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    • 56. 发明授权
    • Separation of a mixture of C.sub.4 -hydrocarbons by extractive
distillation
    • 通过萃取蒸馏分离C {HD 4 {B-烃的混合物
    • US4162198A
    • 1979-07-24
    • US906469
    • 1978-05-17
    • Dieter StockburgerKlaus VolkamerDetlef BenderKlaus-Juergen SchneiderHarald SchwentkerUlrich WagnerHans-Martin Weitz
    • Dieter StockburgerKlaus VolkamerDetlef BenderKlaus-Juergen SchneiderHarald SchwentkerUlrich WagnerHans-Martin Weitz
    • B01D3/40C07C1/00C07C7/08C07C9/00C07C11/00C07C11/167C07C67/00B01D3/06
    • C07C7/08B01D3/40Y10S203/20
    • A process for separating, by means of a selective solvent, a mixture of C.sub.4 -hydrocarbons which contains some hydrocarbons which are more soluble in the selective solvent and some which are less soluble therein, in which process the hydrocarbon mixture is separated, in an extractive distillation zone, into a top product which contains the less soluble hydrocarbons and an extract which contains the more soluble hydrocarbons and the selective solvent, the extract, taken off as the bottom product, is subjected to a flash evaporation and the resulting vapor component of the extract is recycled to the extractive distillation zone while the liquid phase remaining after the flash evaporation is fed to a solvent recovery zone, in which the liquid phase obtained from the flash evaporation is separated into a product containing the hydrocarbons and, as the bottom product, the selective solvent which has been freed from the hydrocarbons, the resulting selective solvent is recycled to the extractive distillation zone and the product which is obtained from the solvent recovery zone and contains the hydrocarbons is partially or completely recycled to the extractive distillation zone, after increasing the pressure in a compression zone, in which process the extract taken off the extractive distillation zone is brought, prior to the flash evaporation to a higher pressure than the pressure in the extractive distillation zone and thereafter the extract which is under this higher pressure is heated, in a heat exchange zone, by indirect heat exchange with the selective solvent obtained as the bottom product from the solvent recovery zone, and the heated extract is subsequently let down, in the flash evaporation, to a pressure which is at least equal to the pressure in the extractive distillation zone and is higher than the pressure in the solvent recovery zone.
    • 通过选择性溶剂分离出含有一些较易溶于选择性溶剂的烃和一些较不溶于其中的烃类的混合物的混合物的方法,在该方法中,烃混合物在萃取过程中分离 蒸馏区,成为含有较少溶解性烃的顶部产物和含有较多可溶性烃和选择性溶剂的提取物,作为底部产物取出的萃取物进行闪蒸,并将得到的蒸气成分 萃取液再循环到萃取蒸馏区,闪蒸蒸发后剩余的液相被送入溶剂回收区,其中将从闪蒸蒸发获得的液相分离成含有烃的产物,作为底部产物, 已经从烃中除去的选择性溶剂,所得到的选择性溶剂被再循环到萃取物中 蒸馏区和从溶剂回收区获得并且含有烃的产物在增加压缩区中的压力之后部分或完全再循环到萃取蒸馏区,在该过程中,提取物从萃取蒸馏区被带走 在闪蒸蒸发到比萃取蒸馏区中的压力高的压力之前,然后将在该较高压力下的提取物在热交换区域中与作为底部产物获得的选择性溶剂进行间接热交换 然后将被加热的提取物在闪蒸中降至至少等于萃取蒸馏区压力的压力,并高于溶剂回收区的压力。