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51. 发明授权

US08461397B2 Oxidation of hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US08461397B2
公开(公告)日：2013-06-11
申请号：US13060805
申请日：2009-08-17
申请人： James R. Lattner , Mark Hagemeister , Jon E. R. Stanat , John S. Buchanan , Jihad M. Dakka , Stephen Zushma
发明人： James R. Lattner , Mark Hagemeister , Jon E. R. Stanat , John S. Buchanan , Jihad M. Dakka , Stephen Zushma
IPC分类号： C07C409/02
CPC分类号： C07C409/08 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in a reaction zone and in the presence of a catalyst comprising a cyclic imide. During the oxidation process, a portion of the reaction medium is continuously or intermittently removed from the reaction zone, is stripped of water and organic acid impurities and then returned to the reaction zone.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质在反应区中与含氧气体接触，并且在包含环状酰亚胺在氧化过程中，反应介质的一部分从反应区连续或间断地除去，汽提水和有机酸杂质，然后返回到反应区。

52. 发明申请

US20110190543A1 Oxidation of Alkylaromatic Compounds 有权
标题翻译：烷基芳族化合物的氧化
公开(公告)号：US20110190543A1
公开(公告)日：2011-08-04
申请号：US13122608
申请日：2009-09-17
申请人： Jihad M. Dakka , Stephen Zushma , Jon E.R. Stanat
发明人： Jihad M. Dakka , Stephen Zushma , Jon E.R. Stanat
IPC分类号： C07C49/00 , C07C37/00
CPC分类号： C07C407/00 , B01J31/006 , B01J31/0247 , B01J2231/70 , C07C37/08 , C07C45/53 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/14 , C07D209/48 , Y02P20/52 , C07C39/04 , C07C49/08
摘要： In a process for oxidizing an alkylaromatic compound to the corresponding hydroperoxide, a feed comprising an alkylaromatic compound is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide. The contacting is conducted at a temperature of about 90° C. to about 150° C., with the cyclic imide being present in an amount between about 0.05 wt % and about 5 wt % of the alkylaromatic compound in the feed and the catalyst being substantially free of alkali metal compounds. The contacting oxidizes at least part of the alkylaromatic compound in said feed to the corresponding hydroperoxide.
摘要翻译：在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，包含烷基芳族化合物的进料在含有环状酰亚胺的催化剂存在下与含氧气体接触。接触在约90℃至约150℃的温度下进行，环状酰亚胺的存在量为进料中烷基芳族化合物的约0.05重量％至约5重量％，催化剂为基本上不含碱金属化合物。接触将至少部分所述进料中的烷基芳族化合物氧化成相应的氢过氧化物。

53. 发明申请

US20110172466A1 Oxidation of Hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US20110172466A1
公开(公告)日：2011-07-14
申请号：US13060805
申请日：2009-08-17
申请人： James R. Lattner , Mark Hagemeister , Jon E.R. Stanat , John S. Buchanan , Jihad M. Dakka , Stephen Zushma
发明人： James R. Lattner , Mark Hagemeister , Jon E.R. Stanat , John S. Buchanan , Jihad M. Dakka , Stephen Zushma
IPC分类号： C07C37/08 , C07C407/00 , C09K3/00
CPC分类号： C07C409/08 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in a reaction zone and in the presence of a catalyst comprising a cyclic imide. During the oxidation process, a portion of the reaction medium is continuously or intermittently removed from the reaction zone, is stripped of water and organic acid impurities and then returned to the reaction zone.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质在反应区中与含氧气体接触，并且在包含环状酰亚胺在氧化过程中，反应介质的一部分从反应区连续或间断地除去，汽提水和有机酸杂质，然后返回到反应区。

54. 发明申请

US20110092742A1 Process for Producing Alkylbenzene Hydroperoxides 审中-公开
标题翻译：生产烷基苯氢过氧化物的方法
公开(公告)号：US20110092742A1
公开(公告)日：2011-04-21
申请号：US12996238
申请日：2009-07-14
申请人： Jihad M. Dakka , Stephen Zushma
发明人： Jihad M. Dakka , Stephen Zushma
IPC分类号： C07C407/00 , C07C37/08
CPC分类号： C07C409/10 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C49/08 , C07C39/04
摘要： In a process for producing alkylbenzene hydroperoxides, a feed comprising (i) sec-butylbenzene, (ii) cumene in an amount greater than 10 wt % of the total feed and (iii) at least one of iso-butylbenzene and tert-butylbenzene in an amount up to 20 wt % of the total feed is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH, and NO2 or from the atoms H, F, Cl, Br, and I, provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3; and R3 can be any of the entities listed for R1. The contacting is conducted under conditions to convert the sec-butylbenzene and cumene to their associated hydroperoxides.
摘要翻译：在制备烷基苯氢过氧化物的方法中，包含（i）仲丁基苯，（ii）大于总进料的10重量％的量的枯烯的进料和（iii）至少一种异丁基苯和叔丁基苯中的至少一种在包含通式（I）的环状酰亚胺的催化剂存在下，将高达20重量％的总进料的量与含氧气体接触：其中R 1和R 2各自独立地选自烃基和取代的或具有1至20个碳原子的烃基，或由SO 3 H，NH 2，OH和NO 2基团或原子H，F，Cl，Br和I组成的烃基，条件是R 1和R 2可以通过共价键彼此连接键; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1〜3; 而R3可以是为R1列出的任何实体。在将仲丁基苯和异丙基苯转化成其相关联的氢过氧化物的条件下进行接触。

55. 发明申请

US20100234589A1 Oxidation of Hydrocarbons 失效
标题翻译：碳氢化合物的氧化
公开(公告)号：US20100234589A1
公开(公告)日：2010-09-16
申请号：US12601549
申请日：2008-07-11
申请人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
发明人： Jihad M. Dakka , James C. Vartuli , Stephen Zushma
IPC分类号： C07C27/10 , C07C51/235 , C07D201/02 , C07C407/00 , C07C37/08 , C07C45/53
CPC分类号： C07C409/08 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/53 , C07C51/313 , C07C407/00 , C07C407/003 , C07C409/04 , C07C409/10 , C07C2601/14 , Y02P20/52 , C07C55/14 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/14
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1是0,1或2; m为1至3，R3可为R1列出的任何实体。接触产生包含氧化烃产物和式（I）的未反应酰亚胺催化剂的流出物，流出物用碱的水溶液处理以产生包含至少部分式（I）的未反应的酰亚胺催化剂的水相，和包含氧化烃产物的有机相。然后可以回收有机相。

56. 发明申请

US20100228047A1 Oxidation of Hydrocarbons 有权
标题翻译：碳氢化合物的氧化
公开(公告)号：US20100228047A1
公开(公告)日：2010-09-09
申请号：US12678419
申请日：2008-10-08
申请人： Francisco M. Benitez , Jihad M. Dakka , Edmund J. Mozeleski , Stephen Zushma , John Scott Buchanan , Jon E. Stanat
发明人： Francisco M. Benitez , Jihad M. Dakka , Edmund J. Mozeleski , Stephen Zushma , John Scott Buchanan , Jon E. Stanat
IPC分类号： C07C51/255 , C07C39/12 , C07C409/02 , C07C27/12 , C07C49/04 , C07C61/08 , C07C45/27 , C07C33/34
CPC分类号： C07C409/08 , C07B41/00 , C07C37/07 , C07C37/08 , C07C37/20 , C07C45/33 , C07C45/53 , C07C51/313 , C07C407/00 , C07C409/04 , C07C409/10 , C07C409/14 , C07C2601/14 , C07C49/403 , C07C55/14 , C07C39/04 , C07C39/16
摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N, and CR3; each of X and Z is independently selected from C, S, CH2, N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; l is 0, 1, or 2; m is 1 to 3; and R3 can be any of the entities listed for R1. The contacting is conducted under conditions such as to maintain the concentration of both water and organic acids in the reaction medium below 50 ppm.
摘要翻译：在将烃类氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质与含氧气体在含有通式（I）：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代烃基，或从SO 3 H，NH 2，OH和NO 2基团，或从原子H，F，Cl，Br和我提供R1和R2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; l为0,1或2; m为1〜3; 而R3可以是为R1列出的任何实体。在使反应介质中的水和有机酸的浓度保持在50ppm以下的条件下进行接触。

57. 发明申请

US20090270296A1 HydroxyAromatic Functionalized Polyalpha-Olefins 有权
标题翻译：羟基芳族官能化聚α-烯烃
公开(公告)号：US20090270296A1
公开(公告)日：2009-10-29
申请号：US12108312
申请日：2008-04-23
申请人： Abhimanyu Onkar Patil , Margaret May-Som Wu , Stephen Zushma , Anura Abhimanyu Patil
发明人： Abhimanyu Onkar Patil , Margaret May-Som Wu , Stephen Zushma , Anura Abhimanyu Patil
IPC分类号： C10M107/22
CPC分类号： C08F8/00 , C07C37/14 , C07C39/06 , C08L101/00 , C10M107/30 , C10M177/00 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10N2220/022 , C10N2220/023 , C10N2230/02 , C10N2230/08 , C10N2230/10 , C08F10/14 , C08L2666/06 , C10N2260/06 , C08F110/10 , C08F10/04
摘要： This invention relates to a hydroxyaromatic functionalized polyalpha-olefin comprising the product of the combination of: a) a polyalpha-olefin comprising one or more C3 to C20 linear alpha-olefins and having at least 10% vinylidene unsaturation, a viscosity index of 80 to 400, an Mn of 300 to about 20,000, and a pour point of 0° C. or less; and b) a hydroxyaromatic moiety; wherein the analine point of the functionalized polyalpha-olefin is at least 10° C. lower than the analine point of the polyalpha-olefin.
摘要翻译：本发明涉及包含以下组合的产物的羟基芳族官能化聚α-烯烃：a）包含一种或多种C 3至C 20直链α-烯烃并且具有至少10％亚乙烯基不饱和度的聚α-烯烃，粘度指数为80至 400，Mn为300〜约20,000，倾点为0℃以下; 和b）羟基芳族部分; 其中官能化的聚α-烯烃的分析点比聚α-烯烃的分析点低至少10℃。

58. 发明申请

US20080242895A1 Polyketone Plasticizers 失效
标题翻译：聚酮增塑剂
公开(公告)号：US20080242895A1
公开(公告)日：2008-10-02
申请号：US12058397
申请日：2008-03-28
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C45/27
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

59. 发明授权

US06809058B2 Multi-dentate late transition metal catalyst complexes and polymerization methods using those complexes 失效
标题翻译：多齿后期过渡金属催化剂配合物和使用这些配合物的聚合方法
公开(公告)号：US06809058B2
公开(公告)日：2004-10-26
申请号：US09941881
申请日：2001-08-28
申请人： Lisa Saunders Boffa , Abhimanyu Onkar Patil , Donald Norman Schulz , Robert Timothy Stibrany , Joseph Anthony Sissano , Stephen Zushma
发明人： Lisa Saunders Boffa , Abhimanyu Onkar Patil , Donald Norman Schulz , Robert Timothy Stibrany , Joseph Anthony Sissano , Stephen Zushma
IPC分类号： B01J3100
CPC分类号： C08F4/54 , C07F1/005 , C08F10/02 , C08F110/02 , C08F210/02 , C08F220/10
摘要： The instant invention provides a late transition metal complex which can be used with an activating cocatalyst to produce polymers and copolymers. The invention also provides methods for polymerizing olefins, as well as copolymers having polar monomers incorporated therein. More specifically, the invention provides a composition having the formula LMXZn, wherein M is selected from the group consisting of Cu, Ag and Au; X is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, nitrate, sulfate, nitrile, hydroxide and any other moiety into which a monomer can insert; Z is selected from the group consisting of halide, hydride, triflate, acetate, borate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolate, carbon monoxide, nitrate, nitrile, hydroxide, sulfate, olefins, water, any other neutral coordinating ligand and any other moiety into which a monomer can insert; n equals 0, 1 or 2; and L is a multi-dentate nitrogen-containing ligand.
摘要翻译：本发明提供了可与活性助催化剂一起使用以产生聚合物和共聚物的后过渡金属络合物。本发明还提供了聚合烯烃的方法以及其中掺入极性单体的共聚物。更具体地，本发明提供具有式LMXZn的组合物，其中M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，硝酸盐，硫酸盐，腈，氢氧化物和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，硝酸盐，腈，氢氧化物，硫酸盐，烯烃，水，任何其它中性配位配体和单体可插入的任何其它部分; n等于0,1或2; L是多齿氮含量配体。

60. 发明授权

US06506859B1 Polymerization using late transition metal catalyst complexes formed in situ 失效
标题翻译：使用晚期形成的过渡金属催化剂复合物进行聚合
公开(公告)号：US06506859B1
公开(公告)日：2003-01-14
申请号：US09642487
申请日：2000-08-18
申请人： Abhimanyu O. Patil , Robert T. Stibrany , Stephen Zushma , Enock Berluche , Donald N. Schulz
发明人： Abhimanyu O. Patil , Robert T. Stibrany , Stephen Zushma , Enock Berluche , Donald N. Schulz
IPC分类号： C08F442
CPC分类号： C08F10/00 , C08F110/02 , C08F210/02 , C08F4/54 , C08F2500/03 , C08F220/12
摘要： The invention is directed towards the formation of polymers and copolymers using late transition metal polymerization catalyst complexes which are formed in situ. In the first process step of the instant invention, a composition having the formula MXZn is simultaneously contacted with a ligand and an activating cocatalyst. Referring to the formula, M is selected from the group consisting of Cu, Ag, and Au; X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; Z is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, a neutral coordinating ligand, and any other moiety into which a monomer can insert; n equals 0, 1 or 2. In the second process step of the instant invention, olefinic monomers are contacted with the activated catalyst composition under polymerization conditions.
摘要翻译：本发明涉及使用在原位形成的后过渡金属聚合催化剂络合物形成聚合物和共聚物。在本发明的第一工艺步骤中，具有式MXZn的组合物与配体和活化助催化剂同时接触。参考式，M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃，中性配位配体和单体可插入的任何其它部分; n等于0,1或2.在本发明的第二工艺步骤中，烯烃单体在聚合条件下与活化的催化剂组合物接触。

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