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51. 发明申请

US20080227634A1 Porous Organo-Metallic Skeleton Material Containing an Additional Polymer 有权
标题翻译：含有附加聚合物的多孔有机金属骨架材料
公开(公告)号：US20080227634A1
公开(公告)日：2008-09-18
申请号：US12093656
申请日：2006-11-14
申请人： Ulrich Muller , Michael Hesse , Markus Schubert , Melanie Urtel , Jens Assmann , Philippe Desbois
发明人： Ulrich Muller , Michael Hesse , Markus Schubert , Melanie Urtel , Jens Assmann , Philippe Desbois
IPC分类号： B01J20/26
CPC分类号： B01J31/1691 , B01D53/02 , B01D2257/108 , B01J20/226 , B01J20/28097 , B01J20/3206 , B01J20/327 , B01J20/3272 , B01J20/3276 , B01J20/3278 , B01J31/06 , B01J31/2239 , B01J2531/16 , B01J2531/22 , B01J2531/23 , B01J2531/26 , B01J2531/31 , B01J2531/842 , B01J2531/847 , C01B3/0015 , C25B3/12 , F17C11/00 , Y02E60/328
摘要： The invention relates to a porous metal-organic framework material for taking up at least one substance, the framework material comprising at least one at least bidentate organic compound bound by coordination to at least one metal ion, and the framework material having at least in part pores which comprise a polymer which is suitable to adsorb the at least one substance. In addition, the invention relates to a method for producing the framework material, a method for taking up at least one substance by the framework material and also to the use of the framework material, in particular for the storage, separation, controlled release or chemical reaction of a substance taken up.
摘要翻译：本发明涉及用于吸收至少一种物质的多孔金属 - 有机骨架材料，所述骨架材料包含至少一种至少二齿的有机化合物，所述至少二齿有机化合物通过配位至少一种金属离子结合，所述骨架材料至少部分地具有包含适于吸附至少一种物质的聚合物的孔。此外，本发明涉及一种生产骨架材料的方法，一种通过骨架材料吸收至少一种物质的方法，还涉及骨架材料的使用，特别是用于储存，分离，控释或化学品物质的反应。

52. 发明申请

US20080221302A1 Catalyst and Process for the Polymerization of Cyclic Ethers 有权
标题翻译：催化剂和循环醚聚合方法
公开(公告)号：US20080221302A1
公开(公告)日：2008-09-11
申请号：US12088208
申请日：2006-11-30
申请人： Stephan Hatscher , Michael Hesse , Tobias Wabnitz , Stefan Kashammer , Rolf Pinkos
发明人： Stephan Hatscher , Michael Hesse , Tobias Wabnitz , Stefan Kashammer , Rolf Pinkos
IPC分类号： C08G65/20
CPC分类号： B01J21/16 , B01J23/40 , B01J23/745 , B01J23/75 , B01J37/0009 , B01J37/0036 , C08G65/10 , C08G65/20 , C08G65/2642
摘要： The present invention provides a catalyst comprising a mixture of at least one acid-activated sheet silicate with a transition metal oxide of groups 8 and/or 9 of the Periodic Table of the Elements and also a process for preparing polytetrahydrofuran, polytetrahy-drofuran copolymers, diesters or monoesters of these polymers, in which tetrahydrofuran is polymerized in the presence of at least one telogen and/or comonomer over such a catalyst.
摘要翻译：本发明提供一种催化剂，其包含至少一种酸活化的硅酸盐与元素周期表第8和/或9族的过渡金属氧化物的混合物，以及制备聚四氢呋喃，聚四氢呋喃共聚物的方法，这些聚合物的二酯或单酯，其中四氢呋喃在这种催化剂存在下在至少一种开环和/或共聚单体存在下聚合。

53. 发明授权

US07411081B2 Process for preparing and organometallic framework material 有权
标题翻译：制备方法和有机金属骨架材料
公开(公告)号：US07411081B2
公开(公告)日：2008-08-12
申请号：US10755231
申请日：2004-01-13
申请人： Ulrich Mueller , Gerald Lippert , Olga Schubert , Michael Hesse , Reinhard Hess , Michael Stoesser , Omar M. Yaghi
发明人： Ulrich Mueller , Gerald Lippert , Olga Schubert , Michael Hesse , Reinhard Hess , Michael Stoesser , Omar M. Yaghi
IPC分类号： C07F3/06 , C07F15/00 , C07F15/02 , B01J31/12
CPC分类号： C07F3/003 , B01J20/226
摘要： A process for preparing an organometallic framework material comprising reacting at least one metal salt with at least one at least bidentate compound capable of coordination to the metal ion of said metal salt, in the presence of an aqueous solvent system and at least one base wherein at least one bidentate compound comprises at least carboxy group and at least one further group which is not a carboxy group and which is capable of forming a hydrogen bridge linkage.
摘要翻译：一种制备有机金属骨架材料的方法，包括使至少一种金属盐与至少一种能够与所述金属盐的金属离子配位的至少二齿化合物在水性溶剂体系和至少一种碱的存在下反应，其中在至少一个二齿化合物至少包含羧基和至少一个不是羧基并且能够形成氢桥键的另外的基团。

54. 发明授权

US07371917B2 Preparation of olefins by metathesis over a carbide or oxycarbide of a transition metal 失效
标题翻译：通过在过渡金属的碳化物或碳氧化物上复分解制备烯烃
公开(公告)号：US07371917B2
公开(公告)日：2008-05-13
申请号：US10811940
申请日：2004-03-30
申请人： Markus Schubert , Till Gerlach , Michael Hesse , Juergen Stephan , Volker Boehm , Andreas Brodhagen , Frank Poplow
发明人： Markus Schubert , Till Gerlach , Michael Hesse , Juergen Stephan , Volker Boehm , Andreas Brodhagen , Frank Poplow
IPC分类号： C07C6/02
CPC分类号： C07C6/04 , B01J21/08 , B01J23/30 , B01J27/22 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/08 , C07C2523/14 , C07C2527/22
摘要： Process for preparing a compound having a nonaromatic C—C double or triple bond (compound A) from another compound or a mixture of other compounds having a nonaromatic C—C double or triple bond (compound B), which comprises bringing the compound (B) into contact with a heterogeneous catalyst comprising carbides or oxycarbides of a transition element at from 50 to 500° C.
摘要翻译：制备具有非芳族CC双键或三键（化合物B）的其它化合物或其它化合物的混合物的具有非芳族CC双键或三键的化合物（化合物A）的方法（化合物B），其包括使化合物（B）与包含50-500℃的过渡元素的碳化物或碳氧化物的多相催化剂

55. 发明申请

US20080096761A1 Preparation of supports for catalysts 审中-公开
标题翻译：催化剂载体的制备
公开(公告)号：US20080096761A1
公开(公告)日：2008-04-24
申请号：US10588390
申请日：2005-02-02
申请人： Shahram Mihan , Michael Hesse
发明人： Shahram Mihan , Michael Hesse
IPC分类号： B01J32/00
CPC分类号： C08F210/16 , B01J37/036 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F4/025 , C08F4/24 , C08F4/65916
摘要： The invention relates to a process for preparing a support for catalysts, which comprises: a) preparing a hydrogel; b) milling the hydrogel to give a finely particulate hydrogel; c) producing a slurry based on the finely particulate hydrogel; d) drying the slurry comprising the finely particulate hydrogel to give the support for catalysts, wherein a finely particulate hydrogel in which at least 5% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦3 μm; and/or at least 40% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦12 μm, and/or at least 75% by volume of the particles, based on the total volume of the particles, have a particle size in the range from >0 μm to ≦35 μm, is produced in step b).
摘要翻译：本发明涉及一种制备催化剂载体的方法，其包括：a）制备水凝胶; b）研磨水凝胶以得到细颗粒水凝胶; c）基于细颗粒水凝胶生产浆料; d）干燥包含细颗粒状水凝胶的浆料，得到催化剂载体，其中细颗粒状水凝胶，其中基于颗粒总体积的至少5体积％的颗粒的粒径范围从0um到<= 3mum; 和/或至少40体积％的颗粒，基于颗粒的总体积，其粒度范围为>0μm至≤12μm，和/或至少75体积％基于粒子的总体积的颗粒的粒度在>0μm至<=35μm的范围内，在步骤b）中产生。

56. 发明申请

US20070227898A1 Method for Electrochemical Production of a Crystalline Porous Metal Organic Skeleton Material 有权
标题翻译：一种结晶多孔金属有机骨架材料的电化学生产方法
公开(公告)号：US20070227898A1
公开(公告)日：2007-10-04
申请号：US10580407
申请日：2004-11-22
申请人： Ulrich Muller , Hermann Putter , Michael Hesse , Markus Schubert , Helge Wessel , Jurgen Huff , Marcus Guzmann
发明人： Ulrich Muller , Hermann Putter , Michael Hesse , Markus Schubert , Helge Wessel , Jurgen Huff , Marcus Guzmann
IPC分类号： C25B3/12
CPC分类号： C25B3/12 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J31/1691 , B01J31/1805 , B01J31/1815 , B01J31/2239 , B01J31/226 , B01J2531/16 , B01J2531/26 , B01J2531/842 , C01B3/0015 , C01B21/0455 , C01B23/0057 , F17C11/005 , H01M8/04216 , Y02C10/08 , Y02E60/327 , Y02E60/328 , Y02P20/133 , Y02P70/56 , Y10S95/90 , Y10S502/526
摘要： A method of electrochemically preparing a crystalline, porous, metal-organic framework material comprising at least one at least bidentate organic compound coordinately bound to at least one metal ion, in a reaction medium comprising the at least one bidentate organic compound, wherein at least one metal ion is provided in the reaction medium by the oxidation of one anode comprising the corresponding metal.
摘要翻译：一种在包含至少一种二齿有机化合物的反应介质中电化学制备结晶多孔的金属 - 有机骨架材料的方法，其包含与至少一种金属离子配位结合的至少二齿有机化合物，其中至少一种金属离子通过包含相应金属的一个阳极的氧化在反应介质中提供。

57. 发明申请

US20070036697A1 Multi-zone jacketed pipe reactor for carrying out exothermic gaseous phase reactions 审中-公开
标题翻译：用于进行放热气相反应的多区夹套管式反应器
公开(公告)号：US20070036697A1
公开(公告)日：2007-02-15
申请号：US10482398
申请日：2003-12-31
申请人： Friedrich Gutlhuber , Manfred Lehr , Gunnar Heydrich , Gunther Windecker , Stephan Schlitter , Michael Hesse , Markus Rosch , Alexander Weck , Rolf Fischer
发明人： Friedrich Gutlhuber , Manfred Lehr , Gunnar Heydrich , Gunther Windecker , Stephan Schlitter , Michael Hesse , Markus Rosch , Alexander Weck , Rolf Fischer
IPC分类号： B01J19/00 , F28D21/00
CPC分类号： B01J8/067 , B01J2208/00212 , B01J2208/00221 , B01J2208/0053 , B01J2208/00849 , B01J2219/00259 , F28D7/0066 , F28D7/0091 , F28F9/22
摘要： A multi-zone jacketed pipe reactor (2; 60; 90; 130) for carrying out exothermic gaseous phase reactions and with at least one reaction zone (I) working with vaporisation cooling, at least one reaction zone (II) working with circulation cooling and, possibly, with additional zones (III, IV) is characterised in that one reaction zone (I) working with vaporisation cooling forms the first reaction zone to which is connected an additional reaction zone (II) working with circulation cooling. In this way there occurs at the beginning of the reaction, when the latter is most violent, very intensive cooling at a precisely controllable temperature and especially as well a temperature that is constant across the entire cross-section of the reactor while subsequently in a subsequent reaction zone working with circulating cooling by means of global counter-flow guidance of the heat transfer agent a constant cooling of the reaction gas is achieved.
摘要翻译：用于进行放热气相反应的多区夹套管式反应器（2; 60; 90; 130）和至少一个用蒸发冷却工作的反应区（I），至少一个循环冷却工作的反应区（II）并且可能地具有另外的区域（III，IV），其特征在于用蒸发冷却工作的一个反应区域（I）形成连接有循环冷却工作的附加反应区域（II）的第一反应区域。以这种方式，在反应开始时发生，当后者在精确控制的温度下是最猛烈的，非常强烈的冷却，特别是在反应器的整个横截面上恒定的温度，随后在随后的反应区域通过传热剂的全局逆流引导进行循环冷却，实现了反应气体的恒定冷却。

58. 发明申请

US20060135824A1 Process for the alkoxylation of monools in the presence of metallo-organic framework materials 失效
标题翻译：在金属 - 有机骨架材料存在下烷基化单醇的方法
公开(公告)号：US20060135824A1
公开(公告)日：2006-06-22
申请号：US11285070
申请日：2005-11-23
申请人： Ulrich Mueller , Olga Metelkina , Michael Hesse , Michael Stoesser , Peter Haas , Omar Yaghi
发明人： Ulrich Mueller , Olga Metelkina , Michael Hesse , Michael Stoesser , Peter Haas , Omar Yaghi
IPC分类号： C07C41/03
CPC分类号： C08G65/2606 , C07C41/03 , C08G18/283 , C08G65/2645 , C08G65/266 , C08G2101/00 , C07C43/11
摘要： The present invention relates to a process for the alkoxylation of a monool with at least one alkoxylating agent to an alkoxylated alcohol wherein a catalyst is employed which comprises a metallo-organic framework material of metal ions and at least bidentate coordinately bound organic ligands.
摘要翻译：本发明涉及使用至少一种烷氧基化剂将烷氧基化为烷氧基化醇的方法，其中使用包含金属离子的金属有机骨架材料和至少二齿配位结合的有机配体的催化剂。

59. 发明申请

US20060099398A1 Shaped bodies containing metal-organic frameworks 有权
公开(公告)号：US20060099398A1
公开(公告)日：2006-05-11
申请号：US10983629
申请日：2004-11-09
申请人： Michael Hesse , Ulrich Muller
发明人： Michael Hesse , Ulrich Muller
IPC分类号： B27N3/00 , B32B3/00
CPC分类号： F17C11/005 , B01J20/0244 , B01J20/226 , B01J20/28011 , B01J20/2803 , B01J20/28042 , B01J20/28057 , B01J20/3007 , B01J20/3035 , B01J20/3042 , B01J31/1691 , B01J35/1028 , B01J37/0009 , B01J2231/005 , B01J2531/26 , Y02E60/324 , Y10T428/249953 , Y10T428/249967 , Y10T428/24997 , Y10T428/25 , Y10T428/298
摘要： The present invention relates to shaped bodies containing a metal-organic framework material (MOF) as well as a process for the preparation thereof and their use especially as catalyst or storage medium.

60. 发明申请

US20060052239A1 Supported catalyst containing rhenium and method for hydrogenation of hydrogenation of carbonyl compounds in liquid phase by means of said catalyst 有权
标题翻译：含有铼的载体催化剂和通过所述催化剂在液相中氢化羰基化合物的方法
公开(公告)号：US20060052239A1
公开(公告)日：2006-03-09
申请号：US10534621
申请日：2003-11-06
申请人： Markus Schubert , Michael Hesse , Rolf-Hartmuth Fischer , Take Constantinescu
发明人： Markus Schubert , Michael Hesse , Rolf-Hartmuth Fischer , Take Constantinescu
IPC分类号： B01J27/24 , C07D305/12 , C07D307/02
CPC分类号： C07D307/33 , B01J21/18 , B01J23/007 , B01J23/6567 , B01J23/688 , B01J23/84 , B01J23/8896 , B01J35/002 , B01J37/0213 , C07D307/08 , C07D315/00 , Y10S502/506 , Y10S502/512
摘要： The present invention provides a process for hydrogenating carbonyl compounds, in particular C4-dicarboxylic acids to mixtures of tetrahydrofuran and gamma-butyrolactone, over supported rhenium catalysts, wherein rhenium and at least one further metal of groups VIII or Ib of the Periodic Table of the Elements, in particular ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir), platinum (Pt), copper (Cu), silver (Ag) or cobalt (Co), is applied to the support in the form of at least one bimetallic precursor compound, and also to these catalysts.
摘要翻译：本发明提供了一种将羰基化合物，特别是C 4 - 二羧酸氢化成四氢呋喃和γ-丁内酯的混合物在负载的铼催化剂上的方法，其中铼和至少一种另外的VIII族金属或铑（Ru），铑（Rh），钯（Pd），锇（Os），铱（Ir），铂（Pt），铜（Cu），银（Ag ）或钴（Co）以至少一种双金属前体化合物的形式施用于载体，以及这些催化剂。

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