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    • 55. 发明申请
    • Stabilization of transition metal complexes for catalysis in diverse environments
    • 过渡金属络合物在不同环境中的稳定化
    • US20040122189A1
    • 2004-06-24
    • US10684137
    • 2003-10-10
    • Krzysztof MatyjaszewskiNicolay Tsarevsky
    • C08F004/06
    • C08F4/00
    • This present invention is directed towards the identification or design, preparation, and use of suitable transition metal complexes for use as catalysts. The transition metal complexes may comprise heterodonor ligands. The present invention is also directed toward a method of determining the suitability of a transition metal complex for use in a catalytic reaction, such as, but not limited to, atom transfer radical polymerization (nullATRPnull), atom transfer radical addition (nullATRAnull), atom transfer radical cyclization (nullATRCnull), and other catalytic redox reactions. The method assists in the approximate determination of the fundamental properties of the transition metal complex in a reaction media, such as, but not limited to, solubility, redox potential, stability towards acidic, basic, or ionic species, conditional radically transferable atom phylicity, and propensity toward disproportionation and therefore, the suitability of the complex to be used as a catalyst in the reaction media. The method provides a basis for prediction and evaluation of the properties of a transition metal complex for a particular selective catalytic reaction in a broad range of reaction environments. An understanding of the principles of the disclosed method allows a transition metal complex to be tuned to specific reaction medium by selecting a transition metal complex and ligand combination having the desired qualities.
    • 本发明涉及用作催化剂的合适的过渡金属络合物的鉴定或设计,制备和使用。 过渡金属络合物可以包含异源供体配体。 本发明还涉及确定用于催化反应的过渡金属络合物的适用性的方法,例如但不限于原子转移自由基聚合(“ATRP”),原子转移自由基加成(“ATRA” “),原子转移自由基环化(”ATRC“)和其他催化氧化还原反应。 该方法有助于近似测定反应介质中过渡金属络合物的基本性质,例如但不限于溶解度,氧化还原电位,对酸性,碱性或离子物质的稳定性,条件可自由基转移的原子幽门, 和歧视倾向,因此复合物在反应介质中作为催化剂的适用性。 该方法提供了在广泛的反应环境中用于特定选择性催化反应的过渡金属络合物的性质的预测和评估的基础。 对所公开方法的原理的理解允许过渡金属络合物通过选择具有所需质量的过渡金属络合物和配体组合来调节到特定的反应介质。
    • 57. 发明申请
    • Sulfur-containing poly (unsaturated carboxylic acid) and its uses and production process
    • 含硫聚(不饱和羧酸)及其用途及生产工艺
    • US20040044151A1
    • 2004-03-04
    • US10641939
    • 2003-08-15
    • Nippon Shokubai Co., Ltd.
    • Atsuro YonedaTakahiro TsumoriKoji FukuharaShigeru Yamaguchi
    • C08F004/06
    • C11D3/378C08F20/04
    • There are disclosed a novel sulfur-containing poly(unsaturated carboxylic acid) and its uses and production process. A sulfur-containing poly(unsaturated carboxylic acid) having a weight-average molecular weight (Mw) of 500 to 4,500 and a molecular weight distribution (Mw/Mn) of not more than 2.5 is obtained by a production process comprising the step of polymerizing an unsaturated carboxylic acid in the presence of a polymerization initiator to thereby obtain the poly(unsaturated carboxylic acid), wherein: a combination of a persulfate and a bisulfite is used as the polymerization initiator, wherein the polymerization initiator is adjusted in such a manner that: the total amount of the polymerization initiator as used is not smaller than 10 g equivalents per 1 mol of the unsaturated carboxylic acid as used, and the amount of the bisulfite accounts for not smaller than 8 g equivalents of the total amount of the polymerization initiator as used; and the polymerization temperature is controlled so as to be in the range of 25 to 99null C. This polymer is used as an essential component of a detergent builder and a kaolin dispersant.
    • 公开了一种新型含硫聚(不饱和羧酸)及其用途和生产工艺。 通过制造方法得到重均分子量(Mw)为500〜4500,分子量分布(Mw / Mn)为2.5以下的含硫的聚(不饱和羧酸),其包括聚合 在聚合引发剂的存在下使用不饱和羧酸,从而得到聚(不饱和羧酸),其中:使用过硫酸盐和亚硫酸氢盐的组合作为聚合引发剂,其中聚合引发剂的调节方式如下: :所使用的聚合引发剂的总量相对于每1mol不饱和羧酸为10g当量以上,并且亚硫酸氢盐的量不少于聚合引发剂总量的8g当量 如使用; 并将聚合温度控制在25至99℃的范围内。该聚合物用作洗涤剂助洗剂和高岭土分散剂的必需组分。