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51. 发明授权

US5972204A Phosphorous-containing zeolite with structural type CON, its preparation and its use for catalytic cracking 失效
标题翻译：具有结构型CON的含磷沸石，其制备及其用于催化裂化
公开(公告)号：US5972204A
公开(公告)日：1999-10-26
申请号：US014424
申请日：1998-01-27
申请人： Avelino Corma Canos , Eric Benazzi , Herve Caufriez , Maria Jose Diaz Cabanas , Maria Sol Grande Casas , Miguel Angel Camblor Fernandez , Gil Mabilon
发明人： Avelino Corma Canos , Eric Benazzi , Herve Caufriez , Maria Jose Diaz Cabanas , Maria Sol Grande Casas , Miguel Angel Camblor Fernandez , Gil Mabilon
IPC分类号： B01J29/85 , B01J29/86 , B01J35/00 , C01B39/12 , C01B39/48 , C10G11/05 , B01J29/70
CPC分类号： C01B39/12 , B01J29/85 , B01J29/86 , B01J35/0006 , C01B39/48 , C10G11/05
摘要： A phosphorous-containing zeolite with structural type CON in its aluminosilicate or borosilicate form contains at most 10% by weight of phosphorous. A process for its preparation is described, starting from existing zeolites (SSZ-26, SSZ-33 or CIT-1) or from beta zeolites and an organic structuring agent or template which is 1-N,N,N-trimethyl adamantammonium hydroxide or 2-N,N,N-trimethyl adamantammonium hydroxide. The zeolite is used for catalytic cracking of hydrocarbon feeds.
摘要翻译：具有硅铝酸盐或硼硅酸盐形式的结构型CON的含磷沸石含有至多10重量％的磷。描述了其制备方法，从现有的沸石（SSZ-26，SSZ-33或CIT-1）或β沸石和作为1-N，N，N-三甲基金刚烷基氢氧化铵的有机结构剂或模板开始， 2-N，N，N-三甲基金刚烷基氢氧化铵。沸石用于烃进料的催化裂化。

52. 发明授权

US5057471A Process for the obtainment of a light paraffin isomerization catalyst 失效
标题翻译：用于检测一种浅色异亮氨酸异构化催化剂的方法
公开(公告)号：US5057471A
公开(公告)日：1991-10-15
申请号：US548227
申请日：1990-06-29
申请人： Jesus J. Lazaro Munoz , Avelino Corma Canos , Juana M. Frontela Delgado
发明人： Jesus J. Lazaro Munoz , Avelino Corma Canos , Juana M. Frontela Delgado
IPC分类号： B01J29/20 , C07C5/27
CPC分类号： B01J29/20 , C07C5/2791 , B01J2229/16 , B01J2229/36 , B01J2229/37
摘要： The invention refers to a process for the obtainment of a catalyst useful in the isomerization of light paraffins, fundamentally based on acid treatment of a synthetic mordenite at temperatures between 40.degree. and 100.degree. C. followed by treatment with steam-air at temperatures between 300.degree. and 600.degree. C. which makes is possible to optimize the SiO.sub.2 Al.sub.2 O.sub.3 framework ratio and the amount of extraframework aluminum of the zeolite. The mordenite thus obtained is mixed with an inorganic refractory oxide such as Al.sub.2 O.sub.3 and a metal of group VIII, basically Pt, is added in an amount between 0.1 and 0.5% by weight referred to the final catalyst.The catalyst has been tested in the isomerization of light refinery fractions (C.sub.5 and C.sub.6) and has a high activity and selectively of branched isomers with a low production of gases and a high octane number for the light gasoline obtained.
摘要翻译：本发明涉及获得可用于轻链烷烃异构化的催化剂的方法，其基本上是基于在40℃至100℃之间的合成丝光沸石的酸处理，然后在300℃的温度下用蒸汽 - 空气处理 DEG和600℃，这使得可以优化SiO 2 Al 2 O 3骨架比和沸石的粉末铝的量。由此获得的丝光沸石与无机耐火氧化物如Al 2 O 3和基本上Pt的金属基本上相加，以与最终催化剂相关的0.1至0.5重量％的量加入。催化剂已经在轻馏分馏分（C5和C6）的异构化中进行了测试，并且具有高活性和选择性地具有支链异构体，其中所得到的轻质汽油的气体产量低，辛烷值高。

53. 发明授权

US10427140B2 ITQ-49 material, method for the production thereof and use of same 有权
公开(公告)号：US10427140B2
公开(公告)日：2019-10-01
申请号：US15678636
申请日：2017-08-16
申请人： Avelino Corma Canos , Fernando Rey Garcia , Manuel Hernandez Rodriguez , Jose Luis Jorda Moret
发明人： Avelino Corma Canos , Fernando Rey Garcia , Manuel Hernandez Rodriguez , Jose Luis Jorda Moret
IPC分类号： B01J20/10 , B01J29/70 , C01B39/48 , B01D53/86 , C07C1/22 , B01J29/04 , B01J35/00 , B01D53/04 , B01J20/30 , C10G73/02 , C01B37/00 , C01B39/54 , B01D53/94
摘要： The present invention refers to a microporous crystalline material, to the method for the production thereof and to the use of same, the material having a composition: xX2O3:zZO2:yYO2 in which: X is a trivalent element such as Al, B, Fe, In, Ga, Cr, or mixtures thereof, where (y+z)/x can have values of between 9 and infinity; Z corresponds to a tetravalent element selected from Si, Ge or mixtures thereof; and Y corresponds to a tetravalent element such as Ti, Sn, Zr, V or mixtures thereof, where z/y can have values of between 10 and infinity.

54. 发明授权

US08871979B2 Process for the production of methylene-bridged polyphenyl polyamines 有权
标题翻译：生产亚甲基桥联聚苯胺的方法
公开(公告)号：US08871979B2
公开(公告)日：2014-10-28
申请号：US13133410
申请日：2009-11-26
申请人： Christopher John Mitchell , Avelino Corma Canos , Robert Henry Carr , Pablo Botella Asuncion
发明人： Christopher John Mitchell , Avelino Corma Canos , Robert Henry Carr , Pablo Botella Asuncion
IPC分类号： C07C211/00 , C07C209/60 , C07C209/78
CPC分类号： C07C209/60 , C07C209/78 , C07C211/50
摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps of a) condensing aniline and formaldehyde; b) reacting, in a first catalytic reaction step, said condensate over a solid catalyst, whereby an intermediate mixture is provided; c) converting, in a subsequent catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst, thereby providing said methylene-bridged polyphenyl polyamines.
摘要翻译：根据本发明的由苯胺和甲醛提供亚甲基桥连的聚苯胺的方法包括以下步骤：a）使苯胺和甲醛缩合; b）在第一催化反应步骤中使所述缩合物在固体催化剂上反应，由此提供中间体混合物; c）在随后的催化反应步骤中，将所述中间体混合物在随后的固体催化剂的存在下转化为亚甲基桥连的聚苯胺，从而提供所述亚甲基桥接的聚苯胺。

55. 发明授权

US08337594B2 Use of a microporous crystalline material of zeolitic nature with RHO structure in natural gas processing 有权
标题翻译：在天然气加工中使用具有RHO结构的沸石性质的微孔结晶材料
公开(公告)号：US08337594B2
公开(公告)日：2012-12-25
申请号：US13272586
申请日：2011-10-13
申请人： Avelino Corma Canos , Miguel Palomino Roca , Fernando Rey Garcia , Susana Valencia Valencia
发明人： Avelino Corma Canos , Miguel Palomino Roca , Fernando Rey Garcia , Susana Valencia Valencia
IPC分类号： B01D53/02
CPC分类号： C10L3/10 , B01D53/04 , B01D2253/108 , B01D2256/24 , B01D2257/102 , B01D2257/504 , B01J20/18 , C01B39/48 , C10L3/102 , C10L3/104 , Y02C10/08 , Y02P20/152
摘要： The present invention describes the use of isostructural zeolites with rho zeolitic structure in processes of adsorption and separation of the various components of natural gas.
摘要翻译：本发明描述了在天然气各种成分的吸附和分离过程中使用具有rho沸石结构的异构沸石。

56. 发明授权

US08226925B2 Microporous crystalline material of zeolitic nature, zeolite ITQ-39, method of preparation and uses 有权
标题翻译：沸石性质的微孔结晶材料，沸石ITQ-39，制备方法和用途
公开(公告)号：US08226925B2
公开(公告)日：2012-07-24
申请号：US12525506
申请日：2008-01-31
申请人： Avelino Corma Canos , Manuel Moliner Marin , Fernando Rey Garcia , Jorge Gonzalez Gonzalez
发明人： Avelino Corma Canos , Manuel Moliner Marin , Fernando Rey Garcia , Jorge Gonzalez Gonzalez
IPC分类号： C01B39/46 , C01B39/48
CPC分类号： B01J29/70 , B01J20/18 , C01B39/48
摘要： Described herein are zeolite microporous crystalline materials comprising, in the heated state and in the absence of defects in its crystalline framework manifested by the presence of silanols, the empirical formula: x(M1/nXO2):yYO2:SiO2, wherein M is selected from H+, an inorganic cation of charge +n, and mixtures thereof, X is at least one chemical element having an oxidation state of +3, Y is at least one second chemical element other than Si having an oxidation state +4, x has a value between 0 and about 0.3, y has a value between 0 and about 0.1, and wherein the synthesized material has an X-ray diffraction pattern having at least values of angle 2θ (degrees) and relative intensities (I/I0) described. Process of making the microporous crystalline materials are also disclosed.
摘要翻译：本文描述的是沸石微孔结晶材料，其包括在加热状态下，在不存在由硅烷醇存在的结晶框架中缺陷的情况下，经验式：x（M1 / nXO2）：yYO2：SiO2，其中M选自 H +，电荷无机阳离子+ n及其混合物，X是氧化态为+3的至少一种化学元素，Y是具有氧化态+4以外的除了Si以外的至少一种第二化学元素，x具有值在0和约0.3之间，y具有在0和约0.1之间的值，并且其中合成材料具有至少具有角度2的角度的X射线衍射图案; （度）和相对强度（I / I0）。还公开了制备微孔结晶材料的方法。

57. 发明授权

US08187469B2 Separation of fluids using zeolite ITQ-32 失效
标题翻译：使用沸石ITQ-32分离流体
公开(公告)号：US08187469B2
公开(公告)日：2012-05-29
申请号：US11989330
申请日：2006-07-24
申请人： Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia
发明人： Avelino Corma Canos , Fernando Rey Garcia , Susana Valencia Valencia
IPC分类号： B01D15/00 , B01D15/04 , B01D53/22 , B01D59/12 , B01D53/02 , B01D59/26 , B01D47/00 , B01D53/14 , B01J39/00 , B01J49/00 , C02F1/42 , C02F1/28 , C07C7/144 , C01B33/36 , C07C7/12 , C01B39/00 , C01B21/00 , C01F7/00
CPC分类号： C07C7/13 , B01D15/00 , B01D53/02 , B01D53/04 , B01D53/047 , B01D2253/108 , B01D2253/308 , B01D2256/10 , B01D2256/24 , B01D2257/702 , B01J20/18 , C01B39/48 , C10G25/03 , C10G53/08 , C10G2300/1081 , C10G2300/1092 , C10G2300/805 , C10G2400/20 , C10L3/10 , C10L3/102 , C10L3/12
摘要： The invention relates to a method of separating fluids from mixtures using a zeolite known as ITQ-32 consisting of a two-dimensional pore system comprising channels with openings formed by 8 tetrahedra which are interconnected by channels with openings formed by 12 tetrahedra. The inventive method comprises at least the following steps: a) the zeolite ITQ-32 material is brought into contact with the mixture of fluids, b) one or more of the components are adsorbed in the zeolite ITQ-32 material, c) the non-adsorbed components are extracted, and d) one or more of the components adsorbed in the zeolite ITQ-32 material are recovered.
摘要翻译：本发明涉及一种使用称为ITQ-32的沸石从混合物中分离流体的方法，所述沸石由二维孔隙系统组成，该二维孔隙系统包括由8面四面体形成的开口的通道，该通道由通过由12面四面体形成的开口的通道相互连接。本发明的方法至少包括以下步骤：a）使沸石ITQ-32材料与流体混合物接触，b）一种或多种组分被吸附在沸石ITQ-32材料中，c） - 吸附的组分被提取，并且d）吸收在沸石ITQ-32材料中的一种或多种组分被回收。

58. 发明申请

US20120043195A1 Process for Regenerating Coked Particles 审中-公开
标题翻译：再生焦糖颗粒的方法
公开(公告)号：US20120043195A1
公开(公告)日：2012-02-23
申请号：US13264007
申请日：2009-04-20
申请人： Avelino Corma Canos , Douglas Rundell , Laurent Louis Andre Sauvanaud , George Yaluris
发明人： Avelino Corma Canos , Douglas Rundell , Laurent Louis Andre Sauvanaud , George Yaluris
IPC分类号： C10B57/12
CPC分类号： C10G11/182 , C10G11/05 , C10G2300/1033 , C10G2300/4093 , C10G2300/708 , C10G2300/807 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/28
摘要： A process for regenerating coked particles, which process comprises contacting a hydrocarbon feedstock with solid particles in a reaction zone to produce coked particles, which coked particles are transferred to a regeneration zone in which they are contacted with steam to produce hydrogen and at least one or more oxides of carbon, wherein the solid particles comprise one or more of the following components: (i) an aluminosilicate zeolite comprising one or more of Mn, Ti and Zn; (ii) a Ce-containing aluminosilicate zeolite with a Ce loading of at least 0.05 wt % and/or a molar ratio of total other rare earth elements:Ce in the range of from 0:1 to 5:1; (iii) a magnesium and aluminium-containing anionic clay; (iv) a material with the Perovskite structure.
摘要翻译：一种用于再生焦化颗粒的方法，该方法包括使烃原料与反应区中的固体颗粒接触以产生焦化颗粒，该焦化颗粒被转移到再生区，在再生区中它们与蒸汽接触以产生氢，并且至少一个或更多的碳氧化物，其中固体颗粒包含一种或多种以下组分：（i）包含一种或多种Mn，Ti和Zn的铝硅酸盐沸石; （ii）Ce负载量为0.05重量％以上的Ce含硅铝酸盐沸石和/或其他稀土元素的总摩尔比：Ce为0：1〜5：1的Ce; （iii）含镁和铝的阴离子粘土; （iv）具有钙钛矿结构的材料。

59. 发明授权

US08007765B2 Microporous crystalline material, zeolite ITQ-37, preparation method and use 有权
标题翻译：微孔结晶材料，沸石ITQ-37，制备方法和用途
公开(公告)号：US08007765B2
公开(公告)日：2011-08-30
申请号：US12280590
申请日：2007-02-22
申请人： Manuel Moliner Marin , Maria Jose Diaz Cabanas , Angel Cantin Sanz , Avelino Corma Canos
发明人： Manuel Moliner Marin , Maria Jose Diaz Cabanas , Angel Cantin Sanz , Avelino Corma Canos
IPC分类号： C01B39/46 , C01B39/48
CPC分类号： B01J29/70 , B01J29/04 , B01J2229/20 , C01B37/005 , C01B39/06 , C01B39/12 , C10G11/05 , C10G47/16 , C10G47/18 , C10G47/20 , C10G50/00
摘要： The present invention relates to a microporous crystalline material characterized in that it has the following chemical composition in the calcined from: xX2O3:nYO2:mGeO2 in which (n+m) is at least 5, X is one or more trivalent elements, Y corresponds to one or more tetravalent elements other than Ge, “x” may have any value, including zero, and the ratio Y/Ge is greater than 0.1, and it has a characteristic X-ray diffraction pattern. Its also relates to a method for preparing it and to its use in the conversion of organic-compounds supplies.
摘要翻译：本发明涉及一种微孔结晶材料，其特征在于：其中（x + 2）：mGeO 2中煅烧的xX 2 O 3 :nYO 2：mGeO 2具有以下化学组成，其中（n + m）至少为5，X为一个或多个三价元素，Y对应对于除Ge以外的一种以上的四价元素，“x”可以具有包括0的任何值，并且比率Y / Ge大于0.1，并且具有特征X射线衍射图。它还涉及其制备方法及其在有机化合物用品转化中的应用。

60. 发明授权

US07947252B2 Microporous crystalline material, zeolite ITQ-33, method of preparation and use 有权
标题翻译：微孔结晶材料，沸石ITQ-33，制备和使用方法
公开(公告)号：US07947252B2
公开(公告)日：2011-05-24
申请号：US11795432
申请日：2006-01-17
申请人： Avelino Corma Canos , Manuel Moliner Marin , Maria Jose Diaz Cabanas , Jose Manuel Serra Alfaro , Rafael Casteñeda Sanchez
发明人： Avelino Corma Canos , Manuel Moliner Marin , Maria Jose Diaz Cabanas , Jose Manuel Serra Alfaro , Rafael Casteñeda Sanchez
IPC分类号： C01B39/46 , C01B39/48 , C01B39/04 , B01J29/70
CPC分类号： B01J29/70 , B01J23/22 , B01J23/24 , B01J23/32 , B01J23/42 , B01J23/44 , B01J23/74 , B01J29/7049 , B01J29/78 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/12 , C01B39/48 , C10G11/05 , C10G47/02 , C10G47/16
摘要： The invention relates to a microporous crystalline material which is characterised in that it has the following chemical composition in the calcined state: X2O3:n YO2:m GeO2, wherein (n+m) is equal to at least 5, X is a trivalent element, Y corresponds to one or more tetravalent elements other than Ge and the Y/Ge ratio is greater than 1. Moreover, in the synthesised form without calcination, said material has an X-ray diffraction pattern in which the main lines thereof are as follows: (1), in which (mf) represents relative intensity of between 80 and 100, “d” represents relative intensity of between 20 and 40 and “md” represents relative intensity of between 0 and 20, which is calculated as a percentage with respect to the most intense peak. The invention also relates to the method of preparing said material and the use thereof in the conversion of food products comprising organic compounds.
摘要翻译：本发明涉及一种微孔结晶材料，其特征在于其在煅烧状态下具有以下化学组成：X 2 O 3 :n YO 2：m GeO 2，其中（n + m）等于至少5，X是三价元素，Y对应于除Ge以外的一种以上的四价元素，Y / Ge比大于1.此外，在不进行煅烧的合成形式中，所述材料具有X射线衍射图，其主线如下：（1）其中（mf）表示80〜100的相对强度，“d”表示20〜40的相对强度，“md”表示0〜20的相对强度，以尊重最强烈的高峰。本发明还涉及制备所述材料的方法及其在包含有机化合物的食品的转化中的用途。

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