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    • 56. 发明申请
    • Process for Oligomerizing Olefins Using a Catalyst Based On Silica-Alumina
    • 使用基于二氧化硅 - 氧化铝的催化剂低聚烯烃的方法
    • US20090192342A1
    • 2009-07-30
    • US12360231
    • 2009-01-27
    • Vincent COUPARDAlexandra ChaumonnotLaurent Simon
    • Vincent COUPARDAlexandra ChaumonnotLaurent Simon
    • C07C2/02B01J21/12
    • C07C2/10C10G50/00C10G2300/1081C10G2300/1088C10G2300/1092C10G2400/22
    • A process for oligomerizing an olefinic hydrocarbon feed is described which consists of bringing said feed into contact with a catalyst comprising a silica-alumina, the silica content of said catalyst being in the range 5% to 95% by weight, said catalyst being prepared using a process comprising at least: a) mixing at least one alumina compound which is partially soluble in an acid medium with either at least one silica compound which is completely soluble in the reaction mixture or a combination formed by at least one silica compound and at least one alumina compound, said silica and alumina compounds being completely soluble in the reaction mixture, in order to form a solid precursor of said catalyst; b) hydrothermal treatment of the solid derived from step a) by calcining in moist air for a period in the range 4 to 7 hours.
    • 描述了一种使烯烃进料低聚的方法,其包括使所述进料与包含二氧化硅 - 氧化铝的催化剂接触,所述催化剂的二氧化硅含量在5重量%至95重量%的范围内,所述催化剂使用 一种方法至少包括:a)将至少一种部分可溶于酸性介质的氧化铝化合物与至少一种完全可溶于反应混合物的二氧化硅化合物或由至少一种二氧化硅化合物形成的组合物和至少 一种氧化铝化合物,所述二氧化硅和氧化铝化合物完全溶于反应混合物中,以形成所述催化剂的固体前体; b)通过在潮湿空气中煅烧4至7小时的时间段对来自步骤a)的固体进行水热处理。