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    • 55. 发明专利
    • Coated galvanized steel sheet
    • 涂镀钢板
    • JP2012116088A
    • 2012-06-21
    • JP2010267701
    • 2010-11-30
    • Nippon Steel Corp新日本製鐵株式会社
    • FUDA MASAHIROSHOJI HIROMASAMORISHITA ATSUSHIHAYASHI KIMITAKA
    • B32B15/08C23C22/07C25D9/10
    • PROBLEM TO BE SOLVED: To provide a chromate-free coated galvanized steel sheet which has extremely excellent corrosion resistance, workability, scratch resistance, chemical resistance or the like without using hexavalent chromium whose environmental load is high.SOLUTION: In the surface treated steel sheet, at least one side of a galvanized steel sheet is provided with a silicon oxide-based film, and on the surface of the silicon oxide-based film, an organic resin-based film is coated. The organic resin-based film includes at least one kind selected from a carboxyl group, a hydroxyl group, a sulfonic acid group and a silanol group in the structure. The ratio (I/I) of the infrared absorption spectrum intensity Iderived from Si-OH to the infrared absorption spectrum intensity Iderived from an Si-O-Si bond, in the silicon oxide film, is at least 0.1.
    • 要解决的问题:提供一种不使用环境负荷高的六价铬的,具有极好的耐腐蚀性,可加工性,耐刮擦性,耐化学性等的无铬酸盐镀锌钢板。 解决方案:在表面处理钢板中,镀锌钢板的至少一侧设置有氧化硅系膜,在氧化硅系膜的表面上,有机树脂系膜为 涂。 有机树脂类膜在结构中包含选自羧基,羟基,磺酸基和硅烷醇基中的至少一种。 红外吸收光谱强度I SiOH的比例(I SiOH / I SiOSi 来自Si-OH的SiO 2 / SB>至氧化硅膜中由Si-O-Si键衍生的红外吸收光谱强度I SiOSi 为0.1以上。 版权所有(C)2012,JPO&INPIT
    • 56. 发明专利
    • Chromate-free color-coated metal sheet
    • 无铬无色涂层金属片
    • JP2012116057A
    • 2012-06-21
    • JP2010266796
    • 2010-11-30
    • Nippon Steel Corp新日本製鐵株式会社
    • MORISHITA ATSUSHIHAYASHI KIMITAKAFUDA MASAHIRO
    • B32B15/08B05D7/14
    • PROBLEM TO BE SOLVED: To provide an inexpensive chromium-free color-coated metal sheet which does not comprise hexavalent chromium having a high environmental load properties and has extremely superior designability (coloring properties and concealing properties including a worked part), moisture resistance, corrosion resistance, workability, scratch resistance, chemical resistance or the like.SOLUTION: The chromate-free color-coated metal sheet has a color-coating film (α) formed by coating at least one side of a metal sheet with an aqueous color composition (X) comprising the aqueous dispersion (A) of an organic resin (a) comprising an anionic functional group; the aqueous dispersion (B) of a color pigment (b2) dispersed by using a water-soluble acrylic resin (b1) as a dispersant; and the aqueous dispersion (C) of colloidal silica particles (c), and performing heating and drying.
    • 要解决的问题:为了提供不含有具有高环境负荷性能的六价铬并且具有非常优异的设计性(着色性能和包括加工部分的隐蔽性)的廉价的无铬彩涂金属片,水分 电阻,耐腐蚀性,可加工性,耐擦伤性,耐化学性等。 解决方案:不含铬酸盐的彩色金属片具有通过用包含水性分散体(A)的水性颜料组合物(X)涂覆金属片的至少一面而形成的着色涂膜(α) 包含阴离子官能团的有机树脂(a) 通过使用水溶性丙烯酸树脂(b1)作为分散剂分散的着色颜料(b2)的水性分散体(B) 和胶体二氧化硅粒子(c)的水分散液(C),进行加热干燥。 版权所有(C)2012,JPO&INPIT
    • 59. 发明专利
    • Surface-treated metallic material
    • 表面处理金属材料
    • JP2003301274A
    • 2003-10-24
    • JP2002110674
    • 2002-04-12
    • Nippon Steel Corp新日本製鐵株式会社
    • FUDA MASAHIROKANAI HIROSHIYAMAOKA IKURO
    • B05D7/14B05D7/24B32B15/08C23C22/48C23C28/00
    • C23C28/00
    • PROBLEM TO BE SOLVED: To provide a surface-treated metallic material which does not include harmful hexavalent chromium, has high corrosion resistance, and has adequate solvent resistance and workability.
      SOLUTION: The surface-treated metallic material is made by applying a treatment liquid comprising a water-soluble thermosetting resin, a cross-linking agent, and a polyphenol compound, on a metallic material. Preferably, the water-soluble thermosetting resin is selected among a polyester resin, an epoxy resin, and a urethane resin; the cross-linking agent is selected from an amino resin and isocyanate; and the polyphenol compound is tannic acid, and is contained in an amount of 0.1 mass% or more but 50 mass% or less with respect to the total solid content. The surface-treated steel sheet employed for the metallic material is preferably a galvanized steel sheet. The treated film preferably includes, with respect to the total solid content, silicon oxide of 1 mass% or more but 40 mass% or less, an organic-Si-based compound and/or an organic-Ti-based compound of 0.1 mass% or more but 30 mass% or less, and a solid lubricant of 1 mass% or more but 40 mass% or less.
      COPYRIGHT: (C)2004,JPO
    • 要解决的问题:提供不含有害六价铬的表面处理金属材料,具有高耐腐蚀性,并且具有足够的耐溶剂性和可加工性。 解决方案:表面处理的金属材料通过在金属材料上涂覆包含水溶性热固性树脂,交联剂和多酚化合物的处理液而制成。 优选地,水溶性热固性树脂选自聚酯树脂,环氧树脂和聚氨酯树脂; 交联剂选自氨基树脂和异氰酸酯; 多酚化合物为单宁酸,相对于固体成分总含量为0.1质量%以上且50质量%以下。 用于金属材料的表面处理钢板优选为镀锌钢板。 相对于总固体成分,经处理的膜优选包含1质量%以上且40质量%以下的氧化硅,0.1质量%的有机Si系化合物和/或有机Ti系化合物, 以上且30质量%以下,固体润滑剂为1质量%以上且40质量%以下。 版权所有(C)2004,JPO
    • 60. 发明专利
    • Galvanized steel sheet superior in heat resistance and corrosion resistance
    • 耐腐蚀和耐腐蚀性优良的钢板
    • JP2003073851A
    • 2003-03-12
    • JP2001264728
    • 2001-08-31
    • Nippon Steel Corp新日本製鐵株式会社
    • ISAKI TERUAKIFUDA MASAHIRO
    • C23C22/53C23C28/00
    • C23C28/3225C23C22/53C23C28/345C23C2222/10
    • PROBLEM TO BE SOLVED: To produce a galvanized steel sheet coated with a chemical conversion coating film, capable of being used for home electric appliances, car components or the like, which does not contain hexavalent chromium to reduce an environmental load, and mainly contains an inorganic component so as to be used also for heat resisting applications. SOLUTION: (1) The galvanized steel sheet superior in heat resistance and corrosion resistance, is obtained by treating a steel sheet with a conversion coating solution, which contains the inorganic components of a trivalent chromium compound (A) and water dispersible silica (B) as main components, and further a component for giving lubricity (C), and water. (2) The galvanized steel sheet superior in heat resistance and corrosion resistance is obtained by treating a steel sheet with the conversion coating solution according to claim (1), wherein a ratio of solid of the component (B) is 10-90 wt.% to the total solid of the coating solution of 100 wt.%. (3) The galvanized steel sheet superior in heat resistance and corrosion resistance according to either one of claim 1 or 2 is the one wherein the solution includes a metal salt of nitric acid (D) as an additional component, and the metal in the metal salt of nitric acid includes at least one kind selected from the group consisting of alkaline earth metals, Co, Ni, Fe, Zr, and Ti.
    • 要解决的问题:为了生产涂覆有化学转化涂膜的镀锌钢板,能够用于不含六价铬的家用电器,汽车部件等以降低环境负荷,并且主要包含 无机组分,以便用于耐热应用。 解决方案:(1)耐热性和耐腐蚀性优异的镀锌钢板通过用含有三价铬化合物(A)和水分散性二氧化硅(B)的无机成分的转化涂层溶液处理钢板而获得, 作为主要成分,还有用于赋予润滑性(C)的成分和水。 (2)通过用权利要求1所述的转化涂布液处理钢板,得到耐热性和耐腐蚀性优异的镀锌钢板,其中成分(B)的固体比例为10-90wt。 %至100重量%的涂布溶液的总固体。 (3)根据权利要求1或2中任一项所述的耐热性和耐腐蚀性优异的镀锌钢板是其中所述溶液包含作为附加成分的硝酸金属盐(D)和所述金属中的金属 硝酸盐包括选自碱土金属,Co,Ni,Fe,Zr和Ti中的至少一种。