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51. 发明专利

JPH1192514A COMPONENT OF CATALYST FOR POLYMERIZATION OF OLEFIN, CATALYST FOR POLYMERIZATION OF OLEFIN AND MANUFACTURE OF POLYOLEFIN 失效
公开(公告)号：JPH1192514A
公开(公告)日：1999-04-06
申请号：JP17538998
申请日：1998-06-08
申请人： MITSUI CHEMICALS INC
发明人： MAKIO HARUYUKI , IMUDA JUNICHI
IPC分类号： C08F4/02 , C08F4/609 , C08F4/619 , C08F4/6192 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To reduce the deterioration of catalyst performance by carrying in a pore of a porous inorganic carrier a polymer having an aromatic ring and/or a polar group and an organoalminumoxy compound and/or an organoboron compound. SOLUTION: A porous inorganic carrier having a pore size of 10-300 μm, a specific surface area of 50-1,000 m /g, a pore volume of 0.3-2.5 ml/g and a bulk density of 0.1-0.6 g/ml is optionally calcined at 100-1,000 deg.C, and then impregnated with a monomer having an aromatic ring and/or a polar group. The monomer is polymerized within a pore of the inorganic carrier to obtain a solid component in which a polymer having an aromatic ring and/or a polar group is carried in a pore of the inorganic carrier. The solid component is brought into contact with a boron-containing organoalminumoxy compound of Formula (I) (wherein R is a 1-10C hydrocarbon group and R is H, a halogen atom or the same as R ) and/or an organoboron compound to obtain a solid catalyst carrying the polymer having an aromatic ring and/or a polar group and the organoalminumoxy compound and/or the organoboron compound.

52. 发明专利

JPH1192449A PRODUCTION OF HYDROXYPEROXIDE 失效
公开(公告)号：JPH1192449A
公开(公告)日：1999-04-06
申请号：JP18474398
申请日：1998-06-30
申请人： MITSUI CHEMICALS INC
发明人： MATSUI NARIKAZU , KURODA HIROSHI , HIROKANE SHINYA , MAKIO HARUYUKI , TAKAI TOSHIHIRO , KATOU KOUJI , FUJITA TERUNORI , KAMIMURA MAKOTO
IPC分类号： B01J31/02 , C07B61/00 , C07C407/00 , C07C409/04 , C07C409/06 , C07C409/08 , C07C409/10 , C07C409/12
摘要： PROBLEM TO BE SOLVED: To obtain the subject corresponding compound in high yield, as a practical accumulation rate is sustained by oxidizing a hydrocarbon with an oxygen-containing gas in the presence of a specific compound. SOLUTION: In the presence of (A) a radical scavenger (preferably a radical of oxygen, nitrogen, phosphorus, sulfur, carbon or silicon or compounds generating these radicals), (B) a hydrocarbon, preferably an arylalkyl hydrocarbon of the formula (P and Q are each H or an alkyl; X is an integer of 1-3; Ar is an x-valent aromatic hydrocarbon group) (particularly cumene) is oxidized with (C) an oxygen-containing gas) to predominantly convert to the corresponding hydroxyperoxide selectively. The amount of the component A is preferably 0.00001-5.0 pts.wt. per 100 pts.wt. of the component B. Thus, the hydrocarbon is converted to the corresponding hydroperoxide in high selectivity.

53. 发明专利

JPH1112322A HIGH-STIFFNESS POLYPROPYLENE AND ITS PRODUCTION 失效
公开(公告)号：JPH1112322A
公开(公告)日：1999-01-19
申请号：JP17180797
申请日：1997-06-27
申请人： MITSUI CHEMICALS INC
发明人： HAMA SHUNICHI , KOJO SHINICHI , MAKIO HARUYUKI , KAWAKITA KAZUMITSU , SUGIMURA KENJI
IPC分类号： C08F4/658 , C08F10/06
摘要： PROBLEM TO BE SOLVED: To produce the subject polypropylene capable of eluting a specified amount or more of a component at a specific temperature by temperature rising elution fractionation by (co)polymerizing propylene, etc., in the presence of a catalyst containing a specific solid titanium catalyst component, an organoaluminum compound and a specified organosilicon compound containing a specific cyclic amino group. SOLUTION: This polypropylene is capable of eluting >=5% component at >=140 deg.C by temperature rising elution fractionation and is obtained by (co) polymerizing propylene, etc., in the presence of a catalyst containing a solid titanium catalyst component obtained by bringing a liquid magnesium compound into contact with a liquid titanium compound and an electron donor, an organolauminum compound and an organosilicon compound, represented by formula I (formula II is a cyclic amino group which may contain a substituent group R ; R is methyl, etc.), and containing the specific cyclic amino group.

54. 发明专利

JP2000136208A POLYMERIZATION CATALYST FOR OLEFIN AND PRODUCTION OF CATALYST AND OLEFIN POLYMER 失效
公开(公告)号：JP2000136208A
公开(公告)日：2000-05-16
申请号：JP31140198
申请日：1998-10-30
申请人： MITSUI CHEMICALS INC
发明人： MAKIO HARUYUKI , TSUTSUI TOSHIYUKI
IPC分类号： C08F4/64 , C08F4/605 , C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To obtain the subject catalyst capable of efficiently producing a granular olefin polymer having a high bulk density and a narrow particle size distribution by pre-polymerizing a specific monomer in the presence of a porous carrier and a specific compound, etc., in a specific solvent. SOLUTION: This catalyst for polymerizing an olefin is obtained by pre- polymerizing (A) a monomer having a polymerizable double bond in the presence of (B) a porous carrier, (C) a transition metal compound, (D) an organic boron compound and/or (E) an organoaluminum compound in (F) a medium in which the ingredient C does not dissolve. As the ingredient A, an α-olefin, a polar group-containing compound, a vinyl compound, a polyene compound, etc., are cited. As the ingredient B, a carrier, etc., in which a polymer is filled in pores, is preferably used. As the ingredient C, a compound, etc., containing a transition metal of the 4th group of the periodic table, is preferably used. As the ingredient F, a fluorine-containing organic compound, etc., are cited.

55. 发明专利

JPH10316710A OLEFIN POLYMERIZATION CATALYST AND PROCESS FOR POLYMERIZING OLEFIN 失效
公开(公告)号：JPH10316710A
公开(公告)日：1998-12-02
申请号：JP12948097
申请日：1997-05-20
申请人： MITSUI CHEMICALS INC
发明人： MAKIO HARUYUKI , DOI YASUSHI , FUJITA TERUNORI
IPC分类号： C08F4/64 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To obtain an olefin polymerization catalyst which has excellent olefin polymerization activity and can give a polyolefin having excellent properties by including a transition metal compound (e.g. titanium compound), an organometallic compound, an organoaluminumoxy compound and a compound forming an ion pair with the transition metal compound. SOLUTION: The transition metal compound is represented by the formula (wherein M is a transition metal of group 3-11 in the periodic table, especially desirably titanium; R to R are each hydrogen, a halogen, a hydrocarbon group, an organosilyl, an amido, nitrile or the like, provided that not all of them can be hydrogen atoms; m is a number satisfying the valence of M; X is hydrogen, a halogen, a 1-20 C hydrocarbon group, an oxygenic group or the like; and when a plurality of Xs are present, they,may form a ring) and is desirably one in which the dianion of a structure derived by the removal of the metal has an energy difference of 9.00 or below, particularly 8.00 or below between the maximum occupied orbit and the minimum occupied orbit as measured by the MOPAC VERSION 6.00 Hamiltonian PM3 method.

56. 发明公开

EP2450361A4 ORGANOMETALLIC COMPOUNDS AND PROCESS FOR PREPARATION THEREOF 有权
标题翻译： VERFAHREN ZU IHRER HERSTELLUNG有机玻璃
公开(公告)号：EP2450361A4
公开(公告)日：2013-12-18
申请号：EP10794168
申请日：2010-06-30
申请人： MITSUI CHEMICALS INC
发明人： OCHIAI TAKASHI , MAKIO HARUYUKI
IPC分类号： C07F3/06 , C07F3/02 , C07F5/00 , C07F5/06 , C08F2/38
CPC分类号： C07F3/06 , C07F7/184 , C08F10/00 , C08F2/01
摘要： It is an object of the present invention to provide a novel organometallic compound functioning usefully as a chain transfer agent and the like in polymerization reaction of a double-bond containing compound. The present invention provides an organometallic compound represented by the following general formula (1) and a production method thereof. (in the general formula (1), M is a magnesium atom, a zinc atom, an Al-R 11 group, or a Ga-R 11 group; R 1 and R 10 are each independently a hydrocarbon group having 1 to 20 carbon atoms, or R 1 and R 10 may be united with each other to form a divalent connecting group (R 101 ) having 4 or more carbon atoms and thus form a ring; R 2 to R 9 are each independently a hydrogen atom, or a hydrocarbon group having 1 to 20 carbon atoms; Q 1 and Q 3 are each independently a divalent hydrocarbon group; Q 2 is a divalent connecting group containing a linkage by a heteroatom excluding carbon; h, j, k, m, and p are each independently 0 or 1; n is an integer of 0 to 10; and r is an integer of 0 to 1000.
摘要翻译：本发明的目的是提供一种在含双键键合的化合物的聚合反应中可用作链转移剂等的新的有机金属化合物。本发明提供由以下通式（1）表示的有机金属化合物及其制备方法。（通式（1）中，M为镁原子，锌原子，Al-R 11基或Ga-R 11基; R 1和R 10各自独立地为碳原子数1〜20的烃基原子或R 1和R 10可以彼此结合形成具有4个或更多个碳原子并因此形成环的二价连接基团（R 101）; R 2至R 9各自独立地为氢原子或具有1至20个碳原子的烃基; Q 1和Q 3各自独立地为二价烃基; Q 2为包含不含碳的杂原子的键连的二价连接基团; h，j，k，m和p各自为独立地为0或1; n为0〜10的整数，r为0〜1000的整数。

57. 发明公开

EP1666507A4 POLYOLEFIN FUNCTIONAL AT EACH END 有权
标题翻译：两端功能化聚烯烃
公开(公告)号：EP1666507A4
公开(公告)日：2008-07-30
申请号：EP04772741
申请日：2004-08-27
申请人： MITSUI CHEMICALS INC
发明人： MAKIO HARUYUKI , FUJITA TERUNORI
IPC分类号： C08F8/00 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F8/00 , C08F8/20 , C08F110/02 , C08F110/06 , C08F4/64048
摘要： A polyolefin which is functional at each end and which is represented by the following general formula (I) and has a molecular-weight distribution (Mw/Mn) as determined by gel permeation chromatography (GPC) of 1.0 to 1.5. It is useful in various applications. X-P-Y (I) (In the formula (I), X and Y may be the same or different and each is a group containing at least one element selected among oxygen, sulfur, nitrogen, phosphorus, and halogens; and P represents a chain consisting mainly of units of an olefin constituted of carbon atoms and hydrogen atoms only, provided that X and Y are bonded respectively to the two ends of P.)

58. 发明公开

EP2871216A4 POLYMER PARTICLES AND USE THEREOF 审中-公开
标题翻译： POLYMERPARTIKEL UND ANWENDUNG DAVON
公开(公告)号：EP2871216A4
公开(公告)日：2016-03-02
申请号：EP13813625
申请日：2013-06-28
申请人： MITSUI CHEMICALS INC
发明人： NAKAYAMA NORIO , MAKIO HARUYUKI , TAKAHASHI KATSUYUKI
IPC分类号： C08L101/02 , C08F8/08 , C08F8/32 , C08F10/02 , C08J3/12 , C08K3/08 , C08K3/22 , C08K5/00 , C08K5/07 , C08K5/1545 , C08K5/42 , C08K5/56 , C09K3/00 , C09K9/02 , C09K11/06 , G01K11/20
CPC分类号： C09K11/025 , C08F8/32 , C08K9/10 , C09D5/26 , C09D11/037 , C09D11/50 , C09K9/02 , C09K11/06 , C09K2211/1011 , C09K2211/1018 , C09K2211/14 , C09K2211/182 , C09K2211/185 , G01K11/20 , G02B5/23 , Y10T428/2982 , C08F8/08 , C08F10/02

59. 发明公开

EP1881014A4 -OLEFIN/UNCONJUGATED CYCLIC POLYENE COPOLYMER, PROCESS FOR PRODUCING THE SAME, AND CROSSLINKABLE COMPOSITION CONTAINING THE COPOLYMER 有权
标题翻译：烯烃 - 非共轭多循环的，过程的物的共聚物和共聚含可固化组合物
公开(公告)号：EP1881014A4
公开(公告)日：2009-06-17
申请号：EP06746227
申请日：2006-05-10
申请人： MITSUI CHEMICALS INC
发明人： MATSUURA SADAHIKO , MATSUI SHIGEKAZU , TERAO HIROSHI , ISHII SEIICHI , MAKIO HARUYUKI , HAKUTA TAKASHI , MURAKAMI HIDETATSU , FUJITA TERUNORI
IPC分类号： C08F210/00 , C08F4/60 , C08F236/20 , C08K5/54 , C08L23/02 , C09D123/02 , C09J123/02 , C09K3/10
CPC分类号： C08F210/00 , C08F10/00 , C08F210/02 , C08F210/16 , C08K5/54 , C08L23/0823 , C09K3/10 , C09K2200/0617 , C08L23/08 , C08F232/00 , C08F2500/03 , C08F2500/25 , C08F2500/20 , C08F210/06 , C08F4/64048
摘要： An α-olefin/unconjugated cyclic polyene copolymer (A) which comprises structural units (I) derived from an α-olefin and structural units (II) derived from a cycloolefin containing a vinyl group, has a molecular-weight distribution (Mw/Mn) of 2.7 or lower, and is noncrystalline or has low crystallinity with a quantity of heat of crystal fusion (ΔH) less than 90 kJ/kg. The copolymer is efficiently produced with a specific transition metal catalyst having a ligand having a phenoxyimine skeleton. The copolymer has a narrower molecular-weight distribution than existing copolymers and has a high vinyl group content. Because of this, the copolymer can give a crosslinked object having excellent tensile properties. When the copolymer is used as a plasticizer for a polymer, e.g., a rubber, the resultant composition shows excellent processability and gives a crosslinked object excellent in mechanical strength, rubber elasticity, etc. Converting vinyl group parts contained in the copolymer to polar groups gives polyolefin materials having various functions imparted thereto.

60. 发明公开

EP3000785A4 METAL OXIDE POROUS PARTICLES, METHOD FOR PRODUCING SAME, AND USE OF SAME 有权
标题翻译： PORÖSEMETALLOXIDPARTIKEL，VERFAHREN ZUR HERSTELLUNG DAVON UND VERWENDUNG DAVON
公开(公告)号：EP3000785A4
公开(公告)日：2017-01-18
申请号：EP14801195
申请日：2014-05-14
申请人： MITSUI CHEMICALS INC
发明人： NAKAYAMA NORIO , WANG HONGBO , MAKIO HARUYUKI
IPC分类号： C01B37/00 , C01B13/32 , C08K7/24 , C08K7/26 , C08L101/00 , C09D7/12 , C09D11/00 , C09D201/00
CPC分类号： A61K9/14 , C01B13/32 , C01B33/12 , C01B37/02 , C01P2004/04 , C01P2004/32 , C01P2004/45 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/12 , C01P2006/16 , C01P2006/17 , C08K7/24 , C08K7/26 , C08L101/00 , C09D7/40 , C09D11/00 , C09D11/037 , C09D201/00 , F16L59/028
摘要： Provided are porous metal oxide particles, in which 50 % mean particle size by volume is equal to or larger than 50 nm and equal to or smaller than 300 nm, ratio of 90 % mean particle size by volume to 50 % mean particle size by volume (D90/D50) is equal to or lower than 2.0, the particles have mesopores having a pore size determined by BJH method of equal to or larger than 5 nm and equal to or smaller than 30 nm, and the structure of the pores is a three-dimensional cubic phase structure.
摘要翻译：提供的是多孔金属氧化物颗粒，其中平均粒径为50％的平均粒径等于或大于50nm且等于或小于300nm，平均粒径为90体积％至平均粒径的50％（D90 / D50）等于或低于2.0，颗粒具有通过BJH方法确定的孔径等于或大于5nm且等于或小于30nm的孔径，并且孔的结构为三维立方相结构。

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