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51. 发明申请

US20090012229A1 PARTIALLY AROMATIC COPOLYAMIDES WITH A HIGH CRYSTALLINITY 审中-公开
标题翻译：具有高结晶度的部分芳族共聚酰胺
公开(公告)号：US20090012229A1
公开(公告)日：2009-01-08
申请号：US12282059
申请日：2007-02-28
申请人： Philippe Desbois , Gerd Blinne , Ralf Neuhaus , Hagen Stawitzki , Hans-Joachim Weis
发明人： Philippe Desbois , Gerd Blinne , Ralf Neuhaus , Hagen Stawitzki , Hans-Joachim Weis
IPC分类号： C08L77/06 , C08G69/26
CPC分类号： C08G69/265 , C08K7/02 , C08L23/00 , C08L23/16 , C08L77/06 , C08L2666/06
摘要： Semiaromatic semicrystalline thermoplastic polyamide molding compositions, comprising A) from 40 to 100% by weight of a copolyamide composed of a1) from 30 to 44 mol % of units which derive from terephthalic acid a2) from 6 to 20 mol % of units which derive from isophthalic acid a3) from 42 to 49.5 mol % of units which derive from hexamethylenediamine a4) from 0.5 to 8 mol % of units which derive from aromatic diamines having from 6 to 30 carbon atoms, where the molar percentages of components a1) to a4) together give 100%, and B) from 0 to 50% by weight of a fibrous or particulate filler C) from 0 to 30% by weight of an elastomeric polymer D) from 0 to 30% by weight of other additives and processing aids, where the percentages by weight of components A) to D) together give 100%.
摘要翻译：半芳族半结晶热塑性聚酰胺成型组合物，其包含A）40〜100重量％的共聚酰胺，其由a1- 30〜44摩尔％的衍生自对苯二甲酸的单元a2）6〜20摩尔％的单元组成，间苯二甲酸a3），42〜49.5摩尔％的来自六亚甲基二胺a4的单元）0.5〜8摩尔％的衍生自具有6〜30个碳原子的芳族二胺的单元，其中组分a1）至a4的摩尔百分数）一起给出100％，B）0-50％重量的纤维或颗粒填料C）0至30％重量的弹性体聚合物D）0至30％重量的其它添加剂和加工助剂，其中组分A）至D）的重量百分比一起得到100％。

52. 发明授权

US07368504B2 Method for the production of impact polystyrene 失效
标题翻译：抗冲聚苯乙烯的生产方法
公开(公告)号：US07368504B2
公开(公告)日：2008-05-06
申请号：US10597785
申请日：2005-02-16
申请人： Philippe Desbois
发明人： Philippe Desbois
IPC分类号： C08F279/02 , C08F4/52
CPC分类号： C08F297/04
摘要： Process for preparation of impact-resistant polystyrene from diene monomers and from styrene monomers via anionic polymerization, where 1) in a stage 1) a rubber solution is prepared from the diene monomers, or from the diene monomers and from the styrene monomers, using an alkali metal organyl compound as initiator and with concomitant use of a solvent, and then 2) in a stage 2), styrene monomer is added to the rubber solution, and the resultant mixture is polymerized anionically to give the impact-resistant polystyrene, and where, after stage 1) and prior to stage 2), an organylaluminum compound and an alkali metal hydride are added to the rubber solution.
摘要翻译：通过阴离子聚合从二烯单体和苯乙烯单体制备耐冲击聚苯乙烯的方法，其中1）在阶段1）橡胶溶液由二烯单体或二烯单体和苯乙烯单体制备，使用碱金属有机化合物作为引发剂，同时使用溶剂，然后2）在阶段2）中，将苯乙烯单体加入到橡胶溶液中，并将所得混合物阴离子聚合，得到耐冲击聚苯乙烯，其中，在阶段1之后）和阶段2之前），向橡胶溶液中加入有机铝化合物和碱金属氢化物。

53. 发明申请

US20070173576A1 Method for the anionic polymerization of oxirans 审中-公开
标题翻译：环氧乙烷的阴离子聚合方法
公开(公告)号：US20070173576A1
公开(公告)日：2007-07-26
申请号：US10595637
申请日：2004-10-30
申请人： Philippe Desbois , Alain Deffieux , Stephane Carlotti , Cyrille Billouard
发明人： Philippe Desbois , Alain Deffieux , Stephane Carlotti , Cyrille Billouard
IPC分类号： C08K5/41
CPC分类号： C08G65/2642 , C08G65/10 , C08G65/105 , C08G65/12
摘要： The invention relates to a process for preparation of homopolymers composed of oxiranes, or of copolymers composed of oxirans and comonomers, via anionic polymerization, which comprises carrying out a polymerization in the presence of a quaternary ammonium and/or phosphonium compound and of a mononuclear organylaluminum compound.
摘要翻译：本发明涉及通过阴离子聚合制备由环氧乙烷或由环氧乙烷和共聚单体组成的共聚物的均聚物的方法，该方法包括在季铵和/或鏻化合物和单核有机铝的存在下进行聚合复合。

54. 发明授权

US07101941B2 Method for anionic polymerization of α-methylstyrene 失效
标题翻译： α-甲基苯乙烯的阴离子聚合方法
公开(公告)号：US07101941B2
公开(公告)日：2006-09-05
申请号：US10545945
申请日：2004-01-28
申请人： Philippe Desbois , Michael Ishaque , Christian Schade , Alain Deffieux , Stéphane Carlotti
发明人： Philippe Desbois , Michael Ishaque , Christian Schade , Alain Deffieux , Stéphane Carlotti
IPC分类号： C08F4/46 , C08F12/12
CPC分类号： C08F4/56 , C08F4/463 , C08F4/52 , C08F112/12 , C08F212/08 , C08F297/04 , C08L9/06 , C08L25/10 , C08L53/02 , C08L2666/24
摘要： Process for preparing homopolymers of α-methylstyrene, or copolymers of α-methylstyrene and comonomers, by anionic polymerization in the presence of an initiator composition, which comprises using an initiator composition in which potassium hydride and at least one organylaluminum compound are present.
摘要翻译：在引发剂组合物的存在下通过阴离子聚合制备α-甲基苯乙烯的均聚物或α-甲基苯乙烯和共聚单体的共聚物的方法，其包括使用其中存在氢化钾和至少一种有机铝化合物的引发剂组合物。

55. 发明申请

US20060020061A1 Stabilised block copolymers made from styrol monomers and diene monomers 审中-公开
标题翻译：由苯乙烯单体和二烯单体制成的稳定的嵌段共聚物
公开(公告)号：US20060020061A1
公开(公告)日：2006-01-26
申请号：US10525088
申请日：2003-07-25
申请人： Konrad Knoll , Ulrike Dardin , Philippe Desbois , Konrad Mitulla , Paul Naegele
发明人： Konrad Knoll , Ulrike Dardin , Philippe Desbois , Konrad Mitulla , Paul Naegele
IPC分类号： C08K5/15
CPC分类号： C08K5/005 , C08K5/13 , C08K5/1535 , C08K5/524 , C08L53/02
摘要： The invention relates to thermoplastic moulded masses containing, a) at least one block copolymer (A), comprising, with relation to (A), a1) 50 to 90 wt. % of at least one styrol monomer, a2) 10 to 50 wt. % of at least one diene monomer, with the following as stabilisers, relative to the moulded mass, b) 0.001 to 0.18 wt. % of at least one benzofuranone derivative (B), c) 0.05 to 1 wt. % of at least one organic phosphite (C), and d) 0.1 to 0.3 wt. % of at least one stabiliser compound (D), selected from sterically hindered phenols and aromatic amines.
摘要翻译：本发明涉及含有a）至少一种嵌段共聚物（A）的热塑性模塑料，其包含与（A）相关的组合物，a1）50-90wt。％的至少一种苯乙烯单体，a2）10〜50wt。％的至少一种二烯单体，以下为稳定剂，相对于模制物质，b）0.001至0.18wt。％的至少一种苯并呋喃酮衍生物（B），c）0.05〜1wt。％的至少一种有机亚磷酸酯（C），和d）0.1〜0.3重量％％的至少一种稳定剂化合物（D），选自空间位阻酚和芳族胺。

56. 发明授权

US06825271B2 Anionically polymerized, impact-resistant polystyrene with capsule particle morphology 失效
标题翻译：阴离子聚合，耐冲击聚苯乙烯与胶囊颗粒形态
公开(公告)号：US06825271B2
公开(公告)日：2004-11-30
申请号：US10275561
申请日：2002-11-07
申请人： Philippe Desbois , Christian Schade , Hermann Gausepohl
发明人： Philippe Desbois , Christian Schade , Hermann Gausepohl
IPC分类号： C08F27902
CPC分类号： C08L51/04 , C08F279/02 , C08F287/00 , C08L53/02 , C08L2666/24 , C08L2666/04
摘要： The invention relates to an anionically polymerised, impact-resistant polystyrene with a dispersed plasticiser phase, comprising particles with capsule particle morphology and method for production thereof.
摘要翻译：本发明涉及具有分散增塑剂相的阴离子聚合抗冲击聚苯乙烯，其包含具有胶囊颗粒形态的颗粒及其生产方法。

57. 发明授权

US06686423B1 Method for carrying out the anionic polymerization of vinylaromatic monomers 失效
标题翻译：进行乙烯基芳族单体阴离子聚合的方法
公开(公告)号：US06686423B1
公开(公告)日：2004-02-03
申请号：US10129512
申请日：2002-05-06
申请人： Philippe Desbois , Volker Warzelhan , Christian Schade , Michel Fontanille , Alain Deffieux , Stephane Menoret
发明人： Philippe Desbois , Volker Warzelhan , Christian Schade , Michel Fontanille , Alain Deffieux , Stephane Menoret
IPC分类号： C08F448
CPC分类号： C08F4/52 , C08F4/44 , C08F4/48 , C08F297/04
摘要： In a process for the anionic polymerization of vinylaromatic monomers or dienes in the presence of a lithium organyl or lithium alcoholate and a magnesium and/or an aluminum compound, a sterically hindered phenol or amine is added.
摘要翻译：在乙烯基芳族单体或二烯的锂聚合的方法中，在锂有机锂或锂醇锂和镁和/或铝化合物的存在下，加入空间位阻酚或胺。

58. 发明授权

US06444762B1 Anionic polymerization process 失效
标题翻译：阴离子聚合工艺
公开(公告)号：US06444762B1
公开(公告)日：2002-09-03
申请号：US09242464
申请日：1999-02-17
申请人： Wolfgang Fischer , Konrad Knoll , Wolfgang Loth , Volker Warzelhan , Alain Deffieux , Philippe Desbois , Michel Fontanille , Stefan Lätsch , Christian Schade , Hermann Gausepohl
发明人： Wolfgang Fischer , Konrad Knoll , Wolfgang Loth , Volker Warzelhan , Alain Deffieux , Philippe Desbois , Michel Fontanille , Stefan Lätsch , Christian Schade , Hermann Gausepohl
IPC分类号： C08F202
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F279/02 , C08F4/46 , C08F4/54 , C08F4/52 , C08F4/48 , C08F212/08
摘要： A process for the continuous anionic polymerization or copolymerization of styrene or diene monomers using an alkali metal alkyl compound as polymerization initiator is carried out in the presence of an alkyl- or arylmetal compound of an element which occurs in at least divalent form as rate regulator, preferably under non-isothermal conditions and without back-mixing in a tubular or tube-bundle reactor, preferably using an alkyl- or arylmetal compound A of the formula R1M1 and an alkyl- or arylmetal compound B of the formula R2nM2 in a molar ratio between B and A of from 0.1:1 to 500:1, where M1 is Li, Na or K; R1 is hydrogen, C1-C20-alkyl, C6-C20-aryl, or C7-C20-alkyl-substituted aryl; M2 is an n-valent element from group 2a, 2b or 3a of the Periodic Table; and R2 is hydrogen, halogen, C1-C20-alkyl or C6-C20-aryl; and a special anionic polymerization initiator containing no Lewis base.
摘要翻译：使用碱金属烷基化合物作为聚合引发剂的苯乙烯或二烯单体的连续阴离子聚合或共聚的方法是在以至少二价形式作为速率调节剂发生的元素的烷基或芳基金属化合物的存在下进行，优选在非等温条件下，并且在管或管束反应器中没有反混合，优选使用式R 1 M 1的烷基或芳基金属化合物A和式R2nM2的烷基 - 或芳基金属化合物B以摩尔比 B和A为0.1：1至500：1，其中M 1为Li，Na或K; R 1为氢，C 1 -C 20烷基，C 6 -C 20 - 芳基或C 7 -C 20烷基取代的芳基; M 2为元素周期表2a，2b或3a的n价元素; 和R 2是氢，卤素，C 1 -C 20烷基或C 6 -C 20 - 芳基; 和不含路易斯碱的特殊的阴离子聚合引发剂。

59. 发明授权

US09427900B2 Composite component comprising a polymer phase and a foamed phase, and processes for producing the same 有权
标题翻译：包含聚合物相和发泡相的复合组分及其制备方法
公开(公告)号：US09427900B2
公开(公告)日：2016-08-30
申请号：US13292403
申请日：2011-11-09
申请人： Philippe Desbois , Olaf Kriha , Bangaru Sampath , Holger Ruckdäschel , Dietrich Scherzer , Freddy Gruber , Klaus Hahn
发明人： Philippe Desbois , Olaf Kriha , Bangaru Sampath , Holger Ruckdäschel , Dietrich Scherzer , Freddy Gruber , Klaus Hahn
IPC分类号： B29C45/00 , B29C44/04 , C08L77/02 , C08J9/36 , C08J9/40
CPC分类号： B29C44/0461 , C08J9/365 , C08J9/405 , C08J2205/052 , C08J2377/00 , C08J2477/02 , C08L77/02
摘要： The present invention relates to a composite component comprising an unfoamed polymer phase and a foamed phase, and to a process for producing the same.
摘要翻译：本发明涉及包含未发泡聚合物相和发泡相的复合组分及其制备方法。

60. 发明授权

US09249270B2 Expandable pelletized materials based on polyester 有权
标题翻译：基于聚酯的可膨胀的造粒材料
公开(公告)号：US09249270B2
公开(公告)日：2016-02-02
申请号：US13209761
申请日：2011-08-15
申请人： Bangaru Dharmapuri Sriramulu Sampath , Olaf Kriha , Holger Ruckdäschel , Philippe Desbois , Freddy Gruber , Klaus Hahn
发明人： Bangaru Dharmapuri Sriramulu Sampath , Olaf Kriha , Holger Ruckdäschel , Philippe Desbois , Freddy Gruber , Klaus Hahn
IPC分类号： C08J9/16 , C08J9/12 , C08J9/00 , C08J9/232 , C08J9/228 , C08K5/01
CPC分类号： C08J9/0061 , C08J9/0038 , C08J9/12 , C08J9/228 , C08J2201/03 , C08J2367/02 , C08J2425/04 , C08J2471/12 , C08K5/01 , C08L69/00
摘要： An expandable pelletized material comprising A) a polymer matrix composed of A1) at least 55% by weight of polyester (based on the entirety of components A1) and A2)) with a total enthalpy of fusion of up to 60 J/g, optionally of one or more melting points in the range from 100 to 300° C. and of one or more glass transition temperatures in the range from 0 to 250° C., and A2) from 0 to 45% by weight (based on the entirety of components A1) and A2)) of one or more thermoplastic polymers different from component A1); B) a physical blowing agent component, and C) optionally further additives is suitable for producing moldable foams for use in the automobile industry, airline industry, construction industry, packaging industry, sports and leisure industry, in transport, in engineering, in lightweight construction, and/or in composite construction.
摘要翻译：一种可膨胀的造粒材料，包括A）由A1）至少55重量％的聚酯（基于组分A1的整体）和A2））组成的聚合物基质，其总熔融焓高达60J / g，任选地的一个或多个熔点为100-300℃，一个或多个玻璃化转变温度为0-250℃，和A2）0-45重量％（基于全部的组分A1）和A2））不同于组分A1）的一种或多种热塑性聚合物; B）物理发泡剂组分，C）任选的其它添加剂适用于生产用于汽车工业，航空工业，建筑业，包装工业，运动休闲产业，运输工程，轻工业建筑中的模制泡沫，和/或复合结构。

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