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    • 51. 发明授权
    • O-Substituted phenylsulfonamides
    • O-取代的苯基磺酰胺
    • US4476321A
    • 1984-10-09
    • US423344
    • 1982-09-24
    • Willy MeyerWerner Fory
    • Willy MeyerWerner Fory
    • C07D239/42A01N41/06A01N43/66A01N47/36A01P13/00C07C20060101C07C67/00C07C301/00C07C311/00C07C311/29C07C313/00C07C317/14C07C317/18C07C317/22C07C317/44C07C323/12C07C323/67C07D239/46C07D239/47C07D239/52C07D239/56C07D251/14C07D251/16C07D251/22C07D251/42C07D251/44C07D251/46C07D521/00C07C143/78
    • C07D521/00A01N47/36
    • N-Phenylsulfonyl-N'-pyrimidinyl- and triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.1 -C.sub.6 haloalkyl radical,E is the methine group or nitrogen,X is oxygen, sulfur, a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is 1 or 2,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 -haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl of at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge, with the proviso that m is 2 when at the same time A is --CHF.sub.2, --CF.sub.3, --CH.sub.2 --CF.sub.3, --CF.sub.2 --CHF.sub.2, --CF.sub.2 --CHFCL, --CF.sub.2 CHFBr or --CF.sub.2 --CHF--CF.sub.3 ; R.sub.3 is OCH.sub.3 or CH.sub.3 ; R.sub.4 is OCH.sub.3, --CH.sub.3, --OC.sub.2 H.sub.5, --CH.sub.2 --O--CH.sub.3 or --CH.sub.2 --CH.sub.2 --OCH.sub.3, and the phenyl nucleus is not substituted or is substituted in the 2-, 3-, 5- or 6-position to the sulfonyl group only by one further substituent selected from the group consisting of F, Cl, Br or --CH.sub.3.
    • 具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基和三嗪基脲及其与胺,碱金属或碱土金属碱或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质 。 在上式中,A是C 1 -C 6卤代烷基,E是次甲基或氮,X是氧,硫,亚磺酰基或磺酰基桥,Z是氧或硫,m是1或2,R1是氢,卤素, C1-C5烷基,C2-C5链烯基或自由基-Y-R5,R2是氢,卤素,C1-C5烷基,C2-C5链烯基,C1-C4-卤代烷基或基团-Y-R5,-COOR6,-NO2或 - CO-NR 7 -R 8,R 3和R 4各自独立地是氢,C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6, 独立于C 1 -C 5烷基,C 2 -C 5烯基或C 2 -C 6炔基,R 7和R 8各自独立地为氢,C 1 -C 5烷基,C 2 -C 5烯基或C 2 -C 6炔基,Y为氧,硫, 亚磺酰基或磺酰基桥,条件是当A同时为-CHF 2,-CF 3,-CH 2 -CF 3,-CF 2 -CHF 2,-CF 2 -CHFCL,-CF 2 -CHFBr或-CF 2 -CHF-CF 3时m为2 ; R3是OCH3或CH3; R4是OCH3,-CH3,-OC2H5,-CH2-O-CH3或-CH2-CH2-OCH3,并且苯基核在2-,3-,5-或6-位没有取代或被取代成 磺酰基只有一个选自F,Cl,Br或-CH 3的取代基。
    • 52. 发明授权
    • N-Phenylsulfonyl-N'-triazinylureas
    • N-苯基磺酰基-N' - 三嗪基脲
    • US4443245A
    • 1984-04-17
    • US458587
    • 1983-01-17
    • Willy MeyerWerner Fory
    • Willy MeyerWerner Fory
    • A01N43/66A01N47/36C07D251/16C07D251/42C07D251/44C07D251/46C07D521/00
    • C07C309/89A01N47/36C07C311/65C07D521/00
    • N-Phenylsulfonyl-N'-triazinyl-ureas of the formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.2 -C.sub.6 -alkenyloxy, a C.sub.2 -C.sub.6 -haloalkenyloxy a C.sub.2 -C.sub.6 -haloalkenylthio, a C.sub.2 -C.sub.6 -haloalkenylsulfinyl or a C.sub.2 -C.sub.6 -haloalkenylsulfonyl radicalZ is oxygen or sulfur,m is 1 or 2,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.1 -C.sub.4 -haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, halogen or alkoxyalkyl of at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.
    • 式“IMAGE”的N-苯基磺酰基-N'-三嗪基脲及其盐与胺,碱金属或碱土金属碱基或季铵碱基具有良好的芽前和芽后选择性除草和生长调节性质。 在上式中,A是C 2 -C 6 - 烯氧基,C 2 -C 6 - 卤代烯氧基,C 2 -C 6 - 卤代链烯基硫基,C 2 -C 6卤代链烯基亚磺酰基或C 2 -C 6 - 卤代烯基磺酰基Z是氧或硫,m是1或 2,R 2是氢,卤素,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基,C 1 -C 4卤代烷基或自由基-Y-R 5,-COOR 6,-NO 2或-CO-NR 7 -R 8,R 3和R 4 各自独立地为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 卤代烷基,卤素或至多4个碳原子的烷氧基烷基,R 5和R 6各自独立地 是C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 6 - 炔基,R 7和R 8各自独立地为氢,C 1 -C 5 - 烷基,C 2 -C 5 - 烯基或C 2 -C 5 - C6炔基,Y是氧,硫,亚磺酰基或磺酰基桥。
    • 53. 发明授权
    • Oxime derivatives for protecting plant crops
    • US4437879A
    • 1984-03-20
    • US398164
    • 1982-07-14
    • Werner ForyHenry MartinGeorg Pissiotas
    • Werner ForyHenry MartinGeorg Pissiotas
    • A01N25/32A01N37/32A01N37/34C07C67/00C07C251/32C07C251/54C07C313/00C07C315/04C07C317/28C07C317/44C07C323/47C07C325/00C07C327/28C07D207/26C07D207/273C07D207/325C07D207/404C07D207/408C07D207/44C07D207/452C07D207/456C07D209/48A01N43/38
    • C07D207/273A01N25/32C07D207/452C07D207/456C07D209/48
    • Oxime derivatives of the formula (I) ##STR1## wherein n is 0, 1 or 2 and m is 0 or 1, andAr is a phenyl radical ##STR2## a naphthyl radical substituted by R.sub.2 and R.sub.3, a 5- to 10-membered heterocyclic radical which contains not more than 3 identical or different heteroatoms N, O and/or S and which is substituted by R.sub.2, R.sub.3 and R.sub.4 and can be substituted by oxo or thiono, or if m is O, Ar is a radical R--CO, wherein R is a radical --OR.sub.5, in which R.sub.5 is an aliphatic group containing not more than 8 carbon atoms or is an araliphatic group containing not more than 15 carbon atoms or is a cycloaliphatic or aromatic group, each containing not more than 10 carbon atoms, while the possible substituents of the aromatic radicals or of the cycloaliphatic radical are halogen, --CN, --NO.sub.2, lower alkyl, lower alkoxy, haloalkyl; or R is a radical --NH--CO--NH--R.sub.7 or a radical --N(R.sub.6)(R.sub.7), wherein R.sub.6 is hydrogen or lower alkyl and R.sub.7 is hydrogen or an aliphatic group containing not more than 8 carbon atoms or an araliphatic group containing not more than 15 carbon atoms, or a cycloaliphatic ##STR3## wherein R.sub.9 is hydrogen, a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, or is lower alkenyl, lower haloalkenyl or lower alkynyl, R.sub.10 is an aliphatic group or a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, R.sub.11 is hydrogen, lower alkyl or cycloalkyl, R.sub.12 is lower alkyl or an aromatic group, while Y is O, S SO, SO.sub.2 or ##STR4## and A is C.sub.2 -C.sub.3 alkylene or C.sub.2 -C.sub.3 alkenylene which is unsubstituted or substituted by halogen, CN or lower alkyl and which together with a carbon chain which is unsubstituted or substituted by halogen, CN or lower alkyl can form a fused ring, and Hal is halogen. These compounds are used for protecting plant crops from the action of aggressive agricultural chemicals.
    • 54. 发明授权
    • N-Phenylsulfonyl-N'-pyrimidinylureas
    • N-苯基磺酰基-N'-嘧啶基脲
    • US4425154A
    • 1984-01-10
    • US458696
    • 1983-01-17
    • Willy MeyerWerner Fory
    • Willy MeyerWerner Fory
    • C07D239/42A01N41/06A01N43/66A01N47/36A01P13/00C07C20060101C07C67/00C07C301/00C07C311/00C07C311/29C07C313/00C07C317/14C07C317/18C07C317/22C07C317/44C07C323/12C07C323/67C07D239/46C07D239/47C07D239/52C07D239/56C07D251/14C07D251/16C07D251/22C07D251/42C07D251/44C07D251/46C07D521/00A01N43/54
    • C07D521/00A01N47/36
    • N-Phenylsulfonyl-N'-pyrimidinyl ureas of the formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.2 -C.sub.6 alkenyloxy, C.sub.2 -C.sub.6 haloalkenyloxy, C.sub.2 -C.sub.6 haloalkenylthio, C.sub.2 -C.sub.6 haloalkenylsulfinyl or C.sub.2 -C.sub.6 haloalkenylsulfonyl radicalZ is oxygen or sulfur,m is 1 or 2,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl of at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.
    • 具有式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲及其与胺,碱金属或碱土金属碱或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质。 在上式中A是C 2 -C 6烯氧基,C 2 -C 6卤代链烯氧基,C 2 -C 6卤代链烯基硫基,C 2 -C 6卤代烯基亚磺酰基或C 2 -C 6卤代烯基磺酰基Z是氧或硫,m是1或2,R 2是氢,卤素, C1-C5烷基,C2-C5链烯基,C1-C4卤代烷基或自由基-Y-R5,-COOR6,-NO2或-CO-NR7-R8,R3和R4分别独立地为氢,C1-C4烷基, 最多4个碳原子的C 1 -C 4烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷基,卤素或烷氧基烷基,R 5和R 6各自独立地是C 1 -C 5烷基,C 2 -C 5链烯基或C 2 -C 6炔基,R 7和R 8 独立于氢,C1-C5烷基,C2-C5链烯基或C2-C6炔基,Y是氧,硫,亚磺酰基或磺酰基桥。
    • 60. 发明授权
    • Agent for the regulation of plant growth
    • 植物生长调节剂
    • US4053497A
    • 1977-10-11
    • US709828
    • 1976-07-29
    • Werner ForyHanspeter FischerDieter LohmannGerd Greber
    • Werner ForyHanspeter FischerDieter LohmannGerd Greber
    • C07F7/08C07F7/18
    • C07F7/1868C07F7/0812
    • The present invention relates to new compositions and methods for the regulation of plant growth, especially for fruit abscission, acceleration of ripening and latex discharge of rubber trees, and to new active substances of the class of .beta.-halogenoethylsilanes.The new active substances in the new composition corresponding to the formula ##STR1## wherein X is chlorine or bromine, A represents a radical --SR.sub.1, --NR.sub.2 R.sub.3, --OR.sub.4, --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --X, B and C each independently represent --CH.sub.3, --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --X, the symbols R.sub.1, R.sub.3 and R.sub.4 representing substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, phenyl or benzyl radicals, R.sub.2 denoting hydrogen or the same as R.sub.3, whereby R.sub.2 and R.sub.3 together with the adjacent nitrogen atom can also form a saturated or unsaturated ring system, and R.sub.4 can furthermore represent the group --COR.sub.5, whereby R.sub.5 stands for alkyl, alkenyl, alkynyl, halogenoalk(en)yl, substituted or unsubstituted phenylalk(en)yl, alkoxyalkyl, alkoxycarbonylalkyl, benzoylalkyl, cycloalkylalkyl, for substituted or unsubstituted phenyl or for a 5- or 6-membered heterocyclic radical.