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    • 52. 发明授权
    • Semiconductor device and method for manufacturing the same
    • 半导体装置及其制造方法
    • US06294481B1
    • 2001-09-25
    • US09232849
    • 1999-01-19
    • Seiji InumiyaYoshio Ozawa
    • Seiji InumiyaYoshio Ozawa
    • H01L213115
    • H01L21/28202H01L21/28185H01L21/2822H01L21/31155H01L21/76224H01L21/823481H01L29/42368H01L29/518
    • A semiconductor device is provided in which a lowering in the breakdown voltage of a gate insulating film (nitrided silicon oxide film) in a boundary region between the upper-end corner portion of the side wall of an element isolating groove and a silicon substrate in the end portion of an element forming region which is formed in contact therewith can be suppressed without causing an increase in the number of steps (time for effecting the steps). An element isolation insulating film is filled into the internal portion of the element isolating groove to cover the end portion of the silicon substrate in the element forming region which is formed in contact with the upper-end portion of the side wall of the element isolating groove, nitrogen is selectively doped into the surface of the silicon substrate in a region of the element forming region other than the end portion thereof with the element isolation insulating film used as a mask, then a portion of the element isolation insulating film lying outside the element isolating groove is removed to expose the upper-end portion of the side wall, and a nitrided silicon oxide film used as the gate insulating film is formed by the heat treatment in an atmosphere containing an oxidizing agent.
    • 提供了一种半导体器件,其中在元件隔离槽的侧壁的上端拐角部分和硅衬底的边界区域中的栅极绝缘膜(氮化硅氧化物膜)的击穿电压降低 可以抑制与其接触形成的元件形成区域的端部,而不会增加步骤数(进行步骤的时间)。 元件隔离绝缘膜被填充到元件隔离槽的内部,以覆盖与元件隔离槽的侧壁的上端部接触形成的元件形成区域中的硅基板的端部 在元件隔离绝缘膜用作掩模的情况下,在除了其端部之外的元件形成区域的区域中的氮衬底的表面中选择性地掺杂氮,然后元件隔离绝缘膜的位于元件外部的部分 去除隔离槽以暴露侧壁的上端部分,并且在包含氧化剂的气氛中通过热处理形成用作栅极绝缘膜的氮化氧化硅膜。
    • 55. 发明授权
    • Semiconductor device manufacturing method
    • 半导体器件制造方法
    • US08435858B2
    • 2013-05-07
    • US13282507
    • 2011-10-27
    • Seiji InumiyaTomonori Aoyama
    • Seiji InumiyaTomonori Aoyama
    • H01L21/336
    • H01L21/28167H01L21/02057H01L21/28088H01L21/28194H01L21/28202H01L21/7624H01L21/823857H01L29/4966H01L29/513H01L29/517H01L29/518H01L29/66795H01L29/785
    • A semiconductor device manufacturing method includes: removing an insulating film on a semiconductor substrate by using wet etching and subsequently oxidizing a surface of the substrate by using a liquid oxidation agent without exposing this surface to an atmosphere, thereby forming a first insulating film containing an oxide of a constituent element of the substrate on the surface of the substrate; forming a second insulating film containing aluminum and another metal element on the first insulating film; forming a high-k insulating film containing at least one of hafnium and zirconium on the second insulating film; forming a metal film on the high-k insulating film; and conducting heat treatment to react the first insulating film and the second insulating film, thereby forming a third insulating film made of a mixture containing aluminum, the another metal element, the constituent element of the substrate, and oxygen.
    • 半导体器件制造方法包括:通过使用湿法蚀刻在半导体衬底上去除绝缘膜,随后通过使用液体氧化剂氧化衬底的表面而不将该表面暴露在大气中,从而形成含有氧化物的第一绝缘膜 所述基板表面上的所述基板的构成元件; 在所述第一绝缘膜上形成含有铝和另一金属元素的第二绝缘膜; 在所述第二绝缘膜上形成含有铪和锆中的至少一种的高k绝缘膜; 在高k绝缘膜上形成金属膜; 进行热处理以使第一绝缘膜和第二绝缘膜反应,从而形成由含有铝,另一金属元素,基板的构成元素和氧的混合物制成的第三绝缘膜。
    • 57. 发明授权
    • Semiconductor device and method for manufacturing same
    • 半导体装置及其制造方法
    • US08183641B2
    • 2012-05-22
    • US12626216
    • 2009-11-25
    • Seiji InumiyaTomonori Aoyama
    • Seiji InumiyaTomonori Aoyama
    • H01L29/76
    • H01L21/823857H01L29/513H01L29/517
    • A silicon oxynitride film is formed on entire surface of a semiconductor substrate, a lanthanum oxide film is formed on the silicon oxynitride film and the lanthanum oxide film is removed from a pMOS region. Then, a nitrided hafnium silicate film serving as a highly dielectric film is formed on the entire surface, an aluminum-containing titanium nitride film is formed, a polysilicon film is formed, and the stacked films are patterned into a gate electrode configuration. Next, impurities are introduced into a source/drain region, and an annealing for activating the impurities is utilized to diffuse the aluminum included in the aluminum-containing titanium nitride film to the interface between the silicon oxynitride film and the nitrided hafnium aluminum silicate film in the pMOS region.
    • 在半导体衬底的整个表面上形成氧氮化硅膜,在氧氮化硅膜上形成氧化镧膜,并从pMOS区域除去氧化镧膜。 然后,在整个表面上形成用作高电介质膜的氮化铪硅酸盐膜,形成含铝的氮化钛膜,形成多晶硅膜,并将层叠的膜图案化为栅电极构造。 接下来,将杂质引入源极/漏极区域,并且利用用于激活杂质的退火将包含在含铝氮化钛膜中的铝扩散到氮氧化硅膜和氮化铪硅酸铝膜之间的界面 pMOS区域。
    • 58. 发明授权
    • Semiconductor device and method of fabricating the same
    • 半导体装置及其制造方法
    • US07989896B2
    • 2011-08-02
    • US12612238
    • 2009-11-04
    • Tomonori AoyamaSeiji InumiyaKazuaki NakajimaTakashi Shimizu
    • Tomonori AoyamaSeiji InumiyaKazuaki NakajimaTakashi Shimizu
    • H01L27/11
    • H01L21/823462H01L21/823412H01L21/823807H01L21/823857H01L27/0629H01L29/517
    • A method of fabricating a semiconductor device according to one embodiment includes: laying out a first region, a second region, a third region and a fourth region on a semiconductor substrate by forming an element isolation region in the semiconductor substrate; forming a first insulating film on the first region and the second region; forming a first semiconductor film on the first insulating film; forming a second insulating film and an aluminum oxide film thereon on the fourth region after forming of the first semiconductor film; forming a third insulating film and a lanthanum oxide film thereon on the third region after forming of the first semiconductor film; forming a high dielectric constant film on the aluminum oxide film and the lanthanum oxide film; forming a metal film on the high dielectric constant film; forming a second semiconductor film on the first semiconductor film and the metal film; and patterning the first insulating film, the first semiconductor film, the second insulating film, the aluminum oxide film, the third insulating film, the lanthanum oxide film, the high dielectric constant film, the metal film and the second semiconductor film.
    • 根据一个实施例的制造半导体器件的方法包括:通过在半导体衬底中形成元件隔离区,在半导体衬底上铺设第一区域,第二区域,第三区域和第四区域; 在所述第一区域和所述第二区域上形成第一绝缘膜; 在所述第一绝缘膜上形成第一半导体膜; 在形成第一半导体膜之后的第四区域上形成第二绝缘膜和氧化铝膜; 在形成第一半导体膜之后,在第三区域上形成第三绝缘膜和氧化镧膜; 在氧化铝膜和氧化镧膜上形成高介电常数膜; 在高介电常数膜上形成金属膜; 在所述第一半导体膜和所述金属膜上形成第二半导体膜; 以及图案化第一绝缘膜,第一半导体膜,第二绝缘膜,氧化铝膜,第三绝缘膜,氧化镧膜,高介电常数膜,金属膜和第二半导体膜。
    • 59. 发明申请
    • SEMICONDUCTOR DEVICE AND METHOD OF FABRICATING THE SAME
    • 半导体器件及其制造方法
    • US20100133626A1
    • 2010-06-03
    • US12612238
    • 2009-11-04
    • Tomonori AoyamaSeiji InumiyaKazuaki NakajimaTakashi Shimizu
    • Tomonori AoyamaSeiji InumiyaKazuaki NakajimaTakashi Shimizu
    • H01L27/06H01L21/28H01L21/8236
    • H01L21/823462H01L21/823412H01L21/823807H01L21/823857H01L27/0629H01L29/517
    • A method of fabricating a semiconductor device according to one embodiment includes: laying out a first region, a second region, a third region and a fourth region on a semiconductor substrate by forming an element isolation region in the semiconductor substrate; forming a first insulating film on the first region and the second region; forming a first semiconductor film on the first insulating film; forming a second insulating film and an aluminum oxide film thereon on the fourth region after forming of the first semiconductor film; forming a third insulating film and a lanthanum oxide film thereon on the third region after forming of the first semiconductor film; forming a high dielectric constant film on the aluminum oxide film and the lanthanum oxide film; forming a metal film on the high dielectric constant film; forming a second semiconductor film on the first semiconductor film and the metal film; and patterning the first insulating film, the first semiconductor film, the second insulating film, the aluminum oxide film, the third insulating film, the lanthanum oxide film, the high dielectric constant film, the metal film and the second semiconductor film.
    • 根据一个实施例的制造半导体器件的方法包括:通过在半导体衬底中形成元件隔离区,在半导体衬底上铺设第一区域,第二区域,第三区域和第四区域; 在所述第一区域和所述第二区域上形成第一绝缘膜; 在所述第一绝缘膜上形成第一半导体膜; 在形成第一半导体膜之后的第四区域上形成第二绝缘膜和氧化铝膜; 在形成第一半导体膜之后,在第三区域上形成第三绝缘膜和氧化镧膜; 在氧化铝膜和氧化镧膜上形成高介电常数膜; 在高介电常数膜上形成金属膜; 在所述第一半导体膜和所述金属膜上形成第二半导体膜; 以及图案化第一绝缘膜,第一半导体膜,第二绝缘膜,氧化铝膜,第三绝缘膜,氧化镧膜,高介电常数膜,金属膜和第二半导体膜。