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51. 发明授权

US6162882A Preparation of novel homo- and copolymers using atom transfer radical polymerization 失效
标题翻译：使用原子转移自由基聚合制备新的均聚物和共聚物
公开(公告)号：US6162882A
公开(公告)日：2000-12-19
申请号：US431871
申请日：1999-11-02
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Yoshiki Nakagawa , Seong Mu Jo
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Yoshiki Nakagawa , Seong Mu Jo
IPC分类号： C08F2/38 , C08F4/00 , C08F4/04 , C08F4/10 , C08F4/16 , C08F4/40 , C08F4/44 , C08F4/54 , C08F4/58 , C08F12/04 , C08F120/44 , C08F265/04 , C08F265/06 , C08F290/06 , C08F291/00 , C08F293/00 , C08F297/00 , C08F297/02
CPC分类号： C08F265/06 , C08F2/38 , C08F4/00 , C08F4/40 , C08F12/04 , C08F265/04 , C08F290/068 , C08F291/00 , C08F293/005 , C08F2438/01
摘要： The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.
摘要翻译：本发明涉及用于合成新的均聚物或嵌段或接枝共聚物的原子（或基团）转移自由基聚合的方法，所述均聚物或嵌段或接枝共聚物任选地含有至少一个极性基团，具有明确的分子结构和窄的多聚体指数，起始系统的存在包括（i）具有可自由基转移的原子或基团的引发剂，（ii）过渡金属化合物和（iii）配体，本发明还涉及合成具有至少两个可用作大分子引发剂组分的卤素基团（i）随后通过原子或基团转移自由基聚合方法形成嵌段或接枝共聚物; 本发明还涉及用于合成支链或超支化聚合物的原子或基团转移自由基聚合方法; 此外，本发明涉及用于合成大分子引发剂的原子或基团转移自由基聚合的方法，其可随后用于制备嵌段或接枝共聚物。

52. 发明授权

US6111022A Preparation of novel homo- and copolymers using atom transfer radical polymerization 有权
标题翻译：使用原子转移自由基聚合制备新的均聚物和共聚物
公开(公告)号：US6111022A
公开(公告)日：2000-08-29
申请号：US206980
申请日：1998-12-08
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Yoshiki Nakagawa , Seong Mu Jo
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Yoshiki Nakagawa , Seong Mu Jo
IPC分类号： C08F2/38 , C08F4/00 , C08F4/04 , C08F4/10 , C08F4/16 , C08F4/40 , C08F4/44 , C08F4/54 , C08F4/58 , C08F12/04 , C08F120/44 , C08F265/04 , C08F265/06 , C08F290/06 , C08F291/00 , C08F293/00 , C08F297/00 , C08F297/02 , C08L33/18
CPC分类号： C08F265/06 , C08F12/04 , C08F2/38 , C08F265/04 , C08F290/068 , C08F291/00 , C08F293/005 , C08F4/00 , C08F4/40 , C08F2438/01
摘要： The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.
摘要翻译：本发明涉及用于合成新型均聚物或嵌段或接枝共聚物的原子（或基团）转移自由基聚合方法，任选地含有至少一个极性基团，具有明确的分子结构和窄的多分散性指数起始系统的存在，包括（i）具有可自由基转移的原子或基团的引发剂，（ii）过渡金属化合物和（iii）配体; 本发明还涉及具有至少两个卤素基团的大分子的合成，其可以用作大分子引发剂组分（i），随后通过原子或基团转移自由基聚合方法形成嵌段或接枝共聚物; 本发明还涉及用于合成支链或超支化聚合物的原子或基团转移自由基聚合方法; 此外，本发明涉及用于合成大分子引发剂的原子或基团转移自由基聚合的方法，其可随后用于制备嵌段或接枝共聚物。

53. 发明授权

US5945491A Preparation of novel homo- and copolymers using atom transfer radical polymerization 失效
公开(公告)号：US5945491A
公开(公告)日：1999-08-31
申请号：US940985
申请日：1997-09-30
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Yoshiki Nakagawa , Seong Mu Jo
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Yoshiki Nakagawa , Seong Mu Jo
IPC分类号： C08F2/38 , C08F4/00 , C08F4/04 , C08F4/10 , C08F4/16 , C08F4/40 , C08F4/44 , C08F4/54 , C08F4/58 , C08F12/04 , C08F120/44 , C08F265/04 , C08F265/06 , C08F290/06 , C08F291/00 , C08F293/00 , C08F297/00 , C08F297/02
CPC分类号： C08F265/06 , C08F12/04 , C08F2/38 , C08F265/04 , C08F290/068 , C08F291/00 , C08F293/005 , C08F4/00 , C08F4/40 , C08F2438/01
摘要： The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydispersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand; the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.

54. 发明授权

US5807937A Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties 失效
标题翻译：基于原子（或基团）转移自由基聚合的方法和具有有用结构和性质的新型（共）聚合物
公开(公告)号：US5807937A
公开(公告)日：1998-09-15
申请号：US559309
申请日：1995-11-15
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
IPC分类号： C08F4/00 , C08F4/06 , C08F4/40 , C08F4/44 , C08F4/50 , C08F12/08 , C08F16/18 , C08F20/00 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F271/02 , C08F291/00 , C08F293/00 , C08F297/00
CPC分类号： C08F271/02 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F4/00 , C08F4/40 , C08F2438/01
摘要： Improved processes have been developed for atom (or group) transfer radical polymerization (ATRP). In one improvement, the ATRP process involves polymerizing in the presence of a (partially) free radical-deactivating amount of the corresponding reduced or oxidized transition metal compound. In a further improvement, the ATRP process involves polymerizing in a homogeneous system or in the presence of a solubilized initiating/catalytic system. The present invention also concerns end-functional, site-specific functional and telechelic homopolymers and copolymers; block, random, graft, alternating and tapered (or "gradient") copolymers which may have certain properties or a certain novel structure; star, comb and "hyperbranched" polymers and copolymers; multi-functional hyperbranched, end-functional polymers; cross-linked polymers and gels; water-soluble polymers and hydrogels (e.g., a copolymer prepared by radical copolymerization of a water-soluble monomer and a divinyl monomer); and an ATRP process using water as a medium.
摘要翻译：已经开发了用于原子（或基团）转移自由基聚合（ATRP）的改进方法。在一个改进中，ATRP方法包括在（部分）游离基失活量的相应还原或氧化的过渡金属化合物的存在下聚合。在进一步的改进中，ATRP方法包括在均相体系中或在溶解的引发/催化体系存在下进行聚合。本发明还涉及终端功能，位点特异性功能和遥爪均聚物和共聚物; 嵌段，随机，接枝，交替和渐缩（或“梯度”）共聚物，其可以具有某些性质或某种新颖结构; 星形，梳状和“超支化”聚合物和共聚物; 多功能超支化，末端官能聚合物; 交联聚合物和凝胶; 水溶性聚合物和水凝胶（例如，通过水溶性单体和二乙烯基单体的自由基共聚制备的共聚物）; 和使用水作为介质的ATRP方法。

55. 发明授权

US09644042B2 Electrochemically mediated atom transfer radical polymerization 有权
公开(公告)号：US09644042B2
公开(公告)日：2017-05-09
申请号：US13993521
申请日：2011-12-16
申请人： Krzysztof Matyjaszewski , Nicola Bortolamei , Andrew Magenau , Armando Gennaro , Abdirisak Ahmed Isse
发明人： Krzysztof Matyjaszewski , Nicola Bortolamei , Andrew Magenau , Armando Gennaro , Abdirisak Ahmed Isse
IPC分类号： C25B3/00 , C08F2/58 , C08F2/38 , C08F4/40
CPC分类号： C08F2/58 , C08F2/38 , C08F4/40 , C08F2438/01
摘要： Electrochemical reduction of an exemplary ATRP catalyst, CIIBr2/Me6TREN, is shown to be an efficient process to mediate and execute an ATRP. The onset of polymerization occurs only through passage of a cathodic current achieved under a reductive potential to form CuIBr2/Me6TREN, within the reaction medium. Unprecedented control over the polymerization kinetics can be attained through electrochemical methods by modulating the magnitude of the applied potential allowing polymerization rate enhancement or retardation. Additional polymerization control is gained through electrochemical “dials” allowing polymerization rate enhancements achieved by larger applied potentials and the ability to successfully switch a polymerization “on” and “off between dormant and active states by application of multistep intermittent potentials.

56. 发明申请

US20140183055A1 ELECTROCHEMICALLY MEDIATED ATOM TRANSFER RADICAL POLYMERIZATION 有权
标题翻译：电化学介质转移自由基聚合
公开(公告)号：US20140183055A1
公开(公告)日：2014-07-03
申请号：US13993521
申请日：2011-12-16
申请人： Krzysztof Matyjaszewski , Nicola Bortolamei , Andrew Magenau , Armando Gennaro , Abdirisak Ahmed Isse
发明人： Krzysztof Matyjaszewski , Nicola Bortolamei , Andrew Magenau , Armando Gennaro , Abdirisak Ahmed Isse
IPC分类号： C08F2/58
CPC分类号： C08F2/58 , C08F2/38 , C08F4/40 , C08F2438/01
摘要： Electrochemical reduction of an exemplary ATRP catalyst, C11Br2/Me6TREN, is shown to be an efficient process to mediate and execute an ATRP. The onset of polymerization occurs only through passage of a cathodic current achieved under a reductive potential to form Cu1Br2/Me6TREN, within the reaction medium. Unprecedented control over the polymerization kinetics can be attained through electrochemical methods by modulating the magnitude of the applied potential allowing polymerization rate enhancement or retardation. Additional polymerization control is gained through electrochemical “dials” allowing polymerization rate enhancements achieved by larger applied potentials and the ability to successfully switch a polymerization “on” and “off between dormant and active states by application of multistep intermittent potentials.
摘要翻译：示例性ATRP催化剂C11Br2 / Me6TREN的电化学还原显示是介导和执行ATRP的有效方法。仅在通过在还原电位下实现的阴极电流以在反应介质内形成Cu1Br2 / Me6TREN才开始聚合。聚合动力学的前所未有的控制可以通过电化学方法通过调节所施加电位的大小允许聚合速率增强或延迟来实现。通过电化学“表盘”获得额外的聚合控制，允许通过更大的施加电位实现聚合速率增强，以及通过施加多步间歇电势成功地将聚合“打开”和“休眠”和“休眠”的能力。

57. 发明申请

US20130158203A1 COMPOSITIONS AND METHOD OF INHIBITING POLYMERIZATION OF VINYL-ARYL MONOMERS 有权
标题翻译：抑制乙烯基单体聚合的组合物和方法
公开(公告)号：US20130158203A1
公开(公告)日：2013-06-20
申请号：US13811574
申请日：2011-07-27
申请人： Nathan T. Kendall , Kishore K. Kar , Mark H. McAdon , Krzysztof Matyjaszewski , Laura Mueller , Charles D. Dukes
发明人： Nathan T. Kendall , Kishore K. Kar , Mark H. McAdon , Krzysztof Matyjaszewski , Laura Mueller , Charles D. Dukes
IPC分类号： C07C7/20
CPC分类号： C07C7/20 , C08F2/00 , C08F12/08 , C08F12/36 , C08F2/40 , C07C15/46 , C07C15/44
摘要： The invention generally relates to a method of inhibiting polymerization of vinyl aryl monomers, a process for increasing number average molecular weight of a polystyrene, and to an inhibitor composition useful therein.
摘要翻译：本发明一般涉及一种抑制乙烯基芳基单体的聚合的方法，一种增加聚苯乙烯的数均分子量的方法以及其中可用的抑制剂组合物。

58. 发明授权

US08367051B2 Preparation of functional gel particles with a dual crosslink network 有权
标题翻译：用双交联网络制备功能性凝胶颗粒
公开(公告)号：US08367051B2
公开(公告)日：2013-02-05
申请号：US12311673
申请日：2007-10-09
申请人： Krzysztof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
发明人： Krzysztof Matyjaszewski , Ke Min , Jung Kwon Oh , James Spanswick , Nicolay V. Tsarevsky
IPC分类号： A61K9/14 , A61K31/74
CPC分类号： C08F293/005 , C08F283/00 , C08F290/00 , C08F290/06 , C08F291/00
摘要： Functional gel particle formed from a crosslinked polymeric network including a fraction of stable crosslinks and a second fraction of cleavable crosslinks are disclosed. Functional compounds may be chemically or physically encapsulated within and/or released from the gel particle by selective cleavage of the cleavable crosslinks. The functional compounds may be delivered and released to a pre-selected target site. Peripheral or other accessible functionality on the surface of the gel particle allows attachment of a surface reactive agent, thereby modifying one or more surface properties of the gel particle. Processes of preparing the gel particles and processes of delivering the functional compounds to a target site are also disclosed.
摘要翻译：公开了由交联的聚合物网络形成的功能性凝胶颗粒，其包括稳定的交联部分和可切割交联的第二部分。官能化合物可以通过选择性裂解可切割交联而化学或物理地包封在凝胶颗粒内和/或从凝胶颗粒释放。功能性化合物可以被递送并释放到预先选择的靶位点。在凝胶颗粒表面上的周边或其他可接近的功能允许附着表面活性剂，从而改变凝胶颗粒的一个或多个表面性质。还公开了制备凝胶颗粒的方法和将功能性化合物递送至靶位点的方法。

59. 发明授权

US08273823B2 Atom transfer radical polymerization in microemulsion and true emulsion polymerization processes 有权
标题翻译：原子转移自由基聚合在微乳液和真乳液聚合过程中
公开(公告)号：US08273823B2
公开(公告)日：2012-09-25
申请号：US11990836
申请日：2006-08-23
申请人： Krzysztof Matyjaszewski , Ke Min
发明人： Krzysztof Matyjaszewski , Ke Min
IPC分类号： C08F2/32 , C08F297/00 , C08F2/22 , C08F4/10
CPC分类号： C08F4/40 , C08F2/22 , C08F212/08 , C08F293/00 , C08F293/005 , C08F2438/01 , C08F220/12
摘要： The invention is directed to a microemulsion polymerization comprising adding a polymerization catalyst precursor, such as a transition metal complex in the higher of two accessible oxidation states, an ATRP initiator, and an organic solvent to an aqueous solution to form an emulsion. Radically polymerizable monomers and a reducing agent may then be added to the emulsion. The reducing agent converts the catalyst precursor to a catalyst for polymerization of the first monomer from the initiator. In certain embodiments the organic solvent may comprise radically polymerizable monomers. The aqueous solution may comprise a surfactant. Further embodiments are directed to an ah initio polymerization process comprising adding a polymerization catalyst precursor; an ATRP initiator, and an organic solvent to an aqueous solution to form an emulsion, wherein the organic solvent comprises second radically polymerizable monomers, adding a reducing agent to convert the catalyst precursor to a catalyst for polymerization of the first radically polymerizable monomer from the initiator; and adding first radically polymerizable monomers to the emulsion.
摘要翻译：本发明涉及一种微乳液聚合方法，其中包括将聚合催化剂前体，例如两种可接近的氧化态中较高的过渡金属络合物，ATRP引发剂和有机溶剂加入到水溶液中以形成乳液。然后将可自由基聚合的单体和还原剂加入到乳液中。还原剂将催化剂前体转化为第一单体从引发剂聚合的催化剂。在某些实施方案中，有机溶剂可以包含可自由基聚合的单体。水溶液可以包含表面活性剂。进一步的实施方案涉及一种开始聚合方法，包括加入聚合催化剂前体; ATRP引发剂和有机溶剂加入到水溶液中以形成乳液，其中有机溶剂包括第二自由基聚合单体，加入还原剂以将催化剂前体转化为用于从引发剂聚合第一可自由基聚合单体的催化剂 ; 并将第一可自由基聚合的单体加入到乳液中。

60. 发明授权

US08252880B2 Atom transfer dispersion polymerization 有权
标题翻译：原子转移分散聚合
公开(公告)号：US08252880B2
公开(公告)日：2012-08-28
申请号：US12451581
申请日：2008-05-23
申请人： Krzysztof Matyjaszewski , Ke Min , James Spanswick
发明人： Krzysztof Matyjaszewski , Ke Min , James Spanswick
IPC分类号： C08F4/00 , C08F2/00 , C08F4/28 , C08F210/00 , C08F36/00
CPC分类号： C08F12/08 , C08F2/14 , C08F2/38 , C08F212/36 , C08F2438/01
摘要： The present disclosure describes a two-step batch dispersion polymerization process for the preparation of substantially uniformed-sized functional (co)polymer particles. The first step of the process includes polymerizing at least one first radically (co)polymerizable monomer by a free radical polymerization process to form a (co)polymer in a stable colloidal dispersion and the second step includes polymerizing the at first radically (co)polymerizable monomer or an additional radically (co)polymerizable monomer in the stable colloidal dispersion by a living/controlled radical (co)polymerization process.
摘要翻译：本公开描述了用于制备基本上均匀尺寸的功能（共）聚合物颗粒的两步间歇分散聚合方法。该方法的第一步包括通过自由基聚合方法聚合至少一种第一自由基（共）可聚合单体，以在稳定的胶态分散体中形成（共）聚合物，第二步包括首先从根本上聚合（共）可聚合单体或通过活/受控自由基（共）聚合方法在稳定的胶体分散体中的另外的自由基（共）可聚合单体。

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