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    • 55. 发明授权
    • Rubber dispersions II
    • 橡胶分散体II
    • US4454305A
    • 1984-06-12
    • US399712
    • 1982-07-19
    • Christian LindnerLothar LiebigKarl-Heinz Ott
    • Christian LindnerLothar LiebigKarl-Heinz Ott
    • C08L33/00C08C1/00C08F279/02C08J3/02C08J3/09C08L7/00C08L9/00C08L21/00C08L25/00C08L33/02C08L33/04C08L51/00C08L51/02C08L67/00C08F279/04
    • C08J3/091C08F279/02C08J2321/00
    • Stable, free-flowing dispersions in organic liquids of rubbers in the form of discrete particles having an average diameter of from 100 to 3000 nm which contains:A--as rubber, from 1 to 20% by weight, based on the total dispersion, of a crosslinked diene rubber; B--from 0 to 20% by weight, based on the total dispersion, of water in the form of a water-in-oil emulsion; C--as the continuous organic phase, from 99 to 66% by weight, based on the total dispersion, of (a) C.sub.1 -C.sub.10 alkyl acrylates or alkyl methacrylates, methyl methacrylate, ethyl acrylate or n-hexyl acrylate; or (b) a mixture of from 85 to 50% by weight of styrene or .alpha.-methyl styrene and from 15 to 50% by weight of acrylonitrile, methacrylonitrile or C.sub.1 -C.sub.6 alkyl acrylates or alkyl methacrylates, methyl methacrylate, ethyl acrylate, n-hexyl acrylate; or (c) a mixture of from 85 to 50% by weight of a C.sub.1 -C.sub.10 alkyl acrylate or alkyl methacrylate and from 15 to 50% by weight of acrylonitrile, methacrylonitrile or styrene; up to 60% by weight of a liquid hydrocarbon can be added to and mixed with (a), (b) and (c),and a process for producing said dispersions.
    • 平均直径为100至3000nm的离散颗粒形式的橡胶有机液体中的稳定的自由流动的分散体,其包含:A-橡胶,基于总分散体积的1至20重量% 交联二烯橡胶; B为0至20重量%,基于总分散体积为油包水乳液形式的水; (a)丙烯酸C1-C10烷基酯或甲基丙烯酸烷基酯,甲基丙烯酸甲酯,丙烯酸乙酯或丙烯酸正己酯的总分散体的99至66重量% 或(b)85至50重量%的苯乙烯或α-甲基苯乙烯和15至50重量%的丙烯腈,甲基丙烯腈或丙烯酸C 1 -C 6烷基酯或甲基丙烯酸烷基酯的混合物,甲基丙烯酸甲酯,丙烯酸乙酯, 丙烯酸己酯 或(c)85至50重量%的丙烯酸C1-C10烷基酯或甲基丙烯酸烷基酯和15至50重量%的丙烯腈,甲基丙烯腈或苯乙烯的混合物; 可以向(a),(b)和(c)中加入高达60重量%的液体烃,并与(a),(b)和(c)混合,以及制备所述分散体的方法。
    • 56. 发明授权
    • Mixtures of thermoplastic polymers in powder form
    • 粉末形式的热塑性聚合物的混合物
    • US5112910A
    • 1992-05-12
    • US743678
    • 1991-08-12
    • Karl-Erwin PiejkoChristian LindnerRalph OstarekHans-Eberhard BraeseKarl-Heinz Ott
    • Karl-Erwin PiejkoChristian LindnerRalph OstarekHans-Eberhard BraeseKarl-Heinz Ott
    • C08J3/00C08L21/00C08L25/12C08L33/06C08L33/12C08L51/04
    • C08L33/06C08J3/005C08L21/00C08L25/12C08L33/12C08L51/04
    • Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.
    • 制备粉末形式的热塑性聚合物的混合物的方法,该方法由以下混合物的水性乳液制备:a)丙烯酸C 2 -C 8烷基酯和/或丁二烯与(基于共聚物)的至少40重量%的颗粒部分交联的橡胶状共聚物。 丙烯腈,苯乙烯或甲基丙烯酸C 1 -C 4烷基酯,b)热塑性树脂,如果合适,c)在二烯或烷基上的苯乙烯,α-甲基苯乙烯,丙烯腈,甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物 丙烯酸酯橡胶,其橡胶含量为50〜95重量% %,其中a)和b)和如果合适的水性乳液c)具有15至50重量%的聚合物含量。 %与凝固溶液同时混合,但在单独的流中,在20℃至100℃连续或半连续,聚合物a)和b),如果合适,c)凝结,将流合并,聚合物 混合物然后分离出来。