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51. 发明专利

JP2012073630A Method of manufacturing antireflection film 有权
标题翻译：制造抗反射膜的方法
公开(公告)号：JP2012073630A
公开(公告)日：2012-04-12
申请号：JP2011247557
申请日：2011-11-11
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： SHIBAYAMA NAOYUKI , YOSHIHARA TOSHIAKI
IPC分类号： G02B1/10 , B05D1/38 , B05D7/24 , B32B7/02 , G02B1/11 , G02B1/111 , G02B1/14 , G02B1/16 , G02B1/18
CPC分类号： G02B5/0242 , G02B1/116 , G02B1/16 , G02F1/133502
摘要： PROBLEM TO BE SOLVED: To provide an antireflection film which can be manufactured at low cost and has excellent optical characteristics, excellent scratch resistance and antistatic function; solving the problem that there have been demands for an anti-reflection film which can be manufactured at low cost, an antireflection film which has excellent antireflection performance and optical characteristics free from interference irregularity, an antireflection film which has high scratch resistance for use on a display surface, and an antireflection film which has antistatic function for preventing adhesion of dust.SOLUTION: An antireflection film is configured in such a manner that an uneven distribution layer and a low refractive index layer are sequentially laminated in this order on at least one surface of a transparent base material. The uneven distribution layer is formed by laminating, from the transparent base side, at least an intermediate layer, a hard coat layer, an antistatic layer that contains a conductive material, and a leveling layer that contains a leveling material in an unevenly distributed manner.
摘要翻译：解决的问题：提供可以低成本制造并具有优异的光学特性，优异的耐擦伤性和抗静电功能的抗反射膜; 解决了可以以低成本制造的抗反射膜的要求，具有优异的抗反射性能和没有干涉不规则性的光学特性的抗反射膜的问题，具有高抗擦伤性的抗反射膜用于显示面和防止灰尘附着的抗静电功能的防反射膜。解决方案：防反射膜以这样的方式配置，使得不均匀分布层和低折射率层依次层叠在透明基材的至少一个表面上。不均匀分布层通过从透明基底侧至少层叠中间层，硬涂层，含有导电性材料的抗静电层，以及包含均匀分布的流平材料的整平层而形成。版权所有（C）2012，JPO＆INPIT

52. 发明专利

JP2008033348A Manufacturing method of antireflection laminated body 有权
标题翻译：抗反应层压体的制备方法
公开(公告)号：JP2008033348A
公开(公告)日：2008-02-14
申请号：JP2007235207
申请日：2007-09-11
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： YOSHIHARA TOSHIAKI
IPC分类号： G02B1/11 , B32B7/02 , G02B1/111 , G02B1/14
摘要： PROBLEM TO BE SOLVED: To provide an antireflection laminated body which has high antireflective performance, is excellent in physical strength, is inexpensive and is excellent in productivity, and to provide a manufacturing method of the antireflection laminated body. SOLUTION: In the antireflection laminated body, an antireflection film of a multilayer composition formed by successively stacking a hard coat layer/a high refractive index layer/a low refractive index layer, or a hard coat layer/a middle refractive index layer/a high refractive index layer/a low refractive index layer is formed on at least one side of a base material, wherein an intermediate boundary layer having an intermediate refractive index of each upper and lower layers which hold the boundary between the same layers is formed on at least one part of the boundary of each layer. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决问题的方案为了提供抗反射性能好的抗反射层叠体，具有优异的物理强度，便宜并且生产率优异，并且提供了防反射层压体的制造方法。解决方案：在防反射层叠体中，通过连续层叠硬涂层/高折射率层/低折射率层或硬涂层/中折射率层而形成的多层组合物的防反射膜在基材的至少一侧形成高折射率层/低折射率层，其中形成具有保持相同层之间的边界的每个上层和下层的中间折射率的中间边界层在每个层的边界的至少一部分上。版权所有（C）2008，JPO＆INPIT

53. 发明专利

JP2005202389A Antireflection laminated body 有权
标题翻译：抗反复层压体
公开(公告)号：JP2005202389A
公开(公告)日：2005-07-28
申请号：JP2004365981
申请日：2004-12-17
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： OHIRA TOMOYA , YOSHIHARA TOSHIAKI , OHATA KOICHI , ANAMI KENJI , TANAKA TOKIKO
IPC分类号： G02B5/30 , B32B7/02 , B32B27/00 , G02B1/10 , G02B1/11 , G09F9/00
摘要： PROBLEM TO BE SOLVED: To provide an antireflection laminated body excellent in all of transparency, surface hardness, abrasion resistance, adhesion, antistatic property and productivity and realizing the restraint of color slurring. SOLUTION: The antireflection laminated body has a transparent supporting body 1, a hard coat layer 2, a conductive layer 3 and an antireflection layer 4. The conductive layer contains a binder matrix including the hydrolyzate of silicon alkoxide shown by a general expression (I) R x Si(OR) 4-x (provided that R shows an alkyl group and x is an integer satisfying 0≤x≤3 in the expression) and conductive particulates whose particle diameter is 1 to 100nm, and satisfies an expression (II) nd=λ/2 [provided that n shows the refractive index of the conductive layer, d shows the film thickness of the conductive layer, and λ shows the wavelength (nm) of light and is a number satisfying 500≤λ≤600]. Then, both of a difference between the refractive index of the supporting body and that of the hard coat layer and a difference between the refractive index of the hard coat layer and that of the conductive layer are set to ≤4%. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供透明性，表面硬度，耐磨性，粘合性，抗静电性和生产率全部优异的抗反射层压体，实现彩色絮凝的约束。防反射层叠体具有透明的支撑体1，硬涂层2，导电层3和防反射层4.导电层含有包含由通式表示的硅烷氧化物的水解物的粘合剂基质（式中，R表示烷基，x表示表达式中满足0≤x≤3的整数），和（I）R（SB）x 粒径为1〜100nm的导电性微粒，满足式（II）nd =λ/ 2 [n表示导电层的折射率，d表示导电层的膜厚，λ表示波长（nm），满足500≤λ≤600]。然后，将支撑体的折射率与硬涂层的折射率之差与硬涂层的折射率与导电层的折射率之差设定为≤4％。版权所有（C）2005，JPO＆NCIPI

54. 发明专利

JP2005199707A Antireflecting laminate 有权
标题翻译：抗反射层压板
公开(公告)号：JP2005199707A
公开(公告)日：2005-07-28
申请号：JP2004365980
申请日：2004-12-17
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： OHIRA TOMOYA , YOSHIHARA TOSHIAKI , OHATA KOICHI , ANAMI KENJI , TANAKA TOKIKO
IPC分类号： G02B1/11 , B32B7/02 , C09D4/02 , C09D5/00 , C09D5/24 , C09D7/12 , C09D183/00
摘要： PROBLEM TO BE SOLVED: To provide an anti-reflecting laminate which is superior in any of a transparency, a surface hardness, an anti-scratching property, an adhesion, an antistatic property and productivity, and keeps a color shade suppressed. SOLUTION: The an antireflecting laminate 5 has a transparent support 1, a hard coated layer 2, an electrically conductive layer 3 and an antireflecting layer 4 wherein the electrically conductive layer contains a binder matrix containing a hydrolyzed material of a silicon alkoxide represented by formula (I) R x Si(OR) 4-x (R=alkyl and x=an integer satisfying 0≤x≤3) and electrically conductive fine particles with a particle diameter of 1-100nm, and satisfies formula (II) nd=λ/4 (n= a reflective index of the electrically conductive layer, d=a thickness of the electrically conductive layer, λ= a wavelength(nm) of light and a number satisfying 450≤λ≤850) and both of a difference between a reflective index of the supporting body and the reflective index of the hard coat layer mentioned above and a difference between the reflective index of the hard coat layer mentioned above and a reflective index of the electrically conductive layer mentioned above are lower than 4%. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决问题：提供透明性，表面硬度，抗划伤性，粘合性，抗静电性，生产性优异的防反射层叠体，抑制着色。解决方案：抗反射层压体5具有透明支撑体1，硬涂层2，导电层3和抗反射层4，其中导电层含有含有表示的硅醇盐的水解材料的粘合剂基体通过式（I）R（S）X（S）S（OR）4 S x（R =烷基，x =满足0≤x≤3的整数）和导电性微粒与粒径为1-100nm，满足式（II）nd =λ/ 4（n =导电层的反射率，d =导电层的厚度，λ=光的波长（nm）满足450≤λ≤850的数字），支撑体的反射率与上述硬涂层的反射率之差与上述硬涂层的反射率之差上述导电层的反射率较低 n 4％。版权所有（C）2005，JPO＆NCIPI

55. 发明专利

JP2004199879A Ion conductor 审中-公开
公开(公告)号：JP2004199879A
公开(公告)日：2004-07-15
申请号：JP2002363434
申请日：2002-12-16
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： IIO KEIICHI , YOSHIHARA TOSHIAKI
IPC分类号： C08G18/71 , C08G59/02 , C08G77/08 , C08G77/46 , H01B1/06 , H01G9/035 , H01M6/18 , H01M10/05 , H01M10/056 , H01M10/40
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide an ion conductor preventing drop in ion conductivity caused by crystallization of a polymer chain, having mechanical strength and flexibility, and comprising an organic/inorganic polymer capable of forming a dense and thick membrane.
SOLUTION: This organic/inorganic hybrid type ion conductor is a polymer having organic functional group modified alkoxysilane (A), an organic compound (B) having a functional group capable of conducting thermal polymerization with the compound (A), an alkali metal compound (C) and/or an alkali metal salt (D) as a starting material, and being obtained by hydrolysis, condensation polymerization reaction, or polymerization reaction through a functional group. The obtained polymer comprises organic skeletons and inorganic skeletons, and at least one of the organic skeletons and the inorganic skeletons represents conductivity, and the optimum condition in synthesis of the ion conductor is found.
COPYRIGHT: (C)2004,JPO&NCIPI

56. 发明专利

JP2004059616A Radical-polymerizable composition and ion-conductive solid electrolyte 审中-公开
公开(公告)号：JP2004059616A
公开(公告)日：2004-02-26
申请号：JP2002216397
申请日：2002-07-25
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： YOSHIHARA TOSHIAKI , IIO KEIICHI
IPC分类号： C08F290/06 , H01B1/06 , H01M10/05 , H01M10/056 , H01M10/40
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide an ion-conductive solid electrolyte which is excellent in productivity and easily handled and can be formed into a rigid, tough and thin film which has high ion conductivity and a high alkali ion transference number, especially a high lithium ion transference number and is electrochemically stable and excellent in physical strength; and a radical-polymerizable composition which is a precursor thereof.
SOLUTION: The radical-polymerizable composition contains, as major components, an alkali metal salt, an organosilicon compound represented by the formula: R
2
x Si(OR
1 )
4-x (wherein R
1 is an alkyl; R
2 is a functional group having a radical-polymerizable ethylene bond; and x is 1, 2, or 3) or its hydrolyzate, and an acrylic compound having at least one radical-polymerizable ethylene bond and at least one ethylene oxide or propylene oxide unit in the molecule.
COPYRIGHT: (C)2004,JPO

57. 发明专利

JP2004027033A Radical polymerizable composition and ion conductor 有权
公开(公告)号：JP2004027033A
公开(公告)日：2004-01-29
申请号：JP2002185914
申请日：2002-06-26
申请人： Toppan Printing Co Ltd , 凸版印刷株式会社
发明人： YOSHIHARA TOSHIAKI , IIO KEIICHI
IPC分类号： C08F299/08 , C08G77/442 , C08G77/46 , H01B1/06 , H01M6/18 , H01M10/05 , H01M10/0565
CPC分类号： Y02E60/122
摘要： PROBLEM TO BE SOLVED: To provide an ion conductor excellent in ion conductivity, alkali ion transport number, physical strength and electrochemical stability, easy to handle, made tough and thin though hard and good in productivity, and a radical polymerizable composition being a precursor of the ion conductor.
SOLUTION: The radical polymerizable composition includes at least an alkali metal alkoxide represented by the formula : M
1 OR
1 (M
1 : an alkali metal, and R
1 : an alkyl group) and an organosilicon compound represented by the formula : R
2
x Si(OR
3 )
4-x (R
2 : a functional group having a radical polymerizable ethylene bond, R
3 : an alkyl group and x : an integer) or a hydrolysate thereof. This composition is cured by heat or the irradiation with active radiation to form the ion conductor. When this is used as a solid electrolyte, a secondary cell used over a long period of time and excellent in reliability can be obtained.
COPYRIGHT: (C)2004,JPO

58. 发明专利

JP2002235036A ANTIREFLECTION LAMINATE 失效
公开(公告)号：JP2002235036A
公开(公告)日：2002-08-23
申请号：JP2001034947
申请日：2001-02-13
申请人： TOPPAN PRINTING CO LTD
发明人： YOSHIHARA TOSHIAKI , OHATA KOICHI , OKUBO TORU
IPC分类号： B05D5/06 , B32B7/02 , B32B9/00 , B32B27/00 , B32B27/30 , C09D5/32 , C09D175/14 , C09D183/02 , C09D183/04 , C09D183/06 , C09D183/08 , G02B1/11 , G02B1/111 , G02B1/14 , G02B1/18
摘要： PROBLEM TO BE SOLVED: To provide an antireflection laminate having low refractive index, practically sufficient physical strength and excellent stainproofness, productivity, or the like, and producible at a low cost. SOLUTION: The objective antireflection laminate has a low-refractive layer obtained by coating at least one surface of a transparent substrate such as a plastic material or glass with a low-refractive coating agent composed mainly of fluorine-containing silicon compounds expressed by the general formula (A) Si(OR)4 (R is an alkyl) and the general formula (B) CF3-(CF2)p-(CH)n-Si(OR)3 ((p) is an integer of 0

59. 发明专利

JP2002069426A LOW REFRACTIVE INDEX COMPOSITION AND OPTICAL MULTILAYER FILM MADE THEREOF 失效
公开(公告)号：JP2002069426A
公开(公告)日：2002-03-08
申请号：JP2000257092
申请日：2000-08-28
申请人： TOPPAN PRINTING CO LTD
发明人： YOSHIHARA TOSHIAKI , OHATA KOICHI
IPC分类号： B32B7/02 , B32B9/00 , C03C17/30 , C08J7/06 , C09D4/00 , C09D5/00 , C09D183/02 , C09D183/04 , C09D183/07 , C09D183/08 , C09K3/00 , G02B1/10 , G02B1/11 , G02B1/111 , G02B1/14 , G02B1/18
摘要： PROBLEM TO BE SOLVED: To provide a composition having a low refractive index, excellent in hardness, scratch resistance, adhesion to a substrate, and antifouling property, and provide an optical multilayer film made of the composition, inexpensive and excellent in productivity. SOLUTION: This composition comprises the following substances as main components, silicon alkoxide represented by the general formula (A): Si(OR)4 (wherein R is alkyl group) and its hydrolysate, an organosilicon compound represented by the formula (B): R'XSi(OR)4-X (wherein R is an alkyl group; R' is a functional group having at its terminals a polymerizable unsaturated bond such as a vinyl group, an acryloyl group, a methacryloyl group, etc.; x is a number of substitutions satisfying the range of 0

60. 发明专利

JP2002006103A ANTIREFLECTIVE FILM, OPTICALLY FUNCTIONAL FILM AND DISPLAY DEVICE 失效
公开(公告)号：JP2002006103A
公开(公告)日：2002-01-09
申请号：JP2000189378
申请日：2000-06-23
申请人： TOPPAN PRINTING CO LTD
发明人： OHATA KOICHI , YOSHIHARA TOSHIAKI
IPC分类号： G02B5/30 , B32B7/02 , G02B1/11 , G02B1/115 , G02B1/14 , G02B1/18 , G02F1/1335
摘要： PROBLEM TO BE SOLVED: To provide a antireflective film having a antireflective layer which resists flaws on the surface caused by abrasion and is free from peeling. SOLUTION: The antireflective film 6 having a hard coat layer 2 at least on one side of a transparent plastic film substrate 1, and the antireflective layer 4 which is composed of either a single layer 4-b having a low refractive index or by alternately laminating a high refractive index layer 4-a and the low refractive index layer 4-b on the hard coat layer, is characterized in that a primer layer 3 composed of a silane coupling agent is formed between the hard coat layer 2 and the antireflective layer 4, and an antifouling layer 5 is formed on the outermost surface of the antireflective layer 4.

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