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61. 发明专利

DE69918013T2 未知
公开(公告)号：DE69918013T2
公开(公告)日：2005-07-14
申请号：DE69918013
申请日：1999-04-13
申请人： BASELL POLYOLEFINE GMBH
发明人： DALL OCCO TIZIANO , RESCONI LUIGI
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F10/02 , C08F210/00 , C08F210/16
摘要： Ethylene based copolymers having high molecular weights, narrow molecular weight distributions, and a very good homogeneous distribution of the comonomer units can be obtained in high yields at temperatures of industrial interest, by carrying out the polymerization reaction in the presence of metallocene catalysts comprising particular bridged bis-indenyl compounds substituted in the 3-position on the indenyl groups.

62. 发明专利

ES2223832T3 PROCEDIMIENTO PARA LA PREPARACION DE COMPOSICIONES TERMOPLASTICAS DE PROPILENO ISOTACTICO Y POLIPROPILENO FLEXIBLE DE ISOTACTICIDAD INFERIOR. 未知
公开(公告)号：ES2223832T3
公开(公告)日：2005-03-01
申请号：ES01929430
申请日：2001-03-12
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , FERRARO ANGELO , BARUZZI GIOVANNI
IPC分类号： C08J5/00 , C08F2/44 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/06 , C08F297/06 , C08L23/10 , C08L23/14
摘要： Procedimiento para la preparación de una composición termoplástica que comprende polimerización del propileno, opcionalmente con una olefina de fórmula CH2=CHR, siendo R hidrógeno, un alquilo de 1 a 20 átomos de carbono o un grupo arilo de 6 a 12 átomos de carbono, en uno o más reactores, en presencia de un catalizador que comprende el producto entre un compuesto Al- alquilo y un componente sólido que comprende por lo menos un compuesto no metaloceno de un metal de transición M1 que contiene Ti y no contiene enlaces M1-ð y un haluro de magnesio.

63. 发明专利

ES2221744T3 PROCESO PARA LA FABRICACION DE COPOLIMEROS DE ETILENO CON ALFA-OLEFINAS. 未知
公开(公告)号：ES2221744T3
公开(公告)日：2005-01-01
申请号：ES99923426
申请日：1999-04-13
申请人： BASELL POLYOLEFINE GMBH
发明人： DALL OCCO TIZIANO , RESCONI LUIGI
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F10/02 , C08F210/00 , C08F210/16
摘要： La invención se refiere a copolímeros basados en el etileno que tiene alto peso molecular, baja distribución de pesos moleculares, y muy buena distribución homogénea de unidades de comonómeros que se pueden obtener con altos rendimientos a temperaturas de interés industrial, realizando la reacción de polimerización en presencia de catalizadores de metaloceno que incluyen compuestos particulares puenteados bis-indenilo sustituidos en la posición 3 de los grupos indenilo.

64. 发明专利

AU2003296585A1 PROCESS FOR PREPARING 1-BUTENE COPOLYMER AND COPOLYMER THEREOF 未知
公开(公告)号：AU2003296585A1
公开(公告)日：2004-06-23
申请号：AU2003296585
申请日：2003-11-14
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PELLICONI ANTEO , GARAGNANI ENEA
IPC分类号： C08F2/00 , C08F4/642 , C08F4/659 , C08F210/08
摘要： A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH2=CHZ, wherein Z is a C3C20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R and R are hydrocarbon groups; R and R are hydrogen atoms or hydrocarbon groups; T and T , equal to or different from each other are a moiety of formula (lI), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R , R , R , R and R , equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.

65. 发明专利

AU2003257448A8 Catalyst system for the polymerization of olefins 未知
公开(公告)号：AU2003257448A8
公开(公告)日：2004-01-23
申请号：AU2003257448
申请日：2003-07-09
申请人： BASELL POLYOLEFINE GMBH
发明人： CAMURATI ISABELLA , FOCANTE FRANCESCA , RESCONI LUIGI , GUIDOTTI SIMONA
IPC分类号： C07F5/02 , C08F4/645 , C08F10/00 , C08F4/659 , C08F4/6592 , C08F110/02
摘要： An organometallic compound obtainable by contacting a compound having the following formula (I), wherein: R a is a hydrocarbon radical; R b , R c and R d , are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (11) MtR 1 3 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R 1 are selected from the group consisting of halogen atoms, halogenated C 6 -C 20 aryl and halogenated C 7 -C 20 alkylaryl groups.

66. 发明专利

ES2197714T3 未知
公开(公告)号：ES2197714T3
公开(公告)日：2004-01-01
申请号：ES99972216
申请日：1999-11-10
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI
IPC分类号： C07C2/86 , C07C13/465 , C07F7/00 , C07F7/08 , C07F9/50 , C07F17/00 , C08F4/64 , C08F4/642 , C08F10/00
摘要： A new class of methylene-bridged metallocenes of formula (I), wherein M is a transition metal of group 3, 4, 5, 6, lanthanide or actinide; X is a monoanionic sigma ligand; R can be alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl radicals; R can be halogen, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl radical; p is 0-3; m is 0-2; and n is 0-4. Furthermore, the corresponding ligands, a new process for their preparation and catalysts systems containing said methylene-bridged metallocenes are described.

67. 发明专利

DE69623833T2 未知
公开(公告)号：DE69623833T2
公开(公告)日：2003-07-31
申请号：DE69623833
申请日：1996-03-01
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , JONES ROBERT L
IPC分类号： B01J31/00 , C07F7/08 , C07F7/30 , C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
摘要： Metallocene compounds having two fluorenyl ligands bridged with a single silicon or germanium atom, said atom having two substituent groups containing a total of at least four carbon atoms, are useful as catalyst components for the polymerization of olefins. Particularly, it is possible to prepare high molecular weight atactic polypropylene with improved yields with respect to the known catalysts.

68. 发明专利

DE60001901D1 未知
公开(公告)号：DE60001901D1
公开(公告)日：2003-05-08
申请号：DE60001901
申请日：2000-01-31
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI
IPC分类号： C07F7/00 , C07F7/28 , C08F4/60 , C08F10/00
摘要： A new process, particularly simple, convenient and practical, for the direct synthesis of organometallic compounds of formula(I):wherein (ZR1m)n is a divalent group bridging A and A'; A and A' re independently -O-, -S-, or -N(R2)-, wherein R2 is hydrogen, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl; M is a transition metal belonging to group 3, 4, 5, 6 or to the lanthanide or actinide groups; L is a monoanionic sigma ligand, such as alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl, optionally containing Si or Ge; L' is halogen or -OR3, R3 being an hydrocarbon radical; m is 0, 1 or 2; n is 1-8; p is 1-3; q is 0-2. Said process comprises reacting the ligand (H-A)(ZR1m)n(A'-H) with about 1 molar equivalent of ML's in the presence of about (2+p) molar equivalents of LjB or LMgL', wherein B is an alkaline or alkaline-earth metal, s ranges from 3 to 6, and j is 1 or 2.

69. 发明专利

ES2181816T3 未知
公开(公告)号：ES2181816T3
公开(公告)日：2003-03-01
申请号：ES96103118
申请日：1996-03-01
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , JONES ROBERT L
IPC分类号： B01J31/00 , C07F7/08 , C07F7/30 , C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
摘要： Metallocene compounds having two fluorenyl ligands bridged with a single silicon or germanium atom, said atom having two substituent groups containing a total of at least four carbon atoms, are useful as catalyst components for the polymerization of olefins. Particularly, it is possible to prepare high molecular weight atactic polypropylene with improved yields with respect to the known catalysts.

70. 发明专利

DE69432040D1 未知
公开(公告)号：DE69432040D1
公开(公告)日：2003-02-27
申请号：DE69432040
申请日：1994-08-31
申请人： BASELL POLYOLEFINE GMBH
发明人： RESCONI LUIGI , PIEMONTESI FABRIZIO , GALIMBERTI MAURIZIO
IPC分类号： C08F10/02 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/52
摘要： Homo- and copolymers of ethylene endowed with very high molecular weights and narrow molecular weight distributions are obtainable by carrying out the polymerization reaction in the presence of a metallocene-based catalyst wherein the metallocene is stereorigid and it is in its meso isomeric form.

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