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51. 发明授权

US4294971A Preparation of N-aryloxazolidine-2,4-diones 失效
标题翻译： N-芳基恶唑烷-2,4-二酮的制备
公开(公告)号：US4294971A
公开(公告)日：1981-10-13
申请号：US127759
申请日：1980-03-06
申请人： Franz Merger , Friedrich Towae
发明人： Franz Merger , Friedrich Towae
IPC分类号： B01J23/00 , C07B61/00 , C07D263/44 , C07D263/52 , C07D263/04
CPC分类号： C07D263/44
摘要： N-Aryloxazolidine-2,4-diones are prepared by reacting a nitrobenzene with a 2-hydroxycarboxylic acid ester and carbon monoxide in the presence of selenium and a basic compound under super-atmospheric pressure and at an elevated temperature.The N-aryloxazolidine-2,4-diones of the formula I, obtainable by the process of the invention are valuable active ingredients and starting materials for the preparation of crop protection agents, dyes and drugs.
摘要翻译：通过在超大气压和升高的温度下，在硒和碱性化合物的存在下，使硝基苯与2-羟基羧酸酯和一氧化碳反应来制备N-芳基恶唑烷-2,4-二酮。通过本发明的方法获得的式I的N-芳基恶唑烷-2,4-二酮是用于制备作物保护剂，染料和药物的有价值的活性成分和起始材料。

52. 发明授权

US4278805A Process for the preparation of an aryl mono-, di-, and/or polyurethane 失效
标题翻译：芳基单 - ，二 - 和/或聚氨酯的制备方法
公开(公告)号：US4278805A
公开(公告)日：1981-07-14
申请号：US135246
申请日：1980-03-31
申请人： Franz Merger , Friedrich Towae
发明人： Franz Merger , Friedrich Towae
IPC分类号： C08G18/70 , C07C125/07 , C07C125/063 , C07C125/077
CPC分类号： C08G18/701
摘要： A process for the preparation of an aryl-mono and/or polyurethane comprising the steps ofA. reacting a primary aromatic mono, di-, and/or polyamine with an O-alkyl carbamate in the presence of alcohol and catalysts, andB. separating the ammonia and other by-products from the aliphatic and/or cycloaliphatic di- and/or polyurethane.The reaction is preferably carried out in the presence of urea. The aryl mono-, di-, and/or polyurethanes produced are valuable end and intermediate products. They can be transferred into the corresponding isocyanates which can then be used for the preparation of polyurethanes.
摘要翻译：一种制备芳基单和/或聚氨酯的方法，包括以下步骤：在醇和催化剂存在下，使伯芳基单，二胺和/或多胺与氨基甲酸O-烷基酯反应。从脂族和/或脂环族二酯和/或聚氨酯中分离氨和其它副产物。反应优选在尿素存在下进行。所生产的芳基单，二和/或聚氨酯是有价值的终端和中间产物。它们可以转移到相应的异氰酸酯中，然后可以将其用于制备聚氨酯。

53. 发明授权

US4239641A Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators 失效
标题翻译：多元醇，羧酸，羟基羧酸和/或它们的酯与多元醇的粘合调节剂的应用
公开(公告)号：US4239641A
公开(公告)日：1980-12-16
申请号：US59777
申请日：1979-07-23
申请人： Johannes Perner , Paul Diessel , Dieter Stoeckigt , Franz Merger , Juergen Paetsch
发明人： Johannes Perner , Paul Diessel , Dieter Stoeckigt , Franz Merger , Juergen Paetsch
IPC分类号： C11D3/20 , C11D3/065 , C11D3/43 , C11D11/02
CPC分类号： C11D3/2093 , C11D3/2065 , C11D3/2075 , C11D3/2086 , C11D3/2044
摘要： A method for regulating the viscosity of aqueous detergent and cleanser slurries, in which there are added to the slurries, as viscosity regulators, dihydric, trihydric or tetrahydric aliphatic alcohols, monobasic aliphatic carboxylic acids, hydroxycarboxylic acids, esters of the said alcohols and the said acids or mixtures of these, in which compounds the alcohols, carboxylic acids and hydroxycarboxylic acids, and the individual components of the esters, are of 5 to 9 carbon atoms, of which one is a quaternary atom, the alcohols and hydroxycarboxylic acids carry exclusively primary alcohol groups, and the carboxylic acids and hydroxycarboxylic acids have the carboxyl group bonded to the quaternary carbon atom.
摘要翻译：一种用于调节添加到浆料中的粘度调节剂，二元，三元或四元脂肪醇，一元脂族羧酸，羟基羧酸，所述醇和所述醇的酯的水性洗涤剂和清洁剂浆料的粘度的方法酸或它们的混合物，其中醇，羧酸和羟基羧酸以及酯的单个组分的化合物为5至9个碳原子，其中一个为季原子，醇和羟基羧酸仅具有一级醇基，羧酸和羟基羧酸具有与季碳原子键合的羧基。

54. 发明授权

US4192949A Preparation of aralkyl phenyl ethers and alkyl phenyl ethers 失效
标题翻译：芳烷基苯基醚和烷基苯基醚的制备
公开(公告)号：US4192949A
公开(公告)日：1980-03-11
申请号：US915716
申请日：1978-06-15
申请人： Franz Merger , Friedrich Towae , Ludwig Schroff, deceased
发明人： Franz Merger , Friedrich Towae , Ludwig Schroff, deceased
IPC分类号： C07C69/017 , B01J31/00 , C07B61/00 , C07C41/00 , C07C41/16 , C07C43/20 , C07C43/23 , C07C43/257 , C07C45/00 , C07C45/71 , C07C47/56 , C07C47/575 , C07C49/82 , C07C49/825 , C07C49/84 , C07C67/00 , C07C69/76 , C07C201/00 , C07C201/12 , C07C205/37 , C07C253/00 , C07C255/54 , C07C313/00 , C07C319/20 , C07C323/20 , C07C43/22 , C07C43/24 , C07C43/25
CPC分类号： C07C41/16 , C07C201/12 , C07C45/67 , C07C45/71 , C07C67/31
摘要： Phenol ethers are prepared by reacting phenols with dialkyl carbonates in the presence of tertiary amines and/or phosphines. The aralkyl aryl ethers and alkyl aryl ethers obtained are starting materials for the manufacture of dyes, crop protection agents and scents.
摘要翻译：酚醚通过在叔胺和/或膦存在下使酚与碳酸二烷基酯反应来制备。获得的芳烷基芳基醚和烷基芳基醚是用于制备染料，作物保护剂和香料的起始原料。

55. 发明授权

US5576449A Preparation of 2-substituted but-2-ene-1,4-dial-4-acetals and novel hemiacetals of glyoxal monoacetals 失效
标题翻译： 2-取代的丁-2-烯-1,4-表面-4-缩醛的制备和乙二醛单缩醛的新半缩醛
公开(公告)号：US5576449A
公开(公告)日：1996-11-19
申请号：US314955
申请日：1994-09-29
申请人： J urgen Frank , Johann-Peter Melder , Franz Merger , Tom Witzel
发明人： J urgen Frank , Johann-Peter Melder , Franz Merger , Tom Witzel
IPC分类号： C07D319/06
CPC分类号： C07D319/06
摘要： The preparation of 2-substituted but-2-ene-1,4-dial-4-acetals of the formula I ##STR1## in which the substituents R.sup.1 to R.sup.4 stand for hydrogen or C.sub.1 -C.sub.6 aliphatic radicals, and R.sup.2 and R.sup.3 or R.sup.1 and R.sup.2 are in each case common members of an aliphatic 4-membered to 7-membered ring, which can contain a hetero atom, and R.sup.5 denotes an alkyl, alkenyl, or alkynyl radical having from 1 to 12 C atoms, which can be substituted by cycloaliphatic, aromatic or heterocyclic radicals or by hydroxy, ether, thioether, acyl, alkylamino, carboxy, or carbalkoxy groups, an optionally substituted aryl radical or an alkoxy, alkylthio, or acyloxy group, whereina) glyoxal is caused to react with a 1,3-propanediol of the formula II ##STR2## in aqueous solution in the presence of an acid to form a monoacetal of the formula III ##STR3## is neutralized, and if necessary the components more readily volatile than the monoacetal III are distilled off,b) the monoacetal III obtained is caused to react with an aldehyde R.sup.5 CH.sub.2 --CHO in the presence of from 0.01 to 10 mol %, based on glyoxal, of a catalyst mixture of a secondary amine and an acid to form an aldol of the formula IV ##STR4## the components which are more volatile than the aldol IV being distilled off if necessary, andc) the aldol IV is dehydrated in the presence of a water-eliminating agent to form the product I,and novel hemiacetals of glyoxal monoacetals.
摘要翻译：制备其中取代基R 1至R 4代表氢或C 1 -C 6脂族基团的式I I 2的2-取代的丁-2-烯-1,4-二甲氧基-4-缩醛，以及R 2和R 3 或者R 1和R 2各自为可以含有杂原子的脂肪族4元〜7元环的共同成员，R 5表示具有1〜12个C原子的烷基，烯基或炔基，其可以被脂环族，芳族或杂环基取代，或被羟基，醚，硫醚，酰基，烷基氨基，羧基或烷氧基取代，任选取代的芳基或烷氧基，烷硫基或酰氧基，其中a）使乙二醛反应与式II II的1,3-丙二醇在酸存在下在水溶液中形成式III的单缩醛中和，如果需要，组分比单缩醛更容易挥发 III蒸馏掉，b）使获得的单缩醛III与醛反应在基于乙二醛的0.01至10mol％的存在下，将仲胺和酸的催化剂混合物形成式IV的醛醇，得到更具挥发性的组分如果需要，醛醇IV被蒸馏，和c）醛醇IV在除水剂存在下脱水以形成产物I，和乙二醛单缩醛的新型半缩醛。

56. 发明授权

US5516928A Preparaion of 3.cyano-3,5,5-trimethylcyclohexanone 失效
标题翻译： 3.氰基-3,5,5-三甲基环己酮的制备
公开(公告)号：US5516928A
公开(公告)日：1996-05-14
申请号：US395322
申请日：1995-02-28
申请人： Klaus Mundinger , Gerhard Laqua , Tom Witzel , Franz Merger
发明人： Klaus Mundinger , Gerhard Laqua , Tom Witzel , Franz Merger
IPC分类号： C07C253/10 , C07C255/46
CPC分类号： C07C253/10 , C07C2101/14
摘要： A process for the preparation of 3-cyano-3,5,5-trimethylcyclohexanone by the reaction of isophorone with hydrogen cyanide in the presence of quaternary ammonium catalysts at temperatures ranging from 80.degree. to 180.degree. C. and pressures ranging from 0.5 to 20 bar, in which the ammonium catalysts used are salts of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 denote C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.8 cycloalkyl, aryl, C.sub.7 -C.sub.18 aralkyl or C.sub.2 -C.sub.18 hydroxyalkyl andX denotes HCO.sub.3 or ##STR2## with the proviso that R.sup.4 stands for C.sub.1 -C.sub.8 alkyl when X is ##STR3##
摘要翻译：在季铵催化剂存在下，通过异佛尔酮与氰化氢反应制备3-氰基-3,5,5-三甲基环己酮的方法，温度范围为80-180℃，压力范围为0.5-20 其中使用的铵催化剂是通式I的盐，其中R 1，R 2，R 3，R 4表示C 1 -C 18烷基，C 5 -C 8环烷基，芳基，C 7 -C 18芳烷基或C 2-8芳烷基， C18羟烷基，X表示HCO3或者“IMAGE”，条件是当X为时，R4代表C1-C8烷基，

57. 发明授权

US5386053A Multistep, continuous preparation of organic polyisocyanates 失效
标题翻译：多步连续制备有机多异氰酸酯
公开(公告)号：US5386053A
公开(公告)日：1995-01-31
申请号：US28009
申请日：1993-03-08
申请人： Andreas Otterbach , Hans V. Schwarz , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Otto Mattner
发明人： Andreas Otterbach , Hans V. Schwarz , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Otto Mattner
IPC分类号： C08G18/72 , C07C263/00 , C07C263/04 , C07C263/20 , C07C265/00 , C07C265/04 , C07C265/10 , C07C265/14 , C08G71/00 , C08G71/04 , C07C263/06
CPC分类号： C07C263/04 , C07C2101/14 , Y02P20/582
摘要： A multistep process for the continuous preparation of organic polyisocyanates, preferably aliphatic or cycloaliphatic diisocyanates, by reacting the corresponding organic polyamines with carbonic acid derivatives and alcohols to give monomeric polyurethanes and pyrolyzing the latter involves separating the resultant polyisocyanates and worthless residues in certain reaction steps and recycling the reusable by-products into earlier steps.
摘要翻译：通过使相应的有机多胺与碳酸衍生物和醇反应得到单体聚氨酯并热解后者，连续制备有机多异氰酸酯，优选脂族或环脂族二异氰酸酯的多步骤方法包括在某些反应步骤中分离得到的多异氰酸酯和无价值残基，将可重复使用的副产品回收到早期步骤中。

58. 发明授权

US5380919A Preparation of neopentyl glycol hydroxypivalate 失效
标题翻译：新戊二醇羟基新戊酸酯的制备
公开(公告)号：US5380919A
公开(公告)日：1995-01-10
申请号：US32025
申请日：1993-03-16
申请人： Franz Merger , Martin Schmidt-Radde
发明人： Franz Merger , Martin Schmidt-Radde
IPC分类号： B01J23/04 , C07B61/00 , C07C67/44 , C07C69/675
CPC分类号： C07C67/44
摘要： A process for preparing neopentyl glycol hydroxypivalate by base-catalyzed disproportionation of hydroxypivalaldehyde, wherein the reaction is carried out in the presence of a readily water-soluble alkaline earth metal salt and of an alkali metal hydroxide.
摘要翻译：通过羟基新戊醛的碱催化歧化制备新戊二醇羟基新戊酸的方法，其中反应在容易水溶性的碱土金属盐和碱金属氢氧化物的存在下进行。

59. 发明授权

US5344983A Selective preparation of linear pentane-1,5-diamines in increased yields 失效
标题翻译：线性戊烷-1,5-二胺的选择性制备
公开(公告)号：US5344983A
公开(公告)日：1994-09-06
申请号：US936084
申请日：1992-08-26
申请人： Tom Witzel , Eberhard Fuchs , Franz Merger , Claus-Ulrich Priester
发明人： Tom Witzel , Eberhard Fuchs , Franz Merger , Claus-Ulrich Priester
IPC分类号： B01J23/40 , B01J23/755 , B01J27/10 , B01J27/125 , B01J27/18 , C07B61/00 , C07C209/48 , C07C211/09 , C07C209/00
CPC分类号： C07C209/48
摘要： Process for preparing a pentane-1,5-diamine of the formula ##STR1## where R.sup.1 represents a variety of organic radicals including alkyl which can bear substituents such as hydroxyl, halogen, alkoxy, carbalkoxy, carboxyl, alkylamino, cycloalkyl or aryl, andR.sup.2 and R.sup.3 independently of one another, represent hydrogen or have the same meanings as R.sup.1 or together are a C.sub.4 -C.sub.7 -alkylene chain which is unsubstituted or substituted by one to five C.sub.1 -C.sub.4 -alkyl groups,which comprises:(a) reacting a .gamma.-cyanoketone of the formula ##STR2## where R.sup.1, R.sup.2 and R.sup.3 have the meanings given above, with excess ammonia in a first reaction space on an acidic heterogeneous catalyst at 20.degree.-150.degree. C. and 15-500 bar, and(b) hydrogenating the resulting reaction product in a second separate reaction space in the presence of excess ammonia on a cobalt, nickel or noble metal catalyst at 50.degree.-180.degree. C. and 30-500 bar.Novel pentane-1,5-diamines are obtained, in which R.sup.1 must contain at least two carbon atoms if R.sup.2 and R.sup.3 are both hydrogen. These new compounds containing two primary amine groups possess advantageous properties of lower volatility and also greater asymmetry (with different reactivity of the two amine functions). They provide useful curing agents for epoxides and act as improved components of polyamides.
摘要翻译：制备式（I）的戊烷-1,5-二胺的方法，其中R 1表示各种有机基团，包括可以带有取代基的烷基，例如羟基，卤素，烷氧基，烷氧基，羧基，烷基氨基，环烷基或芳基和R 2和R 3彼此独立地表示氢或具有与R 1相同的含义或一起是未被取代或被一至五个C 1 -C 4 - 烷基取代的C 4 -C 7亚烷基链，其包含：（ a）在20-150℃的酸性非均相催化剂的第一反应空间中使具有上述含义的式（Ia）的式（II）的γ-氰基酮与过量的氨反应，其中R1，R2和R3具有上述含义， 15-500巴，（b）在钴，镍或贵金属催化剂的存在下，在50-180℃和30-500巴下，在第二分开的反应空间中，使得到的反应产物氢化。得到新的戊烷-1,5-二胺，如果R2和R3都是氢，其中R1必须含有至少两个碳原子。这些含有两个伯胺基团的新化合物具有较低的挥发性和更大的不对称性（两种胺官能团的不同反应性）的有利特性。它们为环氧化物提供有用的固化剂，并且作为聚酰胺的改进组分。

60. 发明授权

US5254757A Preparation of 2,2-bis-hydroxymethyl-butanediol-(1,4) 失效
标题翻译：制备2,2-双羟甲基丁二醇 - （1,4）
公开(公告)号：US5254757A
公开(公告)日：1993-10-19
申请号：US964865
申请日：1993-10-22
申请人： Franz Merger , Martin Schmidt-Radde
发明人： Franz Merger , Martin Schmidt-Radde
IPC分类号： C07B61/00 , C07C29/141 , C07C31/24 , C07C45/59 , C07C45/75 , C07C47/19 , C07C27/04 , C07C29/145 , C07C31/18
CPC分类号： C07C47/19 , C07C29/141 , C07C31/24 , C07C45/75
摘要： A process for the preparation of 2,2-bis-hydroxymethyl-butanediol-(1,4) of formula I ##STR1## wherein 4-hydroxybutyraldehyde of formula II ##STR2## and/or 2-hydroxytetrahydrofuran of formula III ##STR3## is/are condensed with formaldehyde in the presence of a basic catalyst and the resulting reaction mixture is then catalytically hydrogenated, and 2,2-bis-hydroxymethyl-butanediol-(1,4) is isolated from the hydrogenation product.
摘要翻译：制备式I的2,2-双羟甲基丁二醇 - （1,4）的方法（I）其中式II的4-羟基丁醛和/或2-羟基四氢呋喃式III（III）在碱性催化剂存在下与甲醛缩合，然后将所得反应混合物进行催化氢化，并将2,2-双羟甲基丁二醇 - （1,4）从氢化产物。

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