:a)制备水凝胶; b)研磨水凝胶以得到细颗粒水凝胶; c)基于细颗粒水凝胶生产浆料; d)干燥包含细颗粒状水凝胶的浆料,得到催化剂载体; e)通过将至少一种过渡金属和/或至少一种过渡金属化合物施加到催化剂的载体上,并且如果合适地活化所施加的金属和/或化合物,制备负载型催化剂,其中至少 基于颗粒的总体积,5体积%的颗粒具有在>0μm至<3μm的范围内的粒度; 和/或至少40体积%的颗粒,基于颗粒的总体积,其粒度范围为>0μm至≤12μm,和/或至少75体积% 基于颗粒的总体积的颗粒具有在>0μm至<=35μm的范围内的粒度,在步骤b)中制备,并且可以如步骤a)至d所述制备的载体 )用于在步骤e)中制备催化剂。