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51. 发明申请

US20130310622A1 Catalytically Active Material for the Hydrogenation Treatment of Hydrocarbons 审中-公开
标题翻译：用于烃类氢化处理的催化活性物质
公开(公告)号：US20130310622A1
公开(公告)日：2013-11-21
申请号：US13979146
申请日：2012-01-18
申请人： Raimond L. C. Bonne , Olga Gonsiorová , Hans-Heino John
发明人： Raimond L. C. Bonne , Olga Gonsiorová , Hans-Heino John
IPC分类号： B01J27/185 , B01J23/883 , B01J23/78
CPC分类号： B01J27/1853 , B01J23/04 , B01J23/24 , B01J23/58 , B01J23/78 , B01J23/883 , B01J23/8872 , B01J35/1009 , B01J35/1042 , B01J35/1047 , B01J35/1076 , B01J37/0201 , C10G45/08 , C10G45/12 , C10M175/0008 , C10M175/0041
摘要： A catalytically active material having adsorption properties is used for the hydrogenation treatment of hydrocarbons severely contaminated with inorganic constituents.
摘要翻译：具有吸附性质的催化活性材料用于氢化处理被无机成分严重污染的烃。

52. 发明申请

US20120088702A1 PROCESS FOR IMPROVING A RE-REFINED LUBE OIL STREAM 有权
标题翻译：改进润滑油流程的方法
公开(公告)号：US20120088702A1
公开(公告)日：2012-04-12
申请号：US12898881
申请日：2010-10-06
申请人： Steven F. Zink , Tom Kalnes , Mark VanWees
发明人： Steven F. Zink , Tom Kalnes , Mark VanWees
IPC分类号： C10M175/00
CPC分类号： C10M175/0041 , C10G45/10 , C10G45/52 , C10G65/04 , C10G65/08 , C10G2300/1007 , C10G2400/10 , C10M2203/1025 , C10N2220/022
摘要： Embodiments of a process for improving a re-refined lube oil stream are provided. The process comprises the steps of introducing a gas stream comprising hydrogen (H2) and the re-refined lube oil stream comprising hydroprocessed used lube oil to a hydrogenation reactor that contain Group VIII catalyst. A gas to oil feed ratio rate of from about 30 to about 100 Nm3 H2/m3 is used to introduce the streams to the reactor. The hydroprocessed used lube oil is hydrogenated with the H2 in the reactor such that an effluent is formed containing hydrogenated re-refined lube oil having about 2 wt. % or less of aromatics and about 55 wt. % or less of naphthenes. The reactor is operating at a temperature of from about 250 to about 300° C.
摘要翻译：提供了改进再精炼润滑油流的方法的实施方案。该方法包括以下步骤：将包含氢气（H 2）的气流和包含加氢处理的润滑油的再精炼润滑油流引入含有VIII族催化剂的氢化反应器。使用约30至约100Nm 3 H 2 / m 3的气/油进料比率将流引入反应器。加氢处理的润滑油在反应器中用H 2氢化，使得形成含有约2重量％氢化的再精炼润滑油的流出物。％或更少的芳烃和约55wt。％以下的环烷烃。反应器在约250至约300℃的温度下操作。

53. 发明授权

US5166118A Catalyst for the hydrogenation of hydrocarbon material 失效
标题翻译：用于氢化烃材料的催化剂
公开(公告)号：US5166118A
公开(公告)日：1992-11-24
申请号：US340535
申请日：1989-04-19
申请人： Klaus Kretschmar , Ludwig Merz , Klaus Niemann , Jose Guitian , Julio Krasuk , Franzo Marruffo , Klaus Kurzeja
发明人： Klaus Kretschmar , Ludwig Merz , Klaus Niemann , Jose Guitian , Julio Krasuk , Franzo Marruffo , Klaus Kurzeja
IPC分类号： C10C1/20 , C10G1/08 , C10G47/26 , C10M175/00
CPC分类号： C10G1/086 , C10C1/205 , C10G47/26 , C10M175/0041
摘要： A catalyst for the hydrogenation of a hydrocarbon material which is a member selected from the group consisting of red mud, iron oxides, iron ores, hard coals, lignites impregnated with heavy metal salts, carbon black, soots from gasifiers, and cokes produced by the hydrogenation of virgin residues, the catalyst being comprised of at least two separate particle size fractions such that the combined fractions have a particle size distribution between 0.1 and 2,000 microns with 10-40 wt. % of the particles having a particle size greater than 100 microns, and the mixture of fractions not being represented by a straight line when the accumulative weight of the particles vs. particle size which is plotted on log (minus log) vs. log graph paper has a correlation coefficient R.sup.2 less than 0.96 as determined from the equation: ##EQU1## wherein n is the number of experimental points, y is ln [-ln (n/1000)] and x is ln (dp), wherein dp is the particle size (.mu.m) of the particles.
摘要翻译：用于氢化烃材料的催化剂，其是选自红泥，氧化铁，铁矿石，硬煤，浸渍有重金属盐的褐煤，炭黑，来自气化器的烟灰，以及由原始残余物的氢化，催化剂由至少两个分开的粒度级分组成，使得组合级分的粒度分布在0.1至2,000微米之间，10-40重量％当颗粒的累积重量与绘制在对数（减去对数）上的对比粒径相对于对数图纸时，颗粒的粒度大于100微米的颗粒的比例不是直线表示的。具有从以下等式确定的相关系数R2小于0.96：其中n是实验点的数量，y是ln [-ln（n / 1000）]，x是ln（dp），其中dp是颗粒的粒径（μm）。

54. 发明授权

US5064523A Process for the hydrogenative conversion of heavy oils and residual oils, used oils and waste oils, mixed with sewage sludge 失效
标题翻译：重油和残油的加氢转化方法，使用的油和废油，与污泥混合
公开(公告)号：US5064523A
公开(公告)日：1991-11-12
申请号：US267289
申请日：1988-11-04
申请人： Klaus Kretschmar , Ludwig Merz , Klaus Niemann
发明人： Klaus Kretschmar , Ludwig Merz , Klaus Niemann
IPC分类号： C10G47/00 , C10G47/26 , C10M175/00
CPC分类号： C10M175/0041 , C10G47/26
摘要： Process for the hydrogenative conversion of heavy oils and residual oils, used oils and waste oils, mixed with sewage sludge in a typical liquid phase hydrogenator with gases containing hydrogen, with the addition of a finely ground substance that preferably has a large internal surface area, as additive. The additive is added in two different particle size ranges so that a portion of the additive is present as a fine particle size fraction iwth a particle size of 90 .mu.m or less and another portion as a coarse particle size fraction with a particle size of 100 .mu.m to 2000 .mu.m, preferably 100 to 1000 .mu.m with the procedure being carried out with a weight ratio of raw oils to sewage sludge used of 10:1 to 1:1.5. Conversion of vacuum residue of a Venezuelan heavy oil with the addition of 2 wt. % of lignite coke as additive and with the admixture of 10 wt. % industrial or municipal sewage sludge in a liquid phase hydrogenator to obtain useful liquid products in particular, and extensive conversion of the organic fractions of the sewage sludge.
摘要翻译：在含有氢的气体的典型液相氢化器中与重污油和残油，废油和废油进行氢化转化的方法，其中添加了优选具有大的内表面积的精细研磨的物质，作为添加剂。添加剂以两种不同的粒度范围加入，使得一部分添加剂以粒度为90μm以下的细粒度分数存在，另一部分为粒径为100的粗粒径分数以原料油与污泥的重量比为10：1〜1：1.5进行处理，最好为100〜1000μm。委内瑞拉重油的真空残渣转化，加入2wt。％的褐煤焦炭作为添加剂，混合物为10wt。％工业或城市污水处理厂在液相氢化器中特别获得有用的液体产品，并大量转化污泥的有机部分。

55. 发明授权

US4851107A Process for the hydrogenation of heavy and residual oils 失效
标题翻译：重油和残油加氢工艺
公开(公告)号：US4851107A
公开(公告)日：1989-07-25
申请号：US105290
申请日：1987-10-07
申请人： Klaus Kretschmar , Ludwig Merz , Klaus Niemann , Jose Guitian , Julio Krasuk , Franzo Marruffo
发明人： Klaus Kretschmar , Ludwig Merz , Klaus Niemann , Jose Guitian , Julio Krasuk , Franzo Marruffo
IPC分类号： C10G1/00 , C10C1/20 , C10G1/08 , C10G47/02 , C10G47/26 , C10M175/00
CPC分类号： C10M175/0041 , C10C1/205 , C10G1/086 , C10G47/26
摘要： A process for the hydrogenation of heavy oils, residual oils, waste oils, used oils, shell oils, and tar sand oils by hydrogenating a slurry of the oil at a partial hydrogen pressure of 50-300 bar, a temperature of 250.degree.-500.degree. C., a space velocity of 0.1-5 T/m.sup.3 h, and a gas/liquid ratio of 100-10000 Nm.sup.3/ T, wherein the additive comprises two different grain size portions, a fine grain portion having a grain size of 90 microns or less and a coarse grain portion having a grain size of 100-1000 microns.
摘要翻译：通过在50-300巴的部分氢气压力下，在250-500℃的温度下氢化油的浆料来氢化重油，残油，废油，二手油，壳油和焦油砂油的方法 ℃，空速为0.1-5T / m3h，气/液比为100-10000Nm 3 / T，其中添加剂包括两个不同的粒度部分，粒度为90微米的细晶粒部分或更小的粗粒部分和粒径为100-1000微米的粗粒部分。

56. 发明授权

US4816138A Process for cleaning of toxic waste materials by refining and/or elimination of biologically difficult to degrade halogen, nitrogen and/or sulfur compounds 失效
标题翻译：通过精炼和/或消除生物学难以降解卤素，氮和/或硫化合物来清洁有毒废物的方法
公开(公告)号：US4816138A
公开(公告)日：1989-03-28
申请号：US915639
申请日：1986-10-06
申请人： Leo Visser , Ashok S. Laghate
发明人： Leo Visser , Ashok S. Laghate
IPC分类号： A62D3/37 , A62D101/22 , A62D101/26 , A62D101/28 , C10G67/06 , C10M175/00
CPC分类号： A62D3/37 , C10G67/06 , C10M175/0041 , A62D2101/22 , A62D2101/26 , A62D2101/28 , A62D2203/10 , Y10S210/909
摘要： The invention concerns a process for converting toxic liquid waste materials containing harmful amounts of biologically difficult to degrade toxic waste materials containing organic halogen compounds, and which also may contain organically bound oxygen, nitrogen and/or sulfur, into an innocuous hydrocarbon stream. These waste materials together with hydrogen are passed over a hydrogenating catalyst at 250.degree.-400.degree. C. and under increased pressure. The effluent of this hydrogenolysis is cooled and separated into a non-toxic liquid hydrocarbon stream, a hydrogen halogenide, ammonia, and/or a hydrogen sulfide containing stream and a gaseous stream of light hydrocarbons and hydrogen. The waste material which contains 0.5-60 weight % halogen and possibly contains up to 10% sulfur and/or small amounts of nitrogen-containing compounds is conditioned and this conditioned stream is passed, together with hydrogen under a prssure of 30-80 bar and with a LHSV of 0.5-2.5 H.sup.-1, over a column filled with absorbent, to guard the hydrogenating catalyst, and subsequently over the hydrogenating catalyst.
摘要翻译：本发明涉及一种转化有毒液体废物的方法，该废物含有有害量的生物难以降解含有机卤素化合物的有毒废物，并且还可以将有机结合的氧，氮和/或硫转化成无毒的烃物流。这些废物与氢一起在250-400℃和加压下通过氢化催化剂。将该氢解的流出物冷却并分离成无毒液体烃流，卤化氢，氨和/或含硫化氢的物流和轻烃和氢气的气流。调节含有0.5-60重量％卤素并且可能含有至多10％硫和/或少量含氮化合物的废料，并将该调理的流与氢气一起通过30-80巴，在填充有吸收剂的柱上，LHSV为0.5-2.5H-1，以保护氢化催化剂，随后在氢化催化剂上。

57. 发明授权

US3346483A Refining used lubricating oils with sulfuric acid and hydrogenation 失效
标题翻译：用硫酸精炼二手润滑油加氢
公开(公告)号：US3346483A
公开(公告)日：1967-10-10
申请号：US51068465
申请日：1965-11-30
申请人： MAGYNYOMASU KISERLETI INTEZET
发明人： LASZLO SOMOGYI , PAL STEINGASZNER , ISTVAN HLINYANSZKY , JOZSEF HORVATH , JOZSEF KAROLYI
IPC分类号： C10G67/08 , C10M175/00
CPC分类号： C10M175/0041 , C10G2400/10 , C10M175/0016

58. 发明公开

EP2625250A2 PROCESS FOR IMPROVING A RE-REFINED LUBE OIL STREAM 审中-实审
标题翻译：方法用于改善从再精炼的油流转
公开(公告)号：EP2625250A2
公开(公告)日：2013-08-14
申请号：EP11831420.2
申请日：2011-10-04
申请人： UOP LLC
发明人： ZINK, Steven, F. , KALNES, Tom , VANWEES, Mark
IPC分类号： C10G45/00 , C10G45/06 , C10M101/02
CPC分类号： C10M175/0041 , C10G45/10 , C10G45/52 , C10G65/04 , C10G65/08 , C10G2300/1007 , C10G2400/10 , C10M2203/1025 , C10N2220/022
摘要： Embodiments of a process for improving a re-refined lube oil stream are provided. The process comprises the steps of introducing a gas stream comprising hydrogen (H
2 ) and the re-refined lube oil stream comprising hydroprocessed used lube oil to a hydrogenation reactor that contain Group VIII catalyst. A gas to oil feed ratio rate of 30 to 100 Nm
3 H
2 /m
3 is used to introduce the streams to the reactor. The hydroprocessed used lube oil is hydrogenated with the H
2 in the reactor such that an effluent is formed containing hydrogenated re-refined lube oil having 2 wt.% or less of aromatics and 55 wt.% or less of naphthenes. The reactor is operating at a temperature of 250 to 300°C.

59. 发明公开

EP2478958A1 Katalytisch aktives Material für die Hydrierungsbehandlung von Kohlenwasserstoffen 审中-公开
标题翻译： Katalytisch aktives材料fürdie Hydrierungsbehandlung von Kohlenwasserstoffen
公开(公告)号：EP2478958A1
公开(公告)日：2012-07-25
申请号：EP11151421.2
申请日：2011-01-19
申请人： Euro Support Catalyst Group B.V.
发明人： Bonné, Raimond L.C. , Gonsiorová, Olga , John, Hans-Heino
IPC分类号： B01J23/04 , B01J23/887 , C10G45/08 , C10M175/00
CPC分类号： B01J27/1853 , B01J23/04 , B01J23/24 , B01J23/58 , B01J23/78 , B01J23/883 , B01J23/8872 , B01J35/1009 , B01J35/1042 , B01J35/1047 , B01J35/1076 , B01J37/0201 , C10G45/08 , C10G45/12 , C10M175/0008 , C10M175/0041
摘要： Die Erfindung bezieht sich auf ein neuartiges katalytisch aktives Material mit Absorbenseigenschaften für die hydrierende Behandlung von stark mit anorganischen Bestandteilen verunreinigten Kohlenwasserstoffen, und dem Verfahren zu dessen Herstellung
摘要翻译：具有吸附性能的催化活性材料（I）包括陶瓷，超大孔碱性硅铝酸盐。包括用于制备（I）的独立权利要求，其包括将具有直径为0.01-3mm的连续孔的硅铝酸盐的陶瓷颗粒装入或引入，所述陶瓷颗粒具有来自主组I的元素的化合物，并且任选地还包含一种或多种元素化合物来自亚组VI和/或VIII，并在300-800℃热处理陶瓷颗粒。

60. 发明公开

EP1165728A1 PROCEDE DE TRAITEMENT D'UNE HUILE UTILISANT UN FLUIDE A L'ETAT SUPERCRITIQUE 审中-公开
标题翻译：方法的油处理，借助液体生命垂危有关
公开(公告)号：EP1165728A1
公开(公告)日：2002-01-02
申请号：EP00909398.0
申请日：2000-03-01
申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE
发明人： SCHRIVE, Luc , SARRADE, Stéphane , GOURGOUILLON, Didier
IPC分类号： C10M175/00 , C10M175/02 , C11B1/10 , C11B3/00 , C11B7/00 , B01D11/04
CPC分类号： C10M175/0058 , C10M175/0041 , C10M175/005
摘要： The invention relates to a method for treating an oil using a liquid in a supercritical state. The invention relates more specifically to a method for refining an oil in order to separate the pollutants therefrom and to recover a refined oil. The inventive method makes it possible to treat organic, biological and mineral oils and can be used to re-refine petroleum oils, especially used engine oils, using CO2 in a supercritical state. The inventive method essentially comprises an initial stage, wherein the oil is brought into contact with a liquid in a supercritical state in order to separate a light fraction, a heavy fraction and an intermediate majority fraction, followed by treatment of the intermediate fraction in separation and/or reaction stages, whereby said stages are carried out in the presence of the liquid in a supercritical state.

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